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Unit-12-Aldehydes, Ketones-MCQ
Unit-12-Aldehydes, Ketones-MCQ
(d) – +
COO K + OK
– +
2. CH —CH —CCH 4
0% H 2SO4
A i CH3—C—CH3
somerism
3 2 1%HgSO4
O
Structure of ‘A’ and type of isomerism in the above reaction are respectively
(a) Prop-1-en-2-ol, metamerism (b) prop-1-cn-ol, tautomerism
(c) prop-2-en-2-ol, geometrical (d) prop-1-en-2-ol, tautomerism
3. Compound A and C in the following reaction are ............
CH CHO ( A HS
i)CH MgBr O
B H
3
ydroboration
2
C 4
3 (ii)H2O Oxidation
CH3—CH==CH—CH2—C—CH3 CH3—CH==CH—CH2—C—OH
(a) Tollen's reagent (b) Benzoyl peroxide
(c) I2 and NaOH solution (d) Sn and NaOH solution
5. Toluene KM
nO
A S B
OCl 4
H lPd
the product ‘C’ is:
2 2
BaSO 4
11. X Cu
573 K –
(C2H6O) OH
Y
Z
NH2NHCONH2
Identify X, A, Y, Z.
(a) A-methoxymethane, X-ethanol, Y-ethanoic acid, Z-semicarbazide
(b) A-ethanol, X-ethano, Y-but-z-enal, Z-semicarbazone
(c) A-ethanol, X-Acetaldehyde, Y-Butanone, Z-Hydroazone
(d) A-Methoxymethane, X-ethanoicacid, Y-acetate ion and Z-Hydrazine
12. Which of the following reactions will not result in the formation of carbon
carbon bond?
(a) Cannizaro's reaction (b) Wurtz reaction
(c) Friedel craft reaction (d) Reimer Tiemann reaction
13. Priopionic acid with Br2/P yields a dibromo product It’s structure will be:
Br Br
OH OH CH3 OH O
CH3
O
NaOH
(B) + (ii) HVZ reaction
CHO O C—CH3
AlCl3
(C) + CH3—C—Cl (ii) Aldol condensation
CH3
(E) CH CN CH CHO
( i) SnCl2 /HCl
(v) Rosenmund's reduction
3 (ii) H2O/OH+ 3
(F) aO
2CH3CHO N H
CH —CH==CHCHO (vi) Stephen's reaction