Safety Data Sheet

Revision Date: 12/23/2019 Page 1 of 8

SAFETY DATA SHEET

SECTION 1: PRODUCT AND COMPANY INFORMATION

Emergency Telephone Number [1E]

[1D]

10110 Sorrento Valley Road, CHEMTEL CHEMICAL

San Diego, CA 92121 DOMESTIC NORTH AMERICA: 1-800-255-3924
phone 858-350-9474 INTERNATIONAL CALLERS OUTSIDE THE US
TERRITORIES AND CANADA: +1-813-248-0585
fax 858-350-9422
Email: [email protected]
www.aculon.com Revision Date: 12/23/2019

TRADE
[1a,b]
Aculon® ON-470 [1c]
CHEMICAL FAMILY/ Chemical Mixture
NAME(s) APPLICATION/ RESTRICTIONS Hydrophilic Coating

SECTION 2: HAZARDOUS IDENTIFICATION

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

[2A]

Flammable liquids (Category 3), H226

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 4), H312
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

[2B]
LABELING ELEMENTS, Hazard, and Precautionary Statements

Signal word: Danger Pictogram(s):

Hazard statement(s):
H226 Flammable liquid and vapour.
H301 + H331 Toxic if swallowed or if inhaled
H312 Harmful in contact with skin.
H315 Causes skH318 Causes serious eye damage.in irritation.

H335 May cause respiratory irritation.

Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
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P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated
clothing. Rinse skin with water/ shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P322 Specific measures (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for
extinction.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

HAZARDS NOT OTHERWISE CLASSIFIED: none known

[2C]

INGREDIENTS OF UNKNOWN ACUTE TOXICITY >/= 1%:

[2D]

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENT(S)

CHEMICAL NAME/SYNONYMS
[3a,b,d]
CAS NUMBER
[3C]
EINECS NO. CONC.*
Proprietary Active Blend* n/a n/a 0 - 5%
2,2,2-Trifluoroethanol 75-89-8 200-913-6 95 - 100 %

* The specific chemical identity and/or percentage of this material has been withheld as a trade secret.

SECTION 4: FIRST AID MEASURES

[4a]
INHALATION If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a
physician.
[4a]
SKIN CONTACT Wash off with soap and plenty of water. Consult a physician.
[4a]
EYE CONTACT Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

[4a]
INGESTION Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
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MOST
[4b]
The most important known symptoms and effects are described in the labelling (see section 2) and/or
IMPORTANT in section 11
SYMPTOMS &
EFFECTS
[4c]
INDICATION OF no data available
ANY IMMEDIATE
MEDICAL
ATTENTION AND
SPECIAL
TREATMENT
NEEDED

SECTION 5: FIREFIGHTING MEASURES

SUITABLE/
[5a]

UNSUITABLE Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
EXTINGUISHING
MEDIA
[5b]
SPECIFIC Burning may form Carbon oxides, Hydrogen fluoride. Use water spray to cool unopened
HAZARDS IE containers. Flash back possible over considerable distance.
HAZARDOUS
COMBUSTION
PRODUCTS
[5c]
PRECAUTIONS / Wear self contained breathing apparatus for fire fighting if necessary.
SPECIAL In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.Use water spray to
PROTECTIVE cool unopened containers.
EQUIPMENT

SECTION 6: ACCIDENTAL RELEASE MEASURES

[6a]
PERSON Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate
PRECAUTIONS, ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours
PPE, EMERGENCY accumulating to form explosive concentrations. Vapours can accumulate in low areas.
PROCEDURES
[6a]
METHODS & Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing
MATERIALS OF and place in container for disposal according to local regulations. Prevent material from entering
CONTAINMENT & storm sewers or waterways.
CLEANING

SECTION 7: HANDLING AND STORAGE

[7a]
PRECAUTIONS Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Flashback possible over
FOR SAFE considerable distance. Container explosion may occur under fire conditions. Use explosion proof
HANDLING equipment. Keep away from sources of ignition - No smoking.Take measures to prevent the
buildup of electrostatic charge.

CONDITIONS FOR Keep away from heat, sparks, and flame. Keep away from sources of ignition. Flammables-area.
[7b]

SAFE STORAGE Store under inert gas. Moisture sensitive.

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SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

[8a] COMPONENT PEL/ CONTROL BASIS (ACGIH, OSHA NOTES

TWA/ PARAMETERS ETC)
STEL

2,2,2- TWA 0.3 ppm USA. Workplace

Trifluoroethanol, Environmental
75-89-8 Exposure Levels
(WEEL)

[8b] VENTILATION /Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be
ENGINEERING equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust
CONTROLS ventilation to keep airborne concentrations below the permissible exposure limits.
[8c]RESPIRATORY Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
PROTECTION with multi purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
[8c]SKIN PROTECTION Wear appropriate protective gloves to prevent skin exposure. The suitability for a specific
workplace should be discussed with the producers of the protective gloves. Please observe the
instructions regarding permeability and breakthrough time which are provided by the supplier of
the gloves. Also take into consideration the specific local conditions under which the product is
used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and
replaced if there is any indication of degradation or chemical breakthrough.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0.3 mm
Breakthrough time: 480 min
Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.4 mm
Breakthrough time: 30 min
Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected],
test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the CE approved gloves. This recommendation is advisory only and must
be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
anticipated use by our customers. It should not be construed as offering an approval for any
specific use scenario.
[8c]EYE PROTECTION Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
[8c]CLOTHING Wear appropriate protective clothing to prevent skin exposure.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

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[9a] Appearance (physical state, color, Liquid, Clear Colorless [9j] Upper/lower flammability or Lower: 5.5%
etc. explosive limits: UEL: 42%
[9b]Odor no data available [9k]Vapor pressure 93 hPa (70 mmHg) at
25 °C (77 °F)
[9c] Odor threshold no data available [9l]Vapor density ~3 (Air = 1)
[9d]pH no data available [9m]Relative Density 1.3 - 1.5

Melting point/freezing point

[9e]] no data available [9n] Solubility (in H₂O) no data available
Initial boiling point and boiling
[9f]
77 - 80 °C (171 - 176 °F) [9o] Partition coefficient: no data available
range - lit. n-octanol/water

[9g
] Flash point 29 °C (84 °F) - closed [9p] Auto-ignition temperature no data available
cup
[9h
] Evaporation rate no data available [9q] Decomposition no data available
temperature
Flammability (solid, gas)
[9i]
no data available [9r]Viscosity no data available

SECTION 10: STABILITY AND REACTIVITY

REACTIVITY
[10a]
no data available
CHEMICAL
[10b] Stable under recommended storage conditions..
STABILITY
[10c]
POSSIBILITIES OF Vapours may form explosive mixture with air.
HAZARDOUS
REACTIONS
[10d]
CONDITIONS TO Exposure to moisture. Ignition sources, excess heat
AVOID
INCOMPATIBLE
[10e]
Strong oxidizing agents, strong acids, sodium/sodium oxides, potassium. May damage some
MATERIALS forms of plastics with prolonged exposure.
HAZARDOUS
[10f]
Other decomposition products - no data available
DECOMPOSITION In the event of fire: see section 5
PRODUCTS

SECTION 11: TOXICOLOGY INFORMATION

[11a]
LIKELY ROUTES
OF EXPOSURE INHALATION: is not expected if proper ventilation or personal protective equipment is used while
working with this product
INGESTION: Ingestion is not expected if proper industrial hygiene practices are followed, including
no eating, drinking, or smoking while working with chemicals
SKIN: is not expected if proper personal protective equipment (gloves and protective clothing) is
used while working with this product
EYE CONTACT: is not expected if proper personal protective equipment (safety glasses or
goggles) is used while working with this product

SYMPTOMS
[11b]
INHALATION: May cause respiratory irritation. Toxic if inhaled or ingested.
RELATED TO INGESTION: May cause irritation. Toxic if inhaled or ingested.
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PHYSICAL, SKIN: Skin corrosion/irritation: Skin - rabbit Result: Severe skin irritation - 24 h
CHEMICAL & TOXIC EYE CONTACT: Serious eye damage/eye irritation: Eyes - rabbit; Result: Eye irritation - 24 h
CHARACTERISTICS
[11d]
DELAYED / Reproductive toxicity: no data available
IMMEDIATE Specific target organ toxicity - single exposure: Inhalation - May cause respiratory irritation.
EFFECTS, Specific target organ toxicity - repeated exposure: no data available
CHRONIC EFFECTS Aspiration hazard: no data available
FROM Additional Information
SHORT/LONG RTECS: KM5250000
TERM EXPOSURE burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting,
Pulmonary edema.
Effects may be delayed.

NUMERICAL
[11D]
Acute toxicity for 2,2,2-Trifluoroethanol
MEASURES OF LD50 Oral - rat - 240 mg/kg
TOXICITY LC50 Inhalation - rat - 6 h - 470 ppm -
Remarks: Behavioral:Tremor. Behavioral:Ataxia. Skin and Appendages: Other: Hair.
LD50 Dermal - rat - 1,680 mg/kg

Skin corrosion/irritation: Skin - rabbit; Result: Severe skin irritation - 24 h

Serious eye damage/eye irritation: Eyes - rabbit; Result: Eye irritation - 24 h
Respiratory or skin sensitisation:no data available
Germ cell mutagenicity :no data available

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
[11e]

CARCINOGENICITY probable, possible or confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified
as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as
a
carcinogen or potential carcinogen by OSHA.

SECTION 12: ECOLOGICAL INFORMATION

[12a]
ECOTOXICITY The ecological information and warnings are driven by the solvent. See below for the relevant
data for the 2,2,2-Trifluoroethanol. The other components either have no ecotoxicological effects
or no data available.

Toxicity to fish LC50 - LC50 - Pimephales promelas (fathead minnow) - 105 - 135 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: No data available
Toxicity to algae EC50 - No data available

[12b]
PERSISTENCE No data available
AND
DEGRADABILITY
[12c]
BIOACCUMULATI No data available
VE POTENTIAL
[12d]
MOBILITY IN SOIL No data available
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OTHER ADVERSE No data available

[12e]

EFFECTS (OZONE
LAYER ETC.)

SECTION 13: DISPOSAL CONSIDERATIONS

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
[13]

material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a
licensed professional waste disposal service to dispose of this material.

Contaminated Packaging Disposal: Dispose of as unused product.

SECTION 14: TRANSPORTATION INFORMATION

[14a]
UN/NA UN/NA PROPER
[14b] [14ca]
TRANSPORT HAZARD [14d]
PACKING GROUP
SHIPPING NAME CLASS

UN 1992 Flammable Liquid, toxic 3 (6.1) III

n.o.s. (2,2,2,
Trifluoroethanol)

US DOT/IATA Flammable Liquid, toxic n.o.s. (2,2,2, Trifluoroethanol), 3 (6.1), III

Marine Pollutant: no
ENVIRONMENTAL
[14d]

HAZARDS
[14f]
BULK TRANSPORT IMDG: Flammable Liquid, toxic n.o.s. (2,2,2, Trifluoroethanol), 3 (6.1), III EMS-No: F-E,
(MARPOL 73/78/IBC CODE) S-D

[14g]
SPECIAL PRECAUTIONS none known

SECTION 15: REGULATORY INFORMATION

US

TSCA The components in this mixture are listed on the US inventory.

OSHA This document has been prepared in accordance with the SDS requirements
of the OSHA Hazard Communication Standard.
SARA SECTION 302 EXTREMELY No chemicals in this material are subject to the reporting requirements of
HAZARDOUS SUBSTANCES SARA Title III, Section 302.
The following components are subject to This material does not contain any chemical components with known CAS
reporting levels established by SARA numbers that exceed the
Title III, Section 313 threshold (De Minimis) reporting levels established by SARA Title III, Section
313.

Sara 311/312 Hazards Fire Hazard, Acute Health Hazard,

Massachusetts Right To Know No Components Listed
Components
Pennsylvania Right To Know 2,2,2-Trifluoroethanoll, CAS# 75-89-8
Components
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New Jersey Right To Know Components 2,2,2-Trifluoroethanoll, CAS# 75-89-8

California Prop. 65 Components This product does not contain any chemicals known to State of California to
cause cancer, birth defects, or any other reproductive harm.

SECTION 16: OTHER INFORMATION

Revision Date: 12/23/2019 Updated Address Under Section 1

06/12/2018 Updated Emergency Contact
06/06/2018 Updated Emergency Contact and Trademarks
12/07/16 Original Issue

INFORMATION CONTAINED IN THIS SAFETY DATA SHEET IS FOR USE BY TECHNICALLY QUALIFIED PERSONNEL AT THEIR
DISCRETION AND RISK. ALL STATEMENTS, TECHNICAL INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE
BASED ON TESTS AND DATA WHICH WE BELIEVE TO BE RELIABLE, BUT THE ACCURACY OR COMPLETENESS THEREOF IS
NOT GUARANTEED AND NO WARRANT OF ANY KIND IS MADE WITH RESPECT THERETO. SINCE THE COMPANY SHALL
HAVE NO CONTROL OF THE USE OF THE PRODUCT DESCRIBED HEREIN, THE COMPANY ASSUMES NO LIABILITY OF LOSS
OR DAMAGE INCURRED FROM THE PROPER OR IMPROPER USE OF SUCH PRODUCT.
DISCLAIMER
This material must be handled by/under direct supervision of technically qualified persons. Not for drug, household or other uses.