Tehnologia Hlsmelt
Tehnologia Hlsmelt
The HIsmelt Process has its origins in the early Having successfully demonstrated the commercial
1980’s when Rio Tinto Limited identified the viability of the technology, the HRDF was put
potential to adapt the high scrap rate steelmaking under care and maintenance in mid 1999. The plant
and iron bath coal gasification processes developed has been partially demolished in preparation for the
by Klockner Werke to the direct smelting of iron construction of the Kwinana Commercial HIsmelt
ore.(3) Development of the HIsmelt Process Plant. The same location will be used to take
commenced with a 60 tonne K-OBM converter. advantage of some of the existing infrastructure.
After successfully proving the concept, a small
scale pilot plant was constructed and operated at The HIsmelt Process
Maxhutte Works in Germany. The plant design was
based on an enclosed horizontal vessel to overcome HIsmelt is an air based direct smelting technology
process containment issues experienced in the 60 which is simple yet innovative. The HIsmelt
tonne converter trials. process is illustrated in Figure 1. The process
occurs within a vertical Smelt Reduction Vessel
Following the successful conclusion of these trials (SRV) under pressure. The vessel is refractory
the HIsmelt Research and Development Facility lined within the hearth and water cooled in the top-
(HRDF) was established in Kwinana, Western space. The refractory hearth contains the molten
Australia. The plant had a rated capacity of iron bath. A thick slag layer is situated above the
100,000 tpa and was a direct scale-up of the small metal bath. Iron ore fines, coal and fluxes are
scale pilot plant. The principle objective of the injected directly into the melt in the SRV. Upon
HRDF was to demonstrate scale-up of the core contact with the iron bath, dissolution of the carbon
plant (process and engineering) and provide in the coal occurs, which reacts with the oxides in
operating data for commercial evaluation of the the iron bearing feeds, forming carbon monoxide.
technology. Rapid heating of the coal also results in cracking of
the coal volatiles releasing hydrogen.
Whilst the process scale-up was successfully HOT AIR BLAST
demonstrated, the complexity of the engineering, 1200 C
(OXYGEN ENRICHED)
poor plant availability and difficult operational
requirements brought into question the commercial
viability of the plant design. After three years of
operation the plant was substantially reconfigured
WATER-COOLED
to address these issues. The horizontal Smelt PANELS IN TOPSPACE OFFGAS
some preheating, pre-reduction and/or calcination operating campaigns. The longest of these
of the metallic feed and fluxes. Then the offgas is was a 38 day run during which 99.8%
cleaned in a scrubber and used as fuel for the hot plant availability was achieved.
blast stoves or in a co-generation plant.
(2) Production capabilities have been assessed
The vessel is equipped with a forehearth for across the full range of ferrous feed
continuous tapping of hot metal. This maintains a reduction levels from hematite ores
optimum bath level within the SRV and provides a through to DRI feed. Intermediate levels
clean product stream without the need for external of pre-reduction were tested by blending
slag and metal separation. Slag is tapped ore fines with DRI. Oxygen enrichment
periodically through a water cooled notch. of the hot air blast (up to 30% oxygen
content), has been successfully utilised to
HIsmelt has a number of unique features that sets increase the operating intensity of the
it apart from the other direct smelting processes. vessel, resulting in the expected increases
Firstly, HIsmelt uses the metal bath as the primary in productivity.
reaction medium. Other direct smelting processes
generally top-feed ore and coal, with smelting via (3) Extended pilot plant operation with high
char (plus a small amount of metal) in the slag post combustion (PC) and low coal
layer. Dissolved carbon in metal is a more readily consumption has been demonstrated
available reductant than char in slag, since the latter repeatedly. PC in the range of 60-80%
requires a gas-phase intermediate (CO). In other has been achieved routinely and, with cold
words, HIsmelt achieves significantly faster iron ore fines as ferrous feed, coal rates of
smelting rates by using carbon in a more active (i.e. around 880 kg per tonne of hot metal
dissolved) form. (kg/thm) have been recorded. This
translates to a coal rate of 600-620 kg/thm
A second differentiating factor is the degree of for a scaled-up plant with an ore
mixing in the melt. Injecting feed materials preheater.
directly into metal generates a large volume of
“deep” gas. This creates a strong buoyancy-driven (4) A significant portion of the pilot plant
upward plume that in turn causes rapid turnover of operation utilised ore fines with a high
liquid. It has been calculated that this turnover is phosphorus content (0.12% P). The
in the order of tonnes per second. Under these phosphorus removal capability of the
conditions there is very little potential for process has been readily demonstrated
establishing significant temperature gradients with an average of 85-95% of the
(greater than 20-30 oC) in the liquid phase and the phosphorus input reporting to the slag
system operates with an (essentially) isothermal phase.
melt. The rapid mass turnover promotes good heat
transfer from the top space to the bath without (5) Typical steelplant waste materials have
significant over-heating of individual liquid also been successfully utilised. A mixture
droplets. Implications are significant for hearth of blast furnace and LD dusts and sludges,
refractories in the slag-line region, since good millscale, pellet fines and casthouse dusts
mixing leads to the bricks being exposed to low were blended with ore fines and injected
FeO and uniform (low) temperature. without any need for feed agglomeration.
These trials resulted in the expected
HRDF Operations increase in productivity and reduction in
coal consumption. Dust losses were not
The major achievements of the Kwinana HIsmelt increased, achieving iron unit yields of
Research and Development Facility during the greater than 97% which was similar to the
vertical vessel phase of the development were: operation using ore fines. The zinc and
lead components of the waste materials
(1) The Kwinana plant was run cumulatively were found to partition to the dust,
for over 3000 hours (132 days). Total suggesting that reasonably high levels of
metal production was around 22100 zinc and lead can be accommodated and
tonnes, together with 8600 tonnes of slag. potentially recovered. In a commercial
A total of 63000 tonnes of solids facility, these waste materials have a high
(primarily ore, coal and flux) was injected value, reducing coal consumption to less
through the two injection lances. Plant than 650kg/thm without the need for
availability in excess of 99% was preheat.
demonstrated in several continuous
SMELTING REDUCTION FOR IRONMAKING, Bhubaneswar (18 - 19 December 2002) 4
(6) The range of coal types used has allowed implying hearth refractory life well in
their impact on process performance to be excess of 1 year.
quantified. Coals with higher volatile
contents have the expected negative (8) No water leaks have occurred and no
impact on production as a result of the repairs have been required on any of the
energy loss due to gasification and water cooled elements in the Smelt
cracking of the volatile components. Reduction Vessel.
Other potential production impacts from
coal, oxygen, moisture and ash content (9) Handling of hot process offgas in a
have been examined and the findings membrane-type hood has been
accounted for in commercial flowsheeting. demonstrated over a period of 1100
All coal used have exhibited an ability to operating hours. Results show that,
be used in the process and coal selection despite the steady-state nature of the
remains an economic decision. (Table 2). HIsmelt process, the hood readily comes
Throughout these trials, the plant to equilibrium in terms of accretion
produced a consistently high quality hot behaviour. Operation is simple and self-
metal (see Table 3). regulating, requiring little or no operator
intervention.
Ferrous Fe (T) Fe (Met) C Silica +
Materials Alumina Kwinana Commercial HIsmelt Plant
Hamersley – 61.0 % 7.5 %
DSO Fines
(0.075% P)
The outstanding success of the HRDF operation
Hamersley - 62.4 % 5.6 % convinced Rio Tinto Limited to pursue the
Brockman Fines commercial realisation of the HIsmelt Process. In
(0.12%P) 2002 an unincorporated joint venture was formed
DRI 90.5 % 84.2 % 5.5 % between subsidiaries of:
Steelplant Wastes 53.3 % 10.1 % 5.5 %
Coals Fixed Volatiles Ash CV
C • Rio Tinto Limited;
Coal A 73.2 % 9.8 % 12.0 % 28.3 GJ/t • Nucor Corporation;
Coal B 69.3 % 16.8 % 6.9 % 30.5 GJ/t • Mitsubishi Corporation; and
Coal C 68.8 % 25.7 % 4.8 % 32.9 GJ/t • Shougang Corporation;
Coal D 49.9 % 38.5 % 9.4 % 30.2 GJ/t
Conclusion
References