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SAFETY DATA SHEET

PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE


1.
COMPANY/UNDERTAKING
PRODUCT NAME : PERMATREAT® PC-191T

APPLICATION : REVERSE OSMOSIS ANTISCALANT

COMPANY IDENTIFICATION : NALCO EUROPE B.V.


Postbus 627
2300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.

Date issued : 27.08.2010


Version Number : 1.22

COMPANY CONTACT TELEPHONE NUMBERS.


NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)31-707 22 70 Distributor Nalco Mobotec Polska PRZEMYS ŁOWA 55
Sp. z o.o. PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
e-mail: [email protected]
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214121852
NALCO APPLIED SERVICES +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
OF EUROPE BV
NALCO BELGIUM BVBA +32 (0)3-450 69 10 Nalco Switzerland AG (CH) +41 (0)52 235 38 38
NALCO DANMARK ApS +45-48195800 Nalco Company OOO +7 (0)495 980 72 80
NALCO DEUTSCHLAND GmbH +49 (0)69-79340 NALCO ÖSTERREICH + 43(0)1 27026350
(D) Ges.m.b.H. (A)
NALCO ESPAÑOLA S.L. (E) +34 93-4095555 First Distributor: Nalco Czechia Stankova 882/2,CZ-149 00 Praha
s.r.o. (CZ) 4,Czech Republic,+420 267 912
350 & +420 272 913 512
NALCO FINLAND OY (FI) +358 (0)9 2519 5600 Local Support: Nalco Hungary Kft. +36 1 8805610
(HU)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 Local Support: Nalco Österreich +385 (0)1 377 95 21
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Österreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation Office
ROMANIA (RO)
NALCO ITALIANA S.R.L.(I) +39 06-54565000 NALCO LIMITED +44 (0)1606 74488
NALCO NETHERLANDS B.V. +31 (0)13-5952200

For Product Safety information please contact Jacqueline Dudley, e-mail [email protected]

2. HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION :

This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC.

HUMAN HEALTH HAZARDS - ACUTE :

INHALATION :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

May cause irritation of mucous membranes.

SKIN CONTACT :
May cause irritation with prolonged contact.

EYE CONTACT :
Can cause mild irritation.

INGESTION :
May cause gastrointestinal irritation.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC.

4. FIRST AID MEASURES

INHALATION :
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

SKIN CONTACT :
Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician.

EYE CONTACT :
Immediately flush eye with water for at least 15 minutes while holding eyelids open. If symptoms persist, call a
physician.

INGESTION :
Seek medical advice immediately, showing the label and/or SDS. Do not induce vomiting without medical advice.
If conscious, washout mouth and give water to drink.

NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.

5. FIRE FIGHTING MEASURES

FLASH POINT : Not applicable

EXTINGUISHING MEDIA :
Use extinguishing media appropriate for surrounding fire. This product would not be expected to burn unless all
the water is boiled away. The remaining organics may be ignitable.

FIRE AND EXPLOSION HAZARD :


May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :


In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment
recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.
Ensure adequate ventilation. Ensure clean-up is conducted by trained personnel only. Notify appropriate
government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP :


SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste
hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations
indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS :
Do not contaminate surface water. Do not allow material to contaminate ground water system. Prevent material
from entering sewers or waterways.

7. HANDLING AND STORAGE

HANDLING :
Prevent contact with skin, eyes and clothing. Ensure all containers are labeled. Keep the containers closed when
not in use. Keep away from acids and oxidizing agents.

STORAGE CONDITIONS :
Protect product from freezing. Store the containers tightly closed.

SUITABLE CONSTRUCTION MATERIAL :


HDPE (high density polyethylene), Stainless Steel 304, Compatibility with Plastic Materials can vary; we therefore
recommend that compatibility is tested prior to use., Polyethylene, Polypropylene, PVC, 100% phenolic resin liner,
Epoxy phenolic resin

UNSUITABLE CONSTRUCTION MATERIAL :


Brass, Buna-N, EPDM, Neoprene, Polyurethane, Fluoroelastomer, Chlorosulfonated polyethylene rubber

SPECIFIC USE(S) :
REVERSE OSMOSIS ANTISCALANT

For specific dosages and customized applications please contact your representative.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

This product does not contain any substance that has an established exposure limit.

ENGINEERING MEASURES :
General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are
generated.

PERSONAL PROTECTION

GENERAL ADVICE :

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the
way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields. The applicable European
standard can be found in EN 166.

RESPIRATORY PROTECTION :
At ambient temperature none needed for vapour. If product is heated or if aerosol generation is likely, the use of a
half face filter mask is recommended. A suitable filter material depends on the amount and type of chemicals being
handled. Consider the use of filter type: P The applicable European standard can be found in EN 140, EN 137,
EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a positive pressure,
full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory
protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION :
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on
work conditions and what chemicals are handled, but we have positive experience under light handling conditions
using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed.
Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard
can be found in EN 374.

SKIN PROTECTION :
When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended.
The applicable European standard can be found in EN ISO 20345.

EYE PROTECTION :
When handling this product, the use of safety glasses with side shields is recommended. The applicable European
standard can be found in EN 166.

HYGIENE RECOMMENDATIONS :
Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected
area. Launder contaminated clothing before reuse. Keep an eye wash fountain available.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

APPEARANCE Clear Amber - Green

ODOR Ammoniacal

FLASH POINT : Not applicable


SPECIFIC GRAVITY 1.36
SOLUBILITY IN WATER Complete
pH (100 %) 10.5

Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY

STABILITY :
Stable under normal conditions.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.

CONDITIONS TO AVOID :
Freezing temperatures.

MATERIALS TO AVOID :
Strong oxidizing agents, Strong acids

HAZARDOUS DECOMPOSITION PRODUCTS :


Under fire conditions: Oxides of carbon, Oxides of nitrogen

11. TOXICOLOGICAL INFORMATION

The following results are for a similar product.

ACUTE ORAL TOXICITY :


Species: Rat
LD50: > 17,800 mg/kg
Test Descriptor: Similar Product

ACUTE DERMAL TOXICITY :


Species: Rabbit
LD50: > 15,800 mg/kg
Test Descriptor: Similar Product

PRIMARY SKIN IRRITATION :


Species: Rabbit
Draize Score: 0.3 /8.0
Test Descriptor: Similar Product

PRIMARY EYE IRRITATION :


Species: Rabbit
Draize Score: 3.7 /110.0
Test Descriptor: Product

For additional information on the hazard of the preparation, please consult section 2 and 12.

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS :

The following results are for the product, unless otherwise indicated.

ACUTE FISH RESULTS :


Species Exposure LC50 NOEC Method Test Descriptor
Rainbow Trout 96 hrs > 330 mg/l Similar Product

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Bluegill Sunfish 96 hrs > 330 mg/l Similar Product


Sheepshead 96 hrs 8,132 mg/l Similar Product
Minnow
Rainbow Trout 96 hrs 4,530 mg/l 3,600 mg/l Product

ACUTE INVERTEBRATE RESULTS :


Species Exposure LC50 EC50 Method Test Descriptor
Daphnia magna 48 hrs 297 mg/l Similar Product
Grass Shrimp 96 hrs 4,575 mg/l Similar Product

AVIAN RESULTS :
Species Exposure LC50 Method Test Descriptor
Bobwhite Quail 14 Days > 2,510 Similar Product
mg/kg
Mallard Duck 14 Days > 2,510 Similar Product
mg/kg

PERSISTENCY AND DEGRADATION :

Chemical Oxygen Demand (COD) : 230 mg/g

The organic portion of this preparation is expected to be inherently biodegradable.

BIOACCUMULATION POTENTIAL
This preparation or material is not expected to bioaccumulate.

13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if
burned. It can be burned directly in appropriate equipment. Any chemical waste is a potential environmental
pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

EUROPE WASTE CODE :


16 03 04 - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes other than those
mentioned in 16 03 03. If this product is used in any further processes, the final user must redefine and assign the
most appropriate European Waste Catalogue Code.

NATIONAL REGULATIONS CZECH REPUBLIC


Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No.
477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001
Coll.), as amended

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
6 / 10
SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION

AIR TRANSPORT (ICAO/IATA)


Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION

MARINE TRANSPORT (IMDG/IMO)


Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION

15. REGULATORY INFORMATION

CLASSIFICATION AND LABELLING :

This preparation is not regulated, however, we recommend the following safety precautions:

SAFETY PHRASES
S24/25 - Avoid contact with skin and eyes.
S37/39 - Wear suitable gloves and eye/face protection.

NATIONAL REGULATIONS CZECH REPUBLIC


This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.)
This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll.
Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No.
178/2001 Coll. laying down conditions of health protection of employees at work

NATIONAL REGULATIONS GERMANY


WGK 1 (Annex 4)

NATIONAL REGULATIONS HOLLAND


ABM RESULT
ABM RESULT Substance(s) % (w/w)
9B

KIWA-ATA: KIWA-ATA CertifiedK43641

NATIONAL REGULATIONS HUNGARY


Relevant and applicable Hungarian legislation on protection of human health and the environment:

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Decree 44/2000. (XII.27.) EüM (Minister of Health Affairs) and its amendments: Decree 33/2004. (IV.26.) ESzCsM
(Minister of Health, Social and Family Affairs) and Decree 26/2007. (VI.7.) EüM (1907/2006/EK - REACH) on
detailed rules of certain procedures and activities related to dangerous substances and preparations.
Joint Ministerial Decree: 25/2000. (IX.30.) EüM-ESzCsM on chemical safety at work.

NATIONAL REGULATIONS RUSSIAN FEDERATION


The law of Russian Federation "About the sanitary-epidemiological safety of the population", 30 March 1999 N
52-FZ.
The law of Russian Federation "About the safety of the dangerous industrial objects", 21 July 1997 No. 116-FZ.
The law of Russian Federation "About protection of the rights of the consumers", 07 February 1992 N 2300-1.
The law of Russian Federation "Basics of the legislation of
The law of Russian Federation "About the industrial regulation", 27 December 2002 N 184-FZ.
The law of Russian Federation "On Environmental Protection", 10 January 2002, N 7-FZ.
GOST 30333-2007: Chemical production safety passport. General requirements.
GOST 19433-88: Dangerous goods. Classification and marking.
GOST 12.1.007-76 (Occupational safety standards system. Noxious substances. Classification and general safety
requirements).

NATIONAL REGULATIONS, USA


NSF INTERNATIONAL
This product has received NSF/International certification under NSF/ANSI Standard 60 in the reverse osmosis
antiscalant category. The official name is "Miscellaneous Water Supply Products." Concentration 15 mg/l

INTERNATIONAL CHEMICAL CONTROL LAWS


EUROPE

The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories

Safety Data Sheet according to Regulation (EC) No 1907/2006.

Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at [email protected]
or visit our website.

UNITED STATES :
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

CANADA :
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

- REVISED INFORMATION: section(s):


-2
-4
-5
-6
-7
-8
- 11
- 15

This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.

EMERGENCY TELEPHONE NUMBER(S)

Trans-European +32-(0)3-575-5555
Belgium / Luxembourg +32-(0)3-575-0330
Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Czech Republic +420-602-669421
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
France / French Switzerland +33-(0)6-11-07-32-81
Germany / Austria / German Switzerland +49-(0)6232-130128
Hungary +36-30-9-506-447
Italy / Italian Switzerland +39-333-210-7947
Latvia +32-(0)3-575-5555 & Local emergency telephone number 112
The Netherlands +32-(0)3-575-0330
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48(0)14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Russia / Belarus +7-812-449-0474
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovak Republic +421-(0)905-585-938
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
UK and Republic of Ireland +44-(0)7071-223-738
Nalfleet International +32-(0)3-575-5555

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
For additional copies of an MSDS visit www.nalco.com and request access
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SAFETY DATA SHEET
PRODUCT

PERMATREAT® PC-191T

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

POISON CONTROL CENTER TELEPHONE NUMBERS

Belgium +32-70-245245
Czech Republic +420 224 91 92 93
France +33-(0)145-42-59-59 ORFILA
Hungary +36-80-201-199 (ETTSZ, 1096 Budapest, Nagyvárad tér 2)
Latvia + 371 67042473
Slovak Republic +421 (0)2 5477 4166

Prepared By : SHE Department


Date issued : 27.08.2010
Version Number : 1.22

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth
and 0.001 = 1 thousandth

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
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