Rits-21 1

Section – 1 CHEMISTRY
1. In the reaction, 4 A  2 B  3C  A4 B2C 3 . What will be the number of moles of product formed, starting from 1
mole of A,0.6 mol of B and 0.72 mol of C?
(A) 0.25 (B) 0.3 (C) 0.24 (D) 2.32
2. Kinetic energy and pressure of a gas of unit volume and unit mole are related as:
E 3 2
(A) P = 2E (B) P  (C) P  E (D) P  E
2 2 3
3. –1
The heat of formation of NO from its elements is +90 kJ mol . What is the approximate bond dissociation energy
of the bond in NO? Consider BEN  N  941 kJ mol 1 and BEO O  499 kJ mol 1
(A) 630 kJ mol 1 (B) 720 kJ mol 1 (C) 760 kJ mol 1 (D) 810 kJ mol 1
4. Consider the following reaction in which all the reactants and products are in the gaseous state.
2 PQ P2  Q2 ; K1  2.5  105
1 1 1
1 3
. The value of K3 for the equilibrium P2  Q2  R2 PQR is :
PQ  R2 PQR; K 2  5  10 2 2 2
2
(A) 2.5×10–3 (B) 2.5×103 (C) 1.0×10–5 (D) 5×103
5. What is the correct sequence of osmotic pressure of 0.01 M aqueous solution of?
1. Al2  SO4 3 2. K3 PO4 3. BaCl2 4.Urea
(A)  4   3   2   1 (B)  1   2   3   4 (C)  1   2   3   4 (D)  2   4   1   3
6. What will be the electrode potential at pH = 3, if the cell reaction involving quinhydrone electrode is:
(A) 1.48 V (B) 1.20V (C) 1.10 V (D) 1.30 V

7. Which of the following characteristics is not correct for physical adsorption?
(A)Adsorption is spontaneous (B) H & S are negative
(C)Its reversible in nature (D) Degree of adsorption increases with temperature
8. Which are the following pairs of species have identical shapes?
(A) NO2 & NO2 (B) PCl5 & BrF5 (C) XeF4 & ICl4 (D) TeCl4 & XeO4
9. Which of the following is arranged in order of increasing radius?
(A) K   aq   Na   aq   Li   aq  (B) Na   aq   K   aq   Li   aq 
(C) K   aq   Li   aq   Na   aq  (D) Li   aq   Na   aq   K   aq 
10. Metal M  air 


 A 
H 2O
 B HCl
 white fumes; Metal M can be:
(A) Li, Mg or Al (B) Li, Al or K (C) Na, K or Mg (D) Li, Na or K
Space for rough work
FIITJEELtd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
11. Among NH3, PH3, AsH3 and SbH3 which oneis a stronger reducing agent?
(A) NH3 (B) PH3 (C) AsH3 (D) SbH3
12. Which kind of isomerism is exhibited by octahedral Co  NH 3 4 Br2  Cl ?
(A) Geometrical and ionization (B) Geometrical and optical
(C) Optical and ionization (D) Geometrical only
13. Reddish brown (chocolate) precipitate is formed by mixing solutions containing:
3
(A) Cu 2 &  Fe  CN 6  ions (B) Cu 2 & Fe CN 6 ]4 ions (C) Pb2 & SO42 ions (D) Pb2 & I  ions
14. Consider the following reactions
(A) (B) (C) (D)
15.
Product (B) of the above reaction is :
(A) (B) (C) (D)
16.
(A) (B) (C) (D)
Faridabad (Delhi NCR)-FIITJEE Ltd., Sector-15A Market, Near Vidya Mandir Public School, Ajrounda Chowk, Faridabad Ph-0129-4174582
Website: www.fiitjee.com
17. What is the structure of L-glucose?
(A) (B) (C) (D) None of these
18.
End product (C) in above reaction is :
(A) (B) (C) (D)
19.
Select the suitable reagent for above conversion.

(A) CH 2 N 2 /  (B) CBr4 / RLi (C) H 2 C  CH 2 (D) t–BuOK
20.
(A) (C)
(C) (D)
INTEGER TYPE
1. A tetraprotic acid, H 4 X has Ka1  10 3 , Ka2  10 5 , Ka3  10 7 & Ka4  10 11 . 40 mL of the acid
solution which is 0.2 M was titrated with 0.1 M KOH solution using an indicator whose K in is 10 5 . The
ratio of the volume of H 4 X solution to volume of KOH solution needed for the end point will be?
2. At what pOH is the solubility of Zn(OH )2 minimum?
Given: Zn(OH )2 (s ) Zn 2  (aq )  2OH  (aq ) , K sp  1.2 x10 17
Zn(OH )2 (s )  2OH  Zn(OH )24  (aq ) , K = 0.13
3. A waxy crystallive solid(A) with a garlic odour is obtained by burning white P in a steam of air, (A)
reacts vigorously with hot water forming a gas (B) and an acid (C). Gas (B) has unpleasant odour of
rotten fish and is neutral towards litmus. When passed through CuSO4 solution gas (B) produced a
abc d
black ppt. (D). The number of atoms in A, B, C, and D are a, b, c and d respectively. Find .
3
4. Which nitrogen in the given compound is most basic?
5. Find the number of reactions which gives final product via formation of isocynate:
Section – 2 PHYSICS
1. In a Vernier calipers, one main scale division is 1mm and 20 Vernier scale divisions coincide with 17 main scale divisions.
In an experiment, the zero of Vernier scale lies between 45th and 46th marks of main scale and 12th of Vernier scale
coincides with a main scale mark. Which main scale mark is it?
(A) 56th (B) 57th (C) 55th (D) 54th
2. The binding energies of the atoms of elements A and B are Ea and Eb respectively. Three atoms of the element B fuse
to give one atom of element A. This fusion process is accompanied by release of energy E. Find relation between Ea ,
Eb and E.
(A) Ea  3Eb  E  0 (B) Ea  3Eb  E  0
(C) Ea  3Eb  E  0 (D) 3Ea  Eb  E  0
3. There are four rods OA, OC, DE and BE of length L each and two A D
rods AB and CD of length 2L each. They are hinged at all points, O,
F E
A, B, C, D, E and F as shown in figure. The joint E is pulled along O V
the line of symmetry OFE with constant velocity V. What is the
speed of point D when the angle between OA and AB is 120°? C B
3V 3 V 5V
(A) (B) V (C) (D)
4 2 4 2 2
4. Two small blocks of mass m, 2m and a uniform rod of mass m and length
L are connected through ideal strings and pulleys as shown in Figure.
Find the angular acceleration of the rod at the instant when it is
horizontal. m, L
g 18 g
(A) (B)
L 23 L
22 g 36
(C) (D) g m 2m
23 L 37
5. Three charged capacitorsC1 , C2 and C3 having
capacitances 3 F , 6  F and 6  F respectively and having
C1 C2
charge 30  C each are connected along with the resistors
in a circuit as shown in figure. The key K is closed at t=0. Find 10 10 5
the initial current through 5 resistor.
(A) 2/3 A
(B) 4A
C3 K
(C) 1A
(D) 2A
6. A block of mass 2 Kg when passing through origin, is having velocity 4 6 m / s in positive x-direction. Its potential
energy is defined as U   x  6 x  15 , SI units. Its velocity when applied force is minimum is
3 2
(A) 8 m/s (B) 4 m/s (C) 10 24 m/s (D) none of these
7. A spinning ball (uniform solid sphere) of radius R falls vertically on a rough horizontal floor (co-efficient of friction
5u
  0.5 with velocity u. The ball is also rotating about a horizontal axis with angular velocity . The co-efficient of
R
restitution of ball with the floor is 0.5. If the ball still rotates in same direction after collision, what is the new angular
velocity of ball?
3u 35u 2u 27u
(A) (B) (C) (D)
R 8R R 8R
8. A fish in an aquarium approaches a vertical wall at a rate of 3 m/s and observes a fly (in same horizontal level)
approaching it at 8 m/s. If the refractive index of water is 4/3, find the actual velocity of fly.
(A) 3.75 m/s away from wall (B) 3.75 m/s towards wall
(C) 6.67 m/s away from wall (D) 6.67 m/s towards wall
9. A symmetric parabolic bowl (with circular cross section) of height R and 2R

base radius 2R, as shown in figure is filled with a fluid up to the top. A small
circular hole of radius R/20 is made at the bottom of the bowl through
which the fluid leaks out. What amount of time will it take for the bowl to
R
be empty?
800 2 R 800 R
(A) (B)
3 g 3 g Hole
1600 2 R 1600 R
(C) (D)
3 g 3 g
10. Figure shows three concentric thin spherical shells A, B and C of radii R, 2R and 3R. 4
The shell B is earthed and A and C are given charges q and 2q, respectively. What is
the charge on inner surface of outer sphere? 3
(A)  q
2q C B A
(B)
3 2
1
(C) 0
4q
(D)
3
11. A satellite of mass m revolves around earth of mass M in a circular orbit of radius 20R. An external impulse I is provided
to the satellite in the direction of its motion by some means. In subsequent motion, the maximum distance of the
satellite from the center of earth is 30R. Find the value of impulse I.
 7  GM  7  GM
(A) 
  1 m (B) 
  1 m
 6  20 R  6  30 R
 6  GM  6  GM
 5  1 m  5  1 m
(C)  (D) 
  20 R   30 R
12. A uniform horizontal rod of length L, area of cross-section A, mass m and Young’s modulus Y is pulled on a rough
horizontal surface by a force F, such that the friction acting on it is F/2. What if the elongation in the rod?
FL FL 3FL 3FL
(A) (B) (C) (D)
2 AY AY 2 AY 4 AY
13. A conducting rod of length L slides down between a pair of wall and
floor making an angle 120° with each other as shown in figure. There is X X
a uniform magnetic field B perpendicular to the plane of rod, wall and
floor. The speed of the lower tip of rod is V at an instant when it makes B X X
isosceles triangle with wall and floor. What is the magnitude of emf
induced between midpoint and either end of the rod? 120°
V
BLV BLV BLV

(A) BLV (B) (C) (D)
2 4 8
14. In the shown figure, there are two magnetic field regions of same V X X
magnitude B but opposite directions and different widths. All
boundaries are parallel. A particle of charge Q and mass M enters
the left region normal to the boundary with velocity V, crosses it
X X
and also crosses the second region of magnetic field. What is the
angle deviated by the particle?
X X
3Mv
2BQ  
3  1 Mv
2BQ
(A) 15° (B) 30° (C) 45° (D) 60°
15. A particle is executing SHM along X-axis with origin as equilibrium position and time period T. At t = 0, the particle
crosses x = A/2 towards positive extreme. After what time will it reach negative extreme 3 rd time?
5T 8T 31T 19T
(A) (B) (C) (D)
3 3 12 12
16. A wire of length L and non-uniform mass per unit length is hung from the ceiling at an end where the mass per unit
length is  0 . It is found that the velocity of a transverse wave generated at the bottom of the wire moves up with
uniform velocity. What is the mass per unit length at the bottom?
(A) 0 e
  gL /2v 
2
(B) 0 e
  gL / v 
2
(C) 0 e
 gL /2 v 
2
(D) 0 e
 gL / v 
2
17. Three infinitely long wires carrying equal current I are placed along the co-ordinate axes. The directions of currents are
along positive co-ordinate axes. What is the magnetic field at (a, a, a)?
30 I 3 0 I 3 0 I
(A) 0 (B) (C) (D)
2 2 a 2 a 2 a
18. An uncharged parallel plate capacitor having a dielectric constant K is connected to an identical air cored capacitor
charged to a potential V. The two capacitors share the charge and the common voltage is V’. The dielectric constant K is
V ' V V ' V V ' V V V '
(A) (B) (C) (D)
V ' V V' V V'
19. Two rods are welded at one end each and fixed between two vertical walls
without any stress as shown in figure. For left rod Young’s modulus, cross-
sectional area, length and co-efficient of linear expansion are
Y1 , A, L1 and 1 and those of right rod are Y2 , A, L2 and  2 . If the Y1, A, L1,  Y2, A, L2, 2
temperature of the system is increased by  , then by what amount will
the interface shift?
(A)
Y2 2  Y11   towards left (B)
Y2 2  Y11   towards right
 Y2 Y1   Y2 Y1 
     
 L2 L1   L2 L1 
(C)
Y2 2  Y11   towards left (D)
Y2 2  Y11   towards right
 Y2 Y1   Y2 Y1 
     
 L2 L1   L2 L1 
20. Three travelling waves in same direction are superimposed. The equations of waves are y1  A0 sin(kx  t ) ,

y2  3 2 A0 sin(kx  t   ) and y3  4 A0 cos(kx  t ) , if 0    and the phase difference between
2

resultant wave and first wave is , then  is
4
  
(A) (B) (C) (D) None of these
6 12 3
Integer Type
1. In the shown circuit, three Zener diodes are connected in
series each marked Vz  10V , I max  100 mA . If the R
minimum value of resistance R for all diodes to be properly

biased is 10 x , then x  ? RL = 600 
45V
2. Two rods of lengths 2L and L and masses 2m and m respectively are

resting on different horizontal levels, supporting each other at the
topmost tip as shown in figure. If the reaction force at the tip between
xy m, L
the rods is mg , then x + y = ? 2m, 2L
10 53°
37°
1H
3. In the shown circuit, if the power developed by the source is

P, then P + 0.1 = ?
100 F 100
220 V, 50 Hz
4. Two equal and opposite charges of magnitude q are separated by a distance 2l . If the flux of electric field through a
circle of radius l in equatorial plane to the charges and centered at the midpoint of charges is
q 

ln  1  x 
0 
1 

 , then x = ?
x
Section – 3 MATHEMATICS
 1   1  1
1. A  ,  ,B  ,  ,C  ,  be the vertices of a ABC, where ,  are the roots of x2  6P1x  2  0 ;
     
,  are the roots of x2  6P2x  3  0 and ,  are the roots of x2  6P3x  6  0, (where P1,P2 and P3 >0); then
the coordinate of the centroid of ABC is
(A) 1, (C)  2, 
11 
(B)  0, 
11 11
 (D) (3, 11)
 18   8  18  8
10
2. The value of r
r 0
10
Cr 3r ( 2)10r is
(A)20 (B) 10 (C) 300 (D) 30

3. If tan2  tan2   tan2  tan2   tan2  tan2   2 tan2  tan2  tan2   1. then the value of sin2   sin2   sin2  =
(A)0 (B) 1 (C) 2 (D) 3
4. The number of integral solutions of the equation 2x + 2y + z = 20, where x  0, y  0 & z  0 is
(A) 132 (B) 11 (C) 33 (D) 66
5. The mean deviation about A.M. of the number 3, 4, 5, 6, 7 is :
(A)25 (B) 5 (C) 1.2 (D) 0
6. If cosec x  5  x for x  (2, 2) then the number of solution is

4 2
(A)8 (B) 7 (C) 6 (D) 5
7. The area of the region R = { ( x, y) ; x  y & x 2  y 2  1 }, (in sq units) is

(A) 3  /8 (B)  /4 (C)  /2 (D)  /8
8. If the graph of y  ax3  bx2  cx  d, (b  0) is symmetric about the line x = k, the n value of a + k is
(A) – c/(2b) (B) c/(2b) (C) c – bd (D) c
9. Number of solution of the equation, 3( z )2

z3   0 , where z is a complex number is
z
(A)2 (B) 3 (C) 6 (D) 5
10. Let a  3iˆ  2jˆ  2k,

ˆ b  î  2jˆ  2k.
ˆ Then a unit vector perpendicular to both a  b and a  b is
1 1 1 ˆ ˆ ˆ 1 ˆ ˆ ˆ
(A) (2 î  2jˆ  k)
ˆ (B) ( 2 î  2jˆ  k)
ˆ (C) (2 i  2j  k) (C) (i  j  k)
3 3 3 3
(x 2  1)dx
11.  (x  1)
2
x4  1
is equal to -
 2
 1  x2  1   x2  1   x2  1 
(A) sec 1  x c (B) 1
sec 1    c (C)
1
sec 1  c (D) sec 1  c
 2 x    2  2   2 
 2  2x    
12. The greatest and least value of the functions f(x)  x4  2x2  5 on [2, 2] is
(A)13 and 4 (B) 9 and 2 (C) 11 and 3 (D) 14 and 3
  cos1 x
13. lim is
x 1 x 1
1 1 1
(A) (B) (C) (D) 2
2  2
14. If p  (~ p  q) is false, the truth values of p and q are

(A) F, T (B) F, F (C)T, T (D) T, F
15. A and B are two matrices with 32 and 56 elements respectively, then the probability that (AB) is possible, is
(A) 1/9 (B) 1/11 (C) 1/12 (D) 1/14
16. Equation of the curve satisfying xdy  ydx  x2  y2 dx ; y(1)  0 is

(A) y  x2 sin(Inx) (B) y2  x(x 1)2 (C) y2  x2(x 1) (D) y = x sin(Inx)

 [x]  1
17.  
0
ex 
 dx (where[.] denotes greatest integer functions) is equal to
(A) 0 (B) 1 (C)  (D) –1
x2 y 2
18. A tangentto   1intercepts a length of unity from each of the coordinates axes, then, point (a,b) lies on
a 2 b2
(A) x 2  y 2  2 (B) x 2  y 2  1 (C) x 2  y 2  1 (D) x 2  y 2  1
1
19. If f '(x)  f(x) satisfy f(0)  2 and g(x)  x  f(x), then  f(x)g(x)dx 
0
2 2
(A) e (B) 2e (C) e (D) 2e
20. If y  x  1 intersect the x 2  y at P & Q, then point of intersection of tangents at P and Q is
(A) (–2, 4) (B) (–2, –4) (C) ( 2, 4) (D) ( ½,– 1)
INTEGER TYPE
19 i j k
3. If n    (4 ) , then the number of divisors of n of the form 4p  3 , ( p  N ) , is
i 1 j 1 k 1 u 1
equal to

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Section – 1 CHEMISTRY

(A) 1.48 V (B) 1.20V (C) 1.10 V (D) 1.30 V

10. Metal M  air 

Space for rough work

14. Consider the following reactions

(A) (B) (C) (D)

Product (B) of the above reaction is :

(A) (B) (C) (D)

(A) (B) (C) (D)

Space for rough work

(A) (B) (C) (D) None of these

End product (C) in above reaction is :

(A) (B) (C) (D)

Select the suitable reagent for above conversion.

2. At what pOH is the solubility of Zn(OH )2 minimum?

Given: Zn(OH )2 (s ) Zn 2  (aq )  2OH  (aq ) , K sp  1.2 x10 17

Zn(OH )2 (s )  2OH  Zn(OH )24  (aq ) , K = 0.13

4. Which nitrogen in the given compound is most basic?

Space for rough work

(A) 8 m/s (B) 4 m/s (C) 10 24 m/s (D) none of these

9. A symmetric parabolic bowl (with circular cross section) of height R and 2R

Space for rough work

BLV BLV BLV

(A) 15° (B) 30° (C) 45° (D) 60°

Space for rough work

Space for rough work

minimum value of resistance R for all diodes to be properly

2. Two rods of lengths 2L and L and masses 2m and m respectively are

3. In the shown circuit, if the power developed by the source is

Space for rough work

(A)20 (B) 10 (C) 300 (D) 30

6. If cosec x  5  x for x  (2, 2) then the number of solution is

7. The area of the region R = { ( x, y) ; x  y & x 2  y 2  1 }, (in sq units) is

9. Number of solution of the equation, 3( z )2

10. Let a  3iˆ  2jˆ  2k,

Space for rough work

14. If p  (~ p  q) is false, the truth values of p and q are

16. Equation of the curve satisfying xdy  ydx  x2  y2 dx ; y(1)  0 is

(A) 0 (B) 1 (C)  (D) –1

20. If y  x  1 intersect the x 2  y at P & Q, then point of intersection of tangents at P and Q is

(A) (–2, 4) (B) (–2, –4) (C) ( 2, 4) (D) ( ½,– 1)

Space for rough work

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