Arjun

1. Strontium metaphosphate is
(A) Sr (PO3)2 (B) SrHPO3 (C) Sr3(PO4)2 (D) Sr2P2O7
2. Nickel (II) pyroselenate is
(A) Ni2Se2O7 (B) NiSe2O7 (C) Ni2Se2O5 (D) NiSe2O5
3. The formula of sodium tungstate is Na 2WO4 and that of lead phosphate is Pb 3(PO4)2. What is the
formula for lead tungstate ?
(A) PbWO4 (B) Pb2(WO4)3 (C) Pb3(WO4)2 (D) Pb3(WO4)4
4. Mercurous azide is
(A) Hg2(N3)2 (B) HgN3 (C) Hg2N3 (D) Hg(N3)2
5. Which metal exhibits more than one oxidation states?
(A) Na (B) Mg (C) Al (D) Fe
6. The most common oxidation state of an element is –2. The number of electrons present in its outer
most shell is :
(A) 2 (B) 4 (C) 6 (D)8
7. Conversion of PbSO4 to PbS the oxidation number of sulphur in PbS is-
(A) –2 (B) + 6 (C) +4 (D) –1
8. Oxidation state of oxygen in H2O2 is :
(A) –2 (B) –1 (C) +1 (D) +2
9. The oxidation number of phosphorus in Mg2P2O7 is :
(A) +5 (B) –5 (C) +6 (D) –7
10. The oxidation number of Fe in FeS2 is
(A) +4 (B) +2 (C) +1 (D) zero
11. Sodium chlorite is :
(A) NaClO3 (B) NaClO2 (C) NaClO (D) NaClO4
12. Aluminium phosphide is :
(A) AlP3 (B) Al2P3 (C) AlP (D) Al3P2
13. Formula of Dioxygen diflouride is :
(A) OF2 (B) O2F (C) O2F2 (D) O2F3
14. Barium azide is :
(A) BaN (B) Ba2N3 (C) Ba(N3)2 (D) Ba3N2
15. Silicon flouride Formula is :
(A) SiF (B) SiF3 (C) SiF4 (D) SiF6
16. Aluminium carbide is :
(A) Al2C (B) Al4C3 (C) AlC3 (D) AlC
17. In the reaction, 2KClO3  2KCl + 3O2 when 36.75 g of KClO3 is heated, the volume of oxygen
evolved at N.T.P. will be :
(A) 9.74 dm3 (B) 8.92 dm3 (C) 10.08 dm3 (D) 22.4 dm3
18. The mode of expression in which the concentration remains independent of temperature is
(A) Molarity (B) Normality (C) Formality (D) Molality
19. The ratio of the masses of methane and ethane In a gas mixture is 4 : 5. The ratio of number of their
molecules in the mixture is:
(A) 4 : 5 (B) 3 : 2 (C) 2 : 3 (D) 5 : 4
20. Number of moles of KClO 3 that have to be heated to produce 1.0 L of O 2 (g) at STP can be expressed
as
(A) 1/3 (1/22.4) (B) ½(1/22.4) (C) 2/3 (1/22.4) (D) 3/2 (22.4)
Numerical answer type (+4,-1)

21. How many acid are pyro acid in the following given acids ?
(i) H4P2O7 (ii) H4P2O5 (iii) H2S2O3 (iv) HNO2
(v) H3PO4 (vi) HNO3 (vii) H6Si2O7
22. How many of these names are correct.
(i) N3– – Nitride ion
(ii) O2– – Peroxide ion
(iii) ZnO22– – Zincate ion
(iv) SO42– – Sulphite ion
(v) NO2– – Nitrite ion
(vi) PbO22– – Plumbite ion
(vii) Fe2+ – Ferric ion
23. Count the correct number of statement.
(i) Possible O.N. for Nitrogen +5, +4, +3, +1, –3, 0.
(ii) Alkaline earth metal always have oxidation number +1.
(iii) HClO is hypochlorous acid and HClO3 is perchloric acid.
(iv) (NH4)2SO4 is ammonium sulphate
(v) Aluminium hydrogen phosphite is Al(H2PO3)3
(vi) Oxidation number of oxygen in OF2 is +2 and O2F2 is +1
(vii) Cu+, Sn2+, Fe3+, Sn4+ respectively cuprous, stannous, ferrous, stannic, ion.
24. In how many of the compound or ion nitrogen (N) shows positive oxidation state.
(i) NH3 (ii) Na3N (iii) AN (iv) NaNO3 (v) NF3 (vi) HNO2
(vii) NH4+ (viii) N2O3 (ix) Ca(N3)2 (x) Mg3N2
25. How many of the following formula are correctly match with their name.
(i) CaF2  Calcium fluoride
(ii) ICl2  Iodine trichloride
(iii) O2F2  dioxygen diflouride
(iv) AN  Aluminium nitride
(v) Na3BO3  Sodium borate
(vi) Zn2P2O7  Zinc pyrophosphate
(vii) Na2S2O3  Sodium thio sulphate
(viii) XeO4  Xenon tetraoxide
(ix) Mg(ClO4)2  Magnesium perchlorate
(x) Mg(OH)2  Magnesium hydroxide
Target batch

1. 1 mole of N2 and 2 moles of H2 are allowed to react in a 1 dm 3 vessel. At equilibrium, 0.8 mole of NH 3
is formed. The concentration of H2 in the vessel is :
(1) 0.6 mole (2) 0.8 mole (3) 0.2 mole (4) 0.4 mole

2. For the following mechanism , P + Q PQ R at equilibrium is :

[ k represents rate constant ]

(1) (2) (3) (4)

3. Select the reaction for which the equilibrium constant is written as [MX 3] = Keq. [MX2]2 [X2]
2

(1) MX3 MX2 + X2 (2) 2MX3 2MX2+ X2

(3) 2MX2 + X2 2MX3 (4) MX2 +  X2 MX3.

4. What should be the value of KC for the reaction 2SO2(g) + O2(g) 2SO3(g). If the amount are SO3 =
48g, SO2 = 12.8 and O2 = 9.6 at equilibrium and the volume of the container is one litre?
(1) 64 (2) 0.30 (3) 42 (4) 8.5

5. The equilibrium constant (Kp) for the reaction PCl 5(g) PCl3(g) + Cl2(g) is 16. If the volume of the
container is reduced to one half its original volume, the value of K p for the reaction at the same
temperature will be :
(1) 32 (2) 64 (3) 16 (4) 4
6. 4.5 moles each of hydrogen and iodine heated in a sealed ten litre vessel. At equilibrium 3 moles of HI
were found. The equilibrium constant for H2(g) + I2(g) 2HI(g) is :
(1) 1 (2) 10 (3) 5 (4) 0.33
7. In a 20 litre vessel initially each have 1 – 1 mole CO, H 2O CO2 is present, then for the equilibrium of
CO + H2O CO2 + H2 following is true :
(1) H2, more then 1 mole (2) CO, H2O, H2 less then 1 mole
(3) CO2 & H2O both more than 1 mole (4) All of these
8. At 1000 K, the value of K p for the reaction A(g) + 2B(g) 3C(g) + D(g) is 0.05 atmosphere. The
value of KC in terms of R would be :
(1) 20000 R (2) 0.02 R (3) 5 ´ 10–5 R (4) 5 ´ 10–5 ´ R–1
9. In which of the following reactions is Kp < Kc ?
(1) CO(g) + Cl2(g) COCl2 (g) (2) CH4(g) + H2O(g) CO(g) + 3H2(g)
(3) 2BrCl(g) Cl2(g) + Br2(g) (4) I2(g) 2I(g)

10.
Compound X is
(A) H3C–CC–CH3 (B) CH2=CH–CH=CH2

(C) CH3–CH2–CCH (D)

11. Ammonical AgNO3 gives white ppt after reaction with any compound then this reflects the
presence of
(A) One –CHO group (B) One triple bond
(C) A terminal alkyne (D) Compound is unsaturated
12. Which of the following compound gives red ppt with Cu2Cl2 / NH4OH ?
(A) CH3–CC–CH3 (B) CH3–CH2–CCH
(C) CH3–CH2–CH=CH2 (D) CH3–CC–CH=CH2
13. The following two compounds I and II can be distinguished by using reagent

(I) (II)
(a) aq. NaHCO3 (b) Neutral FeCl3
(c) Blue litmus solution (d) Na metal
(e) HCl/ZnCl2 anhydrous
(A) a or c (B) b or e (C) d or e (D) c or d
14. The compound A gives following reactions.

Its structure can be

(A) (B) OHC–(CH2)2–CH=CH–COOH

(C) (D)
15. Which of the following compound will give smell of NH3 with conc. NaOH.

(A) (B)

(C) (D)

16. ; Identify X :

(A) (B)

(C) (D)
17. Which of the following would produce effervescence with sodium bicarbonate?
 (A) (B) (C) (D) All of these

18. Observe the following compound and select +ve & –ve test respectively.

(A) + + + – (B) + + + + (C) + – + – (D) + – – +

19. Lassaigne’s test for the detection of nitrogen will fail in the case of

(A) NHCOPh (B)

(C) NH2–NH2.HCl (D) NHNH2.HCl

20. The sodium extract of an organic compound on treatment with FeSO 4 solution, FeCl3 and
HCl gives red solution. The Red colour of :
(A) Fe(CN)3 (B) K4[Fe(CN)6]3 (C) Fe(CNS)3 (D) Fe2S

Numerical type (+4,-1)

21. How many isomeric alkynes on catalytic hydrogenation gives 3-Ethyl-4-methylheptane ?
22. Find the number of structural isomers of fully saturated cycloalkane of molecular formulae
C6H12 which give three monochloro structural products.
23. How many of the following compounds decolorise Br2 water solution ?

(I) (II) (III) Me–CC–Me (IV)

(V) (VII) ` (VIII) Me–CH=CH–Et (IX)

24. How many structures possible for a compound with the molecular formula C 6H12O which can
give positive iodoform and 2,4-DNP test.
25. Among the following the number of compounds which react with Fehling’s solution is :
O O
|| ||
H
, 3 C – C – H H
, 3 C – CH2 – C – H, , ,
HCHO, HCOOH, CH3COCH3.
1. Which of the following anions are identified by dil. HCl :
(A) NO2–, NO3–, CO32– (B) NO2–, NO3–, SO32– (C) S2–, SO32–, NO2– (D)
– – 2–
CH3COO , I , CO3
2. Two inorganic compounds A and B were heated in a dry test tube. A evolved a
colourless gas which turned lead acetate paper black and B evolved a gas which
turned lime water milky. The anions in A and B respectively are :
2– 2– 2– 3– – –
(A) SO3 , CO 3 (B) S2–, CO 3 (C) PO4 , HSO 3 (D) S2–, NO 3
3. If addition of conc. H2SO4 is made to an unknown salt, a colourless and odourless
gas is produced then which of the following can be present ?
2– –
(A) CO 3 (B) S2– (C) Cl¯ (D) NO 3
4. A gas turns lime water milky and acidified K2Cr2O7 solution green then gas is :
(A) HCl (B) H2S (C) SO2 (D)
CO2
5. A gas has smell like rotten egg and turns lead acetate paper black. The gas is :
(A) NO2 (B) H2S (C) CO2 (D)
SO2
Rotten egg smell
(P)

 dil. H2SO4

CdCO3 suspension –2 (CH3COO)2Pb

Yellow ppt  Salt with X anion Black ppt 
(S) (Q)
Sodium Nitroprusside

Violet
(R)
6.
Anion (X2–) is:
(A) CO32– (B) SO32– (C) S2– (D) S2O32–
7. Sulphide ion reacts with Na2[Fe(CN)5NO] to form a purple coloured compound (X). In
this reaction oxidation state of iron.

(A) changes from +2 to +3 (B) changes from +3 to +2

(C) changes from +2 to +4 (D) does not change.
8. Which of the following reagents turns white precipitate of AgCl yellow ?
(A) NaNO3 (B) Na3AsO3 (C) Na3AsO4 (D) NaCN
9. A Unknown salt (S) when heated with dil. H2SO4 does not evolve brown vapours but
with conc. H2SO4 brown vapours are obtained. The vapours when brought in contact
with AgNO3 solution do not give any precipitate. The salt (S) contains.
(A) NO2– (B) NO3– (C) I– (D) Br–

10.
Compound X is
(A) H3C–CC–CH3 (B) CH2=CH–CH=CH2

(C) CH3–CH2–CCH (D)

11. Ammonical AgNO3 gives white ppt after reaction with any compound then this reflects the
presence of
(A) One –CHO group (B) One triple bond
(C) A terminal alkyne (D) Compound is unsaturated
12. Which of the following compound gives red ppt with Cu2Cl2 / NH4OH ?
(A) CH3–CC–CH3 (B) CH3–CH2–CCH
(C) CH3–CH2–CH=CH2 (D) CH3–CC–CH=CH2
13. The following two compounds I and II can be distinguished by using reagent

(I) (II)
(a) aq. NaHCO3 (b) Neutral FeCl3
(c) Blue litmus solution (d) Na metal
(e) HCl/ZnCl2 anhydrous
(A) a or c (B) b or e (C) d or e (D) c or d
14. The compound A gives following reactions.

Its structure can be

(A) (B) OHC–(CH2)2–CH=CH–COOH

(C) (D)
15. Which of the following compound will give smell of NH3 with conc. NaOH.

(A) (B)
 (C) (D)

16. ; Identify X :

(A) (B)

(C) (D)
17. Which of the following would produce effervescence with sodium bicarbonate?

(A) (B) (C) (D) All of these

18. Observe the following compound and select +ve & –ve test respectively.

(A) + + + – (B) + + + + (C) + – + – (D) + – – +

19. Lassaigne’s test for the detection of nitrogen will fail in the case of

(A) NHCOPh (B)

(C) NH2–NH2.HCl (D) NHNH2.HCl

20. The sodium extract of an organic compound on treatment with FeSO 4 solution, FeCl3 and
HCl gives red solution. The Red colour of :
(A) Fe(CN)3 (B) K4[Fe(CN)6]3 (C) Fe(CNS)3 (D) Fe2S

Numerical type (+4,-1)

21. How many isomeric alkynes on catalytic hydrogenation gives 3-Ethyl-4-methylheptane ?
22. Find the number of structural isomers of fully saturated cycloalkane of molecular formulae
C6H12 which give three monochloro structural products.
23. How many of the following compounds decolorise Br2 water solution ?
 (I) (II) (III) Me–CC–Me (IV)

(V) (VII) ` (VIII) Me–CH=CH–Et (IX)

24. How many structures possible for a compound with the molecular formula C 6H12O which can
give positive iodoform and 2,4-DNP test.
25. Among the following the number of compounds which react with Fehling’s solution is :
O O
|| ||
, H3 C – C – H , H3 C – CH2 – C – H, , ,
HCHO, HCOOH, CH3COCH3.