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SECOND QUARTER EXAM - Chem
SECOND QUARTER EXAM - Chem
Question 1
Correct
In thermodynamics, an ___process is a type of thermodynamic process in which the pressure P of a system remains constant.
a. Isochoric
b. Isobaric
c. Isothermal
d. Isometric
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Question 2
Correct
The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a certain temperature.
a. I and IV
b. I and III
c. II and IV
d. II and III
Question 3
Correct
Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from 45 to 65 degrees Celsius. Molar heat capacity
of aluminum is 24 J/mole.K.
a. 1.35kJ
b. 1.25 kJ
c. 1.065kJ
d. 1.44 KJ
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Question 4
Correct
The equilibrium constant for the reaction is 10. What will be the value of ΔG?
a. 4457 J
b. 4475 J
c. -5744 J
d. 7544 J
Question 5
Correct
Spontaneous processes are those that can proceed with any outside intervention.
a. False
b. True
Question 6
Correct
A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on it. What is the heat change of the
system?
a. -130 J
b. +30 J
c. +130 J
d. -30 J
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Question 7
Correct
a. True
b. False
Question 8
Correct
If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees Celsius, what is the specific heat of substance B?
a. 1.67 J/g. C
b. 0.167 J/g. C
c. 0.176 J/g. C
d. 1.76 J/g. C
Question 9
Correct
A reversible reaction has ΔG negative for forward reaction. What will be the sign for the backward reaction?
a. No sign
b. Negative
c. Positive
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Question 10
Correct
a. False
b. True
Question 11
Correct
a. Hess's Law
c. Calorimetry
Question 12
Correct
a. False
b. True
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Question 13
Correct
____ constant tells how far the reaction has proceeded once the equilibrium is reached.
a. Dielectric
b. Universal gas
c. Equilibrium
d. Cell
Question 14
Correct
Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298 K.
a. +0.45 J
b. -0.45 kJ
c. 0.45KJ
d. 0.50Kj
Question 15
Correct
An isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains
constant.
a. True
b. False
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Question 16
Correct
The ____ of a substance is the amount of energy required to raise the temperature of 1 gram of the substance by 1 degree Celsius.
a. Mass
b. Volume
c. Specific heat
d. Temperature
Question 17
Correct
The standard enthalpy of formation for a simple substance in its most stable state must be non-zero
a. False
b. True
Question 18
Correct
The higher the number of types of molecules, the higher is the degree of disorder.
a. True
b. False
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Question 19
Correct
The lower the concentration of the weak acid decreases the pH of the buffer solution.
a. False
b. True
Question 20
Correct
Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from graphite and oxygen:
a. 2.86 J/mol.K
b. 1.76 J/mol.K
c. 5.31 J/mol.K
d. 3.35 J/mol.K
Question 21
Correct
a. False
b. True
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Question 22
Correct
Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee cup calorimeter and the temperature drops
from 295 oC to 285 o C. Find the value of q for the calorimeter.
(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)
a. -5300 J
b. 5430 J
c. -5430 J
d. 5500 J
Question 23
Correct
___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all changes.
c. Hess's Law
d. Calorimetry
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Question 24
Correct
What happens to the internal energy of the system if work is done on the system?
Question 25
Correct
The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is the heat change of the system?
a. -10 J
b. +10 J
c. -0.10 J
d. +0.10 J
Question 26
Correct
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Question 27
Correct
The standard free energy is found to be zero. What is its equilibrium constant?
a. 10
b. 1
c. 5
d. 0
Question 28
Correct
a. Open system
b. Isolated system
c. Closed system
Question 29
Correct
If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius, what is the specific heat of substance A?
a. 2.5 J/g. C
b. 0.250 J/g. C
c. 250 J/g. C
d. 10 J/g. C
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Question 30
Correct
a. True
b. False
Question 31
Correct
a. ΔS = 0
b. ΔS will decrease
c. ΔS remains constant
d. ΔS will increase
Question 32
Correct
In thermodynamics, an ___process is a type of thermodynamic process in which the temperature T of a system remains constant.
a. Isobaric
b. Isochoric
c. Isometric
d. Isothermal
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Question 33
Correct
c. Reactants only
d. Products only
Question 34
Correct
Non-spontaneous processes are those that do not take place by themselves or is a type of reaction which cannot occur without the input
of work from an external source.
a. True
b. False
Question 35
Correct
Which phase of matter has the greatest motion and least orderly arrangement?
a. Liquid
b. Gas
c. Solid
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Question 36
Correct
If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________
a. The reaction is not at equilibrium, and will make more reactants at the expense of products.
c. The reaction is not at equilibrium, and will make more products at the expense of reactants.
Question 37
Correct
Total change in energy is equal to the sum of the heat and work transferred between the systems and surroundings.
Question 38
Correct
a. Entropy
c. Internal energy
d. Work
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Question 39
Correct
a. Isothermal
b. Isometric
c. Isochoric
d. Isobaric
Question 40
Correct
a. True
b. False
Question 41
Correct
Chemical equilibrium is described as a dynamic process because there is a movement in which the forward and reverse reactions occur at
the same rate to reach a point where the amounts or concentrations of the reactants and products are unchanging with time.
a. False
b. True
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Question 42
Correct
A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol is 64.7 o C and the molar enthalpy of
vaporization if 71.8 kJ/mol. The value of ΔS when 2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.
a. 5.21x107
b. 457
c. 0.457
d. 2.39x10 3
Question 43
Correct
Which of the following is true regarding the concentration of products, for a chemical reaction that is already at equilibrium, assuming no
disruptions to the equilibrium?
a. The concentrations of products will not change because the limiting reagent is gone.
b. The concentrations of products will not change because there are no more reactants.
c. The concentrations of products will not change because the forward and reverse rates are equal.
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Question 44
Correct
Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from liquid at 10° C to vapor at 30° C.
a. 130kJ
b. 126Kj
c. 120kJ
d. 119kJ
Question 45
Correct
___ is the state at which the concentration ratio of products to reactants is observed to be constant.
a. Oxidation
b. Solid
c. Equilibrium
d. Liquid
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Question 46
Correct
Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.
a. ΔS > 0
b. ΔS < 0
c. ΔS = 0
d. ΔS remains constant
Question 47
Correct
What happens to the internal energy of the system if work is done by the system?
Question 48
Correct
The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1 cm³ of water by one degree Celsius.
a. Joule
b. Mole
c. Watt
d. Calorie
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Question 49
Correct
a. a value of Q << 1.
d. K = Q.
Question 50
Correct
Reactions in which the products can react to form back the reactants are said to be ___.
a. Irreversible
b. Decomposition
c. Reversible
d. Combination
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