STANDARD OPERATING PROCEDURES FOR HAZARDOUS AND PARTICULARLY HAZARDOUS

CHEMICALS
For
Hydrochloric Acid

1. PROCEDURE / Hydrochloric Acid is used in Building, Room.

PROCESS
Insert procedure here:

REMEMBER! Always add acid to water to limit exothermic reactions such as

splatter, bubbling and fuming.

A large amount of heat is generated when strong acids are mixed with water.
Adding more acid releases more heat. Adding water to acid forms an extremely
concentrated solution of acid. Heat causes the solution to boil violently,
splashing concentrated acid out of the container.

Adding acid to water, the resulting solution is dilute and the heat released is
absorbed by the water.

Always Add Acid to water.

2. CHEMICAL NAME(S) Hydrochloric Acid- CAS# 7647-01-0; also known as muriatic acid and
and associated hydrogen chloride.
PHYSICAL and
HEALTH  Corrosive chemical. May severely irritate and burn the skin and eyes
HAZARDS with possible eye damage. May be absorbed through the skin.
 May be corrosive to metals.
 Contact with the liquid may cause frostbite.
 May cause respiratory irritation of the nose, throat, and lungs.
 Long term exposure may cause yellowing and erosion of the teeth.
 Exposures may affect the liver and kidneys as well as the mucous
membranes of the eyes, mouth and respiratory tract.

Signal Word: DANGER

Exposure Limits:
DOSH: CEIL: 5 ppm
NIOSH: CEIL: 5 ppm
ACGIH: CEIL: 2 ppm

Toxicological Data:
INHALATION (LC50): 4,701 ppm 0.5 hour [Rat].

*Always refer to the Safety Data Sheet for the most detailed information*

3. NAME OF TRAINER / Principal Investigator Name, Building, Room, Phone Number

RESOURCE Secondary contact Name, Building, Room, Phone Number
PERSON
4. LOCATION OF The Safety Data Sheet (SDS) for Hydrochloric Acid is located in the Laboratory
HEALTH & SAFETY Safety Manual in Building, Room
INFORMATION
Labeling: Containers shall either have original warning label affixed or a label
identifying the contents and hazards.
5. PROTECTIVE Wear at the minimum nitrile, neoprene, butyl, or Viton gloves, chemical splash
EQUIPMENT goggles, and a fully buttoned lab coat. Wash hands after removing gloves.
Always work within a properly functioning, certified laboratory chemical fume
hood.

6. WASTE DISPOSAL Waste Hydrochloric Acid must be managed as Dangerous Waste if the
PROCEDURES solution has a pH of 5 or lower. Collect solution in a compatible container with
a vented lid. The container should be stored away from incompatible materials
such as organic acids, oxidizing agents, strong bases, amines, alkali metals,
metals, aldehydes, epoxides, alcohols, hexalithium disilicide, permanganates
(e.g. potassium permanganate), hydrogen cyanide and fluorine.

A completed Dangerous Waste label should be attached when waste is first

added to the container. When container is full or no longer being used
complete a Chemical Collection Request Form, and deliver to the Waste
Accumulation Area Operator at Building, Room, Phone Number.

If the solution has a pH between 5 and 9 it may be drained discharge. The

solution cannot legally be diluted to alter the pH for disposal purposes

7. DESIGNATED AREA The hydrochloric acid is stored and dispensed in Building, Room.
INFORMATION
Diluted acid solutions using this chemical are prepared immediately prior to use
in Building, Room.

Confine all work with hydrochloric acid to a properly functioning certified

laboratory chemical fume hood.

The designated area(s) should be shown on the floor plan in Laboratories

Chemical Hygiene Plan.

8. DECONTAMINATION Upon Accidental Exposure:

PROCEDURES In case of eye contact, flush eyes with copious amounts of water at an
emergency eyewash station for at least 15 minutes and seek medical attention.

In case of skin contact, flush skin with copious amounts of water for 15
minutes and seek medical attention. For exposure over a large portion of the
body, remove clothing and shoes and rinse thoroughly in an emergency shower
for at least 15 minutes. Seek medical attention.

In case of inhalation, move person to fresh air and seek medical attention.

In case of ingestion, immediately seek medical attention and follow instructions

on SDS.

Upon Accidental Release:

Large Spill: If a significant amount of Hydrochloric acid is spilled outside the
fume hood, immediately evacuate, secure area, and call 911 to contact EH&S.

Small Spill: If a small amount of Hydrochloric acid is spilled (it can be cleaned
up in 10 minutes) and you have been appropriately trained to clean it up, you
may do so. Trained personnel should wear at the minimum nitrile, neoprene,
butyl or Viton gloves, chemical splash goggles, and a fully-buttoned lab coat.

Additional PPE such as respirators may be necessary depending upon material

and concentration. (Note: You must be medically cleared, fit tested and enrolled
in WSU’s respiratory protection program to wear a respirator). If it is necessary
to use a respirator and personnel are not cleared to wear a respirator and not
trained to appropriately clean up the spill, the employee should immediately
evacuate, secure area, and call 911 to contact EH&S.
 Absorb with an inert dry material and place material in an appropriate waste
disposal container (resealable bag, etc.) and dispose of as hazardous waste
(see above WASTE DISPOSAL PROCEDURES).

Please do not use a neutralizer to clean up spill unless you are currently in the
respiratory protection program and have been properly trained.

As with all accidents, report any exposure as soon as possible to your Principal
Investigator or Supervisor. Additional health and safety information on
hydrochloric acid can be obtained by referring to the SDS or by calling the
EH&S Office (335-3041).

9. SPECIAL STORAGE Store in a secured, cool and well-ventilated area away from direct sunlight,
AND HANDLING heat, sparks, flame, or other sources of ignition. Store segregated from
PROCEDURES incompatible chemicals (below). Store in a tightly closed container until ready
for use. Store in secondary containment such as a Nalgene/polypropylene tub.

Keep away from incompatibles such as organic acids, oxidizing agents, strong
bases, amines, alkali metals, metals, aldehydes, epoxides, alcohols,
hexalithium disilicide, permanganates (e.g. potassium permanganate),
hydrogen cyanide and fluorine.
 Certification of Hazard Assessment

Is this document a certification of Hazard Assessment for the processes identified within?
Yes No

If yes, provide the name of the person certifying the Hazard Assessment and the date it was performed:

____________________________________________________________________________________

Name Date

The location of the Hazard Assessment is indicated in the document preceding this form.

Certificate of Employee Training

Name of person providing training for employees working with this process:

___________________________________________________________________________________

The following employees have been trained in when, where and how to use selected PPE, the maintenance,
limitations and disposal of the PPE selected, and have demonstrated the correct use of the PPE selected on
the reverse of this certification.

Name Date Trained

________________________________________ _______________________________

________________________________________ _______________________________

________________________________________ _______________________________

________________________________________ _______________________________

________________________________________ _______________________________

________________________________________ _______________________________

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