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FIITJEE – CM Monthly Test - 1

PHYSICS, CHEMISTRY & MATHEMATICS


Pattern - 1 QP Code: PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 183


BATCHES – 2224 (CLASS – XI)

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. All the section can be filled in PART-A of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For Only One Part.


(i) Part-A (01-07) – Contains seven (07) multiple choice questions which have One or More correct answer.
For each question in the group Q. 01 – 07 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect option is
darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: 1 In all other cases.

(ii) Part-A (08-14) – Contains seven (07) multiple choice questions which have ONLY ONE CORRECT answer.
Each question carries +3 marks for correct answer and -1 mark for wrong answer.

(iii) Part-A (15-18) - This section contains Two paragraphs. Based on each paragraph, there are Two multiple choice
questions. Each question has only one correct answer and carries +3 marks for the correct answer and -1
mark for wrong answer.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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CM-2224-CL-XI-TEST-I-PCM - P2

SECTION – I (PHYSICS)
PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.

1. Two cars C1 & C2 are moving in parallel lanes in the same direction at speed 90 kmph & 108 kmph
respectively. (See figure). As the traffic signal turns red, both applies brake (assume constant
retardation) simultaneously. If they both stop together at the dead line:

108 kmph
Dead line
C2
50 m

90 kmph C1

(A) distance of dead line from C2 is 300 m


(B) distance of dead line from C1 is 250 m
(C) time taken by the cars to ends up after the signal turn red is 15 sec
(D) time taken by the cars to ends up after the signal turn red is 20 sec

2. A man is standing on a horizontal road and observes that rain is falling at angle 45o with the vertical.
The man starts running on the road with constant acceleration 0.5 m/s2. After a certain time from the
start of the motion, it appears to him that rain is still falling at angle 45o with the vertical, with speed
2 2 m/s. Motion of the man is in the same vertical plane in which the rain is falling. Then which of the
following statement(s) are true.
(A) It is not possible
(B) Speed of the rain relative to the ground is 2 m/s.
(C) Speed of the man when he finds rain to be falling at angle 45o with the vertical, is 4 m/s.
(D) The man has travelled a distance 16m on the road by the time he again finds rain to be falling at
angle 45o.

3. Two particles A and B at (0, -a) and (0, 0). At a certain instant ‘B’ starts moving with constant velocity
u ˆi . At the same instant A starts moving with same speed such that its velocity is always directed
towards B.
(A) Distance between them at the instant when velocity of A is at an angle of 60o with x-axis is 2a/3.
(B) The separation between them after very long time is a/3
(C) Distance between them at the instant when velocity of A is at an angle of 60o with x-axis is a/2.
(D) The separation between them after very long time is a/2.

4. A projectile is fired upward with velocity V0 at an angle  and strikes a point (x, y) on the roof (AB) of
the building (as shown) then
y

h V0 P (x, y)

 
x
B

(A) The projectile hits the roof in minimum time if    
2

(B) The projectile hits the roof in minimum time    
4

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CM-2224-CL-XI-TEST-I-PCM - P3

V0  V02  2ghcos2 
(C) The minimum time taken by the projectile to hit the roof is tmin 
gcos 
(D) The projectile never reaches the roof for V0  2gh cos 

5. A dog is running with a constant speed v is chasing a cat that is running with a constant velocity u.
during the chase, the dog always heads towards the cat. At an instant direction of motion of the dog
makes angle  with that of the cat and the distance between them is r.
uv sin 
(A) The magnitude of acceleration of dog at this instant is .
r
uv sin 
(B) Radius of curvature of path followed by dog at this instant is .
r
uv cos 
(C) The magnitude of acceleration of dog at this instant is .
r
ur
(D) Radius of curvature of path followed by dog at this instant .
v cos 

6. Two cars A and B race each other down a straight road. The position of each car as a function of time
is shown. Which of the following statements are true?

Position B

t1 t2 time
(A) At time t2 both cars have travelled the same distance
(B) At time t1 both cars have the same speed.
(C) Both cars have the same speed at some time t  t1
(D) Both cars have the same acceleration at some time t1  t  t 2
        
7. If P  Q  R, Q  R  P and R  P  Q, then
  
(A) P,Q and R are coplanar
 
(B) angle between P and Q may be less than 90o
  
 
(C) P  Q  R cannot be equal to zero
  
(D) P, Q and R are mutually perpendicular

PART – A
(Single Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

8. A particle is moving along the locus: y  k x  k  0  with a constant speed ‘v’. At t  0, it is at the
origin and about to enter the first quadrant of x-y axes. At some later time t  0, v x  v y . At this

moment, a y  a x  

(A) v 2 / k 2 (B) zero


2 2
(C)  v / k (D) none
   
9. Figure shows two vectors a (in y-z plane) and b (in x-y plane) such that a  b  5 units. What is
 
the angle between a and b.

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CM-2224-CL-XI-TEST-I-PCM - P4


a
37o
o y
 37
b

x
1 12 16
(A)   cos (B)   cos 1
25 25
9
(C)   cos 1 (D)   90
25

10. A particle is projected with speed 30 m/s at angle 22.5o with horizontal from ground as shown. AB and
CD are parallel to y-axis and B is highest point of trajectory of particle. CD/AB is
y
C

30 m/s
o B
22.5
0 D
(A) 3 (B) 3/2
(C) 2 (D) 4

11. Two cars A and B moving on two straight tracks inclined at an angle 60o heading towards the crossing
initially their positions are as shown in the figure. Both cars have same speed. Minimum separation
between them during their motion will be:

40 km O
o
AV 60
30 km
V
B
(A) 10 km (B) 5 3 km
20
(C) 5 km (D) km
3

12. Three particles A, B and C situated at vertices of an equilateral triangle, all moving with same
constant speed such that A always move towards B, B always towards C and C always towards A.
Initial separation between each of the particle is a. O is the centroid of the triangle. Distance covered
by particle A when it completes one revolution around O is
C

A B
a

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CM-2224-CL-XI-TEST-I-PCM - P5


(A) 2a 1  e 2 3  (B)
2a
3 
1  e 2 3 

(C) a 1  e2 3
 (D)
2a
3 
1  e 3 
13. The maximum angle to the horizontal at which a stone can be thrown so that it always moves away
from the thrower will be:
 2 2 2 
(A) sin1  (B) sin1 
 3   3 
   
 1   2
(C) sin1  (D) sin1 
 3
  3 
 
  
14. In the diagram below, the vectors u and v are at right angles to each other. The length of v is d. The

horizontal and vertical components of u are a and b respectively.

v


u
d
b

a

Find the vertical component of v in terms of a, b and d.
db ab
(A) (B)
a b
2 2
a  b2
2

da
(C) (D) None of these
a  b2
2

PART – A
(Paragraph Type)
This part contains 2 paragraphs. Based on each paragraph, there are 2 multiple choice questions. Each
question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

A particle is thrown in horizontal direction with speed u from a point P, the top of a tower shown in
figure at vertical height h above the inclined plane of inclination .

15. Find the speed with which the particle is thrown so that it strikes the plane normally.
 2gh   gh 
(A)  (B) 
2  2 
 2  cot    1  cot  
 2gh 
(C)   (D) None of these
 2  tan2  

16. Find the distance from the foot of the tower where the particle will strike.

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CM-2224-CL-XI-TEST-I-PCM - P6

   
h 2h
(A)   (B)  

 
sin  1  cot 2   


 
sin  2  cot 2   

 
h
(C)   (D) None of these

 2
 sin  1  tan   


Paragraph for Questions 17 & 18

Projectile motion is a combination of two 1-dimensional motions: one in horizontal and other in vertical
direction. Motion in 2D means in a plane. Necessary condition for 2D motion is that the velocity vector
is coplanar to the acceleration vector. In case of projectile motion, the angle between velocity and
acceleration will be 0    180. During the projectile motion, the horizontal component of velocity
remains unchanged, but the vertical component of velocity is time dependent.

17. A particle is projected from the origin in x-y plane. Acceleration of the particle in negative y-direction is
. If equation of path of the particle is y  ax  bx 2 , then initial velocity of the particle is

(A)

(B)

 1  a2 
2b 2b
 b
(C) (D)
2
a a2

18. An object is projected from origin in x-y plane in which velocity changes according to the relation

v  aiˆ  bxj.
ˆ Path of particle is
(A) hyperbola (B) circular
(C) elliptical (D) parabolic

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CM-2224-CL-XI-TEST-I-PCM - P7

SECTION – II (CHEMISTRY)
PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.

1. Select the correct statement(s):


(A) The oxidation number of Fe in Fe  CO 5 is zero
(B) The difference in the oxidation state of the two types of oxygen atom in H2SO5 is one
(C) Quantum number l determines the number of angular nodes in an atomic orbital
(D) In case of dxy orbital, probability of finding the electron is maximum along x and y axis.

2. Select the incorrect statement(s).


(A) The maximum number of electrons in phosphorous atom for which n  l  m  3, is 5
(B) Magnetic moment of Xn   Z  26  is 24 B.M, where n = 3.
5
(C) Molar mass of electron is 5.48  10 g / mole
(D) e/m of electron is 1.76  108 coulomb/g

3. An aqueous solution of ammonia has molarity equal to 2.5 M. If density of the solution is 1.5425
gm/mL, then identify the options in which correct concentration terms are mentioned.
5 42.5
(A) Molality = m (B) % w/w 
3 15425
42.5 3
(C) % w/v  (D) Mole fraction of NH3 =
100 103

4. Pick the correct statements from below options.


o
(A) The molecular diameter of He (b = 24 mL mol-1) is approximately 2.7 A
(B) v rms of SO2 at STP is equal to v rms of O3 at STP
8PC VC
(C) R 
3TC
(D) The number of spectral lines of Paschen series seen in (hydrogen like atom) when electron
jumps from 6th excited state to ground state is 3

5. Which of the following will have same kinetic energy per mole as CO2 (at same temperature and
pressure)?
(A) N2O (B) O3
(C) NO2 (D) Ne

6. 0.056 g of a gas occupies 45.4 mL at STP. The gas could be: (R = 0.083 L atm/K –1 mol–1)
(A) Carbon Monoxide (B) Dinitrogen
(C) Nitrogen dioxide (D) Ethyne

7. Select the incorrect statement(s):


(A) At critical temperature all real gases behave like an ideal gas.
(B) The rms velocity of ideal gas molecule will be tripled if pressure is made nine times by decreasing
the volume of container
(C) Van der Waal’s constant a is a measure of attractive force
(D) a is expressed in atm L2 mol–1

PART – A
(Single Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

8. The figure shows a sample of hydrogen atoms having electron revolving in higher orbit n.

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CM-2224-CL-XI-TEST-I-PCM - P8

If this e  makes transition from this orbit ‘n’ to ground state. Numbers of Balmer line emitted are
(A) 1 (B) 2
(C) 4 (D) 6

9. 1.12 g of lime stone was treated with oxalic acid to give CaC2O4. The precipitate decolorized 45 mL of
0.2 N KMnO4 in acid medium. Calculate percentage of CaO in lime stone?
(A) 4.5 (B) 45
(C) 22.5 (D) 18

10. A 100 cm3 solution of H2O2 liberates 0.508 g of iodine form an acidified KI solution. If the strength of
H2O2 solution in terms of volume strength at STP, can be represented by 224  10  x . Find x. (Take
volume occupied by one mole of gas at STP equal to 22.4 litre)
(A) 1 (B) 2
(C) 3 (D) 4

11. A certain solution consists of Na2 CO3 and NaHCO3 , 60 mL of this required 12 mL of 0.05 M H2SO4
using phenolphthalein as indicator. Calculate the amount of Na2 CO3 (in gram) per litre in mixture.
(A) 4.24 gram (B) 2.12 gram
(C) 6.36 gram (D) Insufficient data

12. The orbital angular momentum of an electron in 2s-orbital is


h
(A) (B) zero
4
h h
(C) (D)
2 2

13. Find the number of electrons in Pd, having n  l  0 and m  1 .


(A) 0 (B) 1
(C) 2 (D) 3

14. An evacuated glass vessel weighs 50 g, when empty, 167.0 g when filled with a liquid of density 1.17
g/mL and 50.32 g when filled with and ideal gas at 1 bar pressure at 300 K. Determine the molecular
weight of the gas. (R = 0.083 bar Litre mol-1 K-1)
(A) 123.12 (B) 79.68
(C) 78.18 (D) 81.18

PART – A
(Paragraph Type)
This part contains 2 paragraphs. Based on each paragraph, there are 2 multiple choice questions. Each
question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

A solution of 0.4 g of a compound containing Cu2+, and C2O 24 ions on titration with 0.04 M KMnO4 in
presence of H2SO4 consumes 22.6 mL oxidant. The resulting solution is neutralized by Na2CO3,
acidified with dilute CH3COOH and titrated with excess of KI. The liberated I2 required 11.3 mL of 0.1
M Na2S2O3 for complete reduction.

15. Find millmoles of C2O 24 initially present in solution?


(A) 1.13 (B) 2.26
(C) 5.65 (D) None of these

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CM-2224-CL-XI-TEST-I-PCM - P9

16. If millimoles of C2O 24 and Cu2+ initially present in solution is x and y, respectively. Then, find
5x  10y
.
2
(A) 5.65 (B) 11.30
(C) 6.78 (D) None of these

Paragraph for Questions 17 & 18

In three dimension, wave function may be expressed in polar co-ordinates  r, ,   .


 r, ,   Rr   A  , 
The R(r) is determined by ‘n’ and ‘l’. The A  ,   is determined by ‘l’ and ‘m’.
1
17. Angular part (A) of orbital of Hydrogen atom wave equation = . Hence, atomic orbital is
 4 
y2

(A) 'p y ' orbital (B) 'pz ' orbital


(C) s orbital (D) dz2 orbital

18. The radial node for 2s orbital, in hydrogen atom, occur at a distance x from nucleus. What is x  2a0 ?
1/2 3/ 2
 1  1  Z 2Zr
  2   e
 /2
(a0 = First Bohr’s radius,  2S     , where   )
 4  a
2 2 0  na 0

(A) 2a0 (B) 0


(C) 1.5 a0 (D) None of these

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CM-2224-CL-XI-TEST-I-PCM - P10

SECTION – III (MATHEMATICS)


PART – A
(Multi Correct Answer Type)
This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE THAN ONE is/are correct.


1. If A  B  and cos A  cosB  1 , then which of the following is/are true?
3
1 2
(A) cos  A  B   (B) cos A  cosB 
3 3
1 1
(C) cos  A  B    (D) cos A  cosB 
3 2 3

 
2. If  a  b  sin        a  b  sin      and a tan  b tan  c , then
2 2
(A) b tan   a tan  (B) a tan   b tan 
2bc 2ac
(C) sin   (D) sin  
a2  b2  c 2 a2  b2  c 2

3. Consider x  2eln3  x  2eln3  12 , then identify which of the following statement(s) is(are) correct?
(A) The number of integral solutions of the equation is 7
(B) The number of integral solutions of the equation is 13
(C) The sum of all the integral solutions of the equation is 0
(D) The sum of all the integral solutions of the equation is 28

4. Let L be the number of digits in 3 40 before decimal and M be the number of zeroes in 3 40 after
decimal before a significant digit, then
(A) L  M  39 (B) L  M  2
(C) L  M  1 (D) L  M  38
(Use: log10 3  0.4771 )

5. If L  cos2 84o  cos 2 36o  cos36 o cos84 o


M  cot 73o cot 47o cot13o
N  4 sin156o sin84o sin36o ,
then which of the following option is(are) correct?
(A) L  1 (B) M  tan 2

(C) N  sin (D) LMN  0
4

6. In which of the following, m  n  m, n  R  ?


(A) m   log2 5  and n  log2 20
2
(B) m  log10 2 and n  log2 3 10
 1  1
(C) m  log10 5.log10 20 and n  1 (D) m  log 1   and n  log 1  
2 
3 3 
2

 
7.  
If sin x  20o  2 sin x cos 40 o , where x   0,  , then which of the following hold(s) good?
 2
1
(A) cos 2x  (B) cosec 4x  2
2
x
(C) sec  6  2
2
x
(D) tan  2  3
2
 
PART – A
(Single Correct Answer Type)

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CM-2224-CL-XI-TEST-I-PCM - P11

This part contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

x 2  5x  4
8. The set of values of x satisfying  1 is
x2  4
 8 8 
(A) 0,  (B)  ,  
 5  5 
(C)  ,  2 (D) R

1 1
9. The solution set of inequality  is
2  1 1  2 x 1
x

  4 
(A) 1,   (B)  0, log2   
  3 
  4 
(C)  1,   (D)  0, log2     1,  
  3 

  cot 2 A.cos2 A 
10. For 0  A  , the value of log100   is equal to
 cot A  cos A 
2 2
2
(A) 0 (B) 1
(C) 2 (D) 3

11. The value of log27  sin4   4cos2   cos4   4 sin2  equals


1 2
(A) (B)
3 3
1 4
(C) (D)
9 3

12. The number of integral solution in set of x   10, 10  which satisfy the inequality:
x
log 1  x  x  3   log2 , is
2 x  2x  2x  3
3 2

(A) 9 (B) 11
(C) 13 (D) 15

3 sin2 9o  4 sin4 9o
13. The exact value of is
2 sin2 18o  cos18o  1
(A) 4 (B) 2
1
(C) 1 (D)
2

14. If x  1  x  2  x  4   , where x,   R , has four distinct solutions, then  equals


5
(A) 3 (B)
2
(C) 2 (D) 1

PART – A
(Paragraph Type)
This part contains 2 paragraphs. Based on each paragraph, there are 2 multiple choice questions. Each
question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Questions 15 & 16

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CM-2224-CL-XI-TEST-I-PCM - P12

1
      cos57    cos 63  . cos 57 
m 1 m 1
Let Pn  x   sinn x  cosn x n  N and Q  m   cos 63o
m m
o o o
m  N .
n
Also, given log10 2  0.3010, log10 3  0.4771 .

15. The value of log1.3  Q  2   is equal to


(A) 0 (B) 2
(C) 1 (D) –1


16. The value of 12  P4  x   P6  x   at x  equals
10
(A) 1 (B) 3
1
(C) 6 (D)
12

Paragraph for Questions 17 & 18


Consider the polynomial P  x   x  cos 36o  x  cos 84  x  cos156  .
o o

17. The coefficient of x 2 is


(A) 0 (B) 1
1 5 1
(C)  (D)
2 2

18. The coefficient x is


3 3
(A) (B) 
2 2
3
(C)  (D) Zero
4

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CM-2224-CL-XI-TEST-I-PCM - P13

BATCHES: 2224 (CLASS – XI)


TEST – I (PCM)
PAPER CODE: XXXX.X DATE: DD.MM.YYYY

ANSWER KEYS

SECTION – I (PHYSICS) SECTION – II (CHEMISTRY) SECTION– III (MATHS)


PART - A PART - A PART - A
1. ABD 1. ABC 1. BC
2. CD 2. BC 2. ABC
3. AD 3. AD 3. BC
4. ACD 4. ABC 4. AC
5. AC 5. ABCD 5. ABCD
6. CD 6. AB 6. AD
7. CD 7. ABD 7. ACD
8. C 8. B 8. A
9. B 9. C 9. D
10. D 10. C 10. A
11. B 11. B 11. A
12. B 12. B 12. A
13. B 13. A 13. D
14. C 14. B 14. B
15. A 15. B 15. D
16. B 16. B 16. A
17. B 17. C 17. A
18. D 18. B 18. C

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CM-2224-CL-XI-TEST-I-PCM - P14

HINTS & SOLUTIONS

PHYSICS
PART – A

1. ABD
Sol. (i) Relative initial velocity = 5 m/s, relative final velocity = 0
Relative displacement = 50 m
Relative acceleration = constant
50
 50   t  t  20 sec.
 2 
 25  0 
(ii) Distance of dead line from car C1     20  250m.
 2 

2. CD
Sol.

Vrg Vrm


45
o
45o  V mg

45o 45o 
V Vrm V rg
Vmg

Initial Final
  
Vrg  Vrm  Vmg
  
Vrm  Vrg  Vmg
Vrm cos 45  Vrg cos 45
Vrm  2 2m / s  Vrg
Vrm cos 45  Vmg  Vrg cos 45
1 1
Vmg  2 2 2 2  4m/s
2 2
Using v 2  u2  2as for the motion of man,
v 2  u2  2as
s  16m.

3. AD
Sol.

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CM-2224-CL-XI-TEST-I-PCM - P15

B M 60o
u
u

a L
A

A
ds
 u  ucos  
dt
L t
 ds    ucos   u  dt ...(i)
a 0
Now MB'  L cos 60  L / 2
t
So  u  ucos  dt  L / 2 ...(ii)
0
From (i) and (ii)
L  a  L / 2 L  2a / 3
a  3L / 2
For separation at t  
L f  a  L f
Lf  a / 2

4. ACD
Sol. Wherever it strike the roof tmin when it thrown  to the roof

 
2
y '  hcos 
1
hcos   V0 t  cos t 2
2
V  V02  2gh cos 
t 0
gcos 
y

y'

V0

h  
x
gcos   g sin 
gcos  x'
 g
gsin 

Also for projectile not to reaches the roof


V02
hcos  
2gcos 

5. AC

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CM-2224-CL-XI-TEST-I-PCM - P16

Sol. Acceleration of dog = Normal acceleration.


C

an

D
dv vd vu sin 
a   v 
dt dt r
v2 vr
R  .
an u sin 
u cos

u sin
r
v

u sin 

r

6. CD
Sol. The speed is the slope of the curve, so answer C is true
The acceleration is the second derivation of the position. Since A’s position increases linearly the
second derivative will always be zero. The second derivative of curve B is zero at the point of
inflection which occurs between t1 and t2.

7. CD
  
Sol. P, Q and R are mutually perpendicular vectors.
   
Hence P  B  R  0

8. C
Sol. v 2x  v 2y  v 2 .....(i)
Differentiating with time
dy 1 vy
K 
dx 2 x vx
2v x a x  2v y ay  0 .....(ii)
2
x K At the given moment v x  v y
4
From (i) & (ii)
 K2 
v 2x  1  V
 4x 

 K2    K 2  K 2 v 2x v2
2v x a x  1    v 2x    2   v x  0  ax  



4x    4x   
2x K  4x 2
 2K 2
a y  a x

v2
ay  ax  
K2

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CM-2224-CL-XI-TEST-I-PCM - P17

9. B

Sol. a  a cos370 ˆj  a sin370 kˆ

b  cos370 ˆj  b sin370 cˆ

a.b 16
cos   
ab 25

10. D
Sol.
y

A
1/2 gt2
ut


0 r
2
AB  1/ 2g  T / 2   1/ 8gT 2
CD  1/ 2gT 2
CD / AB  4

11. B
Sol.
40 km
A V
o o
60 60
V 10 sin 60
o
B
40 km 60
10 km

Let consider B as observer


dmin  10 sin 60 km
 5 3 km

12. B
Sol.
C

O
rd0 u
r O
o
30
o 30
A A u B
V a
dr 3
 v cos30   V
dt 2
d
r  v sin 30  v / 2
dt
1 dr
 3
r d
r 
dr
   3  d  r  r0 e  3
r
r0 0
When A completes one revolution   2

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CM-2224-CL-XI-TEST-I-PCM - P18

Time taken t 

r0 1  e 2 3 
3v / 2

Distance travelled D  vt 
2r0
3
1 e 2 3

D
2a
3 
1  e 2 3

13. B
Sol. If stone always moves away from thrower then

dr
 0
dt
  1 
 r  ucos  t ˆi   u  sin   t  gt 2  ˆj
 2 

v  ucos  i   u sin   gt  j
ˆ ˆ

 3 g2 3
r.v  u2 t  ug  sin   t 2  t 0
2 2
g2 2 3
 t  ug  sin   t  u2  0
2 2
8 2 3
sin2      sin1  
9  3 

14. C
Sol.

v

u

b
d sin (90 - )
b
90 –  
a

Vertical compound of v
 dsin  90   
da
 dcos  
a2  b 2

15. A
Sol.
x' - axis

u cos
g sin g cos

u


u sin 
h

+y' - axis

When it strikes the plane it has only velocity along Y’ axis


Hence

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CM-2224-CL-XI-TEST-I-PCM - P19

v x '  0  ucos   gsin t


u cos  u
t  cot 
g sin  g
Displacement along y '  hcos 
1
 hcos   u sin   t  gcos   t 2
2
u cos  1 u2
 hcos   u sin    gcot   2 cot 2 
g sin  2 g
2gh
u 
2  cot 2 

16. B
Sol. Displacement along x’ axis
 v 2x '  u2x '  2a x ' x
u2 cos2  2gh cos2 
x  
2gsin  2gsin  2  cos 2   
Hence total distance  h sin   x
hcot .cos 
  h sin 
2  cot 2 
Simplify to get answer.

17. B
dy dx dx
Sol. y  ax  bx 2 or a  2bx
dt dt dt
dx
  a  2bx 
dt
Initially x  0, v y  av x

d2 y d2 x dx  dx 
  a  2bx    2b 
2 2 dt  dt 
dt dt
2 2
d x  dx 
  a  2bx   2b  
2  dt 
dt
d2 y d2 x
At t  0,  , x  0, 0
dt 2 dt 2
2
 dx  2 
   2b    2b  v x  or v x  v x 
 dt  2b

 v v 2x  v 2y  vx 1 a  2 
 1  a2 
2b

18. D

Sol. v  aiˆ  bxj,
ˆ v  a or dx  adt  x  at
x
bat 2
v y  bx  bat or y 
2
2
ba  x 
 y  y  x 2  parabolic.
2  a 

CHEMISTRY
PART – A

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CM-2224-CL-XI-TEST-I-PCM - P20

1. ABC
Sol. (A) 1 x  5  0  0
x=0
(B)
O
-1 -2
H O S O O H
O

2. BC
Sol. (A) 1s2 2s2 2p6 3s2 3p3
nlm  3
two 2p electrons,
two 3s electrons
one 3p electron.
(B) 24  x  x  2 
x=4
X  Xn 
n = 2 or 4
(C)  9.1 10 28  6.02  10 23
 54.8  10 5 g / mole
e 1.6  10 19
(D)   0.176  109 c / g
m 9.1 10 28

3. AD
Sol. Let 1 L solution, then
WSolvent  1.5425  1000  2.5  17
= 1500 g
2.5 5
m 
1.5 3
42.5
% w/w   100
1542.5
42.5
% w/v   100  4.25
1000
2.5 3
Mole fraction NH3 = =
1500 103
 2.5
18

4. ABC
4 3
Sol. (A) b  4  NA  r
3
4 22 3
24  4  6.022  10 23   r
3 7
r 3  2.378  10 24 cm3
 1.335  10 8 cm
o
r  1.335 A
o
d  2r  2  1.335  2.670 A
o
 2.7 A
(D) 6th excited state, n = 7
Paschen line: 7  3, 6  3, 5  3, 4  3
4 lines

5. ABCD
Sol. KE  T

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CM-2224-CL-XI-TEST-I-PCM - P21

6. AB
45.4 0.056
Sol. 1   0.083  273
1000 Mw
Mw  28
N2 and CO

7. ABD
Sol. (B) rms velocity depends upon KE
(D) a is expressed in atm L2 mol–2

8. B
Sol. n = no. of wave made by e  wave = 4
Balmer lines: 4  2 ; 3  2

9. C
Sol. meqCaO  meqKMnO4
2  millimoles  0.2  45
millimoles = 4.5
4.5  10 3  56
% of CaO   100
1.12
 22.5%

10. C
Sol. meqH2O2  meqI2
W 0.508
2  2
34 254
W = 0.068 g
 g  17  V.S. 1
S   
L  5.6 0.1
0.068 5.6
V.S = 
0.1 17
= 0.224
 224  10 3
x=3

11. B
Sol. meqNa2CO3  meqH2 SO4
= 2  0.05  12
1 millimolesNa2CO3  1.2
1.2  10 3
S g / L   106
60  10 3
= 2.12 g/L

12. B
Sol. Fact

13. A
Sol. 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10
nl  0
l = 0, i.e s
l = 0, ml = 0

14. B
167  50
Sol. Volume of glass vessel =  100 mL
1.17
PV = nRT

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CM-2224-CL-XI-TEST-I-PCM - P22

0.32
1 0.1   0.083  300
Mw
Mw = 79.68

15. B
Sol. meqC O2  meqKMnO4
2 4

2  x  5  0.04  22.6
x = 2.26

16. B
Sol. meqCu2  meqhypo
1 y  1 0.1 11.3
y = 1.13
5x  10y 5  2.26  10  1.13

2 2
= 11.3

17. C
Sol. Angular part of the wave function for an s orbital, do not contain  and .

18. B
1/ 2 3/ 2
 1  1  Z
Sol.  2S        2    e / 2
 4   2 2  a0 
2  0
2  Zr
2 0
na0
2  1 x
2 0
2a0
x = 2 a0
x  2a0  0

MATHEMATICS
PART – A

1. BC
 A B  A B
Sol. 2cos 
2  cos  2   1
   
 A B 1
 cos  
 2  3
 A B 1
 2cos 2   1  3
 2 
1
 cos  A  B   
3

2. ABC
Sol.  a  b  sin        a  b  sin    
sin      ab
 
sin      a b
sin       sin      2a
 
sin       sin      2b

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CM-2224-CL-XI-TEST-I-PCM - P23

2sin  cos  a tan 


  
2cos  sin  b tan 
 
2a tan 2b tan
 2  2
2  2 
1  tan 1  tan
2 2
  
 a tan 2  c 
a 
 b  
b tan
Also    2
  
2

a tan  c 1  tan2
 2  2
1  
b
 
 

3. BC
Sol. x  6  x  6  12

4. AC
Sol. Let N1  340
 log10 N1  40log10 3  40  0.4771  19.084
So, L = 20
Let N2  3 40  log10 N2  40log10 3  40  0.4771  19.084
 M  19

5. ABCD
3
Sol. L  , M  tan51o , N  sin72o
4

6. AD
m  n  log2 5   log2 5  2 
2
Sol. (A)
  log2 5  2  log2 5  1  0
 mn
(B) 23  10
Or 2  101/3
Or log10 2  log10 101/ 3
 m<n
(C) m  log10 5  log10 20
=  log10 10  log10 2  log10 10  log10 2 
 1  log10 2 1  log10 2 
= 1  log10 2 
2

<1
 mn
 1  1
(D) m  log1/ 2    log2 3 and n  log1/3    log3 2
3 2
m log2 3
  log2 3   1
2
 
n log3 2
 m  n  as n  0 

7. ACD
Sol. sin x cos 20o  cos x sin 20o  2 sin x cos 40o
Or 
sin20o cos x  sin x 2cos 40o  cos 20 o 

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CM-2224-CL-XI-TEST-I-PCM - P24

sin20o
Or tan x 
2cos 40o  cos 20o
sin 20o

cos 40  cos 40o  cos 20o
o

sin20o

cos 40  2 sin30o sin 10o
o
 
o
sin20 sin20o
 
sin50  sin10
o o
2cos30o sin 20o
1
 or x  30o
3

8. A
x 2  5x  4
Sol. 1
x2  4
x 2  5x  4
 1  1
x2  4

9. D
Sol. Put 2x  t . Then t > 0. The given inequality becomes
1 2

t 1 2  t
1 2
  0
t 1 2  t

10. A
cot 2 A  cos2 A cot 2 A
Sol. As, 
cot 2 A  cos 2 A  1 
 sin2 A  1
 
cot A  sin A
2 2
  cot 2 A  tan2 A  1
cos2 A

11. A
 
1  cos  1  sin  
2 2
Sol. log27  2
 4cos2   2
 4 sin2  
 
 2 
1  cos   
2
 log27  2
 1  sin2  
 

12. A
 x  x  3 
Sol. log2
x3

 log2 x 2  x  1 
x
 
log2 x 2  log2 x 2  x  1 
 
x  x  x  1  x  1
2 2

 x  1, 1, 2, 4, 5, 6, 7, 8, 9

13. D
3 sin2 9o  4 sin4 9o 3 sin2 9o  4 sin4 9o 1
Sol.  
2 sin 18  cos18  1 cos18o  cos36o
2 o o
2

14. B
Sol. f  x  x  1  x  2  x  4

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CM-2224-CL-XI-TEST-I-PCM - P25

0 1 2 4
5
 
2

15. D
Sol. Q  2   cos2 63o  cos2 57o  cos 63o  cos 57o
 1  sin2 63o  cos2 57o  cos 63o  cos57o
1
 1  cos120o cos6 o  cos120o  cos6o
2
 
1 1 1 1
= 1  cos 6o      cos 6o
2 2 2 2
1 3
= 1 
4 4
3 3
 log1.3    log4/3    1
4
  4

16. A
Sol. 12 P4  x   P6  x  


= 3 sin4 x  cos 4 x  2 sin6 x  cos6 x  
= 3  sin x   2sin  
x  cos2 x   2  sin2 x  cos2 x sin4 x  sin2 x cos2 x  cos4 x  
2
2
x  cos2 2
 
 3 1  2 sin x  cos x   2 1  3 sin x cos2 x 
2 2 3

 3  6 sin2 x  cos2 x  2  6 sin2 x cos2 x


1

17. A
Sol. 
 cos36o  cos84o  cos156o 

cos 60  24o o
  cos  60 o
 24   cos 24 o

 2cos 60o cos 24o  cos 24o


 cos 24o  cos24o  0

18. C
Sol. cos36o  cos84o  cos84o cos156o  cos36 o cos156o
Let   24o
    
 cos 60 o   cos 60o    cos 60o   cos   cos 60 o   cos    
 cos 60  sin   cos  cos 60    cos 60
2 o 2
 o
  o
  
 cos 60  sin   2cos  cos 60 cos 
2 o 2 o

1 3
cos 2 60o  1   1  
4 4

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