10-12-2022 - SR - Super60 - NUCLEUS&STERLING - BT - Jee-Main-PTM-13 - KEY & Sol'S
10-12-2022 - SR - Super60 - NUCLEUS&STERLING - BT - Jee-Main-PTM-13 - KEY & Sol'S
CHEMISTRY
31) 2 32) 1 33) 1 34) 1 35) 1
36) 4 37) 3 38) 3 39) 1 40) 4
41) 3 42) 4 43) 3 44) 2 45) 1
46) 4 47) 1 48) 2 49) 4 50) 3
51) 4 52) 20 53) 4 54) 5 55) 5
56) 40 57) 8 58) 9 59) 3 60) 186
MATHEMATICS
61) 1 62) 4 63) 1 64) 3 65) 2
66) 3 67) 3 68) 3 69) 3 70) 1
71) 4 72) 4 73) 2 74) 3 75) 2
76) 2 77) 2 78) 3 79) 1 80) 2
81) 1 82) 6 83) 1 84) 4 85) 2
86) 1 87) 6 88) 2 89) 2 90) 1
SOLUTIONS
PHYSICS
1. 3
n2 n1 2 1 D L
n D , L T , D L2T 1 M o L2T 1
x2 x1 L
2. Figure (a) can be simplified as follows
5 5
Hence ratio is C : C :C 5:5:3
3 3
3. Potential difference across upper branch is 6 V
C1 3
V2 V 10 3V
1
C C 2 3 7
Hence. Potential difference across 5 F capacitor is 3 V
Thus, charge in 5 F capacitor is Q5 F 5 3 15 C
4. Conceptual
5. Conceptual
6. 3C 3C
Ceq , Total charges q E
3C 3C
2 3CE 2CE 2E
Charge upon capacitor 2 F , Q2
3 3 C 3 C 1 3
C
If C 1 F ; q ' E , Hence Q2 is maximum at C 3 F
Hence graph (B) is correct
7. Before closing the switch
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 2
SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
q q q C
q1 q2 2Q V AB V AC or 1 2 1 1 or q1 2q2
C1 C2 q2 C2
4Q 2Q
Solving, we get q1 , q2
3 3
Q Q 4Q
Charge flown through K is q1 5Q / 6
2 2 3
8. Capacitors 1 F ,2 F and 3 F are in parallel, and their total capacitance is 6 F .
Thus, we have three capacitors in series, each of capacitance 6 F across the 12 V
power supply. So potential drop across each is 12 / 3 4V . So options (3) is correct.
Charge on 2 F capacitor is CV 2 4 8C . So option (1) is correct.
Charge on 6 F capacitor 6 106 4 24C . So option (2) is wrong.
Thus, correct options are (1), (3), and (4)
9. V t
V kt
4 3 4S 4s
r kt r k ' t1/3 p p0 p0
3 r kt1/3
1
pv / s is a straight line
t1/3
10.
5 5
I2 A
33 6
V A 0 3I1 or V A 3V
VB 0 3I 2 or VB 2.5V
Potential difference across capacitor is
1
3V 2.5V 0.5V V
2
Q CV 2 1/ 2 1C
14. U U
Fx 4 x Fy 3 F 4 xiˆ 3 ˆj
x y
At 1,2 F 4iˆ 3 ˆj F F 5
15.
d
Time from O to A, t1 (uniform)
o
u cos 45
d
Time from A to O, t2
eu cos 45o
d 1
Total time t t1 t2 1
o e
eu cos 45
Time for vertical motion (O to O)
1 2 2u sin 45o
0 u sin 45o T gT T t T
2 g
o
d 1 2u sin 45
1
u cos 45o e g
2 o
1 2u sin 45 cos 45
o
u2 3 gd
d 1 sin 90o 3d
e g g g
1 1
1 3 e
e 2
16. LO mv.2 R I cmo
m0 R.2 R mR 20 3mR 2o
17. In equilibrium kx F attraction
2
1 1 V
kx 0 E 2 A K 0.2d 0 A
2 2 0.8d
1 0 AV 2 AV 2
K 0
2 0.64d 2 0.2d 0.256d 3
18. dx xdx R 1 l 1/2
dR
olA 0
dR x , dR x dx
A 0 LA 0
1 2 3/2 2 1
A ol , R l l
0lA 3 3 0A
19. 4
VA VP x 1
40
VA VQ 2 2
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 5
SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
x
(1) - (2) VQ VP 2 2sin t
10
x 20sin t 20
dx
20cos t. cm / s
dt
20 cos t
20. GMm GMm 1 1
E1 GMm
Rh R R R h
GMm 1 1 1
E2 , E1 E2 ,
2 R h R R h 2 R h
1 3 R
, h 3.2 103 km
R 2 R h 2
21. 1 1
T sec t 10T 2sec
f 5
a a0e kt
a0
a0e k 2 e2k 2 2k ln 2
2
a0 ln 2
a0ekt ekt 1000 kt ln1000 t 2.303log10 103
1000 2
2 2.303 3
t 20s
0.7
22. Let at some instant, length x is inside water.
W m ALg , FB w Axg
Acceleration of rod
W FB m ALg Axg x
a g 1
m m AL m L
vdv x v L x
g 1 0 vdv g 0 1 dx
d L L
L
v2 x2 1 1
g x g L v 2 gL 1
2 2 L 2 2
0
a x 5 0.8 4m / s 2
4
: N1 20 2a y 2 3 N 26 N : f N1 2a x 26 2 4
13
24.
y 0.3sin 0.157 x cos 200 t 0.3sin x cos 200 t
20
2 2 2 1
2 A sin x cos t 40m L 4. 80m
T 20 2
25. Applying Kirchhoff’s first law at junction M. we get the current I1 3 A . Applying
Kirchhoff’s first law at junction P. we get the current I 2 1 A
x2 y2 2 5 2
1 1 1 f 3
f k 2 2k 5
f k 11 f 3 f
27. h 3 3
For fig min y y 2cm n y 1cm
1 1 3
1 1
2 4 2
Av Av 4 4 10 1 4 10
F F1 F2 1 2 8 4 12 N
y h y 10 2 10 1
28.
G 5 9 45 1
G G
S S
i 10
1 1
ig 1
5 2 10 G 10 45
S' S'
5 2 7 i
1 7 i
1
ig ig
i 7 i 63 65 ig 2
1 45 1
ig 10 ig 2 2 i 65
29.
2T 2s
b R cos h g h cos
2 R gb 2
30. k2
l R r 1
2
R
k2 2
For solid sphere 0.4 l R r 1 0.4
R2 5
T 2
l
2
R r 1.4
g g
CHEMISTRY
31.
d
ZM
3
a NA
Z 4; M 286; d 9.53 g / cm3
Z M 4 286
a3 200 1024 a 5.85 Ao
d N A 9.53 6 10 23
32. Conceptual
33.
If all the ions along one of the body diagonals are removed,
1 1
Number of A ions removed = 2 (corner share)
8 4
Number of B ion removed = 1
Number of C ion removed = 1
(Since body diagonal ions are inside the cube so they do not share with other ions)
1
Number of A ions left = 4 3.75
4
Number of B ions left = 4 1 3
Number of C ions left = 4 1 3
Thus, formula is A3.75 B3C3 = A5 B4C4
34. In glucose and fructose molecules; C3 , C4 and C5 atoms involve in osazone formation
As these carbon atoms have same configuration in both the molecules, the resultant
osazones are identical
35. a) The two Cl atoms are more effective in stabilizing the anion through inductive
effect
b) F atoms shows – IE where by electron pair on N becomes less available
c) O atom is MeOH is more electronegative than N atom in MeNH 2 . So, the e pair
on O in MeOH is less available MeOH is weaker base than CH 3 NH 2
d) R NH 2 NH 3 Ar NH 2
O
36. CH3
C
CH3
+I HC
37.
O
O 1) O3
O 2) Zn/H2O
O
O
O
O O
38. In an ideal solution the nature of molecular interactions are unchanged. So, heat is
neither liberated nor absorbed. For an ideal solution, Vmix 0 and it obeys Raoult’s
law
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 9
SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
39.
H 3C H 3C
HCN / CN- OH
H3C
H3C CN
(A)
H 3C
OH
H 3C COOH
(B)
40.
CH 3 3 C CH 2 CH 2 OH
K 2Cr2O7
CH 3 3 C CH 2 COOH
A
2 CH3 NH
3 3 C CH 2 COCl
SoCl
2 CH 2
B
CH3 3 C CH 2 CO N CH3 2
LiAlH 4
C
CH 3 3 C CH 2 CH 2 N CH 3 2
D
41. 1000 K f w 1000 5.12 1
T f , So, T f 0.4 K
W m 250 51.2
42. w 1000 R T i
i CRT i , For 1% solution,
M V M
st
43. After 1 ionization
N :1s 2 2 s 2 2 p 2 O :1s 2 2 s 2 2 p3
F :1s 2 2 s 2 2 p 4 Ne :1s 2 2s 2 2 p5 order of subsequent IP :
ns2np2 ns2np4 ns2np3 ns2np5 N F O Ne or Ne O F N
44. As temperature increases, intermolecular force of attraction will become weakes. This
lowers with surface tension and viscosity of the liquid
45. PM
d For the same gas at two different pressures and temperatures,
RT
d1 P1 T2 1.400 760 273 d 1.55 gL1 1.55kgm 3
d 2 P2 T1 d 760 303
46. a) NH 4 NO2 N 2 2 H 2O
b) 2 NaN3 3N 2 2 Na
c) NH 4 2 Cr2O7 N 2 4 H 2O Cr2O3
d) NH 4 NO3 N 2O 2 H 2O
53. 3
Volume of unit cell a3 100 1010 1 1024 cm3
No.of atoms in fcc unit cell = 4
4 24 4 1024
Mass of unit cell = 4 1024 g , Density = 4 gcm 3
25 24
2.4 10 1 10
54. Ag aq Cl aq AgCl 1 mole of Cl ion = 1 mole of AgCl
Moles of the compound = MVL 0.15 0.1 0.015 , Moles of AgCl formed = 0.03
No.of Cl ions furnished by a formula unit of CoCl3 xNH 3 2
Formula of the compound = Co NH 3 5 Cl Cl2 x 5
55. Nylon – 6, Nylon – 6,6, Dacron, glyptal, and Bakelite are step –growth or
condensation polymers.
56. 3RT1 2 RT2
M1 M2
57. pKa1 pka2
Piso
2
58. In simple cubic lattice, packing efficiency is 52%. The co-ordination number of each
x 52
atom = 6. x : 52 and y = 6 8.67
y 6
59. Magnetic moment, n n 2 BM
60. 3 3 o
For bcc, r a r 4.29 1.86 A 186 pm
4 4
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
MATHEMATICS
61. f x is not strictly increasing
62. x
5 4
f x 3sin t 4cos t dt f ' x 3sin x 4cos x, x 4 ,
5
3
4
These values of x is are in third quadrant where both sin x and cos x are negative
5 4
Then f ' x 0 for x , ,
4 3
Hence, f x is decreasing for these values of x . Then the least value of function
4
3
4 3 1
occurs at x . f min imum 3sin t 4cos t dt 2 3
3 5
2 2
4
63. Is one-one when
23 ln1 b2 3b 10 b2 3b 2 0 b 1,2
64. f x T f x 2T ..... f x nT f x
n n 1
n
nf x 1 2 3 .... n 2 3
lim lim
n f x 1 22 32 ... n 2
n n n 1 2n 1 2
6
65. 1 1
lim 1 x ln tan x lim 1 ln tan x 1
x x
4 4
66. 1
f f x x f ' g x g ' x 1 g ' x 1 g x
5
f ' g x
g '' x 5 g x g ' x
4
67.
3 7
Not differentiable at x 3, ,
4 4
69.
f k 2 2k 5 f k 11
k 2 2k 5 k 11 k 3,2
72. 9 16 25 32
Distance of line from centre
25 5
32 7
Shortest distance 5
5 5
73. 4
A.M. , , , 1
4
G.M. , , , 1 1
4
So, equation is x 1 0
74. 1, 1, 1, 1 as 12 12 12 12 0
a
The roots of given equation is equal to 1 S2 2 6
a0
75. 5
A1B 1 B 1A1 C A1 B 1
5
I
76.
77. x2 y 2
x y 2 and 1
9 4
2
dy 2 y dy
1
dx x dx
80. 2
dy ex
Let f x y 2 xy
dx x 12
81. a dy xa . y ay1
a a 1
x .y ; y
a a
, a x a m
a dx a 1 x1
x x
1 y 1 2 1
a .x11 a 1 a
2
A y1 mx1 x1 1 y1x1 1 a
2 m 2 2
For A to be constant 1 a 0
82. dy d 2 y dy
2
2 2
y cos x 2, 2 y sin 2 x, y cos 2 x
dx dx 2 dx
d2y dy 2
2
y 4 y3 cos 2 x 2 cos 2 x 2 cos 2 x 6
dx 2 dx
83. 2
t 2 f x 1 x 1 f t
2
2tf x 1 x 1 f ' t
lim 1 lim 1
t x 1 f t f x 1 t x 1 f 't
x 1 2 f x 1 x 1 f ' x 1 f ' x 1
84. Conceptual
85. e2
xy 1 y dx dy if 0 1 and f 2
k e2
1 1 y y
xdx dy xdx dy
y 1 y y 1 y
1 1 1 1
xdx dy xdx dy
y 14 y y 1 y
x2 O2
log y log 1 y log C , f 0 1 log1 log 2 log C
2 2
log C log 2 C 2
x2 sin
90. 1 1
5
Ar 4 1 x 2/5 dx 4 x x 7/5
7 0 7
8
0