Professional Documents
Culture Documents
Chem Ch-10 DPP
Chem Ch-10 DPP
LAKSHAY (JEE)
Haloalkane & Haloarene DPP-01
1. Identify which of the compound having 2 4. Find the product p in following Rex
alcohol? OH
SOCl2
(A)
Cl Cl
(B) Cl
(A) (B)
(C) Cl
OH
Cl
(D)
(C) (D)
Cl
2. Luca’s Test conduct at fast rate by which
alcohol?
(A) CH3 ––CH2 ––CH2 ––OH 5. Best method to convert alcohol to halide is:
(A) ROH + SOCl2 → R – Cl + SO 2 + HCl
(B) CH3 CH CH3
OH (B) R − OH + PCl3 → R − Cl
CH3 (C) R − OH + PCl5 → R − Cl
(C) H3C C OH (D) R − OH + HCl → R − Cl + H 2O
CH3
(D) None 6. What is the major product of the following
reaction?
CH3
3. Find the product p in following CH3 ––CH2 |
heat
––CH2 ––OH + PX5 → …. CH3 − C — CH CH 3 + HBr ⎯⎯⎯
→
| OH
(A) CH3 ––CH2 ––CH2 ––X CH3
(B) H3C CH CH3 CH3 Br
| |
X (A) CH3 − C — CH CH3
X |
CH3
(C) H3C C CH3 CH3
X |
(B) CH 3 − C — CH 2 CH 2
CH2 CH2 CH2 | |
CH3 Br
(D)
X X
2
LAKSHAY (JEE)
Haloalkane & Haloarene DPP-02
1.
6. Find the product in following reaction- 7. CH3 – CH2 – CH = CH2 + HCl ⎯⎯ → Product
Identify the product in above reaction
(A) CH3 − CH 2 − CH 2 − CH 2
|
(A) Cl
(B) CH3 − CH 2 − CH − CH3
|
(B) Cl
(C) CH3 − CH − CH 2 − CH3
|
(C) Cl
(D) CH 2 − CH 2 − CH = CH 2
(D) None of these |
Cl
Answer Key
1. (A)
2. (A)
3. (B)
4. (A)
5. (B)
6. (A)
7. (B)
LAKSHAY (JEE)
Haloalkane & Haloarene DPP-03
CH3
1. In the given Reaction |
CH3 (iii) CH3 – CH – CH CH 2
C7 H12 (A)
HBr
Br [Major (A) I > II > III (B) II > I > III
(C) III > II > I (D) III > I > II
Product]
CH2
4. What will be major product, when 2-methyl
CH=CH2 butane undergoes bromination in presence
(A) (B) of light ?
(A) 1-bromo – 2 – methyl butane
CH3 (B) 2-bromo – 2 – methyl butane
(C) (D) All of these (C) 2-bromo – 3 – methyl butane
(D) 1-bromo – 3 – methyl butane
(C)
CH3
6.
NBS
hv
P, product P is :
(C) R – X NaF
(D) R – X AgCl
Answer Key
1. (D)
2. (C)
3. (C)
4. (B)
5. (A)
6. (A)
7. (D)
8. (A)
9. (A)
10. (A)
LAKSHAY (JEE)
Haloalkane & Haloarene DPP-04
⊕ (D)
N ≡ N BF4
Cl
3. ∆
→ A, in the Reaction 6. In electrophilic substation Rex Toluene react
with Iodine we use oxidising agent (HNO3,
A is HIO3) due to
(A) fluorobenzene (A) reversible nature of reaction
(B) Benzene (B) irreversible nature of reaction
(C) 1, 4 difluorobenzene (C) redox reaction
(D) 1, 3 difluorobenzene (D) None of these
4. Diazonium Salt + Cu2Cl2 + HCl
Cl ⊕
7. In the sandmeyer reaction – N ≡ N x
→
the reaction is known as - group of diazonium salt is replaced by
(A) halide group
(A) chlorination (B) nitro group
(B) Sandmeyer’s Reaction (C) –OH group
(C) (A) and (B) both (D) –NHNH2 group
(D) Substation Rex
2
NaNO 2 +HCl
→ A
Cu 2 x 2
→ B (C) (D)
[0–5°C Cl
X X
X
(A) (B)
Answer Key
1. (D)
2. (B)
3. (A)
4. (B)
5. (B)
6. (A)
7. (A)
8. (C)
9. (A)
10. (A)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-05
3. SN1 reactivity of the following halides, 7. Assuming no other changes, what is the
(i) (CH3)3CBr (ii) (C6H5)2CHBr effect of doubling oly the concentration of
(iii) (C6H5)2C(CH3)Br (iv) (CH3)2 CHBr the alkyl halide in the following SN1
will be in the order: reaction?
(A) iv > i > ii > iii (B) ii > i > iii > iv (CH3)3CBr + IΘ (CH3)3CI + BrΘ
(C) i > iii > ii > iv (D) iii > ii > i > iv (A) no change
(B) doubles the rate
4. The compound which would undergo SN2 (C) triples the rate
reaction fastest is: (D) quadruples the rate
Cl
8. Which of the following alkyl halides gives
(A)
the fastest SN1 reaction?
Cl (A) CH3CH2CH2Br (B) CH3CHCH3
(B) |
Br
(C) Br (C) CH3CHCH3 (D) CH3CH2CH2I
Br |
I
(D)
9. Which of the following alkyl halides gives 12. Compare rate of reaction with Ag NO 3 or
the fastest SN1 reaction? rate of S N1 reaction:
Br Br
| Br Br
(A) CH 3CHCHCH 3
|
CH 3
(i) (ii) (iii)
(B) CH3CHCH 2 CH 2 Br
| (A) i > iii > ii (B) i > ii > iii
CH3 (C) iii > ii > i (D) ii > i > iii
Br
|
(C) CH 3CCH 2 CH 3 13. Compare rate of reaction with Ag NO 3 or
| rate of SN1 reaction:
CH 3
I I I
(D) ClCH 2 CHCH 2 CH3
|
CH3
(i) (ii) (iii)
10. Which of the following factors has no effect
on the rate of SN1 reactions? (A) i > ii > iii (B) ii > iii > i
(A) the nature of the alkyl halide (C) ii > i > iii (D) i > iii > ii
(B) the nature of the leaving group
(C) the concentration of the alkyl halide
(D) the concentration of the ucleophile
Answer Key
1. (C)
2. (A)
3. (D)
4. (C)
5. (A)
6. (D)
7. (B)
8. (C)
9. (C)
10. (D)
11. (C)
12. (B)
13. (B)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-06
Answer Key
1. (D)
2. (A)
3. (C)
4. (A)
5. (B)
6. (C)
7. (B)
8. (C)
9. (C)
10. (A)
11. (C)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-07
(A) (B)
3. Which of the reactions shown below will be
faster?
Reaction-1:
(C) (D)
Reaction-2:
2. In the given reaction:
4. Product (A)
(B)
is:
(A) (B)
(C)
S
+ OH − ⎯⎯→
2
5.
N
A; (B)
Answer Key
1. (A)
2. (A)
3. (B)
4. (A)
5. (C)
6. (D)
7. (A)
8. (A)
9. (B)
10. (A)
11. (C)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-08
Br
2. In the given reaction, CH3OH . [X] as the major product among the elimination
C – CH3
CH3
product is:
CH3
(A) (B) C – CH3
C = CH2
CH3
CH3
(C) CH3 (D)
CH3
CH3
(A) Br (B)
Br
(C) (D)
Br Br
6. Arrange the following in decreasing order of stability of their transition state during elimination by
strong base
Br
Br Br
(I) (II) (III)
(A) II > I > III (B) II > III > I
(C) I > III > II (D) I > II > III
7. 2-Chlorobutane on treatment with alcoholic KOH/ gives mainly:
(A) 2-Butene (B) 1-Butene
(C) 2-Butanol (D) 1-Butyne
8. Select the formula representing the major product of the following reaction
Br H
CH3CH2OK/CH3CH2OH
H CC CH3
CH3 CH2CH3
H H
H CH3 CC CH3
(A) (B)
H2C
CH3 CH2CH3 CH2CH3
Br H
H CH2CH3 H5C2O CC CH3
(C) (D)
CH3 CH3 CH3 CH2CH3
3
Cl
|
t BuO
9. CH3 CH CH CH3
Major product is:
|
CH3
(A) CH3 C CH CH3 (B) CH3 CH CH CH 2
| |
CH3 CH3
OH
|
(C) CH 2 C CH 2 CH3 (D) CH 3 CH CH CH 3
| |
CH3 CH 3
10. Which of the following will undergo fastest elimination reaction with alcoholic KOH?
Br Br
(A) (Cis) (B) (trans)
Me Me
Br Me Br
(C) (D)
Me
MeO ‘K’
X Major
Answer Key
1. (D)
2. (C)
3. (B)
4. (D)
5. (C)
6. (A)
7. (A)
8. (C)
9. (B)
10. (A)
11. (A)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-09
Cl OH
Θ Θ
+ OH + Cl
Θ Θ
(C) (D) Br + OH OH + Br
NO2 NO2
NO2
Cl Cl
NO2 NO2
(C) (D)
NO2 NO2
NO2 NO2
Br Cl
NO2
(C) (D)
NO2 NO2
2
CN
(CH3)2NH
4. Cu2O,
The product is
F
NMe2 CN
(A) (B)
NMe2 NMe2
CN NMe2
(C) (D)
NMe2
F F
5. Which of the following species is expected to have maximum enthalpy in an electrophilic aromatic
substitution reaction?
H E+ H E H+ E E
+ +
+ E+ +
EEE
(I) (II) (III) (IV) (V)
(A) Species (II) (B) Species (III)
(C) Species ((IV) (D) Species (V)
7. The compound with molecular formula C8H10 which give two isomers on electrophilic substitution
with Cl2/FeCl3 or with HNO3/H2SO4 is:
(A) p-Dimethyl benzene (B) m-Dimethyl benzene
(C) o-Dimethyl benzene (D) Ethyl benzene
(A) (B)
(C) (D)
3
Anhydrous AlCl3
+ ICl X:
Cl I
(A) (B)
Cl I
(C) (D)
Cl
I
4
Answer Key
1. (C)
2. (C)
3. (B)
4. (B)
5. (A)
6. (C)
7. (C)
8. (B)
9. (A)
10. (B)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-10
1. The relative reactivity of acyl compounds towards nucleophilic substitution are in the order of
(A) Acid anhydride > Amide > Ester > Acyl chloride
(B) Acyl chloride > Ester > Acid anhydride > Amine
(C) Acyl chloride > Acid anhydride > Ester > Amide
(D) Ester > Acyl chloride > Amide > Acid anhydride
CH3
C–OCH3
PhMgBr
2. (P). Product (P) is:
O (1 equivalent)
CH2–COCH3
O
CH3 O CH3 O
C–Ph C–Ph
(A) (B)
CH2–COCH3 CH2–COCH3
O O
CH3 CH3
C–Ph C–OCH3
(C) (D)
O O
CH2–COCH3 CH2–C–Ph
CH3
O O
OH
OH
(A) (B)
OH
(C) (D)
O CH3
(1) PhMgBr
6. C Products; product obtained in this reaction are:
(2) H+
||
O
(A) disastereomers (B) racemic
(C) pure enantiomer (D) meso
O
CH3NH2
7. C–OCH3 Heat
X,X is:
O
(A) NH–C–CH3 (B) NH–CH2–CHO
O O
(C) C–NH–CH3 (D) C–CH3–NH2
8. Which of the following will undergo acid-base reaction with Gingnard reagent?
(A) HC CH (B) R – OH
(C) R – CO2H (d) All of these
3
Answer Key
1. (C)
2. (D)
3. (D)
4. (B)
5. (C)
6. (B)
7. (C)
8. (D)
LAKSHAY (JEE)
Alkyl and Aryl halides DPP-11
RMgBr
1. Product; The product
S
O O
(A) HSO2 – CH2 – CH2 – CH2 – CH2 – R (B) H – SO2(CH2)3 – R
2.
(i) THF
+ MgBrCH2CH2CH2CH2MgBr (ii) H3O+
O O
product; Product of the reaction is:
O
||
(A) HO – (CH2)3 – C – CH2 – CH2 – CH3 (B)
HO (CH2)3—OH
(C) (D)
HO CH – CH2 – CH3
|
OH HO CH2 – CH2 – CH3
3. Which of the following compound is not a suitable solvent for Grignard reaction?
O
O
(A) (B) (1, 4-dioxane)
O
(THF)
MeO OMe
n-Bu2CuLi
4. Product of the reaction will be:
(n-Bu=n-butyl group)
Br
MeO OMe MeO OMe
(A) (B)
n-Bu n-Bu
OMe Bu OH OH
(C) (D)
Br Br
CH3MgBr
Product
H/H2O
O
Find the product of reaction.
(A) OH (B)
OH
(C) OH (D)
r1
6. (i) + PhMgBr
O
PhCH2CH2OH
r2
(ii) + PhMgBr
O
PhCH2CH2CH2 OH
(A) r2 > r1 (B) r1 > r2
(C) r1 = r2 (D) r1 = 2r2
7. Reaction – 1:
SH O SH OH
|| | CH3
HO C-Cl C
1. xCH3MgBr CH3
2. H3O CH3
OH C
C-Cl
|| | CH3
O OH
3
Reaction – 2:
O OH
|| ||
C–O–Et CH3–C– CH3
1. yCH3MgBr
2. H3O
CH2–Cl
CH2Cl
What is the ratio of (x/y) in above problem?
(A) 1.5 (B) 2
(C) 2.5 (D) 3
8. What product would you expect to obtain from Grignard reaction when an excess of phenylmagnesium
bromide reacts with dimethyl carbonate CH3OCOOCH3?
OH
| OH
(A) CH3 — C — Ph (B) |
| CH3 — CH — Ph
Ph
OH
| O
(C) Ph — C — Ph (D) ||
| CH3 — C — Ph
Ph
MeMgX
(i) P
MgX
(ii) P
MgBr P
(iii) +
10. Which of the following reaction sequences would be the best for synthesis of 2-pentanone?
OH
(A) ||
H3O
CH 3 — CH 2 — CH 2 — C — H ⎯⎯⎯⎯ CH3 MgI
Et 2 O
→ ⎯⎯⎯ →
4
CH 2 — CH 2
(B) | |
H 3 O
CH3 — CH — O ⎯⎯⎯⎯
CH3 MgI
Et 2 O
→ ⎯⎯⎯ →
(C) CH3 — CH2 — CH2 — C H 2 ⎯⎯⎯
CH3 MgI
Et 2 O
⎯
→ ⎯⎯⎯
H3 O
→
OH
||
(D) H3 O
CH3 — CH 2 — C — H ⎯⎯⎯⎯
CH3 MgI
Et 2 O
→ ⎯⎯⎯ →
(propanal)
5
Answer Key
1. (C)
2. (B)
3. (D)
4. (A)
5. (C)
6. (B)
7. (B)
8. (C)
9. (D)
10. (C)