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02 - Atomic Structure - (Exercises)
02 - Atomic Structure - (Exercises)
1. A ball of mass 200 g moving with a velocity of 10 m sec −1. If the error in measurement of
velocity is 0.1%, the uncertainty in its position is
(a) 3.3 10−31 m (b) 3.3 10−27 m
(c) 5.3 10−25 m (d) 2.64 10−32 m
3. If the series limit of wavelength of the Lyman series for the hydrogen atoms in 912 Å, then
the series limit of wavelength for the Balmer series of the hydrogen atom is
(a) 912 Å (b) 912 2 Å
(c) 912 4 Å (d) 912/2 Å
4. The shortest for the Lyman series of hydrogen atom is ….. (Given RH = 109678 cm−1)
(a) 911.7 Å (b) 700 Å
(c) 600 Å (d) 811 Å
5. With increasing quantum number, the energy difference between adjacent orbits of hydrogen
atom
(a) increases (b) decreases
(c) remains constant (d) first increases followed by a decrease
(c) (d)
10. In Bohr’s hydrogen atom, the electronic transition emitting light of longest wavelength is
(a) n = 4 to n = 5 (b) n = 4 to n = 3
(c) n = 3 to n = 2 (d) n = 2 to n = 4
11. The frequency of first line of Balmer series in hydrogen atom is o. The frequency of
corresponding line emitted by singly ionised helium atom is
(a) 2o (b) 4o
(c) o/2 (d) o/4
13. The potential energy of the electron in an orbit of hydrogen atom would be
(a) −mv2 (b) −e2/r2
(c) −1/2 mv2 (d) −e2/2r
14. Which of the following radiations has the highest wave number?
(a) X−rays (b) Microwaves
(c) I. R. rays (d) Radiowaves
15. Which of the following particles moving with same velocity would be associated with smallest
de−Broglie wavelength?
(a) Hydrogen molecule (b) Oxygen molecule
(c) Helium molecule (d) Nitrogen molecule
16. If the velocity of an electron in the first Bohr orbit of a hydrogen atom is V, then its velocity
in the third Bohr orbit will be
(a) V/9 (b) V/3
(c) 9 V (d) 3 V
17. What is the wavelength associated with an electron moving with a velocity of 10 6 m/s? (Given
h = 6.63 × 10−34 Js and m = 9.11 × 10−28 g)
(a) 72.8 nm (b) 0.728 nm
(c) 7.28 nm (d) 7.28 × 10–13 m
18. If the ionization potential for hydrogen atom is 13.6 eV then the second ionization potential
for helium atom should be
(a) 13.6 eV (b) 27.2 eV
(c) 54.4 eV (d) none of these
19. The ratio of the radius of Bohr first orbit for the electron orbiting the hydrogen nucleus to that
of the electron orbiting the deuterium nucleus (mass nearly twice that of H nucleus) is
approximately
(a) 1 : 1 (b) 1 : 2
(c) 2 : 1 (d) 1 : 4
20. Velocity of electron in the first orbit of H−atom as compared to that of velocity of
light is nearly
1 1
(a) th (b) th
10 100
1 1
(c) th (d) th
1000 150
21. Assuming the velocity to be same, which sub−atomic particle possesses smallest de Broglie
wavelength
(a) An electron (b) A proton
(c) An −particle (d) All have same wavelength
22. An electron in H−atom in its ground state absorbs 1.50 times as much as energy as the
minimum required for its escape (13.6 eV) from the atom. Thus KE given to emitted electron
is
(a) 13.6 eV (b) 20.4 eV
(c) 34.0 eV (d) 6.8 eV
25. If wavelength of an electron is equal to distance travelled by it in one second, then correct
relation is
h h
(a) = (b) =
p p
h h
(c) = (d) =
m m
EXERCISE – II
IIT-JEE- SINGLE CHOICE CORRECT
1. An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E
respectively. What is the correct order of their de−Broglie wavelengths?
(a) e > p ~
− (b) p ~
− > e
(c) e > p > (d) < e > p
2. Which of the following electronic transitions requires that the greatest quantity of energy be
absorbed by a hydrogen atom?
(a) n = 1 to n = 2 (b) n = 2 to n = 4
(c) n = 3 to n = 6 (d) n = to n = 1
5. When the frequency of light incident on a metallic plate is doubled above threshold
frequency, the KE of the emitted photoelectrons will be
(a) doubled
(b) halved
(c) increased but will be more than double of the previous KE
(d) unchanged
6. The radius of H−atom in ground state is 0.53 Å. Radius of the first orbit of Li2+ in Å is
(a) 0.106 (b) 0.3
(c) 0.17 (d) 0.53
7. The amount of energy required to remove an electron from a Li 2+ ion in its ground state is
how many times the amount of energy required to remove the electron from a hydrogen atom
in its ground state
(a) 9 (b) 2
(c) 3 (d) 5
8. In an atom, two electrons move around the nucleus in circular orbits of radii R and 4R. The
ratio of the time taken by them to complete one revolution is
(a) 1 : 4 (b) 4 : 1
(c) 1 : 8 (d) 8 : 7
9. A 3p−orbital has
(a) two angular nodes
(b) two radial nodes
(c) one radial and one angular node
(d) one radial and two angular nodes
10. Which of the following statement is not correct?
(a) The shape of an atomic orbital depends on the azimuthal quantum number.
(b) The orientation of an atomic orbital depends on the magnetic quantum number.
(c) The energy of an electron in an atomic orbital of multielectron atom depends on principal
quantum number.
(d) The number of degenerate atomic orbitals of one type depends on the value of azimuthal
quantum number.
12. The first emission line of Balmer series in H spectrum has the wave number equal to
9 RH 7 RH
(a) (b)
400 144
3 RH 5 RH
(c) (d)
4 36
13. The potential energy of the electron present in the ground state of Li2+ ion is represented by
3e 2 3e
(a) + (b) −
4 0 r 4 0 r
3e 2 3e 2
(c) − (d) −
4 0 r 2 4 0 r
14. If n and l are the principal and Azimuthal quantum numbers respectively, then the expression
for calculating the maximum number of electrons in any orbit is
l =n l =n −1
(a) 2(2l + 1) (b) 2(2l + 1)
l =1 l =1
l =n +1 l =n −1
(c) 2(2l + 1) (d) 2(2l + 1)
l =0 l =0
15. If 0 is the threshold wavelength of a metal and is the wavelength of the incident radiation,
the maximum velocity of the ejected electrons from the metal would be
1/ 2 1/ 2
2hc 0 − 2hc − 0
(a) (b)
m 0 m 0
1/ 2 1/ 2
hc 2h
(c) 2 ( 0 − ) (d) ( − 0 )
m m
16. If kinetic energy of a proton is increased to nine times, the wavelength of the de−Broglie
wave associated with it would become
(a) 3 times (b) 9 times
1 1
(c) times (d) times
3 9
17. If r1 is the radius of the first orbit of hydrogen atom, then the radii of second, third and fourth
orbits in terms of r1 are
(a) r12 , r13 , r14 (b) 8r1, 27r1, 64r1
(c) 4r1, 9r1, 16r1 (d) 2r1, 6r1, 8r1
18. The difference in angular momentum associated with the electron in two successive orbits
of hydrogen atom is
(a) h/ (b) h/2
(c) h/2 (d) (n −1) h/2
19. Difference between nth and (n + 1)th Bohr’s radius of ‘H’ atom is equal to it’s (n−1)th Bohr’s
radius. The value of n is
(a) 1 (b) 2
(c) 3 (d) 4
20. Total number of transitions of an electron from nth shell to 2 nd shell will be
(n − 1) (n − 2) n(n − 1)
(a) (b)
2 2
n(n + 1) n
(c) (d)
2 2
1. The radius of the following orbits are double as that of the first Bohr’s orbit of
hydrogen atom.
(a) He+ (n = 2) (b) Be+3 (n = 2)
(c) O+7 (n = 4) (d) C+5 (n = 3)
6. Which of the following statements are not correct about atomic orbital?
(a) Size of the atomic orbital depends on the azimuthal quantum number.
(b) Shape of the atomic orbital depends on both principal and azimuthal quantum number.
(c) Orientation of an atomic orbital depends on the spin quantum number.
(d) Rotation of an electron in an atomic orbital depends on Heisenberg uncertainty principal.
7. Which of the following sets of quantum numbers are correct for a 3d electron?
1 1
(a) 3, 2, 1, – (b) 3, –2, –1, +
2 2
1 1
(c) 3, 2, –2, + (d) 3, 2, 0, –
2 2
8. Which of the following statements do not form a part of Bohr’s model of hydrogen atom?
(a) Splitting of spectral lines takes place in electric and magnetic field.
(b) Energy of the electron in the orbit is not quantized.
(c) Angular momentum of the electron in the orbit is quantized.
(d) The radius and velocity of the electron in the orbit can be determined simultaneously.
9. The wavelength of the spectral line for an electronic transition depends on
(a) the nuclear charge of the ion containing only one electron.
(b) velocity of electron in an atom undergoing transition.
(c) difference in the energy levels involved in the transition.
(d) circumference of the orbits in which transition taking place.
10. Choose the correct statements from among the following
(a) The total number of spherical nodes in an orbital are n – l – 1.
(b) The total number of angular nodes in an orbital are l.
(c) The number of maxima in the plot between 2 vs r for an orbital is (n – l).
(d) A node is a point in space where the wave function has zero amplitude.
EXERCISE – V
MATCH THE FOLLOWING
1.
Column I
Column II
(For mono electronic species)
I. Radius of nth orbit (A) inversely proportional to Z
II. Energy of electron in nth orbit (B) inversely proportional to n2
III. Velocity of electron in nth orbit (C) inversely proportional to n
IV. Angular momentum of electron (D) proportional to n
(E) proportional to n2
REASONING TYPE
2. Statement-1: If an electron is located within the range of 0.1 Å then the uncertainly in velocity
is approximately 6 × 106 m/sec.
Statement-2: Trajectory of above can be defined.
(a) (A) (b) (B) (c) (C) (d) (D)
3. Statement-1: Hydrogen has only one electron in its orbit but produces several spectral lines.
Statement-2: There are many excited energy levels available.
(a) (A) (b) (B) (c) (C) (d) (D)
1. In a single isolated atom an electron makes transition from 5th excited state to 2nd state then
maximum number of different types of photons observed is
(a) 3 (b) 4
(c) 6 (d) 15
2. The difference in the wavelength of the 2nd line of Lyman series and last line of bracket series
in a hydrogen sample is
119 1271
(a) (b)
8R 8R
219
(c) (d) None of these
8R
3. The wave number of electromagnetic radiation emitted during the transition of electron in
between two levels of Li2+ ion whose principal quantum numbers sum is 4 and difference is
2 is
(a) 3.5 RH (b) 4 RH
8
(c) 8 RH (d) RH
9
EXERCISE – IV
SUBJECTIVE PROBLEMS
2. Consider the hydrogen atom to be a proton embedded in a cavity of radius a0 (Bohr radius)
whose charge is neutralized by the addition of an electron to the cavity in vacuum infinitely
slowly. Estimate the average total energy of an electron in its ground state in a hydrogen
atom as the work done in the above neutralization process. Also, if the magnitude of average
KE is half the magnitude of average potential energy, find the average potential energy.
3. When a certain metal was irradiated with light of frequency 3.2 × 10 16 Hz, the photoelectrons
emitted has twice the kinetic energy as did photoelectrons emitted when the same metal was
irradiated with light of frequency 2.0 × 1016 Hz. Calculate 0 for the metal.
4. Calculate the energy required to excite 1.23 litre of hydrogen gas at 1 atm and 300 K
to the first excited state of atomic hydrogen. The energy for the dissociation of H–H bond is
436 kJ mol–1. Also calculate the minimum frequency of photon to break this bond.
5. A certain dye absorbs light of = 4530 Å and then fluorescence light of wavelength
5080 Å. Assuming that under given conditions 47% of the absorbed energy is re–emitted out
as fluorescence, calculate the ratio of quanta emitted out to the number of quanta absorbed.
7. Wavelength of high energy transition of H atom is 91.2 nm. Calculate the corresponding
wavelength of He+ ion.
8. Find out the number of waves made by a Bohr electron in one complete revolution in its
3rd orbit.
9. The photo electric emission requires a threshold frequency 0. For a certain metal
1 = 2200 Å and 2 = 1900 Å produce electrons with a maximum kinetic energy
KE1 and KE2, if KE2 = 2KE1. Calculate 0.
ANSWERS
EXERCISE – I
11. (b) 12. (d) 13. (a) 14. (a) 15. (b)
16. (b) 17. (b) 18. (c) 19. (a) 20. (d)
21. (c) 22. (d) 23. (a) 24. (c) 25. (d)
EXERCISE – II
IIT-JEE-SINGLE CHOICE CORRECT
11. (b) 12. (d) 13. (d) 14. (d) 15. (a)
16. (c) 17. (c) 18. (b) 19. (d) 20. (a)
REASONING TYPE
EXERCISE – IV
SUBJECTIVE PROBLEMS
1. 2a0.
1 Ze 2
2. –
40 a 0
5. 0.527
7. 22.8 nm
8. 3
h
10. (a) 2.19 × 108 cm/sec (b) 3.32 Å (c) 2 =
2