Unit-12-Aldehydes, Ketones-MCQ

Unit-12 : Aldehydes, Ketones and Carboxylic Acids
MULTIPLE CHOICE QUESTIONS
1. Which product is formed when CHO is treated with concentrated

KOH solution?
+ –______
KO -CHO
(a)
-CH2—OH
– +
(b) COO K +
(c) K+O– -COO–K+ + K+O– O –K +
(d) – +
COO K + OK
– +

2. CH —CH —CCH 4  
0% H 2SO4
 A i   CH3—C—CH3
somerism
3 2 1%HgSO4
O
Structure of ‘A’ and type of isomerism in the above reaction are respectively
(a) Prop-1-en-2-ol, metamerism (b) prop-1-cn-ol, tautomerism
(c) prop-2-en-2-ol, geometrical (d) prop-1-en-2-ol, tautomerism
3. Compound A and C in the following reaction are ............
CH CHO  (    A HS
i)CH MgBr O
 B H
3

ydroboration
2
 C 4
3 (ii)H2O  Oxidation
(a) identical (b) position isomer

(c) functional isomer (d) optical isomer
4. The most suitable reagent for the following conversion?
O O
CH3—CH==CH—CH2—C—CH3 CH3—CH==CH—CH2—C—OH
(a) Tollen's reagent (b) Benzoyl peroxide
(c) I2 and NaOH solution (d) Sn and NaOH solution
5. Toluene  KM
nO
 A S  B 
OCl 4

H lPd
 the product ‘C’ is:
2 2
BaSO 4
(a) C6H5 CH2—OH (b) C6H5CHO

(c) C6H5COOH (d) C6H5CH3
6. Increasing order of rate of HCN addition to compound (I-IV) is
(i) HCHO (ii) CH3COCH3
(iii) PHCOCH3 (iv) PHCOPH
(a) iv < ii < iii < i (b) iv < iii < ii < i
(c) iii < iv < ii < i (d) i < ii < iii < iv
7. Among the following which has the lowest pka value:
(a) CH3COOH (b) HCOOH
(c) (CH3)2CHCOOH (d) CH3—CH2—OH
8. The correct order of acidity in given compounds
(i) FCH2COOH (ii) ClCH2COOH
(iii) NO2CH2COOH (iv) CH3COOH
(a) i > ii > iii > iv (b) iv > iii > ii > i
(c) iii > iv > i > ii (d) iii > i > ii > iv
9. CH3CHO + HCHO  Heat

 A H  B the structure of ‘B’ is:
dilNaOH CN
HO 3
(a) CH2 CH—CH—COOH (b) CH2 CH—CH—OH

OH CN
(c) CH3—CH2—CH—COOH (d) CH3—CH—COOH
OH OH
10. The IUPAC nameof compound is:
O
O
H—C
(a) 2-Formylhex-2-ene-3-one (b) 5-methyl-4-oxo-hex-2-en-5-al

(c) 3-Oxo-2-methylhex-5-enal (d) 3-Oxo-2-methylhex-4-enal
+ –
[Ag(NH3)2 ] /OH
11. X Cu
573 K –
(C2H6O) OH
Y
Z
NH2NHCONH2
Identify X, A, Y, Z.
(a) A-methoxymethane, X-ethanol, Y-ethanoic acid, Z-semicarbazide
(b) A-ethanol, X-ethano, Y-but-z-enal, Z-semicarbazone
(c) A-ethanol, X-Acetaldehyde, Y-Butanone, Z-Hydroazone
(d) A-Methoxymethane, X-ethanoicacid, Y-acetate ion and Z-Hydrazine
12. Which of the following reactions will not result in the formation of carbon
carbon bond?
(a) Cannizaro's reaction (b) Wurtz reaction
(c) Friedel craft reaction (d) Reimer Tiemann reaction
13. Priopionic acid with Br2/P yields a dibromo product It’s structure will be:
Br Br
(a) CH3—CH2—CH—COOH (b) CH3— C—CH2COOH

Br Br
(c) CH3—CH2—COBr (d) CH3—CH—COOH
Br Br Br
14. Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam
and conc HCl is called:
(a) Dow process (b) Cope reduction
(c) Wolf-kishner reduction (d) Clemmenson’s Reduction
15. Acetophenone when reacts with a base, yields a stable compound which has
the structure:
CH3 CH3
CH—CH2—C
(a) (b) CH—CH2—C
CH3 O OH OH
(c) CH—CH (d) CH==CH—C
OH OH CH3 OH O
16. Which of the following compound do not undergo aldol condensation

(a) CH3—CHO (b) C6H5—CHO
O CH3
(c) CH3—C—CH3 (d) CH3—C—CHO
CH3
O
17. The treatment of compound Ph—O—C—Ph with NaOH yields.

(a) Phenol (b) Sodium phenoxide
(c) Sodium benzoate (d) Benzophenone
18. Which of the following conversion can be carried out by demmensen
reduction
(a) Benzaldehyde to benzyl alcohol (b) Cyclohexanone to cyclohexane
(c) Benzoylchloride into benzaldehyde(d) Benzophenone to diphenyl methane
19. Through which of the following reaction number of carbon can be increased
in the chair?
(a) Grignard reagent (b) Cannizaro reaction
(c) Aldol condensation (d) HVZ reaction
20. Benzophenone can be obtained by ..............
(a) Benzoyl chloride + Benzene + anhy. AlCl3
(b) Benzoyl chloride + Diphenylanion
(c) Benzoyl chloride + Phenyl magnesium chloride
(d) Benzene + carbon monoxide + ZnCl2
Assertion Reason Type Questions

The question given below consist of an Assertionand the Reason. Use the following key
to choose the appropriate answer.
(a) Assertion and reason both are CORRECT and reason is the CORRECT
explanation of the assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Assertion and reason both are correct statements but reasson is not correct
explanation of assertion.
21. Assertion : Formaldehyde is a planar molecule.
Reason : It contains sp2 hybridised carbon atom.
22. Assertion : The -hydrogen in carbonyl group is less acidic.
Reason : The anion formed after loss of a—H atom is resonance stabilised.
Matching Column Type

23. Match the reactions given in Column I withthe suitable reagents given in
Column II.
Column-I Column-II
(A) Benzophenone  Diphenylmethane (i) LiAlH4
(B) Benzaldehyde  1-Phenylethanol (ii) DIBAL—H
(C) Cyclohexanone  Cyclohexanol (iii) Zn(Hg)/Conc. HCl
(D) Phenyl benzoate  Benzaldehyde (iv) CH3MgBr
24. Match the example given in Column I with the suitable reagents given in
Column II.
Column-I Column-II
O O
Pd-C/BaSO4
(A) CH2—C—Cl + H2 CH3—C—H (i) Friedel Craft acylation
– +
CHO CH2OH COO Na
NaOH
(B) + (ii) HVZ reaction
CHO O C—CH3
AlCl3
(C) + CH3—C—Cl (ii) Aldol condensation
(D) R—CH2—COOH  B   R—C—COOH (iii) Cannizaro's reaction

r2 / Re d P
CH3
(E) CH  CN     CH CHO
( i) SnCl2 /HCl
(v) Rosenmund's reduction
3 (ii) H2O/OH+ 3
(F) aO
2CH3CHO  N H
 CH —CH==CHCHO (vi) Stephen's reaction

Unit-12-Aldehydes, Ketones-MCQ

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Unit-12 : Aldehydes, Ketones and Carboxylic Acids

MULTIPLE CHOICE QUESTIONS

1. Which product is formed when CHO is treated with concentrated

(c) K+O– -COO–K+ + K+O– O –K +

(a) identical (b) position isomer

(a) C6H5 CH2—OH (b) C6H5CHO

9. CH3CHO + HCHO  Heat

(a) CH2 CH—CH—COOH (b) CH2 CH—CH—OH

(a) 2-Formylhex-2-ene-3-one (b) 5-methyl-4-oxo-hex-2-en-5-al

(a) CH3—CH2—CH—COOH (b) CH3— C—CH2COOH

(c) CH—CH (d) CH==CH—C

16. Which of the following compound do not undergo aldol condensation

17. The treatment of compound Ph—O—C—Ph with NaOH yields.

Assertion Reason Type Questions

Matching Column Type

(D) R—CH2—COOH  B   R—C—COOH (iii) Cannizaro's reaction

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