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Organic Chemistry - Class 12th - Practice MCQs
Organic Chemistry - Class 12th - Practice MCQs
1
Assertion (A): It is difficult to replace chlorine by - 3
OH in chlorobenzene in comparison to that in Which one is the most acidic compound?
chloroethane.
1.
Reason (R): Chlorine carbon (C—Cl) bond in
chlorobenzene has a partial double bond character due to
resonance.
2
Carbonyl compound is treated with---
in Clemmensen reduction .
3.
4.
Page: 1
Organic Chemistry - Class Contact Number:
4
Match the structures given in Column I with the 6
names in Column II. The reaction,
CH3 CH3
Column I Column II | |
1. 4-Bromopent-2-ene is called
1. Williamson synthesis
3. Etard reaction
B.
4. Gatterman-Koch reaction
2. 4-Bromo-3-methylpent-2-ene
C.
3. 1-Bromobut-2-ene
D.
4. 1-Bromo-2-methylpent-2-ene
Codes
A B C D
1. 2 3 4 1
2. 1 2 3 4
3. 1 4 3 2
4. 4 1 3 2
5
Match the items of Column I and Column II.
Column I Column II
1. (i) → (e) (ii) → (c) (iii) → (b) (iv) → (a) (v) → (d)
2. (i) → (c) (ii) → (e) (iii) → (a) (iv) → (b) (v) → (d)
3. (i) → (e) (ii) → (d) (iii) → (b) (iv) → (a) (v) → (c)
4. (i) → (b) (ii) → (d) (iii) → (a) (iv) → (c) (v) → (e)
Page: 2
Organic Chemistry - Class Contact Number:
7
The major product of the following reaction is:
8
The compound is treated with
a concentrated aqueous KOH solution. The products
obtained are:
strong heating 1.
−−−−−−−−→
1.
2.
2. 3.
4.
3.
9
The correct structure of 1-Chloro-4-
ethylcyclohexane among the following is-
1.
4.
2.
3.
Page: 3
Organic Chemistry - Class Contact Number:
10
The correct structure of 2-Chloro-3-methylpentane 13
Match the items in column I with the items in
among the following is-
column II.
1.
Column I Column II
i.
a. 2-Hydroxycyclopentane
2. carbaldehyde
ii.
b. Di-sec-butyl ketone
3.
iii.
c. α-Methoxypropionaldehyde
4. None of the above
11
Consider the following reaction,
iv.
Zn dust CH3 Cl Alkaline KMnO4
Anhy. AlCl3
the product, Z, is
1. Toluene
2. Benzaldehyde
3. Benzoic acid
4. Benzene
12
The order of reactivity of following alcohols with 4. a-iv; b-iii; c-i; d-ii
I . CH CH — CH OH
3 2 2
II.
14
What is the correct order of reactivity of alcohols in
the following reaction?
ZnCl2
(4)3°> 1°> 2°
15
Benzaldehyde and acetaldehyde can be
1. (I) >(II)> (III)
distinguished by:
3. NH reaction
4. Wolff-Kishner's reduction
Page: 4
Organic Chemistry - Class Contact Number:
16
Match the compounds given in Column I with the 17
Match the structures of the compounds given in
effect given in Column II. Column I with the name of the compounds given in
Column II.
Column l Column lI
Column I Column II
A. Chloramphenical 1. Malaria
A.
B. Thyroxine 2. Anaesthetic
1. Phenetole
D. Chloroform 4. Goiter
B.
5. Blood substituent
2. o-Cresol
Codes
A B C D
2. 3 4 1 2
3. 5 4 3 2
C.
4. 4 5 3 2
3. Catechol
D.
4. Resorcinol
Codes
A B C D
1. 2 4 1 3
2. 3 1 4 2
3. 1 4 3 2
4. 4 3 2 1
Page: 5
Organic Chemistry - Class Contact Number:
18
Identify the compound Y in the following reaction.
20
Assertion: p-Nitrophenol is more acidic than
phenol.
2.
21
Which of the following alkyl halide undergo
rearrangement in SN1 reaction?
CH3
1. CH 3 − C − CH − CH3
3. |
CH3
|
2.
4. 3.
4. All of these
22
The correct order of increasing acidic strength is
1. phenol < ethanol < chloroacetic acid < acetic acid
19
Consider the reaction
2. ethanol < phenol < chloroacetic acid < acetic acid
1. Ethanol
2. Methanol
4. water
Page: 6
Organic Chemistry - Class Contact Number:
23
Phenol on treatment with dil.HNO3, gives two 25
products P and Q. P is steam volatile but Q is not P and
Q are. respectively
1.
P2 O5
−
−→ Product
Product is?
1.
2.
2.
3.
3.
4.
4.
24
Toluene reacts with a halogen in the presence of
iron (III) chloride giving ortho and para halo
compounds. The reaction is
Page: 7
Organic Chemistry - Class Contact Number:
26
In a set of reactions, m-bromobenzoic acid gave a 28
Among the following sets of reactants which one
product D. Identify the product D
produces anisole?
1. CH3CHO, RMgX
SOCl2 N H3 N aOH
−−
−→ B−
−→ C −−−→ D
Br2 29
The reaction that does not give benzoic acid as the
1. major product is-
1.
K2 Cr2 O7
−−−−−→
2.
2.
( i ) NaOCl
−−−−−→
+
( ii ) H3 O
3.
3.
PCC
−
−→
4.
+
KMnO4 /H
4. −−−−−−→
30
Which of the following reagents can be used to
oxidize primary alcohols to aldehydes?
27
Which compounds will not reduce Fehling's 1. (I, II, III)
solution?
2. (II, III, IV)
1. Methanal
3. (I, III, IV)
2. Ethanal
4. (I, II, IV)
3. Trichloroethanal
4. Benzaldehyde
Page: 8
Organic Chemistry - Class Contact Number:
31
Identify ‘Y’ in
33
The process of converting alkyl halides into
alcohols involves .........
1. Addition reaction
3. Dehydrohalogenation reaction
−−−−→ X −−−→
oxidation heating
34
In which of the following molecules is carbon atom
marked with an asterisk (*) is asymmetric?
32
In the given reaction, the product obtained is-
1.
2.
3.
Page: 9
Organic Chemistry - Class Contact Number:
35
In the following reactions,
36
Through which of the following reactions number
of carbon atoms can be increased in the chain?
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
1.
37
In which of the following polymers ethylene glycol
is one of the monomer units
2.
3. 38
Which of the following enhances the leathering
property of soap?
1. Sodium carbonate
2. Sodium rosinate
3. Sodium stearate
4. Trisodium phosphate
4.
Page: 10
Organic Chemistry - Class Contact Number:
39
Match the reactions given in Column I with the 40
Which of the following is the correct representation
suitable reagents given in Column II. for intermediate of nucleophilic addition reaction to the
given carbonyl compound (A) :
Column l
Column ll
(Reactions) (Reagents)
a.
B. Benzaldehyde → 1-Phenylethanol 2. DlBAL-H
3.
C. Cyclohexanone → Cyclohexanol
Zn(Hg)/Conc.HCl
b.
D. Phenyl benzoate → Benzaldehyde 4. CH3MgBr
Codes
A B C D
1. 2 3 4 1
c.
2. 3 4 1 2
3. 1 4 3 2
4. 4 3 2 1
d.
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
41
What mass of isobutylene is obtained from 37 g of
tertiary butyl alcohol by heating with 20% H2SO4 at 363
K, if the yield is 65%?
1. 16 g
2. 18.2 g
3. 20 g
4. 22 g
42
The commercial name of polyacrylonitrile is.
(1) Dacron
(3) PVC
Page: 11
Organic Chemistry - Class Contact Number:
43
Which of the following statements is not true about 45
Match the polymers given in Column I with their
low-density polyethylene?
repeating units given in Column II.
1. Tough
2. Hard
1.
44
Match the polymers given in Column I with their [CH2 − CH] n
Codes
A. Acrilan
3.
A B C D B. [CH − CH2
polystyrene
|
1. 2 3 4 1
C. Novolac
2. 3 1 2 4 D. Buna-N
CN] n
3. 1 4 3 2
4. 4 3 2 1 5.
Codes
2. 3 1 4 2
3. 1 4 3 2
46
Assertion: Polytetrafluoroethylene is used in
making non-stick cookware.
Page: 12
Organic Chemistry - Class Contact Number:
47
The most useful classification of drugs for 51
Assertion: Preservative is added to food items.
48
Which of the following chemicals can be added for 4. Assertion is the correct statement reason is the wrong
sweetening of food
statement.
calories?
1. Sucrose
52
In disaccharides, if the reducing groups of
2. Glucose
monosaccharides, i.e., aldehydic or ketonic groups are
3. Aspartame
bonded, these are non-reducing sugars. Which of the
4. Sucralose
1.
49
Match the class of compounds given in Column I
with their functions given in Column II.
Column I Column II
1. Communicate messages between two
A.
neurons and that between neurons to
Antagonists
muscles.
2. Bind to the receptor site and inhibit its
B. Agonists
natural function. 2.
C. Chemical 3. Crucial to the body's communication
messenger process.
D. Receptors 4. Mimic is the natural messenger.
Codes
A B C D
1. 2 4 1 3
3.
2. 3 1 4 2
3. 1 4 3 2
4. 4 3 2 1
50
Assertion: Transparent soaps are made by
4.
Reason: Ethanol makes things invisible.
Page: 13
Organic Chemistry - Class Contact Number:
53
DNA does not have -
56
1. Adenine
Of the following, which is the product formed when
2. Thymine
cyclohexanone undergoes aldol condensation followed
3. Cytosine
by heating?
4. Uracil
1.
54
Match the following enzymes given in Column I
with the reactions they catalyze given in Column II.
Column I
Column II
(Enzymes) (Reactions)
A. 2.
Invertase
1. Decomposition of urea into
B. Maltase
NH and CO
3 2
C. Zymase
2. Conversion of glucose into ethyl alcohol.
D. Urease
3. Hydrolysis of maltose into glucose.
3.
Codes
A B C D
4.
55
Which of the following polymers can have strong
intermolecular forces?
(a) Nylon
(b) Polystyrene
(c) Rubber
(d) Polyesters
1. (a, d)
2. (a, c)
3. (a, b)
4. (b, c)
57
Phenol and benzoic acid can be distinguished by:
1. Aqueous NaHCO3
2. Aqueous NaNO3
3. Aqueous NaOH
4. Conc. H2SO4
Page: 14
Organic Chemistry - Class Contact Number:
58 60
Which of the following is correct statement ?
LiBr
4. In cyclic structure of fructose, there are 6
−−−−−−−−→ M ajor product
carbons and one oxygen atom
SN 2 conditions
The product X is :-
1. 61
The difference between amylose and amylopectin is
62
Assertion: Aldehydes and ketones both react with
Tollen’s reagent to form a silver mirror.
Reason: Both aldehydes and ketones contain a carbonyl
3. group.
59
The correct order of strengths of the carboxylic
acids
1. I>II>III
2. II>III>I
3. III>II>I
4. II>I>III
Page: 15
Organic Chemistry - Class Contact Number:
63
64
RCOOH →RCH2OH. This mode of reduction of an
Predict the products in the given reactions,
acid to alcohol can be affected only by:
1. Zn/HCl
2. Na-alcohol
4. LiAlH4
65
Molecules whose mirror image is non-
superimposable over them are
1. 2 -Bromobutane
2. 1-Bromobutane
3. 2-Bromopropane
4. 2-Bromopropan-2-ol
66
Which is not an alcohol?
67
An organic compound (A) (MF C4H10O) upon
dehydrogenation gives a compound (B) which forms
phenyl hydrazone with phenylhydrazine and both the
compounds (A) and (B) respond to iodoform test.
3.
4.
Page: 16
Organic Chemistry - Class Contact Number:
68
In the given reation, majot product is-
69
Assertion(A): Ortho and para nitrophenols are more
acidic than phenol.
Product
1. Both assertion and reason are true, and reason is the
70
In the given reation, products are respectively-
(CH3)3C-O-C2H5+ HI→ A + B
2. 1. (CH3)3C-OH; CH3CH2I
2. (CH3)3C-I; CH3CH2I
3. (CH3)3C-I; CH3CH2OH
71
Given below are two statements:
The product of reaction of phenol with bromine
I
depends on the nature of solvent.
72
Assertion: The α -hydrogen atom in carbonyl
Reason: The anion formed after the loss of the α-
Page: 17
Organic Chemistry - Class Contact Number:
73
CH 3 MgBr+
76
Assertion: The IUPAC name of the compound
H3 O
+
M g/ether
is 2-ethoxy-2-methylethane.
H Br H CH O
−−→ A−
−→ B−−−−−→ C −−−→ D is
2. Both Assertion and Reason are true but the Reason is
77
Benzylamine may be alkylated as shown in the
following equation?
74
The major product of the following reaction
1. CH Br
sequence will be
3
2. C6 H5 Br
3. C6 H5 CH2 Br
4. C2 H5 Br
PhCOCl / Pyridine CH3 COCl/AlCl3 Zn−H g/H Cl/ΔBr2 /F e
−−−−−−−−−−→−−−−−−−−−→−−−−−−−−−→−−−→
(1) (2) (3) (4)
78
Consider the reactions,
(1) (i) CH3CH2CH2NH2+HCl→ A
(ii) (C2H5)3N+HCl→ B
2. CH3CH2CH2Cl ; (C2H5)3NCl
3. CH3CH2CH2NH3+ ; (C2H5)3NH+
(4)
75
Xylene on oxidation with acidic KMnO gives:
4
1. Phthalic acid
2. Isophthalic acid
3. Terephthalic acid
Page: 18
Organic Chemistry - Class Contact Number:
79
In the following reaction sequence
81
−−−−−−−−→ X −−−−−−−→ Y
2. H2 O2 / NaOH
X and Y are
1.
NaNO2 +HCl
2
0°−5°C
1. 4
2. 3
2. 3. 2
4. 1
82
Which one of the following is most reactive
1.
4.
2.
3.
80
Assertion: Boiling points of alcohols and ethers are
high.
83
Correct statement among the following regarding
the water present in egg upon boiling is:
1. Precipitated out.
Page: 19
Organic Chemistry - Class Contact Number:
84
Vitamin that cannot be stored in our body is-
88
The reagents that can be used to convert benzene
1. Vitamin K
diazonium chloride to benzene are
2. Vitamin C
a. SnCl2 / HCI
3. Vitamin E
b. CH3CH2OH
4. Vitamin A
c. H3PO2
d. LiAlH4
85
RNA upon hydrolysis, generates different Choose the correct option
1. Doubly - stranded.
2. (b, c)
2. Single - stranded.
3. (c, d)
89
The product of the following reaction is ............
86
The order of reactivity of the following Compounds
in electrophilic monochlorination at the most favourable
position is
1. (a, b)
2. (b, c)
3. (c, d)
90
Arenium ion involved in the bromination of aniline
is ................
87
Which of the following species are involved in the
carbylamine test?
a. R—NC
b. CHCl3
c. COCl2
1. (a, b)
2. (b, c, d)
2. (b, c)
3. (a, c, d)
3. (c, d)
4. (a, b, d)
4. (a, d)
Page: 20
Organic Chemistry - Class Contact Number:
91
Which of the following amines can be prepared by 94
Which of the following reactions belong to
Gabriel synthesis?
electrophilic aromatic substitution?
b. 2-phenylethylamine
2. Coupling reaction of aryldiazonium salts
d. Aniline
4. Acylation of aniline
1. (a, b)
1. (a, b)
2. (b, c)
2. (b, c)
3. (c, d)
3. (c, d)
4. (a, d)
4. (a, d)
92
Which of the following reactions is/are correct?
95
What is the type of polymerization reaction between
the given monomers?
1. Addition polymerization
4. Substitution polymerization
1. (a, b)
2. (b, c)
96
The compound that can be used as an antiseptic for
3. (c, d)
wounds:
4. (a, c)
1. CH I
2. CH CI
3
93
Under which of the following reaction conditions, 4. CH Br
3
1. KCN
conc. HNO3
3. HCN
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
Page: 21
Organic Chemistry - Class Contact Number:
98
Identify products A and B for the following
reaction:
Fill OMR Sheet*
*If above link doesn't work, please go to test link from
where you got the pdf and fill OMR from there. After
filling the OMR, you would get answers and explanations
for the questions in the test.
1.
3.
4.
99
A primary alkyl halide would prefer to undergo
..........
3. α ‐ elimination
4. racemisation
100
The chemical compounds that are used for the
treatment of stress or mental disorder are known as:
1. Analgesics
2. Tranquilizers
3. Antibiotics
4. Antihistamines
Page: 22