DAY SIX UNIT TEST 1 (General Chemistry) 61

DAY SIX

Unit Test 1
(General Chemistry)
1 Correct set of four quantum numbers for valence electron 8 Hybridisation of the nitrogen atom and electronic
of rubidium (Z = 37) is geometry around nitrogen atom in pyridine is
1 1 (a) sp 3 , pyramidal (b) sp 2 , trigonal planar
(a) 5, 0, 0, + (b) 5, 1, 0, +
2 2 (c) sp 2 , linear (d) sp 3 , tetrahedral
1 1
(c) 5, 1, 1, + (d) 6, 0, 0, +
2 2 9 The geometry of H 2S and its dipole moment are
(a) angular and non-zero (b) angular and zero
2 Four diatomic species are listed below in different (c) linear and non-zero (d) linear and zero
sequences. Which of these represents the correct order
of their increasing bond order? 10 For CO, isotherm is of the type as shown. Near the point
(a) O−2 < NO < C22 −< He2+ (b) NO < C22 − < O2− <
He2+
A, compressibility factor Z is
(c) C22 − < He2+ < NO < O2− (d) He+2 < O2− < NO < C22 − CO
B Ideal
3 The de-Broglie wavelength of an electron accelerated by pV
A
a potential difference of ‘V ’ volts is given by the relation
12.28 12.28
(a) Å (b) cm p
V V
12.28 12.28 b b a a
(c) m (d) Å (a) 1 + (b) 1 − (c) 1 + (d) 1 −
V V V V RTV RTV

4 Number of spectral lines of Lyman series of electron 11 If Na + ion is larger than Mg 2+ ion and S 2− ion is larger
than Cl − ion, which of the following will be stable in water?
when it jumps from 6 to first level (in Lyman series) is
(a) 9 (b) 12 (c) 15 (d) 18 (a) Sodium chloride (b) Sodium sulphide
(c) Magnesium chloride (d) Magnesium sulphide
5 The equivalent weight of a solid element is found to be 9.
12 Which of the following is paramagnetic?
If the specific heat of the element is 1.05 J g −1 K −1, then
(a) CO 2 (b) NO (c) O 2–
2 (d) CN–
its atomic weight is
(a) 17 (b) 21 (c) 25 (d) 27 13 Which of the following is correct order of bond angle x
and y ?
6 The first line in the Balmer series in the H-atom will have
the frequency. H H
14 –1 15 –1
O O
(a) 4.56 × 10 s (b) 3.29 × 10 s O O
(c) 8.22 × 1015 s –1 (d) 8.05 × 1013 s –1 H x F y
7 The orbital angular momentum of an electron in 2s orbital (a) x > y (b) y > x
is (c) x = y (d) None of these
1 h
(a) ⋅ (b) zero 14 The number of antibonding electron pairs in O 22– ion, on
2 2p
h h the basis of MO theory is
(c) (d) 2⋅
2p 2π (a) 4 (b) 3 (c) 2 (d) 5
62 40 DAYS ~ NEET CHEMISTRY DAY SIX

15 Consider the following changes, 24 The root mean square velocity of hydrogen is 5 times
A → A+ + e − ; E1 and A+ → A 2+ + 2e – ; E2 than that of nitrogen. If T is the temperature of the gas,
then
The energy required to pull out the two electrons are E 1
(a) TH 2 = TN 2 (b) TH 2 > TN 2
and E 2 respectively. The correct relationship between
two energies would be (c) TH 2 < TN 2 (d) TH 2 = 7 TN 2
(a) E1 < E 2 (b) E1 = E 2 (c) E1 > E 2 (d) E1 ≥ E 2 25 0.16 g of a substance on vaporisation displaces 26.2 mL
16 Which of the following statement is correct regarding of moist air at 17°C and 764 mm. Weight of substance at
BeCl2? STP is (aqueous tension at 17°C = 14 mm)
(a) It violates octet rule and has sp 2 -hybridisation (a) 37.11 (b) 41.56 (c) 73.62 (d) 79.12
(b) It has sp-hybridisation and follow octet rule 26 Carbon disulphide is an example of
(c) It violates octet rule and has linear structure
(a) ionic liquid (b) H-bonded liquid
(d) All of the above
(c) polar liquid (d) non-polar liquid
17 Cortisone is a molecular substance containing 21 atoms
27 An ideal gas obeying kinetic gas equation can be
of carbon per molecule. The mass percentage of carbon
liquefied if
in cortisone is 69.98%. Its molar mass is
(a) its temperature is more than critical temperature
(a) 176.5 (b) 252.2 (c) 360.1 (d) 287.6
(b) its pressure is more than critical pressure
18 An inorganic substance has the following composition. (c) its pressure is more than critical pressure but
N = 35%, H = 5% , O = 60% temperature is less than critical temperature
On being heated, it yielded a gaseous compound (d) it cannot be liquefied at any value of p and T
containing N = 63 . 63% and O = 36. 37%. Which of the
following reaction can be suggested based on the given
28 Four elements A, B, C, D have atomic numbers
data? Z − 1, Z + 1, Z − 2 and Z + 2 respectively. If Z is 9 then
(a) 2HNO 3 → N2O 5 + H2O
bond between which pair of elements will be ionic?
(b) NH2OH + HONO → N2O + 2H2O (a) A and C (b) D and C
(c) NH4NO 3 → N2O + 2H2O (c) D and B (d) B and C
(d) 2HNO 3 → N2O 3 + H2O 29 Specific volume of cylindrical virus particle is
19 A metal forms two oxides. The higher oxide contains 6.02 × 10−2 cc/g whose radius and length are 7 Å and
20% oxygen, while 4.29 g of lower oxide when converted 10 Å respectively. If NA = 6. 02 × 10 23, find molecular
to higher oxide becomes 4.77 g. The equivalent weight of weight of virus
metal in the two oxides lower and higher respectively are (a) 15.4 kg/mol (b) 1.54 × 104 kg/mol
(a) 32 and 48 (c) 3.08 × 104 kg/mol (d) 3.08 × 10 3 kg/mol
(b) 48 and 32 30 In PO 3−
4 ion, the formal charge on the oxygen atom of
(c) 64 and 32
P − O bond is ª NCERT Exemplar
(d) same equivalent weight for both, i.e. 32
(a) +1 (b) –1 (c) – 0.75 (d) + 0.75
20 50 mL of 10 N H2SO4, 25 mL of 12 N HCl and 40 mL of
31 If the electron falls from n = 3 to n = 2 in hydrogen atom
5 NHNO3 were mixed together and the volume of the
then emitted energy is
mixture was made 1000 mL by adding water. The
(a) 10.2 eV (b) 12.09 eV
normality of the resultant solution will be
(c) 1.9 eV (d) 0.65 eV
(a) 1 N (b) 2 N (c) 3 N (d) 4 N
32 Molecular shapes of SF4, CF4 and XeF4 are
21 The equivalent weight of an element is 4. Its chloride has
(a) the same with 2, 0 and 1 lone pair of electrons
VD 59.25. Then the valency of the element is
respectively
(a) 4 (b) 3 (c) 2 (d) 1
(b) the same with 1, 1 and 1 lone pair of electrons
22 Group 15th of the periodic table consists of the elements respectively
N, P, As, Sb and Bi. On moving from N to Bi, the oxides (c) different with 0, 1 and 2 lone pairs of electrons
of the elements of general formula M 2O 3 become respectively
(a) stronger reducing agent (b) more ionic (d) different with 1, 0 and 2 lone pairs of electrons
(c) more volatile (d) more basic respectively

23 Inhaled air contains O 2 at a pressure of 160 torr. The 33 Arrange S, O and Se in the ascending order of electron
capacity of a human lung is about 3.0 L. Body temperature affinity
is 37°C. The mass of O 2 filling a lung upon respiration is (a) Se < S< O (b) Se < O < S
(a) 8 g (b) 0.80 g (c) 16 g (d) 0.16 g (c) S < O < Se (d) S < Se < O
DAY SIX UNIT TEST 1 (General Chemistry) 63

34 Gradual addition of electronic shells in the noble gases 3. equivalent mass of its hydride is 13
causes a decrease in their 4. molar mass of its hydride is 25
(a) ionisation energy (b) atomic radius
39 Match the type of bond (given in Column I) with method
(c) boiling point (d) density
of formation (given in Column II) and choose the correct
35 V vs T curves at different pressures p1 and p2 for an ideal option from the codes given below.
gas (are shown below)
p1 Column I Column II

A. BCl 3 1. Linear
p2 2−
V B. [PdBr4 ] 2. Planar triangular

C. SF6 3. Tetrahedral
T
D. I−3 4. Octahedral
Which one of the following is correct?
p2 1 5. Square planar
(a) p1 > p2 (b) p1 < p2 (c) p1 = p2 (d) =
p1 2
The correct match is
36 Elements X, Y and Z have atomic numbers 19, 37 and 55 A B C D A B C D
respectively. Which of the following statement is true (a) 2 3 4 1 (b) 5 3 2 1
about them? (c) 2 5 4 1 (d) 5 4 3 2
(a) Their ionisation potential would increases with
Direction (Q. Nos. 40-41) Each of these questions
increasing atomic number
contains two statements : Assertion and Reason. Each of
(b)Y would have an ionisation potential between those X these questions also has four alternative choices, only one of
and Z which is the correct answer. You have to select one of the
(c) Z would have the highest ionisation potential codes (a), (b), (c) and (d) given below.
(d)Y would have the highest ionisation potential (a) Assertion is true, Reason is true; Reason is the correct
explanation for Assertion
Direction (Q. Nos. 37-38) In the following questions more
(b) Assertion is true, Reason is true; Reason is not the
than one answers given may be correct. Select the answers
correct explanation for Assertion
and mark it according to the codes.
(c) Assertion is true, Reason is false
Codes
(d) Assertion is false, Reason is true
(a) 1, 2 and 3 are correct (b) 1 and 2 are correct
(c) 2 and 4 are correct (d) 1 and 3 are correct 40 Assertion Most probable velocity is the velocity
37 Select the correct statement(s) about C 4− ion. possessed by maximum fraction of molecules at the
3
1. It reacts with H2O forming C3H6 same temperature
2. It reacts with H2O forming C3H4 Reason On collision, more and more molecules acquire
higher speed at the same temperature.
3. It has three sigma and one pi bonds
4. It has two sigma and two pi bonds 41 Assertion Compressibility factor for hydrogen varies with
pressure with positive slope at all pressures.
38 A bivalent metal ion has equivalent mass of 12. Then,
Reason Even at low pressure, repulsive forces dominates
1. equivalent mass of its oxide is 20
in hydrogen gas.
2. molar mass of its oxide is 40

ANSWERS
1 (a) 2 (d) 3 (a) 4 (c) 5 (d) 6 (a) 7 (b) 8 (b) 9 (a) 10 (d)
11 (d) 12 (b) 13 (a) 14 (a) 15 (a) 16 (c) 17 (c) 18 (c) 19 (c) 20 (a)
21 (b) 22 (d) 23 (b) 24 (c) 25 (c) 26 (d) 27 (d) 28 (b) 29 (a) 30 (c)
31 (c) 32 (d) 33 (b) 34 (a) 35 (a) 36 (b) 37 (d) 38 (a) 39 (c) 40 (a)
41 (b)