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Hopper-Like Single Crystals of Sodium Chloride Grown at The Interface of Metastable Water Droplets
Hopper-Like Single Crystals of Sodium Chloride Grown at The Interface of Metastable Water Droplets
DOI: 10.1002/ange.201101704
Crystal Growth
Angewandte
Chemie
6168 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Angew. Chem. 2011, 123, 6168 –6171
Angewandte
Chemie
Intrinsic shapes of inorganic crystals are produced under collected by the removal of supernatant. The identical
equilibrium thermodynamic and kinetic conditions, which is procedure was also used for the preparation of KCl crystals.
due to the relative order of surface energy at different The structure and composition of the products, confirmed
crystallographic planes.[1] During the evolution in shapes, the by means of X-ray diffraction (XRD) measurement, are face-
lower-energy planes grow while the higher energy planes centered cubic NaCl with phase purity (JCPDS, 89-3615;
disappear, and this process can be modified when the surface Supporting Information, Figure S1). The NaCl precipitates
energy at certain plane is altered or the growth along certain consist of microparticles, most of which are in the size range
direction is hindered.[2] Currently, organic ligands or additives 10–40 mm, as revealed by scanning electron microscopy
have been widely used to control/tune the growth rate of (SEM; Figure 1 a). Individual particles have a highly spherical
different planes in aqueous solutions for the formation of
various nanostructures and polyhedrons.[3–5] In combination
with the control of organic ligands/additives, interfacial
growth at air/liquid, liquid/liquid, or solid/liquid interfaces is
a promising alternative to complex heterogeneous and
hierarchical architectures.[6] Such results give us a general
impression that these approaches are successful in the control
of crystallographic morphology of water-insoluble com-
pounds, such as metals, oxides, sulfides, and insoluble
salts.[7–9] On the other hand, water-soluble salts as a large
family of inorganic compounds have recently been explored
for the production of heterogeneous crystalline shapes and
structures by controlling the evaporation of saturated aque-
ous solution, but their intrinsic crystal growth is hardly
changed.[10–13] The impressive structures/architectures have
rarely been reported.
Sodium chloride and potassium chloride are the most
representative examples of water-soluble salts that always
appear in the form of highly regular cubes in both natural and
artificial environments.[14, 15] A change in their intrinsic growth
nature for the production of other shapes and structures has Figure 1. a) Overview SEM image of NaCl spherulites with hollow
not yet been achieved, but is very important for the under- spherical architecture. The high-magnification SEM images (upper and
standing of growth mechanism of various crystals. Herein, we lower insets) show that the NaCl hollow microspheres are built up of
report the hopper-like single crystals of NaCl and KCl and blocks of cubic hopper-like single crystals. b) SEM images showing the
their self-assembly at interface of metastable water micro- sizes of hopper-like crystal blocks at hollow microspheres with differ-
droplets. In a typical experiment, cyclohexane (8 mL) was ent diameters. (See the text for further details.)
first mixed with acetone (20 mL) and then agitated for 30 min
at room temperature. A aqueous NaCl solution (1m, 7.5 mL) shape and hollow interior, thus suggesting the growth of NaCl
was subsequently injected into the above organic mixture at the interface between water microdroplets and the mixing
through a syringe pinhole (25 mm diameter) under vigorous organic phase. Surprisingly, cubic hopper-like single crystals
agitation. After 10 min, the white NaCl precipitates were appeared when one of the single microspheres was further
magnified (upper inset of Figure 1 a). The hollow micro-
spheres were completely built up of tens of uniform hopper-
like single crystals with a size of about 10 mm. With a further
[*] J. Zhang, Dr. S. Zhang, Dr. Z. Wang, Prof. Dr. Z. Zhang, S. Wang, magnification, it can be clearly seen that every individual
Prof. Dr. S. Wang
crystal has one deep rectangle hole open toward the outside
Institute of Intelligent Machines, Chinese Academy of Sciences
Hefei, Anhui, 230031 (China) of the sphere, but the highly regular cubic shape with equal
Fax: (+ 86) 551-5591-156 dimensions and sharp edges is still maintained (as indicated
E-mail: [email protected] with arrows in the bottom inset of Figure 1 a). The same
[email protected] microspheres and hopper-like single crystals were also
J. Zhang, Prof. Dr. S. Wang observed for KCl (Supporting Information, Figure S2).
Department of Chemistry The hopper-like crystals have very similar size in an
University of Science & Technology of China identical hollow microsphere, but the building blocks at
Hefei, Anhui, 230026 (China)
different hollow microspheres have different sizes. As shown
[**] This work was supported by The National Basic Research Program
in Figure 1 b, the sizes of hopper-like crystal blocks are 10, 3.4,
of China (No. 2009CB939902), an Innovation Project of Chinese
Academy of Science (No. KJCX2-YW-H2O), and the National and 1.4 mm in three microspheres with diameters of 68, 23,
Natural Science Foundation of China (No. 51002159, 20925518, and and 10 mm, respectively. Because the sizes of water micro-
21075123). droplets dispersed in the organic phase have a relatively wide
Supporting information for this article is available on the WWW distribution, the larger interfacial area of large droplets must
under http://dx.doi.org/10.1002/anie.201101704. lead to the formation of more nuclei at this interface of
Angew. Chem. 2011, 123, 6168 –6171 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.angewandte.de 6169
Zuschriften
organic solvent/water. As NaCl concentration in all droplets is at this h001i direction. However, the growth of other {001}
the same, the density n of nuclei at the interfaces of different- planes and the {111} planes maintained the original growth
sized droplets is very similar. Thus, the size of single crystal rates. As a result, the cubic hopper-like single crystals and
block can be estimated as Vcrystal = (c (4/3)pR3)/1(n4pR2) = their uniform arrangement in the form of hollow micro-
cR/31n, where c, R, and 1 are the concentration of NaCl, the spheres were achieved.
radius of microdroplet, and the density of NaCl, respectively. Furthermore, the growth of the hopper-like crystals may
This equation reveals that the crystal blocks become smaller also be related to the diffusion rate of the ions and the growth
with the decrease of size of hollow microspheres. rate of the crystals based on the concentration gradient
The mechanisms of NaCl crystal growth and microsphere around the interface of metastable water microdroplets.
formation were proposed and further demonstrated by tuning Experimentally, the ions for crystal growth were continuously
the experimental conditions and monitoring the intermediate supplied from the water microdroplets. At the areas in/near
products (Figure 2). Detailed experiments reveal that the the water microdroplets, the rate of the ion diffusion is
relatively fast with respect to that of crystal growth, and the
concentration of ions is relatively uniform in/near the water
microdroplets. Growth takes place at the entire crystal
surfaces controlled by the crystal growth rate, giving rise to
a normal cube. At the areas far from the water microdroplets
(the faces of the crystals toward outside), the rate of diffusion
is relatively slow with respect to the growth rate, and the
growth becomes diffusion-limited.[9] The concentration of
ions is largely decreased close to the centers of the crystal
faces toward outside, which may lead to the preferential
growth of sidewalls and give rise to hopper-like crystals.
More experimental observations have been performed to
confirm the critical role of the nonpolar species in the
formation of hollow spherical structure and hopper-like NaCl
cube: a) when n-hexane replaced cyclohexane in the syn-
thesis, similar hopper-like NaCl cubes in the arrangement of
hollow microspheres were also obtained; b) the use of
n-pentanol, with a polar hydroxy group, led to the NaCl
cubes with a small/shallow pit open toward outside; c) when
cyclohexane was replaced by cyclohexylamine with basic
amino groups, hollow NaCl microspheres were produced, but
normal NaCl cubes rather than hopper-like ones were
Figure 2. Mechanisms for the formation of metastable water micro-
droplets, NaCl nucleation at the interface, and the growth process of
observed at the microspheres (Supporting Information, Fig-
cubic hopper-like single crystals. The SEM images (bottom) show the ure S5–S7).
time-dependent evolution of NaCl crystal morphology. The most direct evidence for the above growth process
was obtained by monitoring the evolution of intermediate
products by SEM (the bottom images of Figure 2). At the
absence of cyclohexane leads to the formation of normal initial stage (1 minute), hollow microsphere composed of
cubic NaCl crystallites, and neither hopper-like shape nor small regular NaCl cubes appeared. With the increase of
spherical architecture was observed (Supporting Information, growth period to 2.5 minutes, a single pit was formed on every
Figure S3), suggesting the crucial role of cyclohexane for the cubic block. Subsequently, the pits developed into larger and
formations of hollow spherical architecture and hopper-like deeper holes with the growth of NaCl cubes after 5 minutes.
single crystals. Cyclohexane is completely compatible with Finally, the hopper-like single crystals and their uniform
acetone, but incompatible with water (phase diagram in the arrangement in the form of hollow microsphere were formed
Supporting Information, Figure S4). On the other hand, (10 minutes). As another strong support, the hopper-like hole
acetone is compatible with water, and as such, the presence became smaller and smaller and finally disappeared with the
of cyclohexane can temporally stabilize the water micro- decrease of cyclohexane dose from 8 mL to 0.1 mL (Figure 3),
droplets by reducing the diffusion rate of acetone into water which further confirms the above growth mechanisms. More
droplets, as shown in Figure 2. Such formation of metastable experimental observations, including the effects of temper-
water microdroplets provides an unconventional environ- atures, are given in detail in the Supporting Information.
ment for the unique growth of hopper-like crystals. The slow In summary, we have developed a new strategy of
diffusion of acetone into water droplets results in the super- exploiting metastable water droplets to control the growth
saturation of NaCl and the initial nucleation at the surface of and assembly of water-soluble inorganic salts. The interfacial
water droplets. The NaCl nutrient from the water droplets is interaction between nonpolar species and crystal surface can
sustainably supplied for the uniform growth of NaCl single successfully change the growth nature of water-soluble salts,
crystals. Meanwhile, the cyclohexane molecules contacting and an unexpected structure and morphology was produced
with the (001) plane toward organic phase prevent the growth that had not previously been achieved by traditional
6170 www.angewandte.de 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Angew. Chem. 2011, 123, 6168 –6171
Angewandte
Chemie
.
Keywords: crystal growth · self-assembly · single crystals ·
sodium chloride · water droplets
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Angew. Chem. 2011, 123, 6168 –6171 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.angewandte.de 6171