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2/9/23, 10:23 AM SECOND QUARTER EXAM: Attempt review

Home / My courses / BAED-CHEM2122-2212S / SECOND QUARTER EXAMINATION / SECOND QUARTER EXAM

Started on Thursday, 9 February 2023, 9:35 AM


State Finished
Completed on Thursday, 9 February 2023, 10:23 AM
Time taken 48 mins 17 secs
Marks 50.00/50.00
Grade 100.00 out of 100.00

Question 1
Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process is a type of thermodynamic process in which the pressure P of a system remains constant.

a. Isochoric 

b. Isobaric

c. Isothermal

d. Isometric 

Your answer is correct.

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Question 2

Correct

Mark 1.00 out of 1.00

The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a certain temperature.

H2(g)   +   I2(s)     ⇌   2 HI(g) K = 45


Which of the following is true regarding this equilibrium?

I. The reaction is product favored.

II. The reaction is reactant favored.


III. Equilibrium lies to the right.

IV. Equilibrium lies to the left.

a.  I and IV

b.  I and III

c.  II and IV

d. II and III

Your answer is correct.

Question 3
Correct

Mark 1.00 out of 1.00

Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from 45 to 65 degrees Celsius. Molar heat capacity
of aluminum is 24 J/mole.K. 

a. 1.35kJ

b. 1.25 kJ

c. 1.065kJ

d. 1.44 KJ

Your answer is correct.

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Question 4

Correct

Mark 1.00 out of 1.00

The equilibrium constant for the reaction is 10. What will be the value of ΔG?

a. 4457 J

b. 4475 J

c.  -5744 J

d. 7544 J

Your answer is correct.

Question 5
Correct

Mark 1.00 out of 1.00

Spontaneous processes are those that can proceed with any outside intervention.

a. False

b. True

Your answer is correct.

Question 6
Correct

Mark 1.00 out of 1.00

A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on it. What is the heat change of the
system?

a.  -130 J

b. +30 J

c.  +130 J

d. -30 J

Your answer is correct.

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Question 7

Correct

Mark 1.00 out of 1.00

If ΔG is positive, the reaction is spontaneous in the reverse direction.

a. True

b. False

Your answer is correct.

Question 8

Correct

Mark 1.00 out of 1.00

If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees Celsius, what is the specific heat of substance B?

a. 1.67 J/g. C

b. 0.167 J/g. C

c.  0.176 J/g. C

d. 1.76 J/g. C

Your answer is correct.

Question 9
Correct

Mark 1.00 out of 1.00

A reversible reaction has ΔG negative for forward reaction. What will be the sign for the backward reaction?

a. No sign

b. Negative

c. Positive

Your answer is correct.

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Question 10

Correct

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Melting and vaporization are examples of exothermic process.

a.  False

b. True

Your answer is correct.

Question 11

Correct

Mark 1.00 out of 1.00

The equation that relates enthalpy, temperature and entropy is

a. Hess's Law

b. Second Law of Thermodynamics

c.  Calorimetry

d. Gibbs Free Energy

Your answer is correct.

Question 12
Correct

Mark 1.00 out of 1.00

Freezing and condensation are examples of exothermic process.

a.  False

b. True

Your answer is correct.

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Question 13

Correct

Mark 1.00 out of 1.00

____ constant tells how far the reaction has proceeded once the equilibrium is reached.

a. Dielectric

b. Universal gas

c.  Equilibrium 

d. Cell 

Your answer is correct.

Question 14
Correct

Mark 1.00 out of 1.00

Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298 K.

a. +0.45 J

b. -0.45 kJ

c. 0.45KJ

d. 0.50Kj

Your answer is correct.

Question 15
Correct

Mark 1.00 out of 1.00

An isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains
constant.

a. True

b. False

Your answer is correct.

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Question 16

Correct

Mark 1.00 out of 1.00

The ____ of a substance is the amount of energy required to raise the temperature of 1 gram of the substance by 1 degree Celsius.

a.  Mass 

b. Volume

c. Specific heat  

d. Temperature 

Your answer is correct.

Question 17
Correct

Mark 1.00 out of 1.00

The standard enthalpy of formation for a simple substance in its most stable state must be non-zero

a.  False

b.  True

Your answer is correct.

Question 18
Correct

Mark 1.00 out of 1.00

The higher the number of types of molecules, the higher is the degree of disorder.

a. True

b. False

Your answer is correct.

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Question 19

Correct

Mark 1.00 out of 1.00

The lower the concentration of the weak acid decreases the pH of the buffer solution.

a. False

b. True

Your answer is correct.

Question 20

Correct

Mark 1.00 out of 1.00

Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from graphite and oxygen:

       C(s) + O2(g) → CO2(g)


Standard Entropy in J/mol.K  for:      C= 5.740                    O2 = 205.14   CO2=213.74    

a. 2.86  J/mol.K  

b. 1.76 J/mol.K 

c.  5.31 J/mol.K  

d.  3.35 J/mol.K  

Your answer is correct.

Question 21
Correct

Mark 1.00 out of 1.00

If ΔG is 1, the system is at equilibrium.

a. False

b. True

Your answer is correct.

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Question 22

Correct

Mark 1.00 out of 1.00

Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of  water in a coffee cup calorimeter and the temperature drops
from 295 oC to 285 o C. Find the value of q for the calorimeter.

(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)

a. -5300 J

b. 5430 J

c. -5430 J

d.  5500 J

Your answer is correct.

Question 23
Correct

Mark 1.00 out of 1.00

___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the reaction is the sum of all changes.

a.  Second Law of Thermodynamics

b. Gibbs Free Energy

c.  Hess's Law

d. Calorimetry

Your answer is correct.

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Question 24

Correct

Mark 1.00 out of 1.00

What happens to the internal energy of the system if work is done on the system?

a. Internal energy will decrease 

b.  Internal energy remains constant

c. Internal energy will increase 

Your answer is correct.

Question 25
Correct

Mark 1.00 out of 1.00

The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is the heat change of the system?

a.  -10 J

b.  +10 J

c. -0.10 J

d. +0.10 J

Your answer is correct.

Question 26
Correct

Mark 1.00 out of 1.00

Which of the following is true for a chemical reaction at equilibrium?

a. Only the forward reaction stops

b. Only the reverse reaction stops

c. The rates of the forward and reverse reactions are equal

d. Both the forward and reverse reactions stop

Your answer is correct.

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Question 27

Correct

Mark 1.00 out of 1.00

The standard free energy is found to be zero. What is its equilibrium constant?

a. 10

b. 1

c. 5

d. 0

Your answer is correct.

Question 28
Correct

Mark 1.00 out of 1.00

What kind of thermodynamic system is coffee held in a cup?

a. Open system

b. Isolated system

c. Closed system  

Your answer is correct.

Question 29
Correct

Mark 1.00 out of 1.00

If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius, what is the specific heat of substance A?

a. 2.5 J/g. C

b.  0.250 J/g. C

c. 250 J/g. C

d. 10 J/g. C

Your answer is correct.

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Question 30

Correct

Mark 1.00 out of 1.00

In exothermic reaction, heat is liberated into the surroundings.

a. True

b. False

Your answer is correct.

Question 31

Correct

Mark 1.00 out of 1.00

Predict the entropy change (ΔS) if the temperature of crystal is increased.

a. ΔS = 0 

b. ΔS will decrease 

c. ΔS remains constant

d. ΔS will increase  

Your answer is correct.

Question 32
Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process is a type of thermodynamic process in which the temperature T of a system remains constant.

a. Isobaric

b. Isochoric 

c. Isometric 

d. Isothermal

Your answer is correct.

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Question 33

Correct

Mark 1.00 out of 1.00

A chemical equilibrium may be established by starting a reaction with __________

a. All the above

b. Any quantities of reactants and products.

c. Reactants only

d. Products only 

Your answer is correct.

Question 34
Correct

Mark 1.00 out of 1.00

Non-spontaneous processes are those that do not take place by themselves or  is a type of reaction which cannot occur without the input
of work from an external source.

a. True

b. False

Your answer is correct.

Question 35
Correct

Mark 1.00 out of 1.00

Which phase of matter has the greatest motion and least orderly arrangement?

a. Liquid

b. Gas

c. Solid

Your answer is correct.

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Question 36

Correct

Mark 1.00 out of 1.00

If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________

a. The reaction is not at equilibrium, and will make more reactants at the expense of products.

b. The reaction is at equilibrium.

c. The reaction is not at equilibrium, and will make more products at the expense of reactants.

d. The value of K will decrease until it is equal to Q

Your answer is correct.

Question 37
Correct

Mark 1.00 out of 1.00

Total change in energy is equal to the sum of the heat and work transferred between the systems and surroundings.

a. Second Law of Thermodynamics

b. Third Law of Thermodynamics

c. First Law of Thermodynamics

Your answer is correct.

Question 38
Correct

Mark 1.00 out of 1.00

Which one of the following thermodynamic quantities is not a state function?

a.  Entropy

b.  Gibbs free energy

c. Internal energy

d.  Work

Your answer is correct.

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Question 39

Correct

Mark 1.00 out of 1.00

In thermodynamics, an ___process, also called a constant-volume process.

a.  Isothermal

b. Isometric 

c. Isochoric 

d.  Isobaric

Your answer is correct.

Question 40
Correct

Mark 1.00 out of 1.00

A photochemical reaction is one of the examples of non-spontaneous reaction.

a.  True

b. False

Your answer is correct.

Question 41
Correct

Mark 1.00 out of 1.00

Chemical equilibrium is described as a dynamic process because there is a movement in which the forward and reverse reactions occur at
the same rate to reach a point where the amounts or concentrations of the reactants and products are unchanging with time.

a. False

b. True

Your answer is correct.

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Question 42

Correct

Mark 1.00 out of 1.00

A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol is 64.7 o C and the molar enthalpy of
vaporization if 71.8 kJ/mol. The value of ΔS when  2.15 mol of CH3OH (l) vaporizes at 64.7 o C is ___ J/K.

a. 5.21x107   

b. 457

c.  0.457

d. 2.39x10 3    

Your answer is correct.

Question 43
Correct

Mark 1.00 out of 1.00

Which of the following is true regarding the concentration of products, for a chemical reaction that is already at equilibrium, assuming no
disruptions to the equilibrium?

a. The concentrations of products will not change because the limiting reagent is gone.

b. The concentrations of products will not change because there are no more reactants.

c. The concentrations of products will not change because the forward and reverse rates are equal.

d. The concentrations of products will change continually because of reversibility

Your answer is correct.

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Question 44

Correct

Mark 1.00 out of 1.00

Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from liquid at 10° C to vapor at 30° C.

a. 130kJ

b. 126Kj

c. 120kJ

d.  119kJ

Your answer is correct.

Question 45
Correct

Mark 1.00 out of 1.00

___ is the state at which the concentration ratio of products to reactants is observed to be constant.

a. Oxidation 

b. Solid 

c. Equilibrium

d.  Liquid 

Your answer is correct.

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Question 46

Correct

Mark 1.00 out of 1.00

Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.

a. ΔS >  0 

b. ΔS < 0  

c. ΔS = 0  

d. ΔS remains constant

Your answer is correct.

Question 47
Correct

Mark 1.00 out of 1.00

What happens to the internal energy of the system if work is done by the system?

a. Internal energy remains constant

b. Internal energy will increase 

c. Internal energy will decrease

Your answer is correct.

Question 48
Correct

Mark 1.00 out of 1.00

The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1 cm³ of water by one degree Celsius.

a. Joule

b. Mole

c.  Watt

d. Calorie

Your answer is correct.

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Question 49

Correct

Mark 1.00 out of 1.00

An equilibrium that strongly favors products has __________

a.  a value of Q << 1.

b. a value of K >> 1. 

c. a value of K << 1. 

d. K = Q.

Your answer is correct.

Question 50
Correct

Mark 1.00 out of 1.00

Reactions in which the products can react to form back the reactants are said to be ___.

a. Irreversible

b. Decomposition

c. Reversible

d. Combination 

Your answer is correct.

◄ FIRST QUARTER EXAM

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