Exercise

Periodic Table & Periodicity
 Marked Questions may have for Revision Questions.
PART - I : SUBJECTIVE QUESTIONS

Section (A) : Development of Periodic Table & Modern Periodic Table
A-1. Explain the following :
(i) Why argon (atomic mass = 39.94) has been placed before potassium (atomic mass = 39.10) in the
Modern periodic table ?
(ii) There are only 14 lanthanides and only 14 actinides in Modern periodic table.
A-2. Why the third period of Modern periodic table contains 8 elements and not 18?
Section (B) : Shielding Effect & Zeff
B-1. Tell the relation between effective nuclear charge (Zeff), atomic number (Z) and shielding constant ().
Explain it qualitatively.
B-2. Which orbital electrons are known to shield the nuclear charge improperly ? Does this generate some
irregularity in properties of elements ?
Section (C) : Oxidation states & Inert pair effect
C-1. Pb4+ compounds are very good oxidising agents. Explain.
C-2. Arrange the following in correct order of stability :
(i) Ga+, In+, Tl+ (ii) As+5, Sb+5, Bi+5
Section (D) : Atomic and Ionic radius
D-1. Explain why cations are smaller and anions larger in radii than their parent atoms ?
D-2. The atomic radii of palladium and platinum are nearly same. Why ?
D-3. In the ionic compound KF, the K+ and F– ions are found to have practically identical radii, about 1.34 Å
each. What can you predict about the relative atomic radii of K & F ?
Section (E) : Ionisation energy
E-1. Why second ionization enthalpy is always higher than the first ionisation enthalpy for every element ?
E-2. The first ionization enthalpy of carbon is greater than that of boron, whereas the reverse is true for
second ionization enthalpy. Explain.
E-3. Among the elements B, Al, C and Si, (i) which element has the highest first ionisation enthalpy ?
(ii) which element has the most metallic character ?
Justify your answer in each case.
Section (F) : Electron gain enthalpy
F-1. Be and Ne have positive values of electron gain enthalpy against the general trend in their period in
Modern periodic table. Explain.
F-2. Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower
ionisation enthalpy than nitrogen. Explain.
Section (G) : Electronegativity
G-1. Among alkali metals, which element do you expect to be least electronegative ?
G-2. Explain the following according to Modern periodic table :
(a) Electronegativity of elements increase on moving from left to right in a period.
(b) Ionisation enthalpy decrease in a group from top to bottom.
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PART - II : ONLY ONE OPTION CORRECT TYPE
A-1. The period number in the long form of the periodic table is equal to :
(A) magnetic quantum number of any element of the period.
(B) atomic number of any element of the period.
(C) maximum Principal quantum number of any element of the period.
(D) maximum Azimuthal quantum number of any element of the period.
A-2. Which one of the following statements related to the modern periodic table is incorrect :
(A) The p-block has 6 columns, because a maximum of 6 electrons can occupy all the orbitals in a
p-subshell.
(B) The d-block has 8 columns, because a maximum of 8 electrons can occupy all the orbitals in a
d-subshell.
(C) Each block contains a number of columns equal to the number of electrons that can occupy that
subshell.
(D) The block indicates value of Azimuthal quantum number () for the last subshell that received
electrons in building up the electronic configuration.
A-3. The elements in which electrons are progressively filled in 4f-orbital are called :
(A) actinoids (B) transition elements (C) lanthanoids (D) halogens
A-4. Which of the following statements is not correct regarding hydrogen :
(A) It resembles halogens in some properties.
(B) It resembles alkali metals in some properties.
(C) It can be placed in 17th group of Modern periodic table.
(D) It cannot be placed in 1st group of Modern periodic table.
A-5. Atomic number of Ag is 47. In the same group, the atomic numbers of elements placed above and
below Ag in Long form of periodic table will be :
(A) 29, 65 (B) 39, 79 (C) 29, 79 (D) 39, 65
A-6. In modern periodic table, the element with atomic number Z = 118 will be :
(A) Uuo; Ununoctium; alkaline earth metal (B) Uno; Unniloctium; transition metal
(C) Uno; Unniloctium; alkali metal (D) Uuo; Ununoctium; noble gas
Section (B) : Shielding Effect & Zeff
B-1. The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer
shell electrons is :
(A) s > p > d > f (B) f > d > p > s (C) p < d < s > f (D) f > p > s > d
B-2. Which of the following is generally true regarding effective nuclear charge (Z eff) :
(A) It increases on moving left to right in a period.
(B) It remains almost constant on moving top to bottom in a group.
(C) For isoelectronic species, as Z increases, Zeff decreases.
(D) Both (A) and (B).
B-3. Among following species which of them have maximum Zeff.
(A) Sn (B) Sn4+ (C) In (D) In+
B-4. From the given set of species, point out the species from each set having highest Z eff
(a) O2–, F–, Na+ (b) Li, Be, Na (c) He, Li+, H–
a b c a b c
(A) Na+ Be Li+ (B) O2– Li H–
– +
(C) F Na He (D) Na Be He
Section (C) : Oxidation states & Inert pair effect
C-1. The atomic number of an element which can not show the oxidation state of +3 is-
(A) 13 (B) 32 (C) 33 (D) 17
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C-2. The most common oxidation state of an element is –2. The number of electrons present in its outer
most shell is -
(A) 2 (B) 4 (C) 6 (D) 8
C-3. Most stable oxidation state of gold is :
(A) + 1 (B) +3 (C) +2 (D) zero
C-4. Which can have both +ve and –ve oxidation states in their compounds
(A) F (B) I (C) Na (D) Al
C-5. The oxidation state of nitrogen varies from :

(A) –3 to + 5 (B) 0 to +5 (C) –3 to 1 (D) +3 to +5
C-6. Which metal exhibtis more than one oxidation states in their compounds
(A) Na (B) Mg (C) Al (D) Fe
C-7. Electrons of which subshell do not participate in bonding due to inert pair effect ?
(A) 6s (B) 6p (C) 5d (D) 4f
C-8. Thallium shows different oxidation states because :
(A) of its high reactivity (B) of inert pair of electrons
(C) of its amphoteric nature (D) its is a transition metal
C-9. In which of the following elements, + 3 oxidation state is more stable than + 5 ?
(A) P (B) As (C) N (D) Bi
C-10. Which of the following is correct order of stability :
(A) Tl3+ > Bi3+ (B) PbO2 > PbO (C) BiI5 < BiF5 (D) Sn2+ = Ge2+
Section (D) : Atomic and Ionic radius

D-1. Select correct statement about radius of an atom :
(A) Values of Vander waal's radii is larger than those of covalent radii because the Vander waal's forces
are much weaker than the forces operating between atoms in a covalently bonded molecule.
(B) The metallic radii is smaller than the Vander waal's radii, since the bonding forces in the metallic
crystal lattice are much stronger than the Vander waal's forces.
(C) Both (A) & (B)
(D) None of these
D-2. Match the correct atomic radius with the element :
S.No. Element Code Atomic radius (pm)
(i) Be (p) 74
(ii) C (q) 88
(iii) O (r) 111
(iv) B (s) 77
(v) N (t) 66
(A) (i) – r, (ii) – q, (iii) – t, (iv) – s, (v) – p (B) (i) – t, (ii) – s, (iii) – r, (iv) – p, (v) – q
(C) (i) – r, (ii) – s, (iii) – t, (iv) – q, (v) – p (D) (i) – t, (ii) – p, (iii) – r, (iv) – s, (v) – q
D-3. Choose the correct order of atomic radii of Fluorine and Neon (in pm) out of the options given below :
(A) 72, 160 (B) 160, 160 (C) 72, 72 (D) 160, 72
D-4. The size of isoelectronic species O–2, F– and Na+ is affected by :
(A) nuclear charge (Z)
(B) valence principal quantum number (n)
(C) electron-electron interaction in the outer orbitals
(D) none of the factors because their size is the same.
D-5. Which of the following order of atomic / ionic radius is not correct ?
(A) F < Cl Sr2+ > Rb+ (C) Nb  Ta (D) Li > Be > B
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E-1. Which one of the following statements is incorrect in relation to ionisation enthalpy ?
(A) Ionization enthalpy increases for each successive electron.
(B) The greatest increase in ionization enthalpy is experienced on removal of electron from core of
noble gas configuration.
(C) End of valence electrons is marked by a big jump in ionization enthalpy.
(D) Removal of electron from orbitals bearing lower n value is easier than from orbitals having higher n
value.
E-2. The first ionisation enthalpies (in eV) of N & O are respectively given by :
(A) 14.6, 13.6 (B) 13.6, 14.6 (C) 13.6, 13.6 (D) 14.6, 14.6
E-3. The first ionisation enthalpies of Na, Mg, Al and Si are in the order :
(A) Na < Mg > Al < Si (B) Na > Mg > Al > Si (C) Na < Mg < Al < Si (D) Na > Mg > Al < Si
st
E-4. Which represents alkali metals (i.e. 1 group metals) based on (IE)1 and (IE)2 values (in kJ/mol) ?
(IE)1 (IE)2 (IE)1 (IE)2
(A) X 500 1000 (B) Y 600 2000
(C) Z 550 7500 (D) M 700 1400
E-5. Which of the following relation is correct with respect to first (I) and second (II) ionization enthalpies of
potassium and calcium ?
(A) ICa > IIK (B) IK > ICa (C) IICa > IIK (D) IIK > IICa
Section (F) : Electron gain enthalpy

F-1. Among halogens, the correct order of amount of energy released in electron gain (electron gain
enthalpy) is:
(A) F > Cl > Br > I (B) F < Cl Br > I (D) Cl > Br > F > I
F-2. Which of the following will have the most negative electron gain enthalpy and which the least negative ?
F, P, S, Cl.
(A) P, Cl (B) Cl, F (C) Cl, S (D) Cl, P
F-3. The order of electron gain enthalpy (magnitude) of O, S and Se is :
(A) O > S > Se (B) S > Se > O (C) Se > S > O (D) S > O > Se
F-4. Electronic configurations of four elements A, B, C and D are given below :
(i) 1s22s22p6 (ii) 1s22s22p4 (iii) 1s22s22p63s1 (iv) 1s22s22p5
Which of the following is the correct order of increasing tendency to gain electron :
(A) (i) < (iii) < (ii) < (iv) (B) (i) < (ii) < (iii) < (iv) (C) (iv) < (ii) < (iii) < (i) (D) (iv) < (i) < (ii) < (iii)
F-5. Which of the following statement is correct ?
(A) Electron gain enthalpy may be positive for some elements.
(B) Second electron gain enthalpy always remains positive for all the elements.
(C) egH(K+) = – IE (K)
(D) All of these
Section (G) : Electronegativity
G-1. Which of the following is affected by the stable electron configuration of an atom ?
(a) Electronegativity (b) Ionisation enthalpy (c) Electron gain enthalpy
Correct answer is :
(A) only electronegativity (B) only ionisation enthalpy
(C) both electron gain enthalpy and ionisation enthalpy (D) all of the above
G-2. The electronegativity values of C, N, O and F on Pauling scale :
(A) decrease from carbon to fluorine.
(B) increase from carbon to fluorine.
(C) increase upto oxygen and then decrease upto fluorine.
(D) decrease from carbon to nitrogen and then increase continuously.
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G-3. Correct order of electronegativity of N, P, C and Si on Pauling scale is :
(A) N > P > C > Si (B) C > Si > N > P (C) N C > P > Si
G-4. The correct order of electronegativity on Pauling scale is :
(A) F > Cl > O > S (B) Li > Na > K > Rb > Cs
(C) Be < B < N < C (D) Both (A) and (B)
G-5. Which of the following is most electronegative element.
(A) Li (B) Mg (C) H (D) Na
PART - III : MATCH THE COLUMNS

1. Match the column.
Column-I
Column-II
(Atomic number)
(A) 57 (p) is d-Block or p-Block element
(B) 17 (q) is 4th period element
(C) 19 (r) is violates Aufbou’s principle element
(D) 29 (s) is non metal
(t) is s-Block element

2. Match the column.
Column-I Column-II
(A) O(g) + e– — O– (g) (p) Positive Electron gain enthalpy
(B) O–(g) + e– — O2–(g) (q) Negative Electron gain enthalpy
(C) Na–(g) — Na(g) + e– (r) Exothermic
(D) Mg+(g) + e– — Mg(g) (s) Endothermic
 Marked Questions may have for Revision Questions.
PART - I : ONLY ONE OPTION CORRECT TYPE

1. The statement that is not correct for periodic classification of elements in Modern periodic table is :
(A) The properties of elements are periodic function of their atomic numbers.
(B) Non-metallic elements are less in number than metallic elements.
(C) For transition elements, the 3d-orbitals are filled with electrons after 3p-orbitals and before 4s-
orbitals.
(D) The first ionisation enthalpies of elements generally increase with increase in atomic number as we
go along a period.
2. Which of the following is true about the element 33As according to Modern periodic table :
(A) It is a 5th period element. (B) It is a p-block element.
(C) It belongs to 16th group. (D) It is one among typical elements.
3. Which of the following contains atomic number of only s-block
(A) 55,12,18,53 (B) 13,33,54,83 (C) 3, 20, 55, 87 (D) 22,33,55,66
4. Screening effect is not observed in :
(A) He+ (B) Li2+ (C) Be3+ (D) In all cases
5. Which of the following have higher Zeff than Fluorine.
(A) Cl (B) O (C) F – (D) none of these
6. The oxidation number that iron does not exhibit in its common compounds or in its elemental state is :
(A) 0 (B) +1 (C) +2 (D) +3
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7. Which of the following can show +7 oxidation state?
(A) Mn (B) F (C) In (D) N
8. Which of following does not exist :
(A) TlI3 (B) PbF4 (C) Both (A) and (B) (D) None of these
9. Elements of which period show maximum inert pair effect :
(A) 3 (B) 4 (C) 5 (D) 6
10. When the following five anions are arranged in order of decreasing ionic radius, the correct sequence
is:
(A) Se2–, I–, Br–, O2–, F– (B) I–, Se2–, Br–, F–, O2–
2– – – –
(C) Se , I , Br , F , O 2–
(D) I–, Se2–, Br–, O2–, F–
11. In which of the following compounds, manganese shows maximum radius ?
(A) MnO2 (B) KMnO4 (C) MnO (D) K3[Mn(CN)6]
12. Which of the following is the correct order of ionisation enthalpy ?
(1) Be+ > Be (2) Be > Be+ (3) C > Be (4) B > Be
(A) 2, 3 (B) 3, 4 (C) 1, 3 (D) 1, 4
13. Considering the elements B, Al, Mg, and K, the correct order of their metallic character is :
(A) B > Al > Mg > K (B) Al > Mg > B > K (C) Mg > Al > K > B (D) K > Mg > Al > B
14. Fluorine has the highest electronegativity among the ns2np5 group on the Pauling scale, but the
electron affinity of fluorine is less than that of chlorine because :
(A) the atomic number of fluorine is less than that of chlorine.
(B) fluorine being the first member of the family behaves in an unusual manner.
(C) chlorine can accommodate an electron better than fluorine by utilising its vacant 3d–orbital.
(D) small size, high electron density and an increased electron repulsion makes addition of an electron
to fluorine less favourable than that in the case of chlorine in isolated stage.
15. Which one of the following arrangements represents the correct order of electron gain enthalpy (with
negative sign) of the given atomic species ?
(A) Cl < F < S < O (B) O < S < F < Cl (C) S < O < Cl < F (D) F < Cl < O < S
16. Which of the following statement is incorrect ?
(A) The tendency to attract bonded pair of electron in case of hybrid orbitals follow the order: sp > sp2 >
sp3
(B) Alkali metals generally have negative value of electron gain enthalpy.
(C) Cs+(g) releases more energy upon gain of an electron than Cl(g).
(D) The electronegativity values for 2p-series elements is less than that for 3p-series elements on
account of small size and high inter electronic repulsions.
PART - II : SINGLE AND DOUBLE VALUE INTEGER TYPE

1. Identify the group (in Modern Periodic Table) and valency of a hypothetical element having atomic
number 119. If group number is x and valency is y. Give the the value of x + y.
2. An element belonging to 3d series of modern periodic table has spin magnetic moment = 5.92 B.M. in
+3 oxidation state. Determine the atomic number of element.
3. An element has atomic number 29. It belongs to x period and y group. Give value of 2x + y :
4. How many of the following have greater Zeff than Silicon atom :
(i) Na (ii) Mg (iii) Al (iv) P (v) Cl
(vi) S (vii) N (viii) O (ix) F
5. The most stable oxidation state of chromium is +n, Give the value of ‘n’.
6. How many of the following compounds are found to exist?
(i) BiF5 (ii) TI3 (iii) PbO2 (iv) SnCl2
(v) T2O3 (vi) PbI4 (vii) As2O3
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7. The Lanthanides are characterized by the uniform [+n] oxidation state shown by all the Lanthanides .
What is the value of ‘n’
8. Highest oxidation states shown by Chromium & Manganese are +x & +y respectively. Give the value of
x+y?
9. If internuclear distance between A atoms in A2 is 10Å and between B atoms in B2 is 6Å, then calculate
internuclear distance between A and B in Å. [Electronegativity difference between A and B has
negligible value].
10. Report atomic number of the element having largest size among the following :
Ni, Cu, Zn
11. How many of following atoms have maximum ionization energy than boron.
(i) Be (ii) N (iii) P (iv) Ga (v) S (vi) Mg
12.
Where a, b, c, d, e, f, g, h are 3rd period elements. If difference between atomic number of elements b
and e is x and difference between atomic number of elements c and f is y. What is the value of x – y.
13. Values of IE1, IE2, IE3 of an element are 9.3, 18.2 and 553.8 eV. Predict group number in Modern
Periodic Table.
14. A– (g)  A2+ (g) H = 1100 KJ/mol
A (g)  A2+ (g) H = 1200 KJ/mol
Electron gain enthalphy of A is P × 102 KJ/mol. What is the value of P ?
15. The electron gain enthalpy of a hypothetical element ‘A’ is –3 eV per atom. How much energy in kCal is
released when 10 g of ‘A’ are completely converted to A– ions in gaseous state ?
(Take : 1 eV per atom = 23 kCal mol–1, Molar mass of A = 30 g)
16. What is atomic number of element which have maximum electron affinity in Modern Periodic table.
17. How many of the following elements are more electronegative than Boron.
(i) H (ii) Li (iii) Be (iv) C (v) N (vi) O (vii) F
PART - III : ONE OR MORE THAN ONE OPTIONS CORRECT TYPE

1. The group in modern periodic table in which all the elements do not have same number of electrons in
their outermost shell is (considering upto 6th period) :
(A) 13th (B) 11th (C) 9th (D) 18th
2. Element corresponding to which of these/this atomic number belongs to p-block in Modern Periodic
Table :
(A) 19 (B) 35 (C) 53 (D) 83
3. Which of the following have greater Zeff than Zn :
(A) Cu+ (B) Cu2+ (C) Fe3+ (D) Zn2+
4. Which of the following is/are correct regarding oxidation state of elements in their compounds :
(A) All d-Block elements show multiple oxidation state.
(B) All p-Block elements show multiple oxidation state.
(C) All s-Block elements show single oxidation state.
(D) Some of 18 group elements can show multiple oxidation state.
5. Which of the following elements have + 3 as most popular oxidation state?
(A) Al (B) Xe (C) Cu (D) Sc
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6. Which of the following show non-zero multiple oxidation state ?
(A) S (B) O (C) Zn (D) H
7. Which of the following pairs of elements show similar set of oxidation state ?
(A) O16, O18 (B) Na, K (C) C, Be (D) Zn, Rb
8. Which of the following elements have their lower oxidation state as more stable oxidation state.
(A) O (B) Pb (C) T (D) Bi
9. Which is/are the correct order/s of atomic radius ?
(A) Li Be > B (D) N > O > F
10. Which is/are the correct order/s of atomic radius ?
(A) Mn > Fe > Co (B) Mn  Fe  Co (C) Sc > Ti > V (D) Zn < Cu < Ni
11. Which of the following orders is(are) correct for size :
(A) Al  Ga (B) Te2– > I– > Cs+ > Ba2+
3+
(C) Cr < Cr 6+
(D) Pd  Pt
12. The ionic radii depends upon in the following factors :
(A) Charge on cation
(B) Charge on anion
(C) Shell number of valence shell electron(s) of the ion.
(D) Effective nuclear charge
13. Which of the following statements is/are correct ?
(A) The second ionization enthalpy of oxygen element is greater than that of fluorine element.
(B) The third ionization enthalpy of phosphorus is greater than that of aluminium.
(C) The first ionization enthalpy of aluminium is slightly greater than that of gallium.
(D) The second ionization enthalpy of copper is greater than that of zinc.
14. Which of the following elements will gain one electron more readily in comparison to other elements of
their group ?
(A) S(g) (B) N(g) (C) O(g) (D) Cl (g)
15. Which of the following is/are correct order/s of electron affinity.
(A) N < C < O < F (B) P < Si < S < Cl (C) Si Rb > Na (B) Li < Be F > Br
17. Choose the correct statement(s) :
(A) In general more the ionisation energy more will be electronegativity.
(B) Electronegativity increase means metallic character increases.
(C) In general lower will be the ionisation energy, easier will be to remove electron.
(D) Electron affinity of S is less than that of Cl.
PART - IV : COMPREHENSION
Read the following passage carefully and answer the questions.
Comprehension # 1
In the modern periodic table, elements are arranged in order of increasing atomic numbers which is
related to the electronic configuration. Depending upon the type of orbitals receiving the last electron,
the elements in the periodic table have been divided into four blocks, viz, s, p, d and f. The modern
periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy
shell. In accordance with the Arfbau principle, the seven periods (1 to 7) have 2, 8, 8, 18, 18, 32 and 32
elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long,
the two series of f-block elements, called lanthanoids and actinoids are placed at the bottom of the main
body of the periodic table.
Now answer the following five questions :
1. The element with atomic number 57 belongs to :
(A) s-block (B) p-block (C) d-block (D) f-block
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2. The last element of the p-block in 6th period is represented by the outermost electronic configuration :
(A) 7s27p6 (B) 5f 146d107s27p0 (C) 4f 145d106s26p6 (D) 4f 145d106s26p4
3. Which of the elements, whose atomic numbers are given below, cannot be accommodated in the
present set up of the long form of the periodic table ?
(A) 107 (B) 118 (C) 126 (D) 102
4. The electronic configuration of the element which is just above the element with atomic number 43 in
the same group is ________:
(A) 1s22s22p63s23p63d54s2 (B) 1s22s22p63s23p63d54s34p6
2 2 6 2 6 6 2
(C) 1s 2s 2p 3s 3p 3d 4s (D) 1s22s22p63s23p63d74s2
5. The elements with atomic numbers 35, 53 and 85 are all ________ :
(A) noble gases (B) halogens (C) heavy metals (D) light metals
Comprehension # 2
It is not possible to measure the atomic radius precisely since the electron cloud surrounding the atom
does not have a sharp boundary. One practical approach to estimate the size of an atom of a non-
metallic element is to measure the distance between two atoms when they are bound together by a
single bond in a covalent molecule and then dividing by two. For metals we define the term “metallic
radius” which is taken as half the internuclear distance separating the metal cores in the metallic
crystal. The van der waal’s radius represents the over all size of the atoms which includes its valence
shell in a non bonded situation. It is the half of the distance between two similar atoms in separate
molecules in a solid. The atomic radius decreases across a period and increases down the group.
Same trends are observed in case of ionic radius. Ionic radius of the species having same number of
electrons depends on the number of protons in their nuclei. Sometimes, atomic and ionic radii give
unexpected trends due to poor shielding of nuclear charge by d- and f-orbital electrons.
Now answer the following three questions :
6. Which of the following relations is correct, if considered for the same element :
(A) rVanderwaal > rCovalent > rMetallic (B) rCovalent > rMetallic > rVanderwaal
(C) rVanderwaal > rMetallic > rCovalent (D) rMetallic > rCovalent > rVanderwaa
7. K+, CI–, Ca2+, S2– ions are isoelectronic. The decreasing order of their size is :
(A) Ca2+ > K+ > Cl– > S2– (B) S2– > Cl– > K+ > Ca2+
–
+ 2+
(C) K > Cl > Ca > S 2–
(D) S2– > Cl– > Ca2+ > K+
8. Select the INCORRECT option regarding atomic/ionic sizes :
(A) Zn > Cu (B) Pb2+ > Pb4+ (C) Zr  Hf (D) N3– < Al3+
Comprehension # 3
The periodicity is related to the electronic configuration. That is, all chemical and physical properties are
a manifestation of the electronic configuration of the elements.
The atomic and ionic radii generally decrease in a period from left to right. As a consequence, the
ionization enthalpies generally increase and electron gain enthalpies become more negative across a
period. In other words, the ionization enthalpy of the extreme left element in a period is the least and
the electron gain enthalpy of the element on the extreme right is the highest negative. This results into
high chemical reactivity at the two extremes and the lowest in the centre. Similarly down the group, the
increase in atomic and ionic radii result in gradual decrease in ionization enthalpies and a regular
decrease (with exception in some third period elements) in electron gain enthalpies in the case of main
group elements.
The loss and gain of electrons can be co-related with the reducing and oxidising behaviour, and also
with metallic and non-metallic character respectively, of the elements.
9. The correct order of the metallic character is :
(A) Al > Mg > Na > Si (B) Na > Mg < Al > Si
(C) Na > Mg > Al > Si (D) Al > Mg > Si > Na
10. Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is :
(A) B > C > Si > N > F (B) Si > C > B > N > F
(C) F > N > C > B > Si (D) F > N > C > Si > B
ADVPTP - 33
11. Which of the following statement is correct ?
(A) Ionisation enthalpies of elements decrease along a period and increase along a group in Modern
periodic table.
(B) In the 3rd period of Modern periodic table, the two most reactive elements are sodium and fluorine.
(C) Fluorine has the least negative electron gain enthalpy among all halogens.
(D) Ionisation enthalpy of Pb is greater than that of Sn.
Comprehension # 4
Answer Q.12, Q.13 and Q.14 by appropriately matching the information given in the three
columns of the following table.
Column-1 Column-2 Column-3
(I) Graphite (i) d-block elements (P) Liquid
(II) Transition elements (ii) Group-16 (Q) 6s26p4
(III) Amalgam (iii) Allotropicity (R) Lubricant
(IV) Polonium (iv) Mercury (S) Variable oxidation number.
12. For given content is column-1, the correct combination is :
(A) (I), (iii), R (B) (II), (iv), R (C) (II), (iii), S (D) (IV), (iv), Q
13. For iron the correct combination is :
(A) (III), (iv), Q (B) (II), (i), S (C) (IV), (i), Q (D) (I), (ii), P
14. The incorrect combination is :
(A) (III), (iv), P (B) (III), (i), S (C) (II), (ii), S (D) (IV), (ii), Q
PART - I : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS)

* Marked Questions may have more than one correct option.
1. The incorrect statement among the following is : [JEE- 1997(Cancelled), 2/200]
(A) the first ionization energy of Al is less than first ionization energy of Mg.
(B) the second ionization energy of Mg is greater than second ionization energy of Na.
(C) the first ionization energy of Na is less than first ionization energy of Mg.
(D) the third ionization energy of Mg is greater than third ionization energy of Al.
2. Arrange the following ions in order of their increasing size : Li +, Mg2+, K+, Al3+. [JEE-1997, 1/100]
3. Fill in the blanks :
Compounds that formally contain Pb4+ are easily reduced to Pb2+. The stability of the lower oxidation
state is due to .................
4. Assertion : F atom has a less negative electron affinity than Cl atom. [JEE-1998, 2/200]
Reason : Additional electrons are repelled more effectively by 3p electrons in Cl atom than by 2p
electrons in F atom.
(A) Both Assertion and Reason are true, and Reason is the correct explanation of Assertion.
(B) Both Assertion and Reason are true, but Reason is not correct explanation of Assertion.
(C) Assertion is true but Reason is false.
(D) Assertion is false but Reason is true.
5. Ionic radii of : [JEE-1999, 3/200]
(A) Ti4+ < Mn7+ (B) 35Cl– < 37Cl– (C) K+ > Cl– (D) P3+ > P5+
6. The correct order of radii is : [JEE-2000, 1/35]

(A) N < Be < B (B) F– < O2– < N3– (C) Na < Li < K (D) Fe < Fe2+ < Fe+4
3+
ADVPTP - 34
7. Assertion : The first ionization energy of Be is greater than that of B.
Reason : 2p orbital is lower in energy than 2s. [JEE-2000, 1/35]
(A) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(B) Both Assertion and Reason are true but Reason is not correct explanation of Assertion.
(C) Assertion is true but Reason is false.
(D) Assertion is false but Reason is true.
8. The set representing the correct order of first ionization potential is : [JEE-2001, 1/35]
(A) K > Na > Li (B) Be > Mg > Ca (C) B > C > N (D) Ge > Si > C
9. Identify the least stable ion amongst the following : [JEE-2002, 3/90]
(A) Li– (B) Be– (C) B– (D) C–
11. Among the following, the number of elements showing only one non-zero oxidation state is :
[JEE 2010, 3/163]
O, Cl, F, N, P, Sn, Tl, Na, TI
PART - II : JEE (MAIN) ONLINE PROBLEMS (PREVIOUS YEARS)

1. Which of the following series correctly represents relation between the elements from X to Y ?
XY [JEE(Main) 2014 Online (11-04-14), 4/120]
(1) 3Li  19K Ionization enthalpy increses (2) 9F  35Br Electron gain enthalpy
(3) 6C  32Ge Atomic radii increases (4) 18Ar  54Xe Noble character increases
2. Similarity in chemical properties of the atoms of elements in a group of the periodic table is most closely
related to : [JEE(Main) 2014 Online (12-04-14), 4/120]
(1) atomic numbers (2) atomic masses
(3) number of principal energy levels (4) number of valence electrons
3. Which of the following arrangements represents the increasing order (smallest to largest) of ionic radii
of the given species O2–, S2–, N3–, P3– ? [JEE(Main) 2014 Online (15-04-14), 4/120]
(1) O2– < N3– < S2– < P3– (2) O2– < P3– < N3– < S2–
(3) N3– < O2– < P3– < S2– (4) N3– < S2– < O2– < P3–
4. Which one of the following has largest ionic radius ? [JEE(Main) 2014 Online (19-04-14), 4/120]
(1) Li+ (2) O22– (3) B3+ (4) F–
5. In the long form of the periodic table, the valence shell electronic configuration of 5s25p4 corresponds to
the element present in : [JEE(Main) 2015 Online (10-04-15), 4/120]
(1) Group 17 and period 6 (2) Group 17 and period 5
(3) Group 16 and period 6 (4) Group 16 and period 5
6. The following statements concern elements in the periodic table. Which of the following is true?
[JEE(Main) 2016 Online (10-04-16), 4/120]
(1) The Group 13 elements are all metals.
(2) All the elements in Group 17 are gases.
(3) Elements of Group 16 have lower ionization enthalpy values compared to those of Group 15 in the
corresponding periods.
(4) For Group 15 elements, the stability of +5 oxidation state increases down the group.
7. Consider the following ionization enthalpies of two elements 'A' and 'B'
Element Ionization enthalpy (kJ/mol)
1st 2nd 3rd
A 899 1757 14847
B 737 1450 7731
Which of the following statements is correct ? [JEE(Main) 2017 Online (08-04-17), 4/120]
(1) Both 'A' and 'B' belong to group-1 where 'B' comes below 'A'.
(2) Both 'A' and 'B' belong to group-2 where 'A' comes below 'B'.
(3) Both 'A' and 'B' belong to group-2 where 'B' comes below 'A'.
(4) Both 'A' and 'B' belong to group-1 where 'A' comes below 'B'.
ADVPTP - 35
8. The electronic configuration with the highest ionization enthalpy is :
[JEE(Main) 2017 Online (09-04-17), 4/120]
(1) [Ne] 3s2 3p1 (2) [Ne] 3s2 3p2 (3) [Ne] 3s2 3p3 (4) [Ar] 3d10 4s2 4p3
9. For Na+, Mg2+, F– and O2– ; the correct order of increasing ionic radii is :
[JEE(Main) 2019 Online (15-04-18), 4/120]
(1) O2– < F– < Na+ < Mg2+ (2) Na+ < Mg2+ < F– < O2–
(3) Mg2+ < Na+ < F– < O2– (4) Mg2+ < O2– < Na+ < F–
10. The correct order of electron affinity is : [JEE(Main) 2019 Online (15-04-18), 4/120]
(1) F > Cl > O (2) F > O > Cl (3) Cl > F > O (4) O > F > Cl
11. Aluminium is usually found in +3 oxidation state. In contrast, thalium exists in +1 and +3 oxidation
states. This is due to : [JEE(Main) 2019 Online (09-01-19), 4/120]
(1) inert pair effect (2) lanthanoid contraction
(3) diagonal relationship (4) lattice effect
12. In general, the properties that decrease and increase down a group in the periodic table, respectively,
are : [JEE(Main) 2019 Online (09-01-19), 4/120]
(1) atomic radius and electronegativity
(2) electronegativity and atomic radius
(3) electron gain enthalpy and electronegativity
(4) electronegativity and electron gain enthalpy
13. When the first electron gain enthalpy (eg H) of oxygen is –141 kJ/mol, its second electron gain enthalpy
is : [JEE(Main) 2019 Online (09-01-19), 4/120]
(1) almost the same as that of the first (2) negative, but less negative than the first
(3) a more negative value than the first (4) a positive value
14. The effect of lanthanoid contraction in the lanthanoid series of elements by an and large means :
[JEE(Main) 2019 Online (10-01-19), 4/120]
(1) increase in atomic radii and decrease in ionic radii
(2) decrease in both atomic and ionic radii
(3) increase in both atomic and ionic radii
(4) decrease in atomic radii and increase in ionic radii
15. The electronegativity of aluminium is similar to : [JEE(Main) 2019 Online (10-01-19), 4/120]
(1) Lithium (2) Carbon (3) Boron (4) Beryllium
16. The correct order of the atomic radii of C, Cs, Al, and S is:
[JEE(Main) 2019 Online (11-01-19), 4/120]
(1) C < S < Al <Cs (2) S < C < Al < Cs (3) S < C < Cs < Al (4) C < S < Cs < Al
17. The correct option with respect to the Pauling, electronegativity values of the elements is :
[JEE(Main) 2019 Online (11-01-19), 4/120]
(1) Te > Se (2) Ga < Ge (3) Si < Al (4) P > S
18. The element with Z = 120 (not yet discovered) will be an/a :
[JEE(Main) 2019 Online (12-01-19), 4/120]
(1) transition metal (2) alkali metal
(3) alkaline earth metal (4) inner-transition metal
19. The size of the iso-electronic species Cl–, Ar and Ca2 is affected by :
[JEE(Main) 2019 Online (08-04-19)S1, 4/120]
(1) Nuclear charge (2) Principal quantum number of valence shell
(3) azimuthal quantum number of valence shell (4) electron-electron interaction in the outer orbitals
20. The IUPAC symbol for the element with atomic number 119 would be :
[JEE(Main) 2019 Online (08-04-19)S2, 4/120]
(1) une (2) unh (3) uun (4) uue
21. The element having greatest difference between its first and second ionization energies, is :
[JEE(Main) 2019 Online (09-04-19)S1, 4/120]
(1) Ba (2) K (3) Ca (4) Sc
ADVPTP - 36
22. The isoelectronic set of ions is :
[JEE(Main) 2019 Online (10-04-19)S1, 4/120]
(1) F– , Li+ , Na+ and Mg2+ (2) Li+ , Na+ , O2 – and F–
(3) N3– , Li+ , Mg2+ and O2 (4) N3– , O2– , F– and Na+
23. The group number, number of valence electrons and valency of an element with atomic number 15,
respectively, are :
[JEE(Main) 2019 Online (12-04-19)S1, 4/120]
(1) 16,5 and 2 (2) 15,5 and 3 (3) 15,6 and 2 (4) 16,6 and 3
24. The pair that has similar atomic radii is :
[JEE(Main) 2019 Online (12-04-19)S2, 4/120]
(1) Ti and Hf (2) Mo and W (3) Sc and Ni (4) Mn and Re
25. In comparison to boron, beryllium has :
[JEE(Main) 2019 Online (12-04-19)S2, 4/120]
(1) greater nuclear charge and lesser first ionization enthalpy.
(2) lesser nuclear charge and lesser first ionization enthalpy
(3) lesser nuclear charge and greater first ionization enthalpy
(4) greater nuclear charge and greater first ionization enthalpy
26. The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine, respectively are :
[JEE(Main) 2020 Online (07-01-20)S1, 4/100]
(1) –296, –325, –333 and –349 (2) –333, –349, –325 and –296
(3) –349, –333, –325 and –296 (4) –333, –325, –349 and –296
27. Within each pair of element F & Cl, S & Se, and Li & Na, respectively, the elements that release more
energy upon an electron gain are : [JEE(Main) 2020 Online (07-01-20)S2, 4/100]
(1) Cl, S and Li (2) F, S and Li
(3) F, Se and Na (4) Cl, Se and Na
28. The first ionization energy (in kJ/mol) of Na, Mg, Al and Si respectively, are :
[JEE(Main) 2020 Online (08-01-20)S1, 4/100]
(1) 496, 577, 737, 786 (2) 786, 737, 577, 496
(3) 496, 577, 786, 737 (4) 496, 737, 577, 786
29. The increasing order of the atomic radii of the following elements is :
[JEE(Main) 2020 Online (08-01-20)S2, 4/100]
(a) C (b) O (c) F (d) Cl (e) Br
(1) (a) < (b) < (c) < (d) < (e) (2) (c) < (b) < (a) < (d) < (e)
(3) (b) < (c) < (d) < (a) < (e) (4) (d) < (c) < (b) < (a) < (e)
30. The acidic, basic and amphoteric oxides, respectively, are :
[JEE(Main) 2020 Online (09-01-20)S1, 4/100]
(1) Na2O, SO3, Al2O3 (2) N2O3, Li2O, Al2O3
(3) Cl2O, CaO, P4O10 (4) MgO, Cl2O, Al2O3
ADVPTP - 37
EXERCISE - 1
PART – I
A-1. (i) In modern periodic table, elements have been placed in order of their increasing atomic numbers.
The atomic number of argon is 18 and that of potassium is 19. Thus, argon has been placed before
potassium.
(ii) In lanthanides and actinides, the differentiating electron enters to (n – 2) f-subshell. The maximum
capacity of f-subshell is of 14 electrons. Thus, there are only 14 lanthanides (4f 1–14) and only 14
actinides (5f 1–14).
A-2. In the modern periodic table, each period starts with the filling of a new principal energy level. Thus, the
third period begins with the filling of principal quantum number, n = 3. When n = 3,  = 0, 1, 2. But
according to Aufbau principle, the electrons are added to different orbitals in order of their increasing
energies. Now, the energy of 3d-subshell is higher than that of 4s-subshell. Therefore, in third period,
electrons can be filled in only 3s & 3p-subshells, whose energies increase in the order: 3s < 3p. Now,
s-subshell has one and p-subshell has three orbitals. Hence, in all, there are 4 (1 + 3) orbitals that can
be filled in this period. Since according to Pauli's exclusion principle, each orbital, at the maximum, can
accommodate two electrons. Therefore, 4 orbitals, at the maximum, can have 8 electrons and hence,
fourth period has 8 elements.
B-1. Zeff = Z – 
B-2. d- and f-orbital electrons are known for poor shielding of nuclear charge, because of their scattered
structure. This poor shielding generates some irregularities in properties like atomic radii and ionisation
enthalpy of d-block elements, f-block elements and group-13 elements.
C-1. Pb4+ is less stable than Pb2+ due to inert pair effect. So, Pb4+ compounds are very good oxidising
agents.
C-2. (i) Ga+ < In+ < Tl+ (ii) As+5 > Sb+5 > Bi+5
D-1. The ionic radius of a cation is always smaller than the parent atom because the loss of one or more
electrons increases the effective nuclear charge (Zeff). As a result, the force of attraction of
nucleus for the remaining electrons increases and hence the electron cloud contracts and ionic
radii decreases.
In contrast, the ionic radius of an anion is always larger than its parent atom because the addition of
one or more electrons decreases the effective nuclear charge (Z eff). As a result, the force of
attraction of the nucleus for the remaining electrons decreases and hence electron cloud
expands and the ionic radii increases.
D-2. Due to lanthanide contraction (poor shielding of nuclear charge by 4f-electrons), atomic radii of 4d and
5d elements are nearly same.
D-3. Atomic radius of K is larger than F because the size of cation is smaller than its parent atom while size
of anion is bigger than its parent atom. Thus, atomic radii of K will be greater than 1.34 Å while atomic
radii of F will be less than 1.34 Å.
E-1. Electron is more tightly bound by the nucleus in an cation (i.e. M+) as the number of proton remains the
same as in neutral atom whereas number of electron is one less than the proton. This increases the
attraction between the valence shell electrons and the nucleus (Z eff increases). So, second ionization
enthalpy is always higher than the first ionisation enthalpy for every element.
E-2. Carbon has higher IE1 because of smaller atomic size and greater Zeff. Removal of second electron
from stable 1s2 2s2 configuration in case of B+ requires greater energy. So, B has greater IE2.
E-3. (i) C (ii) Al
ADVPTP - 38
F-1. In Be, the extra electron is to be added in 2p orbital because 2s orbital is completely filled and in Ne, it
is to be added to a noble gas configuration. Since full-filled orbitals and noble gas configuration are
more stable, reluctancy in accepting the electron is found. So, they have positive values of electron gain
enthalpy.
F-2. Nitrogen has stable half filled configuration 2s2 2p3. So removal of one electron will require more energy
than oxygen. Similarly, in nitrogen, addition of one electron will require energy (endothermic) while in
oxygen, addition of one electron will release energy (exothermic).
G-1. Caesium (Cs).
G-2. (a) On moving left to right in a period, tendency of an atom to attract the shared electron pair towards
itself increases due to increasing Zeff. So, electronegativity of elements increase on moving from left to
right in a period.
(b) On moving top to bottom in a group, size increases due to addition of extra shells. So, attraction of
nucleus outermost electron decreases. So, ionisation enthalpy decrease in a group from top to bottom.
PART - II
A-1. (C) A-2. (B) A-3. (C) A-4. (D) A-5. (C)
A-6. (D) B-1. (A) B-2. (D) B-3. (B) B-4. (A)
C-1. (B) C-2. (C) C-3. (D) C-4. (B) C-5. (A)
C-6. (D) C-7. (A) C-8. (B) C-9. (D) C-10. (C)
D-1. (C) D-2. (C) D-3. (A) D-4. (A) D-5. (B)
E-1. (D) E-2. (A) E-3. (A) E-4. (C) E-5. (D)
F-1. (C) F-2. (D) F-3. (B) F-4. (A) F-5. (D)
G-1. (C) G-2. (B) G-3. (D) G-4. (B) G-5. (C)
PART - III
1. (A - p,r) ; (B - p,s) ; (C - q,t) ; (D - p,q,r)
2. (A - q,r) ; (B - p,s) ; (C - s) ; (D - q,r)
EXERCISE – 2
PART - I
1. (C) 2. (B) 3. (C) 4. (D) 5. (D)
6. (B) 7. (A) 8. (D) 9. (D) 10. (D)
11. (C) 12. (C) 13. (D) 14. (D) 15. (B)
16. (D)
PART - II
1. 2 2. 26 3. 19 4. 6 (except i, ii, iii) 5. 3
6. 6 (except (vi)) 7. 3 8. 13 9. 8 10. 30
11. 2 (i, ii) 12. 0 13. 2 14. 1 15. 23
16. 17 17. 5 (except ii, iii)

ADVPTP - 39
PART - III
1. (CD) 2. (BCD) 3. (ABCD) 4. (CD) 5. (AD)
6. (ABD) 7. (AB) 8. (ABCD) 9. (CD) 10. (BC)
11. (ABD) 12. (ABCD) 13. (ABD) 14. (AD) 15. (AB)
16. (BC) 17. (ACD)
PART - IV
1. (C) 2. (C) 3. (C) 4. (A) 5. (B)
6. (C) 7. (B) 8. (D) 9. (C) 10. (C)
11. (D) 12. (A) 13. (B) 14. (C)
EXERCISE – 3
PART - I
1. (B) 2. Al3+ < Mg2+ < Li+ < K+ 3. Inert Pair Effect
4. (C) 5. (D) 6. (B) 7. (C) 8. (B)
9. (B) 11. 2
PART - II
1. (3) 2. (4) 3. (1) 4. (2) 5. (4)
6. (3) 7. (3) 8. (3) 9. (3) 10. (3)
11. (1) 12. (2) 13. (4) 14. (2) 15. (4)
16. (1) 17. (2) 18. (3) 19. (1) 20. (4)
21. (2) 22. (4) 23. (2) 24. (2) 25. (3)
26. (2) 27. (1) 28. (4) 29. (2) 30. (2)
ADVPTP - 40
Relations, Functions & Inverse Trigonometric Functions
 Marked questions are recommended for Revision.

Section (A) : Ordered pair , Cartesian product, Relation, Domain and Range of Relation
A-1. If A = {2, 4, 5}, B = {7, 8, 9}, then find n(A × B).
A-2. If A = {x : x2 – 5x + 6 = 0}, B = {2, 4}, C = {4, 5} then find A × (B  C).
A-3. A and B are two sets having 3 and 4 elements respectively and having 2 elements in common. Find the
number of possible relations which can be defined from A to B.
A-4. If A = {2, 3, 4, 5}, B = {1, 3, 5, 7} and a relation R : A B such that y = 2x –3, xA, yB, then find R.
 x – 1
2
A-5. Let R be a relation defined as R = { (x, y) : y = , x  Z and –3  x  3} then find
(i) Domain of R (ii) Range of R (iii) Relation R
A-6. The Certesian product A × A has 16 elements S = {(a,b)  A × A| a < b}. (–1,2) and (0,1) are two
elements belonging to S. Find the set containing the remaining elements of S.
Section (B) : Types of Relation

B-1. Identify the type of relation among reflexive, symmetric and transitive.
(i) R = {(1, 1), (2, 2), (3, 3), (1, 2), (2, 3), (1, 3)} on set A = {1, 2, 3}.
(ii) P = {(x, y) | x2 + y2 = 1, x, y  R}
B-2. Prove that the relation ''less than'' in the set of natural number is transitive but not reflexive and
symmetric.
B-3. Let A = {p, q , r}. Which of the following is an equivalence relation on A ?

(i) R = {(p, q), (q, r), (p, r), (p, p)}
(ii) R = {(p, p), (q, q), (r, r), (q, p)}
(iii) R = {(p, p), (q, q), (r, r)}
(iv) R = {(p, p), (q, q), (r, r), (p, q), (q, r), (p, r)}
(v) R = {(p, p), (q, q), (r, r), (p, q), (q, p)}
B-4. Let R be a relation on the set N be defined by {(x, y)| x, y  N, 2x + y = 41}. Then prove that R is neither
reflexive nor symmetric and nor transitive.
B-5. Let n be a fixed positive integer. Define a relation R on the set of integers Z, aRb n|(a – b). Then
prove that R is equivalence
B-6. Let S be a set of all square matrices of order 2. If a relation R defined on set S such that
AR B AB = BA, then identify the type of relation of R (A, B S) among reflexive, symmetric and
transitive.
Section (C) : Greatest Integer [ . ], Fractional part {.}, signum and Dirichlet’s function
In this Section [ . ] and { . } denotes greatest integer and fractional part function respectively
C-1. Find the value(s) of x, if {x}, [x] & x are in A.P. :
C-2 Solve the equation
(i) 4[x] = x + {x} (ii) [x]2 = – [x] (iii) {x}2 = – {x} (iv) [2x] = [x]
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website: www.resonance.ac.in | E-mail : [email protected]
ADVRFITF-30
C-3. Find complete set of solution of following

(i) – 5  [x + 1] < 2 (ii) [x]2 + 5[x] – 6 < 0
(iii) –1 < {x} < 0 (iv) –1  [x]  0
C-4. Solve the following equations

(i) sgn ({[x]}) = 0 (ii) sgn(x2 – 2x – 8) = –1
C-5. Find the number of solution of equation (where sgn represent signum function)
(i) sgn (x) = |x| (ii) sgn (x2 – 1) = (x + 1)2
C-6. Draw the graph of

(i) y = [x2 – 2x] , 0  x  2 (ii) y = {log2x}, x  [1/2, 4]
(iii) y = [e ], x  (–, n3]
x
 x x Q
C-7. f(x)  . Find the value of [f(1)] + | [(f(e)] |
1  x x  R  Q
Section (D) : Definition of function, Domain and Range, Classification of Functions

D-1. Check whether the followings represent function or not
(i) x2 + f(x)2 = 36, f(x)  [0, 6] (ii) x2 + f(x)2 = 36, x  [0, 1]
(iii) x2 + f(x)2 = 36, x  [–6, 6] (iv) x2 + f(x)2 = 36
D-2. Find the domain of each of the following functions :

x3  5x  3
(i) f(x) = (ii) f(x) = sin(cos x)
x2  1
1
(iii) f(x) = (iv) f(x) = ex+sinx
x | x |
1 log2 (x  2)
(v) f(x) = + x2 (vi) f(x) =
log10 (1  x) log1/ 2 (3x  1)
cos x  1
(vii) f(x) = n [x + x + 1], where [.] GIF.
2
(viii) f (x) =
2
6  35 x  6 x 2
D-3. Find the domain of definitions of the following functions :

(i) f (x) = 3  2x  21  x (ii) f (x) = 1  1  x2
x2 1 x
(iii) f (x) = (x2 + x + 1)–3/2 (iv) f (x) = +
x2 1 x
1
(v) f(x) = tan x  tan2 x (vi) f (x) =
1  cos x
 5 x  x2 
(vii) f (x) = og1/ 4   (viii) f (x) = og10 (1 – og10(x2 – 5x + 16))
 4
 
D-4. Find the range of each of the following functions :

x x2  9
(i) f(x) = | x – 3 | (ii) f(x) = (iii) f(x) = (iv) f(x) = sin2(x3) + cos2(x3)
1  x2 x3
(v) f(x) = 5 + 3 sin x + 4 cos x (vi) f(x) = 2 – 3x – 5x2
x2 x2  2 x  4
(vii) f (x) = 2 (viii) f (x) =
x  8x  4 x2  2 x  4
ADVRFITF-31
D-5. Find the range of the following functions : (where {.} and [.] represent fractional part and greatest
integer part functions respectively )
1 1
(i) f(x) = 16  x2 (ii) f(x) = (iii) f(x) =
4  3 sin x 1 x
 8  x2   1  1
(iv) f(x) = n   (v) f(x) =   (vi) f(x) =
 x2   sin{x} 
2
x
  16  4 x
1 2
(vii) f (x) = (viii) f (x) = 3 sin  x 2 (ix) f (x) = sin2 x + cos4x
2  cos 3 x 16
(x) f(x) = sec2x – tan2x + sin (sinx + cos x) (xi) f (x)= x4  2 x2 + 5
D-6. Find the range of the following functions : (where {.} and [.] represent fractional part and greatest
integer part functions respectively )
|x4|
(i) f(x) =
x4
(ii) f(x) = 3 | sin x| – 4 |cos x|
sin x cos x
(iii) f(x) = +
1  tan x2
1  cot 2 x
(iv) f (x) = 1 – | x – 2 |
(v) f (x) = x3 – 12x, where x  [–3, 1]
(vi) f(x) = [sin x + [cos x + [tan x+ [secx]]]] Here x  (0, /4)
 
D-7. Find whether the following functions are one-one or many-one & into or onto if f : D  R where D is its
domain.
(i) f(x) = |x2 + 5x + 6 | (ii) f(x) = |nx|
   1
(iii) f(x) = sin 4x :   ,   ( 1, 1) (iv) f(x) = x + , x  (0, )
 8 8  x
1 
 1 3x 2
(v) f(x) = 1  e x  (vi) f(x) = – cos x
4
1  x6 1
(vii) f(x) = 3
(viii) f(x) = x cos x (ix) f(x) =
x sin | x |
D-8. Classify the following functions f(x) defined in R  R as injective, surjective, both or none.
x2
(i) f (x) = x |x| (ii) f (x) = (iii) f(x) = x3  6 x2 + 11x  6
1  x2
D-9. Check whether the following functions is/are many-one or one-one & into or onto
(i) f(x) = tan (2 sin x) (ii) f(x) = tan (sin x)
D-10. Let f : A  A where A = {x : –1  x  1}. Find whether the following functions are bijective.
x
(i) x – sin x (ii) x |x| (iii) tan (iv) x4
4
D-11. Let A be a set of n distinct elements. Then find the total number of distinct functions from A to A ? How
many of them are onto functions ?
Section (E) : Identical functions, Composite functions

E-1. Check whether following pairs of functions are identical or not ?
 x 1
2
(i) f(x) = x 2 and g(x) = (ii)_ f(x) = tanx and g(x) =
cot x
1  cos2x
(iii) f(x) = and g(x) = cos x (iv) f(x) = x and g(x) = enx
2
ADVRFITF-32
E-2. Find for what values of x, the following functions would be identical.
 x  1
f(x) = log (x  1)  log (x  2) and g (x) = log  
 x  2
E-3. Let f(x) = x2 + x + 1 and g(x) = sin x. Show that fog  gof
E-4. Let f(x) = x2, g(x) = sin x, h(x) = x , then verify that [fo (goh)] (x) and [(fog) oh] (x) are equal.
E-5. Find fog and gof, if

(i) f(x) = ex ; g(x) = n x (ii) f(x) = |x| ; g(x) = sin x
1
(iii) f(x) = sin x ; g(x) = x2 (iv) f(x) = x2 + 2 ; g(x) = 1 – ,x1
1 x
E-6. If f(x) = n(x2 – x + 2) ; R  R and

g(x) = {x} + 1 ; [1, 2]  [1, 2] , where {x} denotes fractional part of x.
Find the domain and range of f(g(x)) when defined.
1  x 2 ; x 1
E-7. If f(x) =  and g(x) = 1 – x ; – 2 < x < 1, then define the function fog(x).
 x  1; 1  x  2
x2 x2
E-8. If f(x) = and g(x) = , then find the domain of
x 1 x
(i) fog(x) (ii) gof(x) (iii) fof(x) (iv) fogof(x)

 2x x  Q  {0}
E-9. If f(x) =  , then define fof(x) and hence define fofof.....f(x) where f is ‘n’ times.

 3x x  Qc
 x 1 x4
 
 x2 1  x  3
E-10. Let f(x) =  2x  1 4  x  9 and g(x) =  then, find f(g(x)).
 x  2 3  x  5

 x  7 x9
4x
E-11. If f(x) = , then show that f(x) + f(1 – x) = 1
4x  2
Section (F) : Even/Odd Functions & Periodic Functions

F-1. Determine whether the following functions are even or odd or neither even nor odd :
 ax  1 
f(x) = x  x
 a  1 
(i) sin (x2 + 1) (ii) x + x2 (iii)
 
(iv) f(x) = sin x + cos x (v) f(x) = (x2 – 1) | x |
 | ne x | ; x  1

(vi) f(x) = [2  x]  [2  x] ; 1  x  1 , where [.] is GIF.

 e nx ; x 1
F-2. Examine whether the following functions are even or odd or neither even nor odd, where [ ] denotes
greatest integer function.
(1  2x )7 sec x  x 2  9
(i) f (x) = (ii) f (x) =
2x x sin x
 x | x |, x  1

(iii) f (x) = 1 x  x 2
– 1 x  x 2
(iv) f (x) = [1  x]  [1  x], 1  x  1
  x | x |, x 1

ADVRFITF-33
F-3. Which of the following functions are not periodic (where [ . ] denotes greatest integer function) :
(i) f(x) = sin x (ii) f(x) = x + sin x
(iii) f(x) = [sin 3x] + |cos 6x|
F-4. Find the fundamental period of the following functions :

(i) f (x) = 2 + 3cos (x – 2) (ii) f(x) = sin 3x + cos2x + | tanx |
x x 3 2
(iii) f (x) = sin + sin (iv) f(x)= cos x  sin x.
4 3 5 7
1 sin12x
(v) f(x) = (vi) f(x) =
1  cos x 1  cos2 6x
(vii) f(x) = sec x + cosec x
3 3

Section (G) : Inverse of a function
G-1. Let f : D  R, where D is the domain of f. Find the inverse of f, if it exists
 
1/ 5
(i) f (x) = 1  2 x (ii) f (x) = 4  (x  7)3
(iii) f(x) = n (x + 1  x2 )
(iv) Let f [0, 3]  [1, 13] is defined by f(x) = x2 + x + 1, then find f– 1 (x).
e2x  e2x
G-2. Let f : R  R be defined by f(x) = . Is f(x) invertible ? If yes, then find its inverse.
2
G-3. (a) If f(x) = –x|x|, then find f–1(x) and hence find the number of solutions of f(x) = f –1(x).
5  9  8x 5
(b) Solve 2x2 – 5x + 2 = , where x <
4 4
 
G-4. If g is inverse of f(x) = x3 + x + cosx, then find the value of g(1).

 (  1)x x  Qc 
x x  Qc
G-5. If f(x) =  and g(x) =  are inverse to each other then find all
 x    3x  1 x  Q 1  x
 x Q
2

possible values of .
Section (H) : Definition, graphs and fundamentals & Inverse Trigonometry

H-1. Find the domain of each of the following functions :
sin1 x  3x  1  1 1
(i) f(x) = (ii) f(x) = 1  2x + 3 sin–1   (iii) f(x) = 2sin x
+ 
x  2  x2
H-2. Find the range of each of the following functions :
 3x 2  1 
(i) f(x) = n (sin–1x) (ii) f(x) = sin–1  
 5x 2  1 
 
 (x  1)(x  5) 
(iii) f(x) = cos–1  
 x(x  2)(x  3) 
H-3. Find the simplified value of the following expressions :
  1   1  1 
(i) sin   sin1     (ii) tan cos1  tan1   
 3  2   2  3  
 
  3 
sin–1 cos sin1   
 
(iii)
 

  2 
ADVRFITF-34
n n
H-4. (i) If  cos
i 1
1
i = 0, then find the value of  i· 
i 1
i
2n 2n
(ii) If  sin
i1
1
xi  n , then show that x
i1
i  2n
H-5. Solve the following inequalities:

(i) cos 1 x > cos 1 x2 (ii) arccot2 x  5 arccot x + 6 > 0
(iii) sin x > – 1
–1
(iv) cos–1 x < 2 (v) cot–1 x < – 3
  
H–6. Let f :   ,   B defined by f (x) = 2 cos2x + 3 sin2x + 1. Find B such that f –1
exists. Also find
 3 6
–1
f (x).
Section (I) : Trig (trig–1x), trig–1 (trig x), trig–1 (–x) and Property (/2)
I-1. Evaluate the following inverse trigonometric expressions :

 7   2 
(i) sin–1  sin  (ii) tan–1  tan
 6   3 
 5   7 
(iii) cos–1  cos (iv) sec–1  sec
 4   4 
I-2. Find the value of the following inverse trigonometric expressions :

(i) sin–1 (sin 4) (ii) cos–1 (cos 10)
(iii) tan–1 (tan (– 6)) (iv) cot–1 (cot (– 10))
 1  9 9  
(v) cos–1   cos 10  sin 10  
 2  
I-3. Find the value of following expressions :

(i) cot (tan–1 a + cot–1 a) (ii) sin (sin–1x + cos–1x) , | x |  1
I-4. Solve the inequality tan–1 x > cot–1 x.
Section (J) : Interconversion/Simplification

J-1. Evaluate the following expressions :
 3  1
(i) sin  cos1  (ii) tan  cos1 
 5  3
 41   65 
(iii) cosec  sec 1  (iv) tan  cosec 1

 5   63 
 1  4 2
(v) sin   cos1  (vi) cos  sin1  cos1 
 6 4   5 3 
       1
(vii) sec  tan tan1      (viii) cos tan– 1 sin cot–1  
  3    2
 
 3 3 
(ix) tan cos1    sin1    sec 1 3 
 4 4 
J-2. Find the value of sin–1 (cos(sin–1x)) + cos–1 (sin (cos–1x))
ADVRFITF-35
1
J-3. If tan–1x + cot–1 + 2tan–1z = , then prove that x + y + 2z = xz2 + yz2 + 2xyz
y
1  x 2 – xy
J-4. If cos–1x + 2sin–1x + 3cot–1y + 4tan–1y = 4sec–1z + 5cosec–1z , then prove that z2 – 1  =
x  y 1– x 2
2  2 
J-5. Consider, f(x) = tan–1   , g(x) = sin–1   and h(x) = tan (cos–1(sinx)), then show that
x  4x 
2
0 , x  0
(h(f(x)) + h(g(x)) = 
x , x  0
J-6. Prove each of the following relations :

1 x 1
(i) tan–1 x = –  + cot–1 = sin–1 = – cos–1 when x < 0.
x 1  x2 1  x2
1 1  x2 x
(ii) cos–1x = sec–1 =  – sin–1 1  x2 = + tan–1 = cot –1 when – 1<x< 0
x x 1  x2
J-7. Express in terms of

2x 1
(i) tan–1 to tan–1 x for x > 1 (ii) sin–1 (2x 1  x2 ) to sin–1 x for 1  x >
1  x2 2
(iii) cos–1 (2x2 – 1) to cos–1x for – 1  x < 0
1
  2x  1 
1 1  y
2 
J-8. Simplify tan  sin1    2 cos    , if x > y > 1.

 2  1  x2   1 y
2
 
J-9. Solve for x

1 
(i) cos (2 sin–1x) = (ii) cot–1 x + tan–1 3 =
3 2
 x 1   x 1  2
(iii) tan–1  –1
 + tan  x  2  = 4 (iv) sin–1x + sin–12x =
 x  2    3
Section (K) : Addition and Subtraction Rule

K-1. Prove that
3  8  77 3 5 33
(i) sin–1   + sin–1   = sin–1 (ii) tan–1 + sin–1 = cos–1
 
5  
17 85 4 13 65
 1    1  1  1  1 
(iii) sin–1  –1
 + cot 3 = (iv) tan–1   + tan–1   + tan–1   + tan–1   =
 5  4  
3  
5  
7 8 4
K-2. Find the sum of each of the following series :

1 1 1 1
(i) tan1 2 + tan1 2 + tan1 2 + tan1 2 ........ upto
x  x  1 x  3x  3 x  5x  7 x  7 x  13
n terms.
1 2 2n1
(ii) tan1 + tan1 + ..... + tan1 + .....................upto infinite terms
3 9 1  22n  1
1 2  1 n  n  1
 (iii) sin1 + sin1 + ..... + sin1 + ............ upto infinite terms
2 6 n (n  1)
ADVRFITF-36

Section (A) : Ordered pair , Cartesian product, Relation, Domain and Range of Relation
A-1. If A = {a, b}, B = {c, d}, C = {d, e}, then {(a, c), (a, d), (a, e), (b, c), (b, d), (b, e)} is equal to
(A) A  (B  C) (B) A  (B  C) (C) A × (B  C) (D) A × (B  C)
A-2. If A = {1, 2, 3} and B = {1, 2} and C= {4, 5, 6}, then what is the number of elements in the set A  B C ?
(A) 8 (B) 9 (C) 15 (D) 18
A-3. Let A = {a, b, c} and B = {1, 2}. Consider a relation R defined from set A to set B. Then R can equal to
set
(A) A (B) B (C) A × B (D) B × A
A-4. Let R be relation from a set A to a set B, then

(A) R = A  B (B) R = A  B (C) R  A × B (D) R  B × A
A-5. Let X = {1, 2, 3, 4, 5} and Y = {1, 3, 5, 7, 9}. Which of the following is not a relation from X to Y
(A) R1 = {(x, y) | y = 2 + x, x  X, y  Y} (B) R2 = {(1, 1), (2, 1), (3, 3), (4, 3), (5, 5)}
(C) R3 = {(1, 1), (1, 3) (3, 5), (3, 7), (5, 7)} (D) R4 = {(1, 3), (2, 5), (2, 4), (7, 9)}
A-6. The relation R defined in A = {1, 2, 3} by a R b if –5  a2 – b2  5. Which of the following is false?

(A) R = {(1, 2), (2, 2), (3, 3), (2, 1), (2, 3), (3, 2)} (B) Co-domain of R = {1, 2, 3}
(C) Domain of R = {1, 2, 3} (D) Range of R = {1, 2, 3}
Section (B) : Types of Relation
B-1. The relation R defined in N as aRb b is divisible by a is

(A) Reflexive but not symmetric (B) Symmetric but not transitive
(C) Symmetric and transitive (D) Equivalence relation
B-2. In the set A = {1, 2, 3, 4, 5} a relation R is defined by R = {(x, y)| x, y  A and x < y}. Then R is
(A) Reflexive (B) Symmetric (C) Transitive (D) Equivalence relation
B-3. Which one of the following relations on R is equivalence relation-

(A) x R1y  x2 = y2 (B) x R2y  x  y (C) x R3y  x | y (x divides y) (D) x R4y  x < y
B-4. Let R1 be a relation defined by R1 = {(a, b)| a  b ; a, b  R} . Then R1 is

(A) An equivalence relation on R (B) Reflexive, transitive but not symmetric
(C) Symmetric, Transitive but not reflexive (D) Neither transitive nor reflexive but symmetric
B-5. Let L denote the set of all straight lines in a plane. Let a relation R be defined by R ,, L.
The R is
(A) Reflexive (B) Symmetric (C) Transitive (D) equivalence relation
B-6. Let S be the set of all real numbers. Then the relation R =
{(a, b) : 1 + ab > 0} on S is
(A) Reflexive and symmetric but not transitive (B) Reflexive, transitive but not symmetric
(C) Symmetric, transitive but not reflexive (D) Reflexive, transitive and symmetric
B-7. Consider the following :

1. If R = {(a, b)  N × N : a divides b in N} then the relation R is reflexive and symmetric but not
transitive.
2. If A = {1, 2, 3, 4, 5, 6} and R = {(S1, S2) : S1, S2 are subsets of A, S1  S2}, then the relation R is
not reflexive, not symmetric and not transitive.
Which of the statements is/are correct ?
(A) 1 only (B) 2 only (C) Both 1 and 2 (D) Neither 1 nor 2
ADVRFITF-37
B-8. Let R be a relation over the set N × N and it is defined by (a, b) R (c, d)  a + d = b + c. Then R is
(A) Symmetric only (B) Transitive only (C) Reflexive only (D) Equivalence only
B-9. Let L be the set of all straight lines in the Euclidean plane. Two lines 1 and 2 are said to be related by
the relation R if 1 is parallel to 2. Then R is
(A) Symmetric only (B) Transitive only (C) Reflexive only (D) Equivalence only
B-10. Let R = {(x, y) : x, y  A, x + y = 5} where A = {1, 2, 3, 4, 5} then R is

(A) Reflexive (B) symmetric (C) Transitive (D) Equivalence
B-11. Let S be a set of all square matrices of order 2. If a relation R defined on set S such that
AR B AB = O, where O is zero square matirx of order 2, then relation R is (A, B S)
(A) Reflexive (B) Transitive
(C) Symmetric (D) Not equivalence
Section (C) : Greatest Integer [.], Fractional part {.}, signum and Dirichlet’s function
C-1. The value of [e] – [– ] is, where [.] denotes greatest integer function
(A) 5 (B) 6 (C) 7 (D) 8
C-2. The number of solutions of the equation 2{x} 2 – 5 {x} + 2 = 0 is (where {.} denotes the fractional part
function)
(A) no solution (B) 1 (C) 2 (D) infinite
151
1 n 
C-3. Let f(n) =    , where [.] denotes the greatest integer function, then the value of
 2 100 
 f(n) is
n 1
(A) 101 (B) 102 (C) 104 (D) 103
C-4. Number of solutions of the equation [2x] – 3 {2x} = 1 is (where [ . ] and { . } denote greatest integer and
fractional part function respectively)
(A) 1 (B) 2 (C) 3 (D) 0
 x 2  5x  4 
C-5. The complete solution set of the equation sgn 
  = – 1, where {·} is fractional part function,
 {x} 
is
(A) (1, 4) (B) [1, 4] (C) (– , 1)  (4, ) (D) (1, 2)  (2, 3)  (3, 4)
C-6. sgn(x3 – 4x2 + 3x) = 1, x  Z and x  [– 5, 10], then number of possible values of x is :
(A) 7 (B) 13 (C) 10 (D) 8
C-7. The number of solution of the equation sgn ({x}) = |1– x| is/are (where {•} represent fractional part
function and sgn respresent signum function)
(A) 4 (B) 3 (C) 2 (D) 1
1 x Q
C-8. f(x)  . If f(1) + f(2) + f() + f(p) = 0, then p cannot be
 1 x  RQ
(A) –e (B) 2 (C) 3 (D) 4
Section (D) : Definition of function, Domain and Range, Classification of Functions
 log0.3 (x  1)
D-1. The domain of the function f(x) = is
x 2  2x  8
(A) (1, 4) (B) (– 2, 4) (C) (2, 4) (D) [2, )
ADVRFITF-38
D-2. Range of f(x) = n (3x2 – 4x + 5) is

 11   11   11 
(A)  n ,   (B) [n 10 , ) (C)  n ,   (D)  n , 
 3   6   12 
D-3. Range of f(x) = 4x + 2x + 1 is

(A) (0, ) (B) (1, ) (C) (2, ) (D) (3, )
D-4. Range of f(x) = log 5

( 2 (sinx – cosx) + 3) is
 3
(A) [0, 1] (B) [0, 2] (C) 0,  (D) [1, 2]
 2
2 x2  x  5
D-5. Let f : R  R be a function defined by f(x) = , then f is :
7 x 2  2x  10
(A) one  one but not onto (B) onto but not one  one
(C) onto as well as one  one (D) neither onto nor one  one
D-6. Let f : R  R be a function defined by f(x) = x3 + x2 + 3x + sin x. Then f is:

(A) one  one and onto (B) one  one and into
(C) many one and onto (D) many one and into
3
D-7. Domain of definition of the function f(x) = + log10(x3 – x), is :
4 – x2
(A) (1,2) (B) (–1,0)  (1,2)
(C) (1,2)  (2, ) (D) (–1,0)  (1,2)  (2, )
x
D-8. If f : [0, )  [0, ), and f (x) = , then f is :
1 x
(A) one-one and onto (B) one-one but not onto
(C) onto but not one-one (D) neither one-one nor onto
(x  2)2
D-9. Range of the function f(x) = is
(x  1)(x  3)
(A) (1, ) (B) (–, 1) (C) R – (0, 1] (D) (0, 1]
x2
D-10. Range of the function f(x) = is
x 2  4x  3
(A) (–, 0) (B) R (C) (0, ) (D) R – {0}
D-11. Statement - 1 If f (x) and g (x) both are one one and f(g (x)) exists, then f(g (x)) is also one one.
Statement - 2 If f(x1) = f(x2)  x1 = x2 , then f(x) is one-one.
(A) STATEMENT-1 is true, STATEMENT-2 is true and STATEMENT-2 is correct explanation for
STATEMENT-1
(B) STATEMENT-1 is true, STATEMENT-2 is true and STATEMENT-2 is not correct explanation
for STATEMENT-1
(C) STATEMENT-1 is true, STATEMENT-2 is false
(D) STATEMENT-1 is false, STATEMENT-2 is true
(E) Both STATEMENTS are false
ADVRFITF-39
D-12. Statement - 1 If y = f (x) is increasing in [], then its range is [f (), f () ]
Statement - 2 Every increasing function need not to be continuous.
STATEMENT-1
for STATEMENT-1
0 , x  rational
D-13. If the functions f(x) and g(x) are defined on RR such that f(x) =  ,
 x , x  irrational
0 , x  irrational
g(x) =  , then (f – g) (x) is
 x , x  rational
(A) one-one and onto (B) neither one-one nor onto
(C) one-one but not onto (D) onto but not one-one
Section (E) : Identical functions, Composite functions

E-1. Which of the following pair of functions are identical –
(A) f(x) = sin2x + cos2x and g(x) = 1 (B) f(x) = sec2x – tan2x and g(x) = 1
(C) f(x) = cosec x – cot x and g(x) = 1
2 2
(D) f(x) = nx2 and g(x) = 2nx
E-2. Let f(x) be a function whose domain is [– 5, 7]. Let g(x) = |2x + 5|, then domain of (fog) (x) is
(A) [– 4, 1] (B) [– 5, 1] (C) [– 6, 1] (D) [– 5, 7]
 1 , x  0

E-3. Let g (x) = 1 + x  [ x ] and f (x) =  0 , x  0 . Then for all x, f (g (x)) is equal to (where [.] denotes
1 , x  0

greatest integer function)
(A) x (B) 1 (C) f (x) (D) g (x)
Section (F) : Even/Odd Functions & Periodic Functions

 1  sin x 
F-1. The function f(x) = log   is
 1  sin x 
(A) even (B) odd
(C) neither even nor odd (D) both even and odd
1
F-2. The function f(x) = [x] + , x   is a/an (where [ . ] denotes greatest integer function)
2
(A) Even (B) odd (C) neither even nor odd (D) Even as well as odd
F-3. The graph of the function y = f(x) is symmetrical about the line x = 2, then :
(A) f(x + 2) = f(x – 2) (B) f(2 + x) = f(2 – x) (C) f(x) = f(–x) (D) f(x) = –f(–x)
F-4. Fundamental period of f(x) = sec (sin x) is


(A) (B) 2 (C)  (D) aperiodic
2
F-5. If f (x) = sin  

[ a ] x (where [ . ] denotes the greatest integer function) has  as its fundamental period,
then
(A) a = 1 (B) a = 9 (C) a  [1, 2) (D) a  [4, 5)
ADVRFITF-40
F-6. Find the area below the curve y =  2  2cos2x  but above the x-axis in [–3, 6] is
 
(where [ . ] denotes the greatest integer function) :
(A) 2 square units (B)  square units (C) 6 square units (D) 8 square units
Section (G) : Inverse of a function
e x  e x
G-1. The inverse of the function f(x) = is
e x  e x
1 1 x 1 2x 1 1 x
(A) n (B) n (C) n (D) 2 n (1 + x)
2 1 x 2 2x 2 1 x
1
G-2. If f : [1, )  [2, ) is given by f (x) = x + , then f 1 (x) equals :
x
x x2  4 x x x2  4
(A) (B) (C) (D) 1  x 2  4
2 1  x2 2
G-3. If f : R  R is an invertible function such that f(x) and f –1(x) are also mirror image to each other about
the line y = –x, then
(A) f(x) is odd
(B) f(x) and f–1(x) may not be mirror image about the line y = x
(C) f(x) may not be odd
(D) f(x) is even
ax  b
G-4. If f(x) = , then (fof) (x) = x, provided that
cx  d
(A) d + a = 0 (B) d – a = 0 (C) a = b = c = d = 1 (D) a = b = 1

x 1  x  1
G-5. Let f(x) =  2 the range of h–1(x), where h(x) = fof(x) is

x 1 x  2
(A)  1, 2 (B) [–1, 2] (C) [–1, 4] (D) [–2, 2]
 
G-6. Statement – 1 All points of intersection of y = f (x) and y = f – 1 (x) lies on y = x only.
Statement – 2 If point P (, ) lies on y = f (x), then Q (, ) lies on y = f – 1 (x).
Statement – 3 Inverse of invertible function is unique and its range is equal to the function domain.
Which of the following option is correct for above statements in order
(A) T T F (B) F T T (C) T T T (D) T F T
Section (H) : Definition, graphs and fundamentals of Inverse Trigonometric functions
H-1. The domain of definition of f(x) = sin1 (x  1  2) is:

(A) [ 2, 0]  [2, 4] (B) (2, 0)  (2, 4) (C) [ 2, 0]  [1, 3] (D) ( 2, 0)  (1, 3)
H-2. The function f(x) = cot1 (x  3) x + cos1 x2  3x  1 is defined on the set S, where S is equal to:
(A) {0, 3} (B) (0, 3) (C) {0,  3} (D) [ 3, 0]
H-3. Domain of f(x) = cos–1 x + cot–1 x + cosec–1 x is

(A) [– 1, 1] (B) R (C) (– ]  [1, ) (D) {– 1, 1}
H-4. Range of f(x) = sin–1 x + tan–1 x + sec–1 x is

  3    3    3    3 
(A)  ,  (B)  ,  (C)  ,  (D)  , 
4 4  4 4  4 4  4 4 
ADVRFITF-41
H-5. cosec–1 (cos x) is real if

(A) x  [– 1, 1] (B) x  R

(C) x is an odd multiple of (D) x is a multiple of 
2


H-6. Domain of definition of the function f (x) = sin1 (2 x)  for real valued ' x ' is:
6
 1 1  1 1  1 1  1 1
(A)  4 , 2  (B)  2 , 2  (C)   ,  (D)   , 
     2 9  4 4
   3 
The solution of the equation sin1  tan   sin1   = 0 is
 x  6
H-7.
 4  
(A) x = 2 (B) x =  4 (C) x = 4 (D) x = 3
3
H-8. Number of solutions of the equation cot–1 4  x2  cos1(x2  5)  is :
2
(A) 2 (B) 4 (C) 6 (D) 8
Section (I) : Trig (trig–1x), trig–1 (trig x), trig–1 (–x) and Property (/2)
I-1. If x2, then cos–1 (cosx) is equal to

(A) x (B)  – x (C) 2 + x (D) 2 – x
2
I-2. If sin–1 x + sin–1 y = , then cos–1x + cos–1y is equal to
3
2  
(A) (B) (C) (D) 
3 3 6
I-3. If x  0 and  = sin1x + cos1x  tan1x, then
 3    
(A)    (B) 0    (C) 0   < (D)    
2 4 4 2 4 2

I-4. Number of solutions of equation tan–1(e–x) + cot–1(|nx|) = /2 is :
(A) 0 (B) 1 (C) 3 (D) 2

Section (J) : Interconversion/Simplification
 3 3
J-1. The numerical value of cot  2sin1  cos1  is
 5 5
4 3 3 4
(A) (B) (C) (D)
3 4 4 3
J-2. STATEMENT-1 : tan2 (sec–1 2) + cot2 (cosec– 1 3) = 11.

STATEMENT-2 : tan2  + sec2  = 1 = cot2 + cosec2 
STATEMENT-1
for STATEMENT-1
ADVRFITF-42
1 
J-3. If  is a real root of the equation x3 + 3x – tan2 = 0, then cot–1  + cot–1 – can be equal to
 2
 3
(A) 0 (B) (C)  (D)
2 2

 x  x 2
J-4. If sin–1   + sin–1  1–  + tan–1y = , then :
 2   4  3
   
49
(A) maximum value of x2 + y2 is (B) maximum value of x2 + y2 is 4
3
1
(C) minimum value of x2 + y2 is (D) minimum value of x2 + y2 is 3
2
 1
J-5. If x < 0, then value of tan–1(x) + tan–1   is equal to
x
 
(A) (B) – (C) 0 (D) –
2 2

 1 
J-6. If sin–1x + cot–1   = , then x is equal to
2 2
1 2 3
(A) 0 (B) (C) (D)
5 5 2
 1 
J-7. The numerical value of tan  2 tan1   is
 5 4
7 7 17 2
(A) (B) (C) (D) –
17 17 7 3
Section (K) : Addition and Subtraction Rule
 3x – 3x   x 
K-1. If f(x) = tan–1 
 3 3  x 2 
+ tan–1   , 0  x  3, then range of f(x) is
   3
       
(A) 0,  (B) 0,  (C)  ,  (D) 0, 
 2  4 6 3  3
a b 
K-2. STATEMENT-1 : If a > 0, b > 0, tan– 1   + tan– 1   = .  x = ab .
x x 2
m nm 
STATEMENT-2 : If m, n  N, n  m, then tan– 1   + tan– 1   = 4.
 
n  n  m 
STATEMENT-1
for STATEMENT-1
y
K-3. If cos–1x – cos–1 = , then 4x2 – 4xy cos  + y2 is equal to-
2
(A) 2 sin 2 (B) 4 (C) 4sin2  (D) – 4 sin2 
ADVRFITF-43
PART - III : MATCH THE COLUMN

1. Match the relation defined on set A = {a,b,c} in column I with the corresponding type in column II
Column I Column II
(A) {a,b), (b,a) (p) symmetric but not reflexive and transitive
(B) {(a,b), (b,a), (a,a), (b,b)} (q) equivalence
(C) {(a,b), (b,c), (a,c)} (r) symmetric and transitive but not reflexive
(D) {(a,a), (b,b), (c,c)} (s) transitive but not reflexive and symmetric
2. Column –  Column – 
(A) If S be set of all triangles and f : S  R+, f() = Area (p) one-one
of , then f is
 3 
(B) f : R   ,   and f(x) = cot–1(2x – x2 – 2), then f(x) is (q) many one
 4 
2x 2  x  1
(C) If f : R  R such that f(x) = , then f(x) is (r) onto function
7x 2  4x  4
(D) f : R  R and f(x) = epx sinqx where p, q  R+, then f(x) is (s) into function
3. Match The column

Column –  Column – 
(A) If f(x) is even & g(x) is odd (p) then fog must be odd
(B) If g(x) is periodic (q) then fog must be manyone
(C) If f(x) & g(x) are bijective (r) then fog is periodic
(D) If f(x) is into (s) then fog is injective
(t) then fog is into
4. Let f (x) = sin–1 x, g (x) = cos–1 x and h(x) = tan –1

x. For what complete interval of variation of x the
following are true.
Column –  Column – 
(A) f  x + g  x = /2 (p) [0, )
(B) f (x) + g  1 x 
2
=0 (q) [0, 1]
 1  x2 
(C) g   = 2 h (x) (r) (– , 1)
 1  x2
 
 1 x 
(D) h(x) + h(1) = h   (s) [– 1, 0]
 1 x 
5. Match the column
Column -          Column - 
 (A) Let a, b, c be three positive real numbers     (p) 
a (a  b  c) b (a  b  c) c (a  b  c)
   = tan– 1 + tan– 1 + tan– 1 ,
bc ca ab
then is equal to
(B) The value of the expression
1  
tan 1  tan 2 A  + tan 1 (cot A) + tan 1 (cot3A) for 0 < A < (/4) (q) –
 2  2
is equal to
1
(C) If x < 0, then {cos– 1(2x2 – 1) + 2cos–1 x} is equal to (r) –
2
3  12   16  
(D) The value of sin–1   – cos–1   + cos–1   is equal to (s)
5  13   65  2
ADVRFITF-44


1. For real numbers x and y, we write x R y  x – y + 2 is an irrational number. Then the relation R is-
(A) Reflexive (B) Symmetric (C) Transitive (D) Equivalence relation
2. Let A = N × N be the Certesian product of N and N. Let

S = {((m, n), (p, q))  A × A : m + q = n + p}
Consider the following statements:
I.If ((m,n), (p , q))  S, and ((p,q), (r, s))  S then ((r,s), (m,n))  S
II.There exists at least one element ((m,n), (p, q))  S such that ((p , q), (m, n))  S
Which of the statements given above is / are correct ?
(A) I only (B) II only (C) Both I and II (D) Neither I nor II.
3. Let A = Z, the set of integers. Let R1 = {(m, n)  Z × Z : (m + 4n) is divisible by 5 in Z}.

Let R2 = {(m, n)  Z × Z : (m + 9n) is divisible by 5 in Z}.
Which one of the following is correct ?
(A) R1 is a proper subset of R2 (B) R2 is a proper subset of R1
(C) R1 = R2 (D) R1 is not a symmetric relation on Z
4. Let X be the set of all persons living in a state. Elements x, y in X are said to be related if ‘x < y’,
whenever y is 5 years older than x. Which one of the following is correct?
(A) The relation is an equivalence relation
(B) The relation is transitive only
(C) The relation is transitive and symmetric, but not reflexive
(D) The relation is neither reflexive, nor symmetric, nor transitive
5. If x  0 and y  0, then the area bounded by the graph of [x] + [y] = 2 is (where [ . ] denotes greatest
integer function)
(A) 4 sq. unit. (B) 1 sq. unit (C) 2 sq. unit (D) 3 sq. unit
 1  1
6. If the solution set of [x] +  x   +  x –  = 8 is [a, b), then (a + b) equals to (where [ ] denotes
 2  3
greatest integer function)
19 20
(A) (B) (C) 6 (D) 7
3 3

  x     x  
  x    x 
7. If f(x) = {x} +  x   2 
+ x   2 
+ x   2 
........+  x   2 
, then values of

  1  x    1  2x   
  1  3x    1  99x 
[f( 3 )] is (where [•] denotes greatest integer function and {•} represent fractional part function)
(A) 5050 (B) 4950 (C) 17 (D) 73
8. Number of integral solutions of the inequation x2 – 10x + 25sgn(x2 + 4x – 32)  0

(A) infinite (B) 6 (C) 7 (D) 8
ADVRFITF-45
9. If [x + [2x]] < 3, where [.]denotes the greatest integer function, then x is
 3
(A) [0, 1) (B)  ,  (C) (1, ) (D) (–, 1)
 2
 x 2  5x  6
10. The set of all values of x for which  0 is (where {.} denotes the fractional part function)
1  2{x}
 5  5   5  5 
(A) 2,  {3} (B) (2, 3) (C)  , 3 (D) 2, U , 3
 2   2   2   2 
  1  
11. The domain of the function f (x) = log1/2   log2  1  4   1 is:
  x 
(A) 0 < x < 1 (B) 0 < x  1 (C) x  1 (D) null set
12. If q2  4 p r = 0, p > 0, then the domain of the function f (x) = log (p x3 + (p + q) x2 + (q + r) x + r) is :

 q    q 
(A) R     (B) R   (   ,  1]   
 2p    2p  
  q 
(C) R   (   ,  1)    (D) R
  2p  

x  [x]
13. Let f (x) = , R  A is onto then find set A. (where {.} and [.] represent fractional part and
1  x  [x]
greatest integer part functions respectively )
 1  1  1  1
(A)  0 ,  (B) 0 ,  (C) 0 ,  (D)  0 , 
 2  2  2  2
x
ex  e
14. Let f be a real valued function defined by f(x) = , then the range of f(x) is :
x
ex  e
(A) R (B) [0, 1] (C) [0, 1) (D) 0 , 1
 2 
15. The range of the function f (x) = 
log 2 2  log2 16sin2 x  1 is 
(A) ( 1) (B) ( 2) (C) ( 1] (D) ( 2]
16. Which of the following pair of functions are identical ?

x x x2
(A) 1  sin x , sin + cos (B) x,
2 2 x
 x
2
(C) x2 , (D) n x3 + n x2 , 5 n x
17. If domain of f(x) is (– , 0], then domain of f(6{x}2 – 5 {x} + 1) is (where {} represents fractional part
function).
 1 1  1   1 1
(A) n  3 , n  2  (B) (– , 0) (C) n  6 , n  1 (D) n  2 , n  3 
n   n   nI  
18. Let f: (e, )  R be defined by f(x) =n (n(n x)), then

(A) f is one one but not onto (B) f is onto but not one - one
(C) f is one-one and onto (D) f is neither one-one nor onto
19. If f (x) = 2 [x] + cos x, then f: R  R is: (where [. ] denotes greatest integer function)
(A) oneone and onto (B) oneone and into
(C) manyone and into (D) manyone and onto
ADVRFITF-46
 x | x | 4 ; x  Q

20. If f : R  R be a function such that f(x) =  , then f(x) is
x | x |  3 ; x  Q

(A) one-one, onto (B) many one, onto (C) one-one, into (D) many one, into
21. f (x) = x  1, f: R+  R, g(x) = ex, g: [ 1, )  R. If the function fog (x) is defined, then its domain
and range respectively are:
(A) (0, ) and [0, ) (B) [ 1, ) and [0, )
 1  1 
(C) [ 1, ) and 1  ,   (D) [ 1, ) and   1,  
 e   e 
x
22. Let f : (2, 4)  (1, 3) be a function defined by f (x) = x    (where [. ] denotes the greatest integer
2
1
function), then f (x) is equal to :
x
(A) 2x (B) x +     (C) x + 1 (D) x  1
2
23. The mapping f : R  R given by f (x) = x3 + ax2 + bx + c is a bijection if

(A) b2  3a (B) a2  3b (C) a2  3b (D) b2  3a
24. If the function f: [1, ) [1, ) is defined by f(x) = 2x(x – 1) then f–1 is
(A) (1/2)x(x – 1) (B)
1
2

1  1  4log2 x 
(C)
1
2
 1  1  4log2 x  (D) Not defined
25. Let f : N  N, where f(x) = x + (–1)x – 1 , then the inverse of f is.

(A) f –1(x) = x + (–1)x – 1 , x  N (B) f –1(x) = 3x + (–1)x – 1 , x  N
(C) f (x) = x , x  N
–1
(D) f –1(x) = (–1)x – 1 , x  N
 1   1 
26. tan   cos1 x  + tan   cos1 x  , x  0 is equal to
4 2  4 2 
2 x
(A) x (B) 2x (C) (D)
x 2

 1  sin x  1  sin x 
 
27. The value of cot1   , where < x < , is:
 1  sin x 
 1  sin x 
 2
x  x x x
(A)  (B) + (C) (D) 2 
2 2 2 2 2
 1  x3 
28. The domain of the function f (x) = sin1  3 / 2  + sin (sin x) + log(3{x} + 1) (x2 + 1),
 2x 
 
where {.} represents fractional part function, is:
(A) x  {1} (B) x  R  {1,  1} (C) x > 3, x  I (D) x 
29. A function g(x) satisfies the following conditions

(i) Domain of g is (–, ) (ii) Range of g is [–1, 7]
(iii) g has a period  and (iv) g(2) = 3
Then which of the following may be possible.
 3 ; x  n
(A) g(x) = 3 + 4 sin (n + 2x – 4), n  (B) g(x) = 
3  4 sin x ; x  n
(C) g(x) = 3 + 4 cos (n + 2x – 4), n  (D) g(x) = 3 – 8 sin (n + 2x – 4), n 
ADVRFITF-47
30. The complete solution set of the inequality [cot–1x]2 – 6 [cot–1 x] + 9  0, where [.] denotes greatest
integer function, is
(A) (– , cot 3] (B) [cot 3, cot 2] (C) [cot 3, ) (D) (– , cot 2]
31. The inequality sin– 1 (sin 5) > x2 – 4x holds for

(A) x  2 – 9  2, 2  9  2  (B) x > 2 + 9  2
(C) x < 2 – 9  2 (D) x 
 x2 x3   2 x 4 x6  
32. If sin-1  x    .......  + cos-1  x    .......  = for 0 < | x | < 2 , then x equals
 2 4  2 4  2
   
(A) 1/2 (B) 1 (C) – 1/2 (D) –1
33. cot–1  cos   – tan–1  

cos  = x. then sin x is equal to -
  

(A) tan2   (B) cot2   (C) tan  (D) cot  
2 2 2
34. The Inverse trigonometric equation sin–1 x = 2 sin–1 , has a solution for
3 3 1 1
(A) – << (B) all real values of  (C) ||  (D) || 
2 2 2 2
 
35. If f(x) = cot–1x : R+   0, 
 2
and g(x) = 2x – x2 : R  R. Then the range of the function f(g(x)) wherever define is
       
(A)  0,  (B)  0,  (C)  ,  (D)  
 2  4 4 2  4
36. Given the functions f(x) = e

 
cos1 sin x  
3  , g(x) = cosec1  4
 2cos x 
  and the function
 3 
h(x) = f(x) defined only for those values of x, which are common to the domains of the functions f(x) and
g(x). The range of the function h(x) is :
    
 
(A) [e 6 ,e ] (B) [e 6 ,e  ] (C) (e 6 ,e ) (D) [e 6 ,e 6 ]
PART-II: NUMERICAL VALUE QUESTIONS

INSTRUCTION :
 The answer to each question is NUMERICAL VALUE with two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal
placed.
1. If  and  are the values of x for which {x}, [x], x are in harmonic progression then find the value of
49||. (where [x] and {x} denote integral and fractional part of x resp.)
2. The domain of the function y = sin x  cos x + 7x  x 2  6 is [p,q]  [r,s] then value of p + q + r + s
is
 1
x  2 
3. The domain of f(x) such that the f(x) =  is prime is [x1, x2), then the value of
 1
x  2 

(x13 + x23). [Where [.] denotes greatest integer function less than or equal to x]
ADVRFITF-48
x3  2x 2  3x  2
4. If range of the function f(x) = ; x  R – {0} is (a,b] – {c} then value of
x3  2x 2  2x  1
a + b + 4c is
a  40b  7
5. Range of the function f(x) = |sin x |cos x| + cos x |sin x|| is [a, b] then is equal to
3
6. If f and g are two distinct linear functions defined on R such that they map[–1, 1] onto [0, 2] and
f(x)
h : R – {–1, 0, 1}  R defined by h(x) = , then |h(h(x)) + h(h(1/x))| > n. Then maximum integral
g(x)
value of n is
1
7. If f(x) = , g(x) = f (f(x)), h(x) = f(f(f(x))), then the absolute value of 15(f(x) . g(x) . h(x)) is.
1 x
(where x  0, 1)
8. If f(x) = ax7 + bx3 + cx – 5 ; a, b, c are real constants and f(–7) = 7 then maximum value of
1
|f(7) + 17 cos x| is
3
4a  7 3
9. If f(x) = x + (a – 3) x2 + x + 5 is a one-one function, then sum of all possible integral values of a is
3
Number of solutions of the equation e sin

2
x
10. = tan2x in [0, 10] is
11. Let f(x)= ([a]2 – 5[a] + 4)x3 – (6{a}2 – 5 {a} + 1)x – (tan x) sgn (x) be an even function  x  R, then the
sum of all possible values of '3a' is (where [] denotes G.I. F and {} fractional part functional part
function)
12. Let f be a oneone function with domain {21, 22, 23} and range {x,y,z}. It is given that exactly one of
the following statements is true and the remaining two are false. f(21) = x; f(22)  x ; f(23)  y.
then value of f–1(x) is :
 2 1 2  1 1 x
13. Let f : [– 2 + 1, 2 +1]   ,  be a function defined by f(x) = .
 2 2  1  x2
 1  

If f–1(x) = 
 4x  4x 2  1 , x  0 , then value of 20  17µ is
 2x 2
  , x0
14. If  <  <  are real roots of the equation x3 + 1 = 2 3

2x – 1 then value of + 4 + 10 is
1 2
15. If cos1x + cos1y + cos1z = , where  1  x, y, z 1, then find the value of (x + y2 + z2 + 2 x y z + 60)
2
226
16. The sum of absolute value of all possible values of x for which cos tan 1 sin cot 1 x = .
227
n 
17. If cot1 > , n  N, then sum of square of all possible value of n is
 6

  sin(cos1 x)  cos(sin1 x)  

10
 1

1
If x  (0, 1) and f(x) = sec tan1  
 cos(cos1 x)  sin(sin1 x)  
18. , then f   is
r 2  

   5 r
1  3 sin2   1
19. If sin1   = , then value of (tan  + 50) is equal to
2  5  4cos2  4 2
ADVRFITF-49
20. The number of real solutions of equation 1  cos 2x = 2 sin–1 (sin x), 10  x  10, is/are
21. The number of solution(s) of the equation, sin1x + cos1 (1  x) = sin1 ( x) is µ then value of µ
µ  100
is
7
n
   k 
1 
22. Find the value of 50    
n 1  k 1
cot 1  1  2
  r 
3

  r 1 

1. Let A = {1, 2, 3, 4} and R be a relation in A given
by R = {(1, 1), (2, 2), (3, 3), (4, 4), (1, 2), (2, 1), (3, 1), (1, 3)}, then relation R is
(A) Reflexive (B) Symmetric (C) Equivalence (D) Reflexive and Symmetric
2. For n, m  N, n | m means that n is a factor of m, then relation | is

(A) Reflexive (B) symmetric (C) Transitive (D) Equivalence
3. The inequality [2 – x] + 2 [x – 1]  0 is satisfied by (where [.] denotes greatest integer function) :

(A) x  {0} (B) x  W (C) x  N (D) x  [1, )
{x}
 1 1
4. Values of x satisfying   > are (where {.} denotes the fractional part function)
3 3
1 1 e
(A)  (B) –1 + (C) 2 + 3
(D)
2 9 2
5. Which of the following pairs of the inequations has same solution set. ([x] represents greatest integer
function and {x} represents fractional part function)
(A) [x]  3 and [x] < 4 (B) [x] > 3 and [x]  4
(C) [x] + [–x]  0 and {x} + {–x}  0 (D) sgn(x2 + 1) > 0 and x2 + 7x + 43 > 0
6. Let  <  < , be the real solutions of the equation 2e–{x} = (x + 1), then. ({x} represent fractional of x).
(A)  < 0 (B)  > 0 (C)  < 0 (D)  > 0
7. Consider the equation sgn(x2 – 6x +p) = q. Let 's' be the number of solutions of the equation, identify
the correct assertions :
(A) q = 0, s = 2  p  9 (B) q = 0, s = 2  p < 9
(C) q = 0, s = 0  p  9 (D) q = 0, s = 0  p > 9
8. If P and Q are the sum and product respectively of all integral values of x satisfying the equation
|3[x] – 4x| = 4, then
(where [.] denotes represents greatest integer function)
(A) P = 0 (B) P = 8 (C) Q = –16 (D) Q = –9
 4  x2 
9. If f(x) = sin n   , then
 1 x 
 
(A) domain of f(x) is (– 2, 1) (B) domain of f(x) is [–1, 1]
(C) range of f(x) is [–1, 1] (D) range of f(x) is [–1, 1)

ADVRFITF-50
10. D is domain and R is range of f(x) = x  1 + 2 3  x , then

(A) D : [1 , 3] ; (B) D : (– , 1] [3, ),
(C) R : 1, 3  (D) R :  2 , 10 
   
11. If [ 2 cos x ] + [ sin x ] =  3, then the range of the function, f (x) = sin x + 3 cos x in [0, 2 ] lies in
(where [. ] denotes greatest integer function)
(A) [– 3 , 3 ) (B) [–2, – 3 ] (C) [–3, –1] (D) [–2, – 3 )
12. Let D  [ 1, 1] is the domain of the following functions, state which of them are injective.
 1 1
tan x0
(A) f(x) =  x (B) g(x) = x3
 1 x0

(C) h(x) = sin 2x (D) k(x) = sin (x/2)
13. Let f(x) = x135 + x125 – x115 + x5 + 1. If f(x) divided by x3 – x, then the remainder is some function of x say
g(x). Then g(x) is an :
(A) one-one function (B) many one function (C) into function (D) onto function
14. The function f : X  Y, defined by f(x) = x2  4x + 5 is both oneone and onto if

(A) X = [2, ) & Y = [1, ) (B) X = (–,2] & Y = [1, )
(C) X = [3,) & Y = [2, ) (D) X = (–,2] & Y = (1, )
15. f : N  N where f(x) = x – (–1)x then f is :

(A) one-one (B) many-one
(C) onto (D) into
16. Which one of the following pair of functions are NOT identical ?
(A) e(nx)/2 and x
(B) tan (tanx) and cot (cotx)
(C) cos2x + sin4x and sin2x + cos4x
|x|
(D) and sgn (x), where sgn(x) stands for signum function.
x
ax  1
17. If the graph of the function f (x) = n x is symmetric about y-axis, then n is equal to:
x (a  1)
(A) 1/5 (B) 1/3 (C) 1 / 4 (D) – 1 / 3
 x 2 x  1
18. If f(x) =  & composite function h(x) = |f(x)| + f(x + 2), then
1  x x  1
(A) h(x) = 2x2 + 4x + 4  x  –1
(B) h(x) = x2 + x + 1  –1 < x  1
(C) h(x) = x2 – x – 1  –1 < x  1
(D) h(x) = –2 x>1
 0 for x  0
 2
19. Let f(x) =  x sin x   for  1  x  1 (x  0) , then:

 x x for x  1 or x   1
(A) f(x) is an odd function (B) f(x) is an even function
(C) f(x) is neither odd nor even (D) f  (x) is an even function
ADVRFITF-51
 x 2  1
20. If f : [–2, 2]  R where f(x) = x3 + tanx +   is a odd function, then the value of parametric P,
 P 
where [.] denotes the greatest integer function, can be
(A) 5 5 (D) P = 15
 
21. If f: R  [  1, 1], where f (x) = sin   x   , (where [.] denotes the greatest integer function), then
 2 
(A) f (x) is onto (B) f (x) is into (C) f (x) is periodic (D) f (x) is many one
2 x (sin x  tan x)
22. If f (x) = then it is, (where [.] denotes the greatest integer function)
 x  2 
2 
    3
(A) odd (B) Even (C) many one (D) one-one
23. dentify the statement(s) which is/are incorrect ?

(A) the function f(x) = sinx + cosx is neither odd nor even
(B) the fundamental period of f(x) = cos (sin x) + cos (cos x) is 
(C) the range of the function f(x) = cos (3 sin x) is [ 1, 1]
(D) f(x) = 0 is a periodic function with period 2
sin  [x]
24. If F (x) = , then F (x) is: (where { . } denotes fractional part function and [ . . ] denotes greatest
{x}
integer function and sgn (x) is a signum function)
(A) periodic with fundamental period 1 (B) even
 {x} 
(C) range is singleton (D) identical to sgn  sgn  1
 { x } 

25. Let f : R  R and g : R  R be two one-one and onto functions such that they are mirror images of
each other about the line y = a. If h(x) = f(x) + g(x), then h(x) is
(A) one-one (B) into
(C) onto (D) many-one
26. Which of following pairs of functions are identical.

1
(A) f(x) = e nsec x and g(x) = sec1 x (B) f(x) = tan (tan1 x) and g(x) = cot (cot1 x)
(C) f(x) = sgn (x) and g(x) = sgn (sgn (x)) (D) f(x) = cot2 x. cos2 x and g(x) = cot2 x  cos2 x
3
27. If sin–1x + sin–1y + sin–1z = , then
2
9
(A) x100 + y100 + z100 – =0 (B) x22 + y42 + z62 – x220 –y420 – z620 = 0
x101  y101  z101
x 2008  y 2008  z 2008
(C) x50 + y25 + z5 = 0 (D) 0
(xyz)2009
28. If X = cosec tan1 cos cot1 sec sin1 a and Y = sec cot1 sin tan1 cosec cos1 a; where 0  a < 1. Find the
relation between X and Y. Then
(A) X = Y (B) Y = 3  a2 (C) X  Y (D) X = 2Y
29. If  satisfies the inequation x2 – x – 2 > 0, then a value exists for

(A) sin–1  (B) cos–1  (C) sec–1  (D) cosec–1 
ADVRFITF-52
30. For the function f(x) = n (sin 1 og2 x),

1   
(A) Domain is  , 2 (B) Range is    , n 
2   2
(C) Domain is (1, 2] (D) Range is R
31. In the following functions defined from [–1, 1] to [–1, 1] , then functions which are not bijective are
2
(A) sin (sin–1x) (B) sin–1(sin x) (C) (sgn x) n ex (D) x3 sgn x

1  1 1
 sincot cos tan t    1  2t 2 
32. The expression  1 1  .   can take the value
 2t
2
2 cos tan sincot 2t
 

(A) 1/2 (B) –5 (C) 1 (D) 3/4
1  x2
33. If 0 < x < 1, then tan–1 is equal to:
1 x
1 1 x 1 x 1
(A) cos1 x (B) cos1 (C) cos1 (D) sin1x
2 2 2 2
x 1 
34. If f(x) = cos–1x + cos–1   3  3x 2  , then
2 2 
2  2 
(A) f   = (B) f   =
3 3 3 2
 1   1 1 
(C) f   = (D) f   = 2 cos–1 –
 
3 3  
3 3 3


4n
35. tan 1 is equal to:
n 1 n  2n2  2
4
(A) tan 1 2 + tan 1 3 (B) 4 tan 1 1 (C) /2 

(D) sec 1  2 
36. If sin2 (2 cos–1 (tan x)) = 1 then x may be
 1   1 
(A) x =  + tan–1   (B) x =  – tan–1  
 2  2
 1   1 
(C) x =  + tan–1   (D) x =  – tan–1  
 2  2
37. If sin–1 x + 2 cot–1 (y2 – 2y) = 2 , then

(A) x + y = y2 (B) x2 = x + y (C) y = y2 (D) x2 – x + y = y2
Comprehension # 1
Given a function f : A  B ; where A = {1, 2, 3, 4, 5} and B = {6, 7, 8}
1. Find number of all such functions y = f(x) which are one-one ?
(A) 0 (B) 35 (C) 5P3 (D) 53
2. Find number of all such functions y = f(x) which are onto
(A) 243 (B) 93 (C) 150 (D) none of these
3. The number of mappings of g(x) : B  A such that g(i)  g(j) whenever i < j is
(A) 60 (B) 140 (C) 10 (D) 35
ADVRFITF-53
Comprehension # 2
Let the domain and range of inverse circular functions are defined as follows
Domain Range
  3 
sin–1x [–1, 1] 2, 2 
 
cos–1x [–1, 1] [0, ]
  3 
tan–1x R  2, 2 
 
cot–1x R (0, )
  3 
cosec–1x (–, –1]  [1, )  2 , 2  – {}
 

sec–1x (–, –1]  [1, ) [0, ] –  
2
3
4. sin–1x < then solution set of x is
4
 1   1   1 1 
(A)  , 1 (B)   ,  1 (C)   ,  (D) none of these
 2   2   2 2
   
5. If x  ,  –{0}, then cosec–1 cosec x is
 2 2
(A) 2– x (B) + x (C)  –x (D) – – x
6. If x  [–1, 1], then range of tan–1(–x) is

 3 7   3 5    
(A)  ,  (B)  , (C) [–, 0] (D)   , 
 4 4   4 4   4 4

1. Let f(x) = x2 and g(x) = sin x for all x  R. Then the set of all x satisfying (f o g o g o f) (x) = (g o g o f)
(x), where (f o g) (x) = f(g(x)), is [IIT-JEE 2011, Paper-2, (3, –1), 80]
(A) ± n , n  {0, 1, 2,....} (B) ± n , n  {1, 2,....}

(C) + 2n, n  {.....–2, –1, 0, 1, 2,....} (D) 2n, n  {...., –2, –1, 0, 1, 2,....}
2
  sin      d
2. Let f() = sin  tan1    , where – <  < . Then the value of (f()) is
  )
  cos 2  4 4 d(tan
[IIT-JEE 2011, Paper-1, (4, 0), 80]
3. The function f : [0, 3] [1, 29], defined by f(x) = 2x3 – 15x2 + 36x + 1, is
(A) one-one and onto (B) onto but not one-one
(C) one-one but not onto (D) neither one-one nor onto
[IIT-JEE 2012, Paper-1, (3, –1), 70]
ADVRFITF-54
2    
4*. Let f : (–1, 1)  R be such that f(cos 4) = for   0,    ,  . Then the value(s) of
2  sec  2
 4 4 2
 1
f   is (are) [IIT-JEE 2012, Paper-2, (4, 0), 66]
 3
3 3 2 2
(A) 1 – (B) 1 + (C) 1 – (D) 1 +
2 2 3 3
 23  n 
5. The value of cot 
 n1 
cot –1  1 
 
2k  

is [JEE (Advanced) 2013, Paper-1, (2, 0)/60]
  k 1 
23 25 23 24
(A) (B) (C) (D)
25 23 24 23
6. Match List I with List II and select the correct answer using the code given below the lists :
List - I List – II
1/ 2
  cos(tan–1 y)  y sin(tan–1 y) 
2 
P  1    y 4
takes value 1.
1 5
 y2 –1 –1
 cot(sin y)  tan(sin y)   2 3
 
Q. If cos x + cos y + cox z = 0 = sin x + sin y + sin z then 2. 2
x–y
possible value of cos is
2
  1
R. If cos  – x  cos 2x + sin x sin 2x sec x = cos xsin 2x sec x + 3.
4  2
 
cos   x  cos 2x then possible value of sec x is
4 
S. 
If cot sin–1 1– x2  = sin  tan –1
 x 6  , x  0, 4. 1
then possible value of x is [JEE (Advanced) 2013, Paper-2, (3, –1)/60]
Codes :
P Q R S
(A) 4 3 1 2
(B) 4 3 2 1
(C) 3 4 2 1
(D) 3 4 1 2
  
7. Let f:  – ,   R be given by f(x) = (log(sec x + tanx)) 3 . Then
 2 2
[JEE (Advanced) 2014, Paper-1, (3, 0)/60]
(A) f(x) is an odd function (B) f(x) is a one-one function
(C) f(x) is an onto function (D) f(x) is an even function

8. Let f : [0, 4]  [0, ] be defined by f(x) = cos–1 (cos x). The number of points x [0, 4] satisfying the
10  x
equation f(x) = is [JEE (Advanced) 2014, Paper-1, (3, 0)/60]
10
6 4
9*. If  = 3sin–1   and  = 3cos–1   , where the inverse trigonometric functions take only the
 11  9
principal values, then the correct option(s) is(are) [JEE (Advanced) 2015, P-2 (4, –2)/ 80]
(A) cos  > 0 (B) sin  < 0 (C) cos( + ) > 0 (D) cos  < 0
ADVRFITF-55
10. The number of real solutions of the equation

  
 x 
i
    x
i  
sin–1  
 i1
xi1  x 
i1
 
 2  
 =
2
– cos–1  
 i  1   2   
i1
(  x)i 

 1 1
lying in the interval   ,  is __________. [JEE(Advanced) 2018, Paper-1,(3, 0)/60]
 2 2
  
(Here, the inverse trigonometric functions sin–1x and cos–1x assume values in   ,  and [0, ],
 2 2
respectively).
11. Let X be a set with exactly 5 elements and Y be a set with exactly 7 elements. If  is the number of
one-one functions from X to Y and is the number of onto function form Y to X, then the value of
1
( – ) is ______ . [JEE(Advanced) 2018, Paper-2,(3, 0)/60]
5!
 x  
   x  

12. Let E1 =  x  R : x  1and  0  and E2 =  x  E1 : sin–1  loge    is a real number  .
 x –1  
   x – 1  

  
(Here, the inverse trigonometric function sin–1x assumes values in  – ,  .)
 2 2
 x 
Let f : E1  R be the function defined by f(x) = loge  
 x – 1
  x 
and g : E2  R be the function defined by g(x) = sin–1  loge  
  x – 1 
[JEE(Advanced) 2018, Paper-2,(3, –1)/60]
LIST-I LIST-II
 1   e 
(P) The range of f is (1)  – , 1– e    e – 1,  
   
(Q) The range of g contains (2) (0, 1)
 1 1
(R) The domain of f contains (3) – 2 , 2 
 
(S) The domain of g is (4) (–, 0)  (0, )
 e 
(5)  – , e – 1
 
1 e 
(6) (–, 0)   , 
 2 e – 1
The correct option is
(A) P  4; Q  2; R  1; S  1 (B) P  3; Q  3; R  6; S  5
(C) P  4; Q  2; R  1; S  6 (D) P  4; Q  3; R  6; S  5
13. The value of

 1 10  7  k   7 (k  1)      3 
sec–1 
4  sec 
 12

2
 sec 
  12

2
 in the interval  – ,
   4 4
 equals
 k 0
[JEE(Advanced) 2019, Paper-2 ,(4, –1)/62]
ADVRFITF-56
PART - II : JEE (MAIN) / AIEEE PROBLEMS (PREVIOUS YEARS)

1. Consider the following relations : [AIEEE-2010, (4, – 1), 144]
R : {(x, y)| x ,y are real numbers and x = wy for some rational number w}
m p
S= {  ,  | m, n, p and q are integers such that n, q  0 and qm = pn}
 n q
Then
(1) neither R nor S is an equivalence relation
(2) S is an equivalence relation but R is not an equivalence relation
(3) R and S both are equivalence relations
(4) R is an equivalence relation but S is not an equivalence relation
2. Let R be the set of real numbers. [AIEEE-2011(Part-, (4, – 1), 120]
Statement-1 : A = {(x, y)  R × R : y – x is an integer} is an equivalence relation on R.
Statement-2 : B = {(x, y)  R × R : x = y for some rational number } is an equivalence relation on R.
(1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1.
(2) Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1.
(3) Statement-1 is true, Statement-2 is false.
(4) Statement-1 is false, Statement-2 is true.
3. Consider the following relation R on the set of real square matrices of order 3.
R = {(A, B)|A = P–1 BP for some invertible matrix P}. [AIEEE-2011(Part-, (3, – 1), 120]
Statement -1 : R is equivalence relation.
Statement - 2 : For any two invertible 3 × 3 matrices M and N, (MN)–1 = N–1M–1.
(1) Statement-1 is true, statement-2 is a correct explanation for statement-1.
(2) Statement-1 is true, statement-2 is true; statement-2 is not a correct explanation for statement-1.
(3) Statement-1 is true, statement-2 is false.
(4) Statement-1 is false, statement-2 is true.
1
4. The domain of the function f(x) = is : [AIEEE 2011, , (4, –1), 120]
| x | x
(1) (– , ) (2) (0, ) (3) (–, 0) (4) (–, ) – {0}
5. Let f be a function defined by f(x) = (x–1)2 + 1, (x  1). [AIEEE 2011, , (4, –1), 120]
Statement - 1 : The set {x : f(x) = f–1(x)} = {1, 2}.
Statement - 2 : f is a bijection and f–1(x) = 1 + x  1 , x  1.
(1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1.
(2) Statement-1 is true, Statement-2 is true; Statement-2 is NOT a correct explanation for Statement-1
(3) Statement-1 is true, Statement-2 is false
(4) Statement-1 is false, Statement-2 is true .
6. If x, y, z are in A.P. and tan–1x, tan–1y and tan–1z are also in A.P., then [AIEEE - 2013, (4, –1),120]
(1) x = y = z (2) 2x = 3y = 6z (3) 6x = 3y = 2z (4) 6x = 4y = 3z
1
7. If g is the inverse of a function f and f'(x) = , then g'(x) equal to :
1  x5
[JEE(Main)2014,(4, – 1),120]
1
(1) (2) 1 + {g(x)}5 (3) 1 + x5 (4) 5x4
1  {g(x)}5
ADVRFITF-57
 2x  1
8. Let tan–1y = tan–1x + tan–1   , where |x| < . Then a value of y is
 1– x 2  3
[JEE(Main)2015,(4, – 1), 120]
3x – x 3
3x  x 3
3x – x 3
3x  x3
(1) (2) (3) (4)
1– 3x 2 1– 3x 2 1  3x 2 1  3x 2
 1
9. If f(x) + 2f   = 3x, x  0, and S = {x  R : f(x) = f (–x)} ; then S : [JEE(Main)2016,(4, – 1), 120]
x
(1) contains exactly one element (2) contains exactly two elements.
(3) contains more than two elements. (4) is an empty set.
10. Two sets A and B are as under : A = {(a, b)  R  R : |a –5| < 1 and |b – 5| < 1 } ;
B = {(a, b )  R  R : 4(a– 6)2 + 9(b–5)2  36 }. Then; [JEE(Main)2018,(4, – 1), 120]
(1) A  B =  ( an empty set) (2) Neither A  B nor B  A
(3) B  A (4) A  B
 2   3   3
11. If cos–1   + cos–1   =  x   then x is equal to :
 
3 x  4 x  2  4
[JEE(Main) 2019, Online (09-01-19),P-1 (4, – 1), 120]
145 145 146 145
(1) (2) (3) (4)
12 10 12 11
1 1
12. For x  R – {0, 1}, let f1(x) = , f2(x) = 1 – x and f3(x) = be three given functions. If a function, J(x)
x 1 x
satisfies (f2 J f1 ) (x) = f3(x) is equal to : [JEE(Main) 2019, Online (09-01-19),P-1 (4, – 1), 120]
1
(1) f3(x) (2) f1(x) (3) f3(x) (4) f2(x)
x
 19  n

13. The value of cot   cot 1  1   2p   is : [JEE(Main) 2019, Online (10-01-19),P-2 (4, – 1), 120]
 n1 
  p 1  
19 21 22 23
(1) (2) (3) (4)
21 19 23 22
14. The number of functions f from {1, 2, 3, …., 20}, onto {1,2,3,………..,20} such that f(k) is a multiple of 3,
wherever k is a multiple of 4, is : [JEE(Main) 2019, Online (11-01-19),P-2 (4, – 1), 120]
(1) 5!  6! (2) (15)!  6! (3) 65 × (15)! (4) 56 × 15
Let Z be the set of integers. If A = {x  Z : 2( x 2)( x – 5 x 6)

2
15.  1] and B = {x  Z : – 3  2x – 1  9} then the
number of subsets of the set A × B, is – [JEE(Main) 2019, Online (12-01-19),P-2 (4, – 1), 120]
(1) 218 (2) 212 (3) 215 (4) 210
 1– x   2x 
16. If f(x) = loge  ,| x | 1 , then f   is equal to :
 1 x   1 x2 
[JEE(Main) 2019, Online (08-04-19),P-1 (4, – 1), 120]
(1) (f(x))2 (2) 2f(x) (3) –2f(x) (4) 2f(x2)
ADVRFITF-58
3  1 
17. If = cos –1  ,  = tan–1  , where 0 < , < , then  –  is equal to :
5 3 2
[JEE(Main) 2019, Online (08-04-19),P-1 (4, – 1), 120]
 9   9   9   9 
(1) tan–1  (2) cos–1 
 (3) sin –1 
 (4) tan–1 

 14   5 10   5 10   5 10 
2
  3 cos x  sin x  
18. If 2y   cot –1   , x   0,   then dy is equal to :
  
  cos x – 3 sin x    2 dx
[JEE(Main) 2019, Online (08-04-19),P-1 (4, – 1), 120]
   
(1) x – (2) 2x – (3) –x (4) –x
6 3 3 6
19. Let f(x) = ax (a > 0) be written as f(x) = f1(x) + f2(x), where f1(x) is an even function and f2(x) is an old
function. Then f1(x + y) + f1(x – y) equals : [JEE(Main) 2019, Online (08-04-19),P-2 (4, – 1), 120]
(1) 2f1(x + y) f1(x – y) (2) 2f1(x) f1(y) (3) 2f1(x) f2(y) (4) 2f1(x + y) f2(x – y)
8 2 x – 8 –2 x
20. The inverse function of f(x) = , x(–1, 1), is
8 2x  8 – 2x
[JEE(Main) 2020, Online (08-01-20),P-1 (4, –1), 120]
1  1 x  1  1– x 
(1) loge   (2) loge  
4  1– x  4  1 x 
1  1 x  1  1– x 
(3) (log8 e) loge   (4) (log8 e) loge  
4  1– x  4  1 x 
x[ x ]
21. Let f : (1,3)  R be a function defined by f(x) = , where [x] denotes the greatest integer  x. Then
1 x2
the range of f is : [JEE(Main) 2020, Online (08-01-20),P-2 (4, –1), 120]
3 4  2 1  3 4  2 3  3 4   2 4
(1)  ,  (2)  ,    ,  (3)  ,    ,  (4)  , 
4 5  5 2   5 5  5 5   4 5   5 5
 
22. If f(x) = tan–1(secx + tanx), – < x< , and f(0) = 0, then f(1) is equal to :
2 2
1 2  1  1
(1) (2) (3) (4)
4 4 4 4
[JEE(Main) 2020, Online (09-01-20),P-1 (4, –1), 120]
ADVRFITF-59
Relative Motion
 Marked Questions can be used as Revision Questions.

Section (A) : Relative motion in one dimension
A-1. Two parallel rail tracks run north-south. Train A moves due north with a speed of 54 km h –1 and train B
moves due south with a speed of 90 km h–1. A monkey runs on the roof of train A with a velocity of
18 km/h w.r.t. train A in a direction opposite to that of A. Calculate the (a) relative velocity of B with
respect to A (b) relative velocity of ground with respect to B (c) velocity of a monkey as observed by a
man standing on the ground. (d) Velocity of monkey as observed by a passenger of train B.
A-2. A train is moving with a speed of 40 km/h. As soon as another train going in the opposite direction
passes by the window, the passenger of the first train starts his stopwatch and notes that other train
passes the window in 3 s. Find the speed of the train going in the opposite direction if its length is 75 m.
A-3. An object A is moving with 10 m/s and B is moving with 5 m/s in the same direction of positive x-axis.
A is 100 m behind B as shown. Find the time taken by A to meet B.
A-4. The driver of a train A running at 25 ms–1 sights a train B moving in the same direction on the same
track with 15 ms–1. The driver of train A applies brakes to produce a deceleration of 1.0 ms –2.
What should be the minimum distance between the trains to avoid the accident?
Section (B) : Relative motion in two dimensions

B-1. A particle A moves with a velocity 4 î and another particle B moves with a velocity – 3 ĵ . Find VAB , VBA
and their magnitude.
B-2. A ship is steaming due east at 12 ms–1. A woman runs across the deck at 5 ms –1 (relative to ship) in a
direction towards north. Calculate the velocity of the woman relative to sea.
B-3. Two perpendicular rail tracks have two trains A & B respectively. Train A moves towards north with a
speed of 54 km h–1 and train B moves towards west with a speed of 72 km h–1. Assume that both trains
start from same point. Calculate the
(a) Relative velocity of ground with respect to B
(b) Relative velocity of A with respect to B.
B-4. A man is swimming in a lake in a direction of 30° East of North with a speed of 5 km/h and a cyclist is
going on a road along the lake shore towards East at a speed of 10 km/h. In what direction and with
what speed would the man appear to swim to the cyclist.
B-5. A ship is sailing towards north at a speed of 2 m/s. The current is taking it towards East at the rate of
1 m/s and a sailor is climbing a vertical pole on the ship at the rate of 1 m/s. Find the velocity of the
sailor with respect to ground.
Section (C) : Relative motion in river flow & Air flow

C-1. A swimmer’s speed in the direction of flow of river is 16 km h –1. Swimmer's speed against the direction
of flow of river is 8 km h–1. Calculate the swimmer’s speed in still water and the velocity of flow of the
river.
C-2. A man can swim with a speed of 4 km h–1 in still water. How long does he take to cross a river 1 km
wide if the river flows steadily at 3 km h–1 and he makes his strokes normal to the river current? How far
down the river does he go when he reaches the other bank?
C-3. A river is flowing from west to east at a speed of 5 m/min. A man on the south bank of the river, capable
of swimming at 10 m/min in still water, swims across the shortest path distance. In what direction
should he swim?
Toll Free : 1800 258 5555 | CIN : U80302RJ2007PLC024029
ADVRL - 20
Relative Motion
Section (D) : Relative motion in Rain and wind
D-1. A pipe which can rotate in a vertical plane is mounted on a cart. The cart moves uniformly along a
horizontal path with a speed v1 = 2 m/s. At what angle  to the horizontal should the pipe be placed
so that drops of rain falling vertically with a velocity v2 = 6m/s move parallel to the axis of the pipe
without touching its walls? Consider the velocity of the drops as constant due to the resistance of the
air.
D-2. Rain seems to be falling vertically to a person sitting in a bus which is moving uniformly eastwards with
10 m/s. It appears to come from vertical at a velocity 20 m/s. Find the speed of rain drops with respect
to ground.
D-3. To a man walking at the rate of 2 km/hour with respect to ground, the rain appears to fall vertically.
When he increases his speed to 4 km/hour in same direction of his motion, rain appears to meet him at
an angle of 45º with horizontal, find the real direction and speed of the rain.
Section (E) : Velocity of separation & approach

E-1. A particle is kept at rest at origin. Another particle starts from (5m, 0) with a velocity of – 4 î + 3 ĵ m/s.
Find their closest distance of approach.
E-2. Four particles situated at the corners of a square of side ‘a’, move at a constant speed v. Each particle
maintains a direction towards the next particle in succession. Calculate the time the particles will take to
meet each other.

Section (A) : Relative motion in one dimension
A-1. An aeroplane is flying vertically upwards with a uniform speed of 500 m/s. When it is at a height of
1000 m above the ground a shot is fired at it with a speed of 700 m/s from a point directly below it. The
minimum uniform acceleration of the aeroplane now so that it may escape from being hit ? (g = 10 m/s2)
(A) 10 m/s2 (B) 8 m/s2 (C) 12 m/s2 (D) None of these
A-2. A stone is thrown upwards from a tower with a velocity 50 ms–1. Another stone is simultaneously thrown
downwards from the same location with a velocity 50 ms –1. When the first stone is at the highest point,
the relative velocity of the second stone with respect to the first stone is (assume that second stone has
not yet reached the ground) :
(A) Zero (B) 50 ms–1 (C) 100 ms–1 (D) 150 ms–1
A-3. Shown in the figure are the position time graph for two children going home from the school. Which of
the following statements about their relative motion is true after both of them started moving?
Their relative velocity: (consider 1-D motion)
(A) first increases and then decreases (B) first decreases and then increases
(C) is zero (D) is non zero constant.
ADVRL - 21
Relative Motion
A-4. Shown in the figure are the velocity time graphs of the two particles P 1 and P2. Which of the following
statements about their relative motion is true? Magnitude of their relative velocity: (consider 1-D motion)
(A) is zero (B) is non-zero but constant

(C) continuously decreases (D) continuously increases
A-5. Two trains A and B which are 100 km apart are travelling towards each other on different tracks with
each having initial speed of 50 km/h. The train A accelerates at 20 km/h2 and the train B retards at the
rate 20 km/h2. The distance covered by the train A when they cross each other is :
(A) 45 km (B) 55 km (C) 65 km (D) 60 km
A-6. A jet airplane travelling from east to west at a speed of 500 km h –1 eject out gases of combustion at a
speed of 1500 km h–1 with respect to the jet plane. What is the velocity of the gases with respect to an
observer on the ground?
(A) 1000 km h–1 in the direction west to east (B) 1000 km h–1 in the direction east to west
–1
(C) 2000 km h in the direction west to east (D) 2000 km h–1 in the direction east to west
Section (B) : Relative motion in two dimension

B-1. A helicopter is flying south with a speed of 50 kmh –1. A train is moving with the same speed towards
east. The relative velocity of the helicopter as seen by the passengers in the train will be towards.
(A) north east (B) south east (C) north west (D) south west
B-2. Two particles are moving with velocities v1 and v2. Their relative velocity is the maximum, when the
angle between their velocities is :
(A) zero (B) /4 (C) /2 (D) 
B-3. A ship is travelling due east at 10 km/h. A ship heading 30° east of north is always due north from the
first ship. The speed of the second ship in km/h is -
(A) 20 2 (B) 20 (C) 20 3 / 2 (D) 20/ 2
Section (C) : Relative motion in river flow

C-1. A boat, which has a speed of 5 km/h in still water, crosses a river of width 1 km along the shortest
possible path in 15 minutes. The velocity of the river water in km/h is -
(A) 1 (B) 3 (C) 4 (D) 41
C-2. A boat is rowed across a river (perpendicular to river flow) at the rate of 9 km/hr. The river flows at the
rate of 12 km/hr. The velocity of boat in km/hr is:
(A) 14 (B) 15 (C) 16 (D) 17
C-3. A boat which can move with a speed of 5 m/s relative to water crosses a river of width 480 m flowing
with a constant speed of 4 m/s. What is the time taken by the boat to cross the river along the shortest
path.
(A) 80 s (B) 160 s (C) 240 s (D) 320 s
C-4. An airplane pilot sets a compass course due west and maintains an air speed of 240 km/h. After flying
1
for h, he finds himself over a town that is 150 km west and 40 km south of his starting point. The wind
2
velocity (with respect to ground) is :
(A) 100 km/h, 37° W of S (B) 100 km/h, 37° S of W
(C) 120 km/h, 37° W of S (D) 120 km/h, 37° S of W
ADVRL - 22
Relative Motion
Section (D) : Relative motion in Rain and wind
D-1. It is raining vertically downwards with a velocity of 3 km h –1. A man walks in the rain with a velocity of
4 kmh–1. The rain drops will fall on the man with a relative velocity of :
(A) 1 kmh–1 (B) 3 kmh–1 (C) 4 kmh–1 (D) 5 kmh–1
D-2. A man walks in rain with a velocity of 5 kmh–1. The rain drops strike at him at an angle of 45° with the
horizontal. The velocity of the rain if it is falling vertically downward is :
(A) 5 kmh–1 (B) 4 kmh–1 (C) 3 kmh–1 (D) 1 kmh–1
D-3. Raindrops are falling vertically with a velocity of 10 m/s. To a cyclist moving on a straight road the
raindrops appear to be coming with a velocity of 20 m/s. The velocity of cyclist is :
(A) 10 m/s (B) 10 3 m/s (C) 20 m/s (D) 20 3 m/s
D-4. An aeroplane has to go along straight line from A to B, and back again. The relative speed with respect
to wind is V. The wind blows perpendicular to line AB with speed . The distance between A and B is .
The total time for the round trip is:
2 2 2V 2
(A) (B) 2 (C) (D)
V 
2 2 V  2 V 2  2 V  2
2
Section (E) : Velocity of separation & approach

E-1. For two particles A and B, given that rA = 2 î + 3 ĵ , rB = 6 î + 7 ĵ , v A = 3 î – ĵ and vB = x î – 5 ĵ . What is
the value of x if they collide?
(A) 1 (B) – 1 (C) 2 (D) –2
E-2#. Two particles A and B move with velocities v1 and v2 respectively along the x & y axis. The initial
separation between them is ‘d’ as shown in the figure. Find the least distance between them during
their motion.
d.v12 d.v 22 d.v1 d.v 2

(A) (B) (C) (D)
v  v 22
2
1 v  v 22
2
1 v v
2 2
v12  v 22
1 2
PART - III : MATCH THE COLUMN

1. Match the following:
A ball is thrown vertically upward in the air by a passenger (relative to himself) from a train that is
moving as given in column I (vball << vescape). Correctly match the situation as described in the column I,
with the paths given in column II.
Column-  Column-II
(A) Train moving with constant acceleration on a slope then (p) Straight line
path of the ball as seen by the passenger.
(B) Train moving with constant acceleration on a slope then (q) Parabolic
path of the ball as seen by a stationary observer outside.
(C) Train moving with constant acceleration on horizontal ground (r) Elliptical
then path of the ball as seen by the passenger.
(D) Train moving with constant acceleration on horizontal ground (s) Hyperbolic
then path of the ball as seen by a stationary observer outside. (t) Circular
ADVRL - 23
Relative Motion
2. Both A & B are thrown simultaneously as shown from a very high tower.
Column-I Column-II
10m/s
B
A
(A) 10m/s (p) Distance between the two balls at two seconds
is 16 5 m.
10m/s
5m/s
(B) (q) distance between two balls at 2 seconds is

40 m.
10m/s
B
A 37°
10m/s
(C) (r) distance between two balls at 2 sec is 10 5 m.
10m/s
37° B
A 37°
10m/s
(D) (s) Magnitude of relative velocity of B w.r.t A is
5 2 m/s.
(t) magnitude of relative velocity of B with respect

to A is 5 5 m/s.
ADVRL - 24
Relative Motion

1. Two cars are moving in the same direction with a speed of 30 km h –1. They are separated from each
other by 5 km. Third car moving in the opposite direction meets the two cars after an interval of
4 minutes. What is the speed of the third car ?
(A) 35 km h–1 (B) 40 km h–1 (C) 45 km h–1 (D) 75 km h–1
2. A bus is moving with a velocity 10 ms–1 on a straight road. A scooterist wishes to overtake the bus in
100s. If, the bus is at a distance of 1 km from the scooterist, with what velocity should the scooterist
chase the bus? (Neglect size of the bus)
(A) 50 ms–1 (B) 40 ms–1 (C) 30 ms–1 (D) 20 ms–1
3. A coin is released inside a lift at a height of 2 m from the floor of the lift. The height of the lift is
10 m. The lift is moving with an acceleration of 11 m/s 2 downwards. The time after which the coin will
strike with the lift is :
4 2
(A) 4 s (B) 2 s (C) s (D) s
21 11
4. A police van moving on a highway with a speed of 30 km h–1 fires a bullet at a thief’s car speeding away
in the same direction with a speed of 192 km h–1. If the muzzle speed of the bullet is 150 ms –1, with
what speed does the bullet hit the thief’s car (as, seen by thief). According to thief in the car ?
(A) 105 m/s (B) 100 m/s (C) 110 m/s (D) 90 m/s
5. A flag on a bus is fluttering in north direction & wind is blowing in east direction. Then which of the
following will be true -
(A) bus is moving in south direction.
(B) bus is moving in north east direction.
(C) bus may be moving in any direction between south & east.
(D) bus may be moving in any direction between south & west.

6. For four particles A, B, C & D the velocities of one with respect to other are given as VDC is 20 m/s
  
towards north, VBC is 20 m/s towards east and VBA is 20 m/s towards south. Then VDA is
(A) 20 m/s towards north (B) 20 m/s towards south
(C) 20 m/s towards east (D) 20 m/s towards west
7. Two persons P and Q start from points A and B respectively as shown in figure. P and Q have speed
v = 12 m/s in shown directions towards point O. when the distance between P and Q is 120m, then Q
increases its speed to 15 m/s. Then find out who will reach the point O first.
(A) P (B) Q
(C) both P and Q reaches simultaneously (D) Data is insufficient
8. A man crosses the river perpendicular to river flow in time t seconds and travels an equal distance
down the stream in T seconds. The ratio of man's speed in still water to the speed of river water will be :
t2  T2 T2  t2 t2  T2 T2  t2
(A) (B) (C) (D)
t2  T2 T2  t2 t2  T2 T2  t2
ADVRL - 25
Relative Motion
9. Two aeroplanes fly from their respective positions 'A' and 'B' starting at
the same time and reach the point 'C' simultaneously when wind was
not blowing. On a windy day they head towards 'C' but both reach the
point 'D' simultaneously in the same time which they took to reach 'C'.
Then the wind is blowing in
(A) North-East direction
(B) North-West direction
(C) Direction making an angle 0 <  < 90 with North towards East.
(D) North direction
10. A man who is wearing a hat of extended length of 12 cm is running in rain falling vertically downwards
with speed 10 m/s. The maximum speed with which man can run, so that rain drops do not fall on his
face (the length of his face below the extended part of the hat is 16 cm) will be:
15 40
(A) m/s (B) m/s (C) 10 m/s (D) zero
2 3
11. A man is going up in a lift (open at the top) moving with a constant velocity 3 m/s. He throws a ball up at
5 m/sec relative to the lift when the lift is 50 m above the ground. Height of the lift when the ball meets it
during its downward journey is (g = 10 m/s2) [Olympiad (Stage-1) 2017]
(A) 53 m (B) 58 m (C) 63 m (D) 68 m
PART - II : SINGLE AND DOUBLE VALUE INTEGER TYPE

1. Men are running along a road at 15 km/h behind one another at equal intervals of 20 m. Cyclists are
riding in the same direction at 25 km/h at equal intervals of 30 m. At what speed (in km/h) an observer
travel along the road in opposite direction so that whenever he meets a runner he also meets a cyclist?
(Neglect the size of cycle)
2. Two identical trains take 3 sec to pass one another when going in the opposite direction but only
2.5 sec if the speed of one is increased by 50%. Find the time (in sec) one would take to pass the other
when going in the same direction at their original speed.
3. Three elephants A, B and C are moving along a straight line
with constant speed in same direction as shown in figure.
Speed of A is 5 m/s and speed of C is 10 m/s. Initially
separation between A & B is ‘d’ and between B & C is also d.
When ‘B’ catches ‘C’ separation between A & C becomes 3d.
Find the speed of B (in m/s).
4. A man standing on a truck which moves with a constant horizontal acceleration a (= 10 m/s 2) when
speed of the truck is 10 m/s. The man throws a ball with velocity 5 2 m/s with respect to truck. In the
direction shown in the diagram. Find the displacement of ball in meters in one second as observed by
the man. (g = 10 m/s2)
5. A swimmer crosses the river along the line making an angle of 45º with the direction of flow. Velocity of
the river water is 5 m/s. Swimmer takes 6 seconds to cross the river of width 60 m. If the velocity of the
swimmer with respect to water is 5 n m/s, then find n.
ADVRL - 26
Relative Motion
6. An aeroplane has to go from a point A to another point B, 1000 km away due 30º west of north. A wind
is blowing due north at a speed of 20 m/s. The air-speed of the plane is 150 m/s. If the angle at which
the pilot should head the plane to reach the point B is sin–1(1/n) west of the line AB, Then find n.
7. Rain appears to be falling at an angle of 37° with vertical to the driver of a car moving with a velocity of
7 m/sec. When he increases the velocity of the car to 25 m/sec, the rain again appears to fall at an
angle 37° with vertical. If the actual velocity of rain relative to ground is 4n m/s then find n.
8. During a rainy day, rain is falling vertically with a velocity 2m/s. A boy at rest starts his motion with a
constant acceleration of 2m/s2 along a straight road. If the rate at which the angle of the axis of
umbrella with vertical should be changed is 1/n at t = 5s so that the rain falls parallel to the axis of the
umbrella, then find n.
9. Two men P & Q are standing at corners A & B of square ABCD of side 8 m. They start moving along
the track with constant speed 2 m/s and 10 m/s respectively. Find the time (in seconds) when they will
meet for the first time.
10. Two straight tracks AOB and COD meet each other at right angles at point O. A person walking at a
speed of 5 km/h along AOB is at the crossing O at 12 o'clock noon. Another person walking at the
same speed along COD reaches the crossing O at 1:30 PM. If the time at which the distance between
them is least is 12 : T PM, then find T.
11. P is a point moving with constant speed 10 m/s such that its velocity vector always maintains an angle
60° with line OP as shown in figure (O is a fixed point in space). The initial distance between O and P is
100 m. After what time (in sec) shall P reach O.

1. A man standing on the edge of the terrace of a high rise building throws a stone vertically up with a
speed of 20 m/s. Two seconds later an identical stone is thrown vertically downwards with the same
speed of 20 m/s. Then :
(A) the relative velocity between the two stones remain constant till one hits the ground
(B) both will have the same kinetic energy when they hit the ground
(C) the time interval between their hitting the ground is 2 seconds
(D) if the collisions on the ground are perfectly elastic both will rise to the same height above the
ground.
2. A man in a lift which is ascending with an upward acceleration 'a' throws a ball vertically upwards with a
velocity ‘v’ with respect to himself and catches it after ‘t 1’ seconds. Afterwards when the lift is
descending with the same acceleration 'a' acting downwards the man again throws the ball vertically
upwards with the same velocity with respect to him and catches it after ‘t 2’ seconds
(A) the acceleration of the ball with respect to ground is g when it is in air
g (t1  t 2 )
(B) the velocity v of the ball relative to the lift is
t1 t 2
g (t 2  t1 )
(C) the acceleration 'a' of the lift is
t1  t 2
g t1 t 2
(D) the velocity ‘v’ of the ball relative to the man is
(t1  t 2 )
ADVRL - 27
Relative Motion
3. At an instant particle-A is at origin and moving with constant velocity (3iˆ  4ˆj) m / s and particle-B is at
(4, 4)m and moving with constant velocity (4iˆ  3ˆj) m / s . Then :
(A) at this instant relative velocity of B w.r.t. A is (iˆ  7ˆj) m / s
(B) at this instant approach velocity of A and B is 3 2 m/s
(C) relative velocity of B w.r.t. A remains constant
(D) approach velocity of A and B remains constant
4. A person is standing on a truck moving with a constant velocity of 15 m/s on a horizontal road. The man
throws a ball in such a way that it returns to his hand after the truck has moved 60 m. (g = 10 m/s 2)
(A) The speed of the ball as seen from the truck is 20 m/s
(B) The direction of initial velocity of ball is upward as seen from the truck
(C) The initial speed of the ball as seen from the ground is 25 m/s
(D) None of these
5. Two boats A and B having same speed relative to river are moving in a river. Boat A moves normal to
the river current as observed by an observer moving with velocity of river current. Boat B moves normal
to the river as observed by the observer on the ground. Choose the incorrect options.
(A) To a ground observer boat B moves faster than A
(B) To a ground observer boat A moves faster than B
(C) To the given moving observer boat B moves faster than A
(D) To the given moving observer boat A moves faster than B
6. An open elevator is ascending with zero acceleration and speed 10 m/s. A ball is thrown vertically up by
a boy (boy is in elevator) when he is at a height 10 m from the ground, the velocity of projection is
30m/s with respect to elevator. Choose correct option(s) assuming height of the boy very small :
(g = 10 m/s2)
(A) Maximum height attained by the ball from ground is 90 m.
(B) Maximum height attained by the ball with respect to lift from the point of projection is 45 m.
(C) Time taken by the ball to meet the elevator again is 6 sec
(D) The speed of the ball when it comes back to the boy is 20 m/s with respect to ground.
Comprehension # 1
The driver of a car travelling at a speed of 20 m/s, wishes to overtake a truck that is moving with a
constant speed of 20 m s–1 in the same lane. The car’s maximum acceleration is 0.5 m s –2. Initially the
vehicles are separated by 40 m, and the car returns back into its lane after it is 40 m ahead of the truck.
The car is 3 m long and the truck 17m long.
1. Find the minimum time required for the car to pass the truck and return back to its lane?
(A) 10 second (B) 20 second, (C) 15 second (D) none of these.
2. What distance does the car travel during this time?
(A) 500 m (B) 600 m (C) 200 m (D) 300 m
3. What is the final speed of the car ?
(A) 40 m/s (B) 20 m/s (C) 45 m/s (D) 30 m/s
Comprehension # 2
Two particles 'A' and 'B' are projected in the vertical plane with same initial speed u 0 from position (0, 0)
and (, – h) towards each other as shown in figure at t = 0.
y
u0
2
‘A’  g=10 m/s
x
(0,0)
u0 h

‘B’
( 1- h)
ADVRL - 28
Relative Motion
4. The path of particle 'A' with respect to particle 'B' will be
(A) parabola (B) straight line parallel to x-axis.
(C) straight line parallel to y-axis (D) none of these.
5. Minimum distance between particle A and B during motion will be :

(A)  (B) h (C) 2
 b2 (D)  + h
6. The time when separation between A and B is minimum is :

x 2h 2
(A) (B) (C) (D)
u0 cos  g 2u0 cos  u0 cos 
Comprehension # 3
Raindrops are falling with a velocity 10 2 m/s making an angle of 45° with the vertical. The drops
appear to be falling vertically to a man running with constant velocity. The velocity of rain drops change
such that the rain drops now appear to be falling vertically with 3 times the velocity it appeared earlier
to the same person running with same velocity.
7. The magnitude of velocity of man with respect to ground is
(A) 10 2 m/s (B) 5 m/s (C) 20 m/s (D) 10 m/s
8. After the velocity of rain drops change, the magnitude of velocity of raindrops with respect to ground is
(A) 20 m/s (B) 25 m/s (C) 10 m/s (D) 15 m/s
9. The angle (in degrees) between the initial and the final velocity vectors of the raindrops with respect to
the ground is
(A) 8 (B) 15 (C) 22.5 (D) 37

1. Airplanes A and B are flying with constant velocity in the same vertical plane at angles 30° and 60° with
respect to the horizontal respectively as shown in figure. The speed of A is 100 3 ms–1. At time t = 0s,
an observer in A finds B at a distance of 500m. This observer sees B moving with a constant velocity
perpendicular to the line of motion of A. If at t = t0, A just escapes being hit by B, t0 in seconds is:
[JEE (Advanced) 2014; P-1, 3/60]
ADVRL - 29
Relative Motion
PART - II : JEE (MAIN) / AIEEE PROBLEMS (PREVIOUS YEARS)

1. Two stones are thrown up simultaneously from the edge of a cliff 240 m high with initial speed of 10 m/s
and 40 m/s respectively. Which of the following graph best represents the time variation of relative
position of the second stone with respect to the first ? (Assume stones do not rebound after hitting the
ground and neglect air resistance, take g = 10 m/s 2) (The figures are schematic and not drawn to
scale.) [JEE (Main) 2015; 4/120, –1]
(1) (2)
(3) (4)

2. Ship A is sailing towards north-east with velocity v  30î  50 ĵ km/hr where î points east and ĵ points
north. Ship B is at a distance of 80 km east and 150 km north of ship A and is sailing towards west at
10 km/hr. A will be at minimum distance from B in. [JEE (Main) 2019; 4/120, –1]
(1) 4.2 hrs. (2) 2.6 hrs. (3) 3.2 hrs. (4) 2.2 hrs.
3. A particle is moving along the x-axis with its coordinate with time t given by x(t) = 10 + 8t – 3t2. Another
particle is moving along the y-axis with its coordinate as a function of time given by y(t) = 5 – 8t3.
At t = 1s, the speed of the second particle as measured in the frame of the first particle is given as v.
Then v (in m/s) is. [JEE (Main) 2020, 08 January; 4/100, –1]
ADVRL - 30
Relative Motion
EXERCISE-1 EXERCISE-2
PART - I PART - I
Section (A) : 1. (C) 2. (D) 3. (A)
A-1. (a) 144 km/h due south 4. (A) 5. (C) 6. (D)
7. (A) 8. (C) 9. (B)
(b) 90 km/h due north
(c) 36 km/h due north 10. (A) 11. (A)
(d) 126 km/h due north
A-2. 50 km/h A-3. 20 sec. PART – II
A-4. 50 m 1. 5 2. 15 3. 15
4. 0 5. 5 6. 15
Section (B) : 7. 5 8. 26 9. 3
B-1. 4 î + 3 ĵ , – 4 î – 3 ĵ , 5 unit, 5 unit. 10. 45 11. 20
 5 
PART - III
B-2. 13 m/s, tan–1   = 22°37 north of east 1. (ABCD) 2. (ACD) 3. (ABC)
 12 
4. (ABC) 5. (ACD) 6. (ABCD)
B-3. (a) 20 m/s or 72 km/h due east
(b) 25 m/s or 90 km/h at 37°N of E
PART - IV
1. (B) 2. (A) 3. (D)
B-4. 30º N of W at 5 3 km/h. 4. (B) 5. (B) 6. (C)
B-5. ˆi  2 ˆj  kˆ , î  east, ĵ  north, 7. (D) 8. (A) 9. (B)
k̂  vertical upward
EXERCISE-3
Section (C) :
PART - I
1 3 1. 5
C-1. 12 km/h, 4km/h C-2. h, km
4 4
C-3. At an angle 30° west of north
PART - II
1. (3) 2. (2) 3. 580
Section (D) :
D-1.  = tan–1 3 D-2. 10 5 m/s
D-3. 2 2 m/s, 45º with vertical and away from the
man.
Section (E) :
E-1. 3m E-2. a/v
PART - II
Section (A) :
A-1. (A) A-2. (C) A-3. (D)
A-4. (D) A-5. (D) A-6. (A)
Section (B) :
B-1. (D) B-2. (D) B-3. (B)
Section (C) :
C-1. (B) C-2. (B) C-3. (B)
C-4. (A)
Section (D) :
D-1. (D) D-2. (A) D-3. (B)
D-4. (A)
Section (E) :
E-1. (B) E-2. (C)
PART - III
1. (A) – q ; (B) – q ; (C) – q ; (D) – q
2. (A) – q ; (B) – r, t ; (C) – p ; (D) – q
ADVRL - 31

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Periodic Table & Periodicity

 Marked Questions may have for Revision Questions.

PART - I : SUBJECTIVE QUESTIONS

C-5. The oxidation state of nitrogen varies from :

Section (D) : Atomic and Ionic radius

Section (F) : Electron gain enthalpy

PART - III : MATCH THE COLUMNS

Section (E) : Ionisation energy

 Marked Questions may have for Revision Questions.

PART - I : ONLY ONE OPTION CORRECT TYPE

PART - II : SINGLE AND DOUBLE VALUE INTEGER TYPE

PART - III : ONE OR MORE THAN ONE OPTIONS CORRECT TYPE

PART - I : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS)

6. The correct order of radii is : [JEE-2000, 1/35]

PART - II : JEE (MAIN) ONLINE PROBLEMS (PREVIOUS YEARS)

2. (A - q,r) ; (B - p,s) ; (C - s) ; (D - q,r)

11. 2 (i, ii) 12. 0 13. 2 14. 1 15. 23

16. 17 17. 5 (except ii, iii)

 Marked questions are recommended for Revision.

PART - I : SUBJECTIVE QUESTIONS

A-2. If A = {x : x2 – 5x + 6 = 0}, B = {2, 4}, C = {4, 5} then find A × (B  C).

Section (B) : Types of Relation

B-3. Let A = {p, q , r}. Which of the following is an equivalence relation on A ?

C-3. Find complete set of solution of following

C-4. Solve the following equations

C-6. Draw the graph of

Section (D) : Definition of function, Domain and Range, Classification of Functions

D-2. Find the domain of each of the following functions :

D-3. Find the domain of definitions of the following functions :

D-4. Find the range of each of the following functions :

Section (E) : Identical functions, Composite functions

E-5. Find fog and gof, if

E-6. If f(x) = n(x2 – x + 2) ; R  R and

Section (F) : Even/Odd Functions & Periodic Functions

F-4. Find the fundamental period of the following functions :

G-1. Let f : D  R, where D is the domain of f. Find the inverse of f, if it exists

Section (H) : Definition, graphs and fundamentals & Inverse Trigonometry

H-5. Solve the following inequalities:

I-1. Evaluate the following inverse trigonometric expressions :

I-2. Find the value of the following inverse trigonometric expressions :

I-3. Find the value of following expressions :

I-4. Solve the inequality tan–1 x > cot–1 x.

Section (J) : Interconversion/Simplification

J-2. Find the value of sin–1 (cos(sin–1x)) + cos–1 (sin (cos–1x))

J-6. Prove each of the following relations :

J-7. Express in terms of

J-9. Solve for x

Section (K) : Addition and Subtraction Rule

K-2. Find the sum of each of the following series :

PART - II : ONLY ONE OPTION CORRECT TYPE

A-4. Let R be relation from a set A to a set B, then

A-6. The relation R defined in A = {1, 2, 3} by a R b if –5  a2 – b2  5. Which of the following is false?

Section (B) : Types of Relation

B-1. The relation R defined in N as aRb b is divisible by a is

B-3. Which one of the following relations on R is equivalence relation-

B-4. Let R1 be a relation defined by R1 = {(a, b)| a  b ; a, b  R} . Then R1 is

B-7. Consider the following :

B-10. Let R = {(x, y) : x, y  A, x + y = 5} where A = {1, 2, 3, 4, 5} then R is

Section (D) : Definition of function, Domain and Range, Classification of Functions

D-2. Range of f(x) = n (3x2 – 4x + 5) is

D-3. Range of f(x) = 4x + 2x + 1 is

D-4. Range of f(x) = log 5

D-6. Let f : R  R be a function defined by f(x) = x3 + x2 + 3x + sin x. Then f is: