Cblechpl 06125
Cblechpl 06125
SECTION-A
Directions (Q. Nos. 1-18) : The following questions are multiple-choice questions with one correct answer.
Each question carries 1 mark. There is no internal choice in this section.
1. Which one of the following will produce maximum depression of freezing point?
View Solution (a) K SO (b) NaCl
2 4
6. What are the products formed by the chlorination of methane in diffused sunlight?
View Solution (a) CCl (b) CH Cl
4 2 2
11. Which of the following aqueous solution should have the highest boiling point?
View Solution (a) 1.0 M NaOH (b) 1.0 M Na 2 SO 4
(c) 1.0 M NH 4 NO 3 (d) 1.0 M KNO 3
12. Which of the following statement for order of reaction is not correct?
View Solution (a) Order can be determined experimentally
(b) Order of reaction is equal to sum of the powers of concentration terms in differential rate
law
(c) It is not affected with the stoichiometric coefficient of the reactants
(d) Order cannot be fractional
14. Mercuric chloride reacts with ammonia gas and forms white precipitate. The molecular formula
View Solution of white precipitate is –
Hg ^NH 3h2 Cl 2
(a) HCl 2 $ 2NH 3 (b)
(c) Hg ^NH 2h Cl 2 (d)
Hg ^NH 2h Cl
Directions (Q. No. 15-18) : Each of the following questions consists of two statements, one is Assertion
and the other is Reason. Give answer :
17. Assertion : According to transition state theory for the formation of an activated complex. one
View Solution of the vibrational degree of freedom.
Reason : Energy of the activated complex is higher than the energy of reactant molecules.
(a) Both Assertion and Reason are correct and Reason is a correct explanation of the Assertion.
(b) Both Assertion and Reason are correct but Reason is not the a correct explanation of the
Assertion.
(c) Assertion is correct but Reason is incorrect.
(d) Both the Assertion and Reason are incorrect.
SECTION-B
Directions (Q. No. 19-25) : This section contains 7 questions with internal choice in two questions. The
following questions are very short answer type and carry 2 marks each.
25. (i) What happens when iodoform is heated with silver powder? Write the chemical equation.
View Solution (ii) Out of ethyl bromide and ethyl chloride which has higher boiling point and why?
Section-C
Directions (Q. No. 26-30) : This section contains 5 questions with internal choice in two questions. The
following questions are short answer type and carry 3 marks each.
28. Write the electronic configuration of Cu+ and also draw the figure.
View Solution
o
Arrange the following compounds in the increasing order of their boiling points :
CH 3 CH 2 CH 2 CHO , CH 3 CH 2 CH 2 CH 2 OH ,
H 5 C 2 - O - C 2 H 5, CH 3 CH 2 CH 2 CH 2 CH 3
SECTION-D
Directions (Q. No. 31-32) : The following questions are case-based questions. Each question has an internal
choice and carries 4 marks each. Read the passage carefully and answer the questions that follow.
31. Oxidation of Aldehydes and Ketones (Popoff’s Rule)Aldehydes differ from ketones in their
View Solution oxidation reactions.
Aldehydes are easily oxidised to carboxylic acids on treatment with common oxidising agents
like HNO3, KMnO4, K2Cr2O7, etc. Even mild oxidising agents mainly Tollen’s reagent, Fehling’s
solution, Benedict reagents, also oxidise aldehydes.
Ketones are difficult to oxidise. They are oxidised by strong oxidising agents at elevated temperature.
Their oxidation involves C—C cleavage to form mixture of carboxylic acids. The oxidation of
ketones is governed by Popoff’s rule. ‘In unsymmetrical ketones, on oxidation of ketones to
32. Most distinctive properties of transition metal complexes is their wide range of colours. The
View Solution colour of complex is complementary to that which is absorbed. The complementary colour is
the colour generated from the wavelength left over. The following table gives the relationship
of the different wavelength absorbed and the colour observed.
Table : Relationship between the Wavelength of Light absorbed and the Colour observed in
some Coordination Entities Coordination entity
Coordination entity Wavelength of light Colour of light Colour of
absorbed (nm) absorbed coordination entity
[CoCl(NH3)5] 535 Yellow Violet
[Co(NH3)5 500 Blue Green Red
(H2O)]3+
[Co(NH3)6]3+ 475 Blue Yellow Orange
[Co(CN)6]3-
310 Ultraviolet Pale Yellow
[Cu(H2O)4]2+ 600 Red Blue
[Ti(H2O)6]3+ 489 Blue Green Violet
(a) Why does [Co(CN)6]3- absorb U.V. light and not from visible region?
(b) Why is [Ti(H2O)6]3+ violet in colour where as [Cu(H2O)4]2+ is blue?
(c)
(i) If CFSE for [Co(NH3)6]3+ is 27000 cm-1, what is CFSE for [Cu(H2O)4]2+?
(ii) Why is [Ti(H2O)6]4+ colourless?
o
(d) What will be the correct order for the wavelength of absorption for the following complexes?
Give reason.
[Co(CN)6]3-, [Co(NH3)6]3+, [Cu(H2O)6]2+
SECTION-E
Directions (Q. No. 33-35) : The following questions are long answer type and carry 5 marks each. Two
questions have an internal choice.
34. What are the shortcomings of valence bond theory for bonding in complexes? Briefly describe
View Solution the crystal field theory.
o
Briefly describe the importance of coordination compounds in:
(i) Qualitative analysis
(ii) Extraction of metals
(iii) Biological systems
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