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VITEEE Chemistry 2013: - Download From
VITEEE Chemistry 2013: - Download From
(a)
Br Br
C(CH3)3 C(CH3)3
OH
(d)
Br
OCH3
(c) Cl
C(CH3)3
C(CH3)3
3. An optically active compound ‘X’ has molecular formula C4H8O3. It evolves CO2 with aqueous
NaHCO3. ‘X’ reacts with LiAlH4 to give an achiral compound.’X’ is
OH OMe
4.
Conc.H2SO4
Products
Product is/are
(a) (b)
KHSO4 HClO
A B
5. Glycerol
(a) O O
∥ ∥
CH2 = CH CH CH2 –CH CH
Cl OH
(b) O O
∥ ∥
CH2 = CH CH CH2 –CH CH
OHOH
CL
(c) CH3CH2CHO, CH
Cl CH CH
3 2
(d) O
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6. Phenol is heated with phthalic anhydride in the presence of conc. H2SO4. The product gives pink
colour with alkali. The product is
(a) phenolphthalein
(b) Bakelite
(d) flurorescein
NaNO2/HCL CuCN
7. C6H5NH2 X
O0 C
H2O/H+
Y Z,Z is defined as
9. NH4Cl(s) is heated in a test tube. Vapours are braught in contact with red litmus paper, which
changes it to blue and then to red. It is because of
10. Out of H2S2O3, H2S2O4, H2SO5 and H2S2Os peroxy acids are
11. The density of solid argon is 1.65 g per cc at -2330C. If the argon atom is assumed to be a sphere of
radius 1.54x10-8 cm, what per cent of solid argon is apparently empty space? (Ar = 40)
12. When 1 mole of CO2(g) occupying volume 10L at 270C is expended under adiabatic condition,
temperature falls to 150 K. Hence,final volume is
13. Acid hydrolysis of ester is first order reaction and rate constant is given by
.
K= log
Where, Vo, Vt and V are the volumle of standar6d NaOH required to neutralize acid present at a
given time, if ester is 50% neutralized then
(a) V = Vt
(b) V = (Vt –V0)
(c) V = 2Vt –V0
(d) V = 2Vt + V0
14. A near UV photon of 300 nm is absorbed by a gas and then re-emitted as two photons. One photon
is red with wavelength of the second photon is
(a) 1060 nm
(b) 496 nm
(c) 300 nm
(d) 215 nm
17. X Y
The product Y is
O O + HBr
OH
O
(a) O (b) HO
Br
Br
(d)
Br (c) OH HO OH
HO Br
CL CL CL
P Q R
O
∥
R – C – O – R’
21. I a Claisen condensation reaction (when an ester is treated with a strong base)
22. An organic compound B is formed by the reaction of ethyl magnesium iodide with a substance A,
followed by treatment with dilute aqueous acid, Compound B does not react with PCC or PDC in
dichloromethane. Which of the follo-wing is a possible compound for A?
(d) H2C = O
23. O O
∥ ∥
CH3CCH2CH2COCH2CH3
(i) CH3MgBr (one mole)
A
(iI) H3O+
(a) OH O
∥ ∥
CH3 C CH2 CH2 COC3H2CH3
CH3
(b) O O
∥ ∥
CH3 CCH2CH2CCH3
(c)
H3C O O
H3C
24. For the cell reaction 2Ce4+ + Co → 2Ce3+ + Co3+ ; E0cell is 1.89 V. If ECo2+/ is – 0.28 V, what is the value
of / ?
25. A constant current of 30 A is poassed through an aqueous solution of NaCL for a time of 1.00 h.
What is the volume of Cl2 gas at STP produced?
Boat chair
The reaction is of first order in each diagram, with an equilibrium constant of 104. For the
/
conversation of chair form to boat from = 4.35 x 10-8 m at 298 K with pre-exponetial factor of
1012 s-1. Apparent rate constant (= kA / kB) at 298 K is
Zn + Cu2+ ⇌ Cu + Zn2+
Entropy change S0 is 96.5 J mol-1K-1, then temperature coefficient of the emf of a cell is
28. What transition in the hydrogen spectrum would have the same wavelength as the Blasmer
transition, n=4 to n=2 of He+ spectrum?
29. What is the degeneracy of the level of H-atom that has energy − ?
30. Match the following and choose the correct option given below.
(a) H
NH2 NH2
(b)
N
N N
H2
(c) NH2
NH2
NH2
CH3
(d)
C = O
CH2
C
= O
CH3
(a) (b)
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CHO CHO
(c) (d)
OCH3 CH3
CO2 + COONa +
(a) CO2
(b) COONa
35. Benzene diazonium chloride on treatment with hypophosphorous acid and water yield benzene.
Which of the mfollowing is used as a catalyst in this reaction?
(a) LiAlH4
(b) Red p
(c) Zn
Alcoholic
(d) Cu +
p/Br2 KOH O3,H2O
CH2COOH
CF CO H 3 3
D E
KMnO4
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Isomers are
(a) C and E
(b) C and D
(c) D and E
(d) C,D and E
37. When a monosaccharide forms a cyclic hemiacetal, the carbon atom that contained the carbonyl
group is identified as the …. Carbon atom,because
H H
39. Calculate pH buffer prepared by adding 10 mL of 0.10 M acetic acid to 20 mL of 0.1 M sodium
acetate [pKa (CH3COOH) = 4.74]
40. The equivalent conductance of silver nitrate solution at 250 0C for an infinite dilution was found to
be 133.3 -1 cm2 equiv-1. The transport number of Ag+ ions in very dilute solution of AgNO3 is 0,464.
Equivalent conductances of Ag+ and NO-3 (in -1 cm2 equiv-1) at infinite dilution are respectively