Atomic STR

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JEE Mains : Atomic Structure
1. A ball of mass 200 g moving with a velocity of 10 m sec 1. If the error in measurement of velocity is 0.1%, the
uncertainty in its position is
(a) 3.3  1031 m (b) 3.3  1027 m
(c) 5.3  1025 m (d) 2.64  1032 m
2. Which of the following set of quantum numbers represents an impossible arrangement?
n l m s
(a) 3 2 2 1/2
(b) 4 0 0 1/2
(c) 3 2 3 1/2
(d) 5 3 0 1/2
3. If the series limit of wavelength of the Lyman series for the hydrogen atoms in 912 Å, then the series limit of
wavelength for the Balmer series of the hydrogen atom is
(a) 912 Å (b) 912  2 Å
(c) 912  4 Å (d) 912/2 Å
4. The shortest  for the Lyman series of hydrogen atom is ….. (Given RH = 109678 cm1)
(a) 911.7 Å (b) 700 Å
(c) 600 Å (d) 811 Å
5. With increasing quantum number, the energy difference between adjacent orbits of hydrogen atom
(a) increases (b) decreases
(c) remains constant (d) first increases followed by a decrease
6. The number of orbitals in a subshell is equal to
(a) n2 (b) 2l
(c) 2l + 1 (d) m
7. Ground state electronic configuration of nitrogen atom can be represented as
(a) (b)
(c) (d)
8. Which of the following set of quantum numbers belong to highest energy?
1 1
(a) n = 4, l = 0, m = 0, s = + 2 (b) n = 3, l = 0, m = 0, s = + 2
1 1
(c) n = 3, l = 1, m = 1, s = + 2 (d) n = 3, l = 2, m = 1, s = +2
9. If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 3rd orbit is nearly
(a) 2x (b) 6x
(c) 9x (d) x/3
10. In Bohr’s hydrogen atom, the electronic transition emitting light of longest wavelength is
(a) n = 4 to n = 5 (b) n = 4 to n = 3
(c) n = 3 to n = 2 (d) n = 2 to n = 4
11. The frequency of first line of Balmer series in hydrogen atom is o. The frequency of corresponding line
emitted by singly ionised helium atom is
(a) 2o (b) 4o
(c) o/2 (d) o/4
12. The magnetic quantum number for valence electron of sodium is
(a) 3 (b) 2
(c) 1 (d) zero
13. The potential energy of the electron in an orbit of hydrogen atom would be
(a) mv2 (b) e2/r2
(c) 1/2 mv 2
(d) e2/2r
GARG Radiation, Birsa Chowk, Ranchi , Call – 9852566644 , 9852566699

GARG Radiation
14. Which of the following radiations has the highest wave number?
(a) Xrays (b) Microwaves
(c) I. R. rays (d) Radiowaves
15. Which of the following particles moving with same velocity would be associated with smallest deBroglie
wavelength?
(a) Hydrogen molecule (b) Oxygen molecule
(c) Helium molecule (d) Nitrogen molecule
16. If the velocity of an electron in the first Bohr orbit of a hydrogen atom is V, then its velocity in the third Bohr
orbit will be
(a) V/9 (b) V/3
(c) 9 V (d) 3 V
17. What is the wavelength associated with an electron moving with a velocity of 10 6 m/s? (Given h = 6.63 × 10 34
Js and m = 9.11 × 1028 g)
(a) 72.8 nm (b) 0.728 nm
(c) 7.28 nm (d) 7.28 × 10–13 m
18. If the ionization potential for hydrogen atom is 13.6 eV then the second ionization potential for helium atom
should be
(a) 13.6 eV (b) 27.2 eV
(c) 54.4 eV (d) none of these
19. The ratio of the radius of Bohr first orbit for the electron orbiting the hydrogen nucleus to that of the electron
orbiting the deuterium nucleus (mass nearly twice that of H nucleus) is approximately
(a) 1 : 1 (b) 1 : 2
(c) 2 : 1 (d) 1 : 4
20. Velocity of electron in the first orbit of Hatom as compared to that of velocity of
light is nearly
1 1
th th
(a) 10 (b) 100
1 1
th th
(c) 1000 (d) 150
21. Assuming the velocity to be same, which sub-atomic particle possesses smallest de Broglie wavelength
(a) An electron (b) A proton
(c) An a-particle (d) All have same wavelength
22. An electron in H-atom in its ground state absorbs 1.50 times as much as energy as the minimum required for
its escape (13.6 eV) from the atom. Thus KE given to emitted electron is
(a) 13.6 eV (b) 20.4 eV
(c) 34.0 eV (d) 6.8 eV
23. The velocity of an electron in a Bohr’s orbit is
1
¿
(a) n (b) ¿ n
1
2 ¿
(c) ¿ n (d) n2
24. Bohr’s theory is not valid for the species
(a) H atom (b) He+ ion
(c) Li ion
+
(d) Li2+ ion
25. If wavelength of an electron is equal to distance travelled by it in one second, then correct relation is
(a) l =
h
p (b) l = √ h
p
(c) l =
h
m (d) l = √ h
m

GARG Radiation
Answer Key
JEE Mains : Atomic Structure
1. (d) 2. (c) 3. (c) 4. (a) 5. (b)
6. (c) 7. (a) 8. (d) 9. (b) 10. (b)

11. (b) 12. (d) 13. (a) 14. (a) 15. (b)
16. (b) 17. (b) 18. (c) 19. (a) 20. (d)
21. (c) 22. (d) 23. (a) 24. (c) 25. (d)

Atomic STR

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GARG Radiation

Run and managed by IITians & NIFFTians Light of knowledge...

GARG Radiation, Birsa Chowk, Ranchi , Call – 9852566644 , 9852566699

GARG Radiation, Birsa Chowk, Ranchi , Call – 9852566644 , 9852566699

1. (d) 2. (c) 3. (c) 4. (a) 5. (b)

6. (c) 7. (a) 8. (d) 9. (b) 10. (b)

GARG Radiation, Birsa Chowk, Ranchi , Call – 9852566644 , 9852566699

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