Professional Documents
Culture Documents
Jumbo Home Test-1 - Final
Jumbo Home Test-1 - Final
TARGET JEE-ADVANCE
IRP
JUMBO HOME
TEST
Cl EtOH OEt
D
O
OH
(A) NaBH4, CH3OD (B) NaBH4, CH3OH (C) NaBD4, CH3OD (D) NaBD4, CH3OH
(E) LiAlD4, CH3OH
3. Predict the major product of the following reaction.
OH
PBr3
Br
Br PBr2
(A) (B) (C) (D)
OPBr2
(E)
OH
N
(A) N (B)
I
(C) (D) O
(E) O
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [2]
+
H3O Conc. H 2SO 4 O 3/H 2O/Zn
5. O + CH3MgBr A B C
A, B and C are :
O
(A) CHO (B) , HCHO
CHO O
(C) (D) CHO
CHO
Na/NH3 C C H2
6. B A
Lindlar catalyst
A and B are :
Br Br
Br
(E)
NH2
9. Predict the product of the following reaction.
1. HgSO4, H2SO4, H2O
Hexyne
2. LiAlH4
3. H2O
O
(A) (B) (C) (D)
OH Li O H
(E)
OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [3]
10. Predict the product of the following reaction
H
2 equiv. HBr
Br
Br Br Br Br
(A) (B) (C) (D)
Br
Br
Br
(E) Br
11. I dentify the reagent from the following list which can easily distinguish between 1-butyne and 2-butyne
(A) Br2, CCl4 (B) Ammonical AgNO3 (C) H+/HgSO4 (D) H2/Pd-BaSO4
NH2
CONH2
(A) (B) (C) (D)
N N
13. Approximate value of KH/KD when PhCHBrCH3 v/s PhCDBrCD3 is allowed to react with t-butoxide :
(A) = 1 (B) < 1 (C) > 1 (D) 0
O OH
15. What product(s) would you expect to obtain from the following reaction?
O
H
NaOCH3, CH3OH
H3C
H3CO
H
(E)
H3C OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [4]
16. Which of the following would not efficiently accomplish the reaction shown ?
OH O
OH OH OH OH
NO2 CH3
(A) (B) (C) (D)
NO2 CN
18. In the given following compound find out the pair of enantiomers and diastereomers respectively.
R – CH – CH – R
Cl Br
(A) 2, 2 (B) 2, 4 (C) 4, 4 (D) 4, 2
21.
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [5]
23. The major product of the following reaction is
Me Br
- +
F PhS Na
dimethylformamide
NO2
F F SPh SPh
(A) (B) (C) (D)
O
||
25. Functional isomers of CH3 – C – OH are :
26. Acetamide is treated separately with the following regents. Which of these would give methylamine ?
(A) PCl5 (B) Sodalime (C) NaOH + Br2 (D) Hot, conc. H2SO4
27. Most reactive toward SN–Ar
F Cl Br I
28. The reagent which does not react with both, acetone and benzaldehyde.
(A) NaHSO3 (B) Phenyl hydrazene (C) Fehling solution (D) Grignard reagent
NH2
29. KOBr
(x)
(x) will be
CONH2
CONH2 CONH2 CONH 2
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [6]
NO2
(i) KOH,
30. (A)
(ii) H3O+ Major product
Cl
F
(A) will be
O
C
(i) KOH
NH
C (ii) Br CH2Cl
O
O O
C C
(A) N – CH2 Br (B) N CH2Cl
C C
O O
O O
C C
(C) N (D) N
C C
O – CH2 Br O CH2Cl
OH OH
HO Br
(A) + (B) +
Br Br
HO Br
(C) + (D) +
Br
(E) +
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [7]
Br
O
|| conc . O Na
AlCl3 Br2 / Fe Zn(Hg) HNO3
33. + CH3 – C – Cl (A) (B) (C) (D) (E)
HCl
Product (E) is
O
NO2
Br O2N
dil KMnO 4 H IO 4 OH –
34. [X] A B
O
Possible structure of [X] is
CH3
35. Which of the following polymer can be formed by using the following monomer unit ?
H
N O
OH
OH
39. In the Cannizzaro reaction given below, 2Ph–CHO Ph–CH2OH + PhCO 2 the slowest step is :
(A) the attack of OH– at the carbonyl group
(B) the transfer of hydride to the carbonyl group
(C) the abstraction of proton from the carboxylic acid
(D) the deprotonation of Ph–CH2OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [8]
40. How many D-aldopentoses are possible ?
CHO
H OH
H OH
a typical aldopentose
H OH
CH2OH
(A) 2 (B) 3 (C) 4 (D) 6
(E) 8
41. Which of the following might you expect to exhibit mutarotation?
HO HO
O OCH3 O OH
(A) HO OH (B) HO OH
OH HO
OH
O
HO
OH HO
OH
O O H HO
HO
O O
O OH H
(C) HO OH (D) (E)
H H H OH
HO CH2OH
H OH
OH H
CHO
(1) N2D4,OD,D2O
42. Final product is :
(2) HI
OMe
OH
CH3 CDO CD2H CD3
O O O O
NH2 NH2 NH
(A) HO (B) H2N (C) NH (D)
O O O
O
44. Which of the following Alcohol will give positive iodoform test
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [9]
45. What products would be formed in the reaction shown ?
CHO
H OH
HO H
H OH excess HIO4
H OH
CH2OH
CO2H CO2H
H OH H OH
HO H HO H CHO
H OH H OH
(A) (B) (C) 2 H OH
H OH H OH
CH2OH
CH2OH CO2H
O O O O
(D) 5 + (E) 3 + 2 + CO2
H OH H H H OH H H
46. The iso-electric point of the following -amino acid will lie at which pH if the following data are pKa1 = 2.2,
pKa2 = 9.0 and pKa3 = 10.4
H 3N (CH2)3 CH COOH
NH3
48. Which of the following reactants on reaction with conc. NaOH followed by acidification gives the following
lactone as the only product?
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [10]
49. Consider the following six compounds (A–F).
CH2OH
CHO CHO CHO C=O CH2OH
HO H HO H H OH H OH HO OH
H O OH HO
H OH H OH HO H H O
H OH H OH
H OH H OH HO H
H OH H HO OH
H OH HO H H OH OH
CH2OH CH2OH CH2OH CH2OH OH H
A B C D E F
CH3 CH3
52. (– CH2 – C – CH2 – C –)n
CH3 CH3
is a polymer having monomer units
OH
HO OH
CH3
(A) Aldohexose (B) Ketoheptose (C) -furanose (D) -pyranose
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [11]
56. Consider the carbohydrates below and choose the statement that is true.
CO2H
CO2H H NH2
CO2H
(C) (D) (E) H NH
H NH2
Me
58. Periodic acid splits glucose and fructose into formic acid and formaldehyde. Ratio of formic acid and
formaldehyde from glucose and fructose is :
(A) 5/1 and 4/2 (B) 5 / 1 and 5/1 (C) 4/2 and 4/2 (D) 5/1 and 3/2
59. How many amino acids are involved in the structure of met-enkephalin?
O O O
H H
N N
N N OH
H H
NH2 O O
HO
S
(A) Three (B) Four (C) Five (D) Six (E) Seven
60. Which of following is essential amino acid?
(A) Glycine (B) Alanine (C) Valine (D) Histidine
61. Number of different tripeptities possible from Glycine, alanine and phenylalanine are :
(A) 9 (B) 18 (C) 27 (D) 81
CH3
H3C CH3 H3C CH3
N N
(A) (B) (C) (D)
(E)
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [12]
64. The three xylenes (dimethyl benzene) do not undergo electrophilic aromatic substitution at the same rate.
CH3 CH 3
Cl2
; rate r3 The correct order of relative rate r1, r2, r3 is :
AlCl3
CH3
(A) r1 = 200 ; r2 = 2, r3 = 1 (B) r1 = 1 ; r2 = 2, r3 = 200
(C) r1 = 2 ; r2 = 200 ; r3 = 1 (D) r1 = 2 ; r1 = 1 ; r3 = 200
CH3
CH3Cl AlCl3
65. (A ) (B)
AlCl3, 25ºC 100ºC
(major ) (major )
CH3
(A) , (B) ,
CH3 CH3
CH3 CH3
66. Total number of different cross aldol condensation product (only structural) obtained when a mixture of (S) 2-
methyl cyclohexanone and 2-butanone is treated with aqueous sodium hydroxide :
O
O
NaOH
+ ??
H2O
Br Br
OH OH HO OH
(A) (B)
Br Br
CH3 CH3
HO H H OH Br
(C) H OH HO H (D)
Br
CH3 CH3
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [13]
68. Total number of stereoisomers theoritically possible for the compound shown below
OH
O
O
HO
(A) 5 (B) 8 (C) 10 (D) 16
Light
69. + N Br or peroxide
(Product)
Final product is :
Br
Br
(A) (B) (C) (D)
Br
pH = 11.8
70. + MnO4– (A) + (B)
(ppt.)
Me Me Me OH
H OH H OH HO H H Me
(A) HO H (B) H OH (C) H OH (D) H OH
Me Me Me Me
Cl
(A) (B) (C) (D) Cl
Cl
Cl
200ºC O3
72. + H2C = CH2 C7H10 (B)
CH3–S–CH3
(A)
Final product (A) and (B) are respectively ?
OHC CHO
OHC CHO
(A) , (B)
CHO
OHC CHO
(C) , CHO (D) ,
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [14]
73. Find product of the reaction below :
HO OH
BF3
O O O O
74. Treatment of a sulfade with 1 mol of 30% aqueous hydrogen peroxide at room temperature gives (A).
Treatment of (A) with a second mole of hydrogen peroxide brings about its oxidation to (B).
H 2O 2 H2O2
S CH3 (P) (Q)
25ºC 25ºC
Identify products (P) and (Q) ?
O
O O
|| ||
(A) P = S – CH3 ; Q = S – CH3 (B) P = OH ; Q =
||
O
O O
||
(C) P = SO3H ; Q = OH (D) P = S – CH3 ; Q = S – CH3
75. Moles of AlCl3 consumed in Friedel Craft alkylation and acylation are respectively :
(A) 0.1, 1.1 mole (B) 0.1, 0.1 mole (C) 1.1, 1.1 mole (D) 1.1, 0.1 mole
CF3I
76. CH3–CH2–CH2–CH = CH2 (A)
light
Major product (A) is
I
(A) CH3CH2CH–CH2–CH2F (B) CH3–CH2–CH2–CH–CH2
I CF3
CF3
(C) CH3CH2CH2CH–CH2 (D) CH3CH2–CH–CH2–CH2–I
CF3 I
HBr (A)
without peroxide
77. CH=CH2
HBr (B)
Peroxide
Final products (A) and (B) are
Br
(A) Product A : ; Product B : CH2–CH2–Br
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [15]
Br
(C) Product A : ; Product B : CH–CH3
Br
Br
(D) Product A : CH2–CH2–Br ; Product B :
78. Total number of products including stereoisomers that are formed when (R)-3-methyl-1-pentene is treated
with following :
CH3
Given the following energy diagram for a hypothetical reaction, which statements would be true of the reac-
tion ?
(A) Product B will be formed faster, but product A would predominate at equilibrium if both reactions are
reversible.
(B) Product A will be formed faster and product A would predominate at equilibrium if both reactions are
reversible.
(C) Product B will be formed faster and product B would predominate at equilibrium if both reactions are
reversible.
(D) Product A will be formed faster, but product B would predominate at equilibrium if both reactions are
reversible.
SO3H
O
1. KOH
NH
2. Br
O 3. H2NNH2
O O
N
(A) N (B) N (C) H 2N (D) H N
2
O O
86. An interesting heterocycle is prepared by the reaction sequence shown below. Which one is it? Try to follow
each step, not just guess at the answer.
1. O3
2. Me2S
3. NH3
N
N N
(A) N (B) (C) (D)
O O
O HO
87. OCH3 OCH3
O O
LiAlH4
O–CH3 H+ H
+
O O
(A) O (B) O
O
O
(C) O (D)
O
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [17]
89. Identify the relationship in products obtained in given reaction.
+ HCl Product(s)
90. Which of the following compounds would you expect to react most rapidly with methanol to do the following
reaction ?
R – Br + CH3OH R – O – CH3 + HBr
Br Br Br
(A) (B) Br
(C) (D)
O O O O
OH
(A) (B) (C) O (D) OH
OH
OH
O
O O
93. An organic compound C3H6O does not give a precipitate with 2,4-Dinitrophenyl hydrazine reagent and does
not react with metallic sodium. It could be:
(A) CH3CH2CHO (B) CH3COCH3 (C) CH2=CH–CH2OH (D)CH2=CH–O–CH3
O O
CH3 – CH2 – NH2 CH3 – C CH3 – CH2 – OH CH3 – C
(I) NH2 (III) OH
(II) (IV)
(A) IV > II > III > I (B) IV > II > I > III (C) II > IV > III > I (D) II > IV > I > III
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [18]
O
(1) NaOI
(B)
KMnO 4
95. (A) (C) + gas
Ph – C – OH + CHI3
(2 ) H
Structure of (A) is
OH OH O
(A) Ph – CH2 – CH – CH2 – OH (B) Ph – C – CH2 – C – H
CH3
OH OH OH
(C) Ph – CH – CH2 – CH2 – OH (D) Ph – CH – C – CH3
CH3
O
O
(C) Ph– CH2–CH=CH–C–H (D) CH3
O
O OH O
HBr
98. ?
CCl4
Product(s) can be
Br
(C) (Minor) (D) (Minor)
Br
99. Which of the following compound has one of the Stereoisomer as a meso compound ?
Cl Cl
Cl Cl
Cl
(A) (B) (C) (D)
Br Cl
Cl
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [19]
100. The correct statement(s) concerning the structures E, F and G is (are)
101. Provide the reagents necessary to carry out the following conversion
CHO COOH
HO H HO H
H OH H OH
HO H HO H
CH2OH CH2OH
NO2 NO2
(A) NO (B) NO (C) (D)
2
103. Which of following on acid catalysed hydrolysis give two product that give positive Iodoform test.
O
(A) O (B)
O
(A) CH3SH (B) CH3SCH3 (C) CH3–CH3 (D) CH3 – S – C – CH3
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [20]
105. Which of the following reactions give explosive compounds.
CH3
OH
Conc. HNO3
(B) Compound
CH2 – OH
Conc. HNO3 + Conc. H2SO4
(C) CH – OH Compound
CH2 – OH
O
|| 1. NaOH / 5–10ºC
(D) H – C – H + CH3 – CHO Compound
excess 2. Conc.HNO3 +
conc.H2SO4,
106. In which of the given reaction cumene is the product.
OH
+
,H , H3PO4
(A) (B)
Cl
Cl
, AlCl3
(C) (D)
AlCl3
107. With reference to the scheme given, which of the given statement(s) about T, U, V and W is (are) correct?
O
O
CH3 T
LiAlH4
CrO3/H (CH3CO)2O
V U excess W
(A) T is soluble in hot aqueous NaOH
(B) U is optically active
(C) Molecular formula of W is C10H18O4
(D) V gives effervescence on treatment with aqueous NaHCO3
108. Heating many alkyl chlorides or bromides in water converts them to alcohols through an SN1 reaction.
In which of the following sets of compounds, correct order of this solvolytic reactivity is shown.
Br
Br
Br Br Br
(A) < < (B) < <
Br
Br I Cl Cl Cl
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [21]
109. Which of the following primary amines can be prepared by the Gabriel synthesis.
NH2 NH2 NH2
(A) NH2 (B) (C) (D)
110. In which of the following pairs, second compound requires less energy for heterolytic cleavage of C – Xbond?
I
(A) Br (B) I
Br
(C) (D)
Br Br
I I
OH
Br2
111. CH2Cl2 ?
O
Identify the product(s)
OH O
O
(A) O (B) O (C) (D) HBr
O
Br
Br
Br
112. For the reaction, predict the major product(s)
(1) OsO4
(2) NaHSO3/H2O
H OH H OH
(A) (B)
OH HO
HO H HO H
(C) (D)
OH HO
CH3
Br2 H Br
113. A
CCl4 H Br
Cold
C2H5
KMnO4
Me
Me Et
(A) A is (B) A is
Et
CH3 CH3
H OH HO H
(C) B is H OH (D) B is H OH (Single product)
C2H5 CH3
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [22]
114. Which of the following gives positive iodoform test?
O OH
OH O
(A) (B) (C) (D)
115. Statement-1 : Tertiary nitrogen atoms at the bridgehead position of bridged bicyclic amines are often more
reactive as nucleophiles than are non cyclic tertiary amines.
Statement-2 : Alkylation of bridged bicyclic amine is faster than a non-cyclic tertiary amine.
N H3C–I
For Example : N
A bridge faster
bicyclic amine H3C I
Et3N H 3C – I
Et3N – CH3 I
A non-cyclic
tertiary amine
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for Statement-1
HBr +
40ºC
Br
P1 Br P2
(major) (major)
Statement-2 :
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [23]
Comprehension
Comprehension # 1
(C)
(Aldehyde)
Conc. H2SO4 1. O3
(A) (B)
2. Zn/H2O
C6H14O
(1º-symmetric (D)
alcohol) (Ketone)
Oxime of Aldehyde (C) and oxime of ketone (D) show geometrical isomerism.
1. Pd/Charcol
117. (B) (P)
2. Br2/Light
3. KOH(alcoholic)
Compound (P) is :
OH
O
(A) , (B) ,
OH
O
(C) , (D) ,
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [24]
Comprehension # 3 (Q.120 to Q.122)
On the basis of given scheme identify each of the compound
mild CH3COOH
(C) (A) (B)
oxidation dil.H2SO4 ester
(i) 50% KOH
(ii) H3O
(i) PCl5
(A) + (D) (E) H – CN + H2O
(ii) NH3
O O O O
(A) (B) (C) (D)
O O H O H O
KOH(conc.) Benzyl
(Q) + K Benzoate
alcohol
1. O3 O
2. Zn/H2O
(P) O
dil. KOH HCN conc. H2SO4
(R) (S) (T)
5 – 10ºC
OH
OH
(C) HOOC (D)
HOOC
OH
O Br O
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [25]
125. Reactant (P) is :
CH = C – CH3
(A) | (B) CH = CH – CH2CH2CH3
CH3
CH3
polymer
O O CHO
COCH3
(A) (B) (C) (D)
(D) C7H10O. (D) on reaction with H2 / Ni give (E) .(E) on reaction with conc. H2SO4 gives (B)
OH
OH OH OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [26]
133. Structure of (B) is :
H CH3
CH3 – CH2 – CH – CH3 CH3ONa
+ +
| CH3OH
Br CH3 H
(major)
Mechanism :
+
+
H CH3O H
|
CH3ONa + CH3 – CH – CH – CH3 CH3 — CH –— CH — CH3
|
Br (trans-2-butene)
Br
anti-coplanar transition state
(staggered conformation
-lower energy)
135. Give the correct order of rate of reaction with alc-KOH
Br Br
(i) (ii) Br (iii)
(A) (i) > (ii) > (iii) (B) (ii) > (i) > (iii) (C) (iii) > (ii) > (i) (D) (iii) > (i) > (ii)
O Cl
O
CC–CH3
Sum of x + y ?
(A) 4 (B) 5 (C) 6 (D) 8
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [27]
Comprehension 10 (Q.139to Q.141)
H3O
( A ) (B) + (C) gives positive iodoform test
LiAlH4
H
(D)
O
O
(C) (D) O
O
H OH
O
H
CH3 || O
CO O
H O
H3C H
CH3 O O
C=C CH3 H CH3 CH2CH=CHCH=CH2
CH3C H C – CH3
|| O
O Pyrethrin-II
Pyrethrosin
142. The total sum of number of tetrahedral stereocentres and all carbon-carbon double bonds about which there
is the possibility for cis-trans isomerism in each molecule.
(A) 10 (B) 11 (C) 12 (D) 13
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [28]
Comprehension 12 (Q.145to Q.147)
Trehalose is found in young mushrooms and is the chief carbohydrate in the blood of certain insects. Trehalose
is a disaccharide consisting of two units of D-glucose joined by a glycoside bond.
CH2OH
O
HO
HO
OH
CH2OH
O O
HO OH
OH
(Trehalose)
145. Which of the following statements are True (T) or False (F) regarding the compound Trehalose.
Statement-I : Trehalose is a reducing sugar.
Statement-II : Trehalose undergo mutarotation.
Statement-III : Trehalose react with Four moles of periodic acid.
Statement-IV : Both the glucose units joined through an -1,1-glycosidic linkage.
Choose the correct alternative :
(A) FTFT (B) FFTF (C) TTFF (D) FFTT
146. How many moles of acetic anhydride (Ac2O) consumed on reaction with Trehalose?
(A) 6 (B) 7 (C) 8 (D) 9
dimethyl sulfide
O
CH3–O–S–O–CH3
147. Trehalose O
Product ?
(excess)
CH2OH CH2OH
O O
MeO HO
CH2OMe
O CH2OH
MeO
O
HO
MeO
(C) OMe (D) HO
OH
CH2OMe OCH3
O O
MeO OMe
OMe
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [29]
Comprehension 12 (Q.148 to Q.150)
A student in the lab had a mixture of three compounds, 4-methyl benzoic acid, 4-methylcyclohexylamine
and 1, 4-dimethyl benzene. In order to separate the three compounds the following extraction (separation)
scheme was followed. At the end of the procedure the student had six separate flasks containing either an
aqueous or an ether solution. Locate each compound by designating the flask expected to contain each
compound. Some relevant pKa data is given :
SCHEME
CO2H
CO2H NH2 CH3
CH3
CH3 CH3 CH3
pKa = 4.4
1. ether
2. HCl (aqueous)
ether aqueous
NaOH NaOH
aqueous ether
Flask : 1 Flask : 2 ether aqueous
5 6
Flask Flask
148. Which flask contains the 4-methyl cyclohexylamine?
(A) 2 (B) 3 (C) 4 (D) 5
O
C–O K
(1) CH3MgBr O3 Conc. KOH/
(A) (B) (C)
(2) H3O Zn CH2OH
(3) H2SO4/
(D)
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [30]
151. Identify compound (A) is
O O
O O
(C) (D)
CH=O
COONa
(C) (D)
OH
NH3
(X) (Y) 2KOBr (Z)
OH
HO Terylene polymer
H ,
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [31]
157. Structure of (X) is
O
162. Structure of (A) is
O O
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [32]
Comprehension 18 (Q.164 to Q.166) :
The trisaccharide Raffinose occurs principally in cottonseed meal
OH
CH2OH
O
HO
OH
CH2
O
HO
HO
OH H
OH
O CH2OH
OH
CH2OH O H
164. Name the 3 mono saccharide units in raffinose respectively from top to bottom :
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [33]
169. In column - I, statements are given and in column - II, structures are provided. Match the statement given in
column - I with corresponding structures shown in column - II
Column - I Column - II
OH
(A) An optically active compound that is oxidized (P)
OH
by MnO2 to an optically inactive compound
OH
OH
OH
(T)
OH
O
||
(A) Ph – C – CH 2 – Cl (P) SN1 & SN2 both reaction are possible
(B) CH3 – O – CH2 – Cl (Q) SN1 & SN2 both are not favorable
Cl
CH2 – Cl
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [34]
171. Column-I Column-II
NH2
| HNO2
(A) CH3 – CH2 – CH – CH3 Major products (P) Elimination reaction
H
(B)
(Q) Diastereomers is formed in the reaction
OH
HNO2
(C) NH2 Major products (R) Racemic mixture will formed
O (1) Mg(Hg)
(D) (S) Carbocation is intermediate
(2 ) H2O
172. There are few reagents given in Column-I and some compounds given in Column-II. Match reagents (of
Column-I) with compounds (of Column-II) in which equilibrium of reactions is in forward direction.
Column-I Column-II
(A) Na (P) Ph – OH
(B) NaOH (Q) R – CO2H
(C) NaHCO3 (R) R – C C – H
(D) NaNH2 (S) R – CH2 – OH
(T) Ph – SO3H
O
(A) (P) 1
R – C – Cl
O
(B) (Q) 2
Cl – C – OEt
O
(D) (S) 4
R R
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [35]
175. Column I Column II
O
(A) (P) Yellow precipitate with NaOI.
CH 3 NH2
O
(B) (Q) Reacts with KOBr to form 1º amine
CH 3 CH3
O
(C) (R) Reduction to form 1º Amine.
Ph H
O
(D) (S) Reacts with LiAlH4 to form 1º Alcohol.
176. Match the chemical conversions in list-I with appropriate reagents in list-II and select the correct answer
using the code given below the lists :
Column-I Column-II
CH3 CHO
COOH
CH3
CH3CH 2OH(aq)
(B) Br (Q) Acidic
1. LiAlH4
(C) CH3 – CHO (R) Alkaline
2. H2O
OH
CH3COO¯Na+ (aq)
(D) (S) Acid - Base reaction.
SO3H
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [36]
178. Compound Laboratory Test
(A) Ph–NH2 (P) NaHCO3 test
(B) Ph–COOH (Q) 2, 4-DNP test
(C) PhCHO (R) AgNO3 + NH3OH test
OH
(D) (S) Br2 / H2O
COOH
(T) NaNO2 + HCl
179. Match the correct resonance energy of the compounds given in column-I
Column-I Column-II
(Resonance energy in kilocalories per mole)
(C) (R) 83
(Anthracene)
(D) (S) 61
(Phenanthrene)
180. Match each of the compounds given in Column-I with the reaction(s), that they can undergo, given in Column-II.
Column-I Column-II
Br
OH
(B) (Q) Elimination
CHO
Br
(D) (S) Esterification with acetic anhydride
NO2
(T) Dehydrogenation
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [37]
181. List-I List-II
Cl
CH2
X1 Orlon Y1 H2C
n
CN
X2 Neoprene Y2 H2C–CH
n
Br2
(A) (P) Electrophilic addition
CCl4
Br2
(B) (Q) Free radical addition
h
183. No. of cyclic hemiacetals (only pyranose form) are possible from D-Glucose and L-Glucose.
184. 0.037 gm of ROH was added to CH3Mg and the gas evolved measured 11.2 ml at STP. What is the
molecular wt. of ROH ? On dehydration ROH given as alkene which on ozonolysis gives acetone as one of
the products ROH on oxidation easily gives an acid containing the same number of carbon atoms. Give the
answer in the form (molecular weight of R–OH – 70).
186. How many of the following reaction schemes will produce a carboxylic acid ?
(1) O3 (2) H2O (1) BH3 THF
(A) (B)
(2) H2O2,NaOH
(1) O3 (1) BH3THF
(C) (D)
(2) DMSO (1) H2O2,NaOH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [38]
(E) N H3O /heat (F) KMnO4
H2SO4,H2O
(1) Mg OH
Br
Na2Cr2O7
(G) (2) CO2 (H) H2SO4, H2O
(3) H3O
Na2Cr2O7
(I) OH H2SO4, H2O
OH
HO H HO H HO H
(ii) &
H H H H H
OH HF D
H D H
(iii) &
OH H F
HO
OH
H CH3
CH3 H
Br H Br H Br CH3
(v) &
H CH3 CH3 CH3 Br H
CH3
H CH3
Cl
H Br
(vi) &
H Cl
H Br CH3
CH3
CH3 CH3
Br H H Br
(vii) &
H OH HO H
CH3 CH3
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [39]
Br Cl Br Br Cl
(viii) Cl Br & Cl
CH3 H3C
CH3 CH3
H OH
(ix) &
HO H
Cl CH3
H CH2CH3
Cl Cl Cl Cl
(ii) &
HO H H OH
(iii) &
O O
(iv) &
(v) &
Br Br
H
H Br
(vi) &
Br
H OH H OH OH
OH
Br Br
H
H Br
(vii) &
Br
H OH H OH OH
OH
Et H Me Me H Me H
(viii) &
Me Et H Et Et
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [40]
CH2CH3
(ix) &
CH3
OH Br OH Br
(x) &
190. How many compound which has one of the stereoisomer as a meso compound
192. x = number of distinct terminal alkyne with molecular formula C5H8 , then what is x = ?
Na
193. CH3 – Cl + C2H5 – Cl (X) = number of dimerised products.
Dry ether
195. How many compounds can undergo SN2 reaction more easily than SN1 ?
Cl
Cl
Cl
(a) Cl (b) CH3Cl (c) (d) (d)
Cl
H O
196. 2
SN1
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [41]
197. Amongst the following, the total number of compounds soluble in aqueous NaOH is
H3C CH3
OCH2CH3 OH
N COOH
CH2OH
(a) (b) (c) (d)
OH CH2CH3 COOH
NO2
CH2CH3
N
H3C CH3
CH3 Br
| | EtOH
198. CH3 – C – CH – CH3 total number of (SN1 + E1) products (Including stereoisomers)
|
CH3
199. In given reactions x, y, z are number of Hydrogen in major products. Then what is the value of x + y + z =
OH
1. LiAlH4 (excess)
CN 2. H2O
O OH
xHIO4
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [42]
203. x = moles of RMgX consumed
O
HO
Cl
OEt
O O
I I
I
Hg 2
(1) LiAlH4 HBr alc. KOH
(a) C CH (b) CH = CH2 ( A )
dil. H2SO4 ( 2 ) H2SO 4 / CCl4
H2SO4
H /
(c)
(d)
OH
OH
alc. KOH
H /
(e)
(f)
OH
Cl
F
F O
(i) Ph – O – CH3 (j) (k) (l)
NO2 Cl
NO2
Br
O Cl
NO2
(m) (n) (o) (p)
OEt Cl
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [43]
208. x = Number of ether which cannot prepared by Willamson ether systhesis.
O – CH3
(a) Ph – O – Ph (b) Ph – O (c)
O
(d) O – CH3 (e) O (f)
(g) O (h) O
OH
SO3H
(v) (vi)
NO2
211. How many compounds will undergo decarboxylation easily under mild conditions
COOH
COOH O O
O O O
(a) (b) (c) OH (d)
OH
O
COOH
COOH
(e) (f) COOH
COOH
212. x = Number of compound which gave carboxylic acid when react with CrO3 . H2SO4.
OH
(a) OH (b) (c) (d)
OH OH
OH
OH
OH
(e) (f) OH (g) (h)
OH OH
(i) (j) OH (k) (l)
OH
OH
(m) (n)
OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [44]
213. x = Number of alcohol which gave ketone by chromic acid?
OH
(a) (b) OH (c) (d)
OH OH
OH
(e) OH (f) (g) OH (h)
OH
214. x = Number of compound when reach with excess CH3MgBr followed by acidification give 3º alcohol.
O
O || O
|| O ||
(a) Et (b) (c)
O Cl
O O
O || ||
(d) || (e) H – C – O – Et (f) H – C – Cl
O O O
|| || ||
(g) (h) CH3 – C – O – C – CH3 (i)
NH2 O O
O O
|| ||
(j) Cl – C – O – Et (k) S O (l)
O
xEtOH y EtOH
215. (i) Acetal
al (ii) Acetal
H
H O
216. x = Number of carbocation more stable than (sec. butyl carbocation) is/are
y = Number of carbocation which undergo rearrangement
O O
O O
NH
(g) (j) (k)
(h) (i)
217. x = number of compound which gives racemic mixture with HBr. What is value of x?
OH CH3
CH2
(a) (b) (c) (d)
OH
CH2
(e) (f) (g) (h) (i)
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [45]
218. How many compound give ketone when reacts with Hg+2/H2SO4
(a) HC CH (b) CH3 – C CH (c) Ph – C CH (d) Ph – C C – Ph
(e) CH3 – CH – C CH (f) CH3 – CH2 – C CH (g) CH3 – C C – Et
CH3
NO2
OH OH
OH NO2
NO2 CH3
O O O O O
(e) (f) (g) (h)
CH3 – C – H Ph – C – Cl Ph – C – O – C – Ph
CH3
Cl
(i) CH (j) CH3 – CH2 – OH
3
CH3
O O NO2
O O
(e) O (f) (g) O (h) (i)
NH2 Cl
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [46]
222. x = Number of compound undergo alkaline hydrolysis.
y = Number of compound react with DIBAL-H to form aldehyde.
Then find the value of x + y
O
(a) CH3 – C N (b) (c) CH3 – O – CH3 (d) CH3 – CH2 – OH
O – CH3
O
O
(e) (f) H2C = CH2 (g) O (h) CH3 – CH3
CH 3 – C – Cl
alc.KOH H2O
223. E2 products = X Br w = SN1 products
Sum of w + x + y + z is
xH
224. Et – O – Et
yH
Ph – O – Et
zH
Ph – O – Ph
x,y and z are moles of HI consumed
Sum of x + y + z ?
Cl
K SH
(a) (b) K SH + CH3 – Cl
CH3 Et
Na SOCl2
(c) H OH (d) H OH
Et CH3
CH3 CH3
SOCl2 PCl5
(e) H OH (f) H OH
Pyridine
Et Et
CH3
TsCl
(g) H OH
Pyridine
25ºC
Et
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [47]
226. x = Number of reaction in which racemic mixture will formed
y = Number of reaction in which carbocation will formed as intermediate
Find out the value of (x + y) is
O O
|| LiAlH4
(a) Ph – C – CH3 (b) LAH
CH3
LiAlH4 H2O
(c) (d) Ph Cl
O
Et
CH3 CH3
+
H3O conc-HI
(e) Ph OCH3 (f) Ph OH
Et Et
OH O
+ –
conc-HI (1) K CN
(g) (h)
H (2) H+
227. In given reactions x, y, z are number of Hydrogen in major products. Then what is the value of x + y + z =
OH
228. Among the following biomolecules, how many have glycosidic bond ?
(a) Protein (b) Starch (c) Glucose (d) Fructose (e) Sucrose (f) Maltose
OH
Cl
CH = O CO2H
conc. KOH
(a) (b)
LiAlH
4
Cl Cl
CO2H Br
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [48]
230. x = Number of compound which are o/p director.
Cl NH2 N=O NO2
O
O
NH – C – CH3 NH2
(e) (f)
O
CH3 SO3H
231. In the given scheme below, the total number of intramolecular aldol condensation products
(excluding streoisomer) formed from 'X' is
CH3
3(i ) O NaOH( aq)
(X)
( ii) Zn, H2O heat
232. How many different types of products possible (including streoisomer) from reductive ozonolysis of given
compound.
OH
NaNO 2 /
LiAlH4
conc. HNO3 HCl
233. (A) (B)
(C) (D)
(or ) Sn / HCl mild-basic
condition
Double bond equivalent of D is
234. x = no. of compound which reacts with HCN then followed by acidification. Lactonization take place
O O O O
C–H C–H
(A) (B) (C) (D)
OH OH OH
O
OH
(E) (F)
OH
OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [49]
235. x = Number of reaction in which new cyclic ring in product will form.
Cl Cl
AlCl3 AlCl3
(a) (b) O
O O
(c) H – C – C – C – C – C – OH H (d) H – O – C – C – C – C – C – OH H
(e) H2C = CH – C – C – C – OH (f) H2C = CH – C – C – C HBr
H
CCl4
CH2–OH
H2O H
(g) SH H (h)
H Cl C–OH
O
O
O
OH H2SO4 H2SO4
(i) (j) + O
O
O O O
(k) PhMgBr (L) KOH/
Cl
Cl O OH
OH OH
– –
(10) Ph – N NCl (11) CHCl3 / OH
Mild-basic
OH
O CH2 – OH
(ix) I (x) (xi) O (xii)
OH
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [50]
OH
O A (Major)
Br 2/H2
238. Br /C
2 S 2
B (Major)
Calculatge (X + Y) where X = number of bromine atoms in A, Y = number of bromine atoms in B.
239. How many atoms groups withdraw the electrons from benzene ring ?
(a) – NO2 (b) – CN (c) – CO2H (d) –CHO (e) –Et (f) –SO3H (g) –N(CH3)2 (h) – N+(CH3)3
Y Ph – NH – NH2
Glucosazone
CHO
H OH
241. HO H
(Ac)2O
H OH
H OH
OH
In above reaction, identify moles of (Ac)2O consumed
O
CO2H
H3O LiAlH4 Dil.KMnO4
245. CO2H (B) HCN (C) (D) (E) (F)
excess
(A)
Find the total number of –OH group present in compound (F) ?
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [51]
CO2H
Br2
246. (A) Meso
CCl4
HO2C
O3 Ca(OH)2 EtOH(excess)
247. (B) (C) (D)
H2O2
/H
(A)
x = Number of ether functional group in compound (D)
y = Moles of NaHCO3 reacts with compound (B).
Find sum of x + y = ?
O3 H2/Pd–C Cl2/h
248. (A) KOH/ (B) (C) Se (D) Zn (E) (F)
CH3–S–CH3 (excess)
aq.KOH
(G)
(1) NaOH(CaO),
(2) H
(H)
O O O O O
249. R–C–O–R, R–CN, R – C – NH2 , R – C – Cl , CH3–C–O–C–CH3 , CH3 – O – CH3
(a) (b) (c) (d) (e) (f)
x = Number of compound reacts with LiAlH4 to give alcohol
y = Number of compound reacts with undergo alkaline hydrolysis
Find the value of x + y – 7 ?
250. Amongst the following, the total number of compound soluble in aqueous NaOH is :
OH OH COOH OH
CH3
NO2 COOH O
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [52]
251. How many compound given below are O/P directors ?
OH NO2 OCH3 CH3
252. Number of isomeric alcohols having molecular formula C4H10O which can be prepared by hydrogenation of
carbonyl compound (aldehyde and ketone). (Include stereo isomers)
NH2
(i)
CHO
254. Ac2O, 2CH3MgBr
– (B) H (C) (D)
AcO /
OH
(A)
Total number of alcohol group in compound (D) ?
O
O O
LiAlH4 xAc 2O
255. (A) (B)
256. x = no. of compound which reacts with excess of CH3MgBr to form 3° alcohol.
O O
(a) (b) O (c) (d)
O OEt
O O O
(e) H – C – OEt (f) Ph – C – Cl (g) H – C – Cl (h) CH3 – C N
O
(i) EtO – C – OEt
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [53]
+2 –
Hg LiAlH4 O3 D2O/DO ND2–OD/
258. C CH (B) (C) H / (D) (E) (G) (F)
(A) H 2 SO 4 Zn Prolonged
Number of deuterium in F is (x).
OH
Br
260. (a) Br2 + h Total number of dibromo products (only structural) = (X)
Cl2/h
(b) Total number of monochloro products (only structural) = (Y)
Sum of (X + Y) = ?
261. Total number (X + Y) of chiral centres in aldopentose (X) and ketopentose (Y) are :
262. x = no. of compound reacts with Na/Liq. NH3 to from trans alkene
Ph Ph Ph
263. O COOC2H5
When the above molecule is reduced with excess LiAlH4 followed by dilute acid hydrolysis, how many
organic products can be isolated by fractional distillation of product mixture.
264. How many following compound can give precipitate of iodoform by reacting with NaO
OH
O O
(a) CH3 – CH2 – C – CH2 – C – CH2 – CH3 (b) (c)
O O HO OH
(d) CH2 – CHO (e) CH3 – CH2 – OH (f) CH3 – CH – CH2 – CH3
Cl
O O
(g) Ph – CH 2 – C – CH 3 (h) CH 3 – C – NH – Et
265. HBr (X) alc.KOH (Y) , Identify the number of E2 product in 'Y'.
major product
266. A compound (A) C4H10O4 yields on acetylation (B) of formula C12H18O. How many hydroxyl groups are
present in compound ? Also write structures of (A) and (B).
267. Number of isomeric alcohols of C5H12O which do not show oxidation with KMnO4.
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [54]
H 2SO 4
268. x
x = number of possible alcohol.
O–Ph
269. OH
x HI
OH
OH
270. A decapeptide (Mol. wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and phenylalanine.
Glycine contributes 47.0% to the total weight of the hydrolysed products. The number of glycine units
present in the decapeptide is :
271. When the following aldohexose exists, the total number of stereoisomers in its furanose form having
D-configuration are :
CHO
CH2
CHOH
CHOH
CHOH
CH2OH
272. A tetrapeptide is formed by four different amino acids (G,A,V,L). If one of the amino acids always occupy the
ends of the peptide, how many sequence of tetrapeptide are possible ?
273. State the number of compounds which are aromatic among the following compounds :
H H H H
H H H H H H
H H
H H
B B H
(e) H – H (f) H H (g) H (h)
H H H H
H H
H H
(i) (j)
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [55]
274. (A) + Ac2O (B)
mol.wt(x) (acetic anhydride) mol.wt = (x+210)
Number of (OH) group present in (A) is
15 15
CONH2 CONH2 CONH2
14
275.
+ + Br2
Product(s)
KOH/
D
D
Can be
15 15 15 15
NH2 NH2 NH2 NH2 NH2 NH2 NH2 NH2 NH2
14 14 14 14
D D D D D
D D D (4) (5) (6) (7) (8) (9)
(1) (2) (3)
276. The total number of hydrogens that can be anti-periplanar to bromine (the leaving group)
Br
H
277. How many carbonyl compound will give aldol condensation reaction
O
CHO
(d) CH3 – CH2 – CHO (e) CH3 – CH2 – C – CH3 (f)
O
278.
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [56]
279. P = Number of anti-aromatic compound :
CH3
O
N
N O
, , CH3COOH , CH3SO3H
NO2
Sum of (P + Q + R + S + T) – 15 is :
280. Among the six possible structural isomers of molecular formula C6H12 (containing cyclopropane ring), total
number of structures that are capable to show Geometrical isomers are x. Find x?
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [57]
Answer Key
Single Correct Choice Type :
1. D 2. D,E 3. B 4. E 5. A 6. D 7. B
102. A,C 103. A,C,D 104. A,B 105. A,B,C,D 106. A,B,C,D
107. A,C,D 108. A,D 109. A,B,C 110. B,D 111. A,C,D
Comprehension
117. A 118. C 119. C 120. A 121. B 122. B 123. C
166. C
169. A – Q, T ; B – R, ; C – S ; D – P
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [58]
171. A – R,S; B – P,Q,S ; C – R,S ; D – T
173. (A - Q) ; (B - R) ; (C - P) ; (D - P)
174. A – Q, T ; B – P, S ; C – R, S ; D – R, S
175. A Q, R ; B P ; C S ; D P
176. A Q ; B R ; C P ; D S
177. A Q ; B P ; C R ; D S, Q
178. A S, T ; B P ; C Q, R, S ; D P, S
179. A–Q;B–S;C–R;D–P
181. A
Subjective
183. 4 184. 4 185. 3 186. 5 187. a = 6, b = 4, c = 8 188. 6
Vibrant Academy (I) Pvt. Ltd. "B-41" Road No.2, IPIA, Kota (Raj.) Ph. 06377791915 (www.vibrantacademy.com) [59]