Republic of the Philippines

Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

LEARNING ACTIVITY SHEET IN GENERAL CHEMISTRY II

Freezing Point Depression and Boiling Point Elevation
Name of Learner: ____________________________________
Grade Level: ____________________________________
Strand/Track: ____________________________________
Section: ____________________________________
Date: ____________________________________

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A. Background Information for Learners

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The lesson is about analysis of concentration of solute in a solution based from
its freezing point depression and boiling point elevation. It involves activities
which can help the students to master the assigned competency.

B. Learning Competency N
Calculate boiling point elevation and freezing point depression from the
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concentration of a solute in a solution (STEM_GC11PPIIId-f-117)

C. Directions/ Instructions
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After going through with this unit, you are expected to:

1. Read and follow each direction carefully.

2. Accomplish each activity for the mastery of competency.
3. Use the Learning Activity Sheets with care.
4. Record your points for each activity
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5. Always aim to get at least 80% of the total number of given items.
6. If you have any questions, contact, or see your teacher through
messenger or text
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D. Exercises / Activities
DAY 1
D.1 INTRODUCTION

a. What I need to Know

After going through with this unit, you are expected to:

1. Differentiate boiling point elevation and freezing point depression

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

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CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

2. Calculate boiling point elevation and freezing point depression from the
concentration of a solute in a solution and
3. Relate the importance of boiling point elevation and freezing point
depression to real life situation.

b. What’s New?

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Activity 1: Find Me!
Encircle the 10 words listed below. Words appear straight across, back-word
straight across, up and down.

COLLIGATIVE ELECTROLYTE NON ELECTROLYTE

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SOLUTIONS IONS VAPOR
PRESSURE BOILING FREEZING
OSMOTIC DEPRESSION ELEVATION
LOWERING
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DISSOCIATE DISSOLVE

E Y K S N O I T U L O S Z K E
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T R N I U C Y E G P G N A R G

Y F O J Z V W J D N F E U N L
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L V I Y T I S B I B V S O V Q

O G T K V N O R O L S I A W D

R C A G L Z E I O E S P X O I

T I V W N W L S R S O N Q N S
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C T E P O I S P E R K T O R S
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E O L L N I Z R O I G Z J I O

L M E G D H P E N X J L R L C

E S I R S E I S E L I H J H I

N O T P D U R A I R M R S M A

O K U N Z G Z F B K F L P H T

N A C O L L I G A T I V E U E

Z E L E C T R O L Y T E F G R

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

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[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

D.2 DEVELOPMENT

a. What I Know?

Activity 2: Test Me!

Directions: Read each question and choose the correct answer. Write your
answer on a separate sheet of paper.

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1. A solution containing 6.35 g of nonelectrolyte dissolved in 500g of water freezes
at -0.465ºC. Determine the molar mass of solute.
a. 50.8 g/mol c. 70.8 g/mol
b. 60.8 g/mol d. 80.8 g/mol

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2. The freezing point of pure camphor is 178.4ºC and its molal freezing point
constant is 40.0ºC/m. Find the freezing point of a solution containing 1.50 g of a

a. 10.7ºC
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compound that has the molar mass 125 g/mol dissolved in 35.0 g of camphor.
c. 12.7ºC
b. 11.7ºC d. 13.7ºC

3. The vapor pressure of a solution containing a nonvolatile solute is directly

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proportional to the
a. molality of the solvent. c. molarity of the solvent.
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b. osmotic pressure of the solute. d. mole fraction of solvent.

4. A solution jof gold(III)nitrate is to be used in electroplating; it has been produced

by dissolving 12.75g Au(NO3)3 in 500mL H2O (density 1.000). What are the
expected freezing point and boiling point?
a. FP = -0.549ºC and BP = 100.14ºC c.FP=-0.495ºCandBP = 100.14ºC
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b. FP = -0.495ºC and BP = 100.14ºC d.FP=-0.495ºCandBP = 111.14ºC

5. Which of the following is NOT a colligative property?

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a) freezing point depression c. osmotic pressure

b) boiling point elevation d) solubility

6. Which of the following colligative properties can provide molar mass of proteins
( or polymers or colloids) with greater precision
a. relative lowering of vapour pressure c. elevation of boiling point
b. depression of freezing point d. osmotic pressure

7. What is the freezing point of 10% (by weight) solution of CH3OH water?
a. -4.5ºC c. -6.5ºC
b. -5.5ºC d. -7.5ºC

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

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[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

8. In a solution, the solvent is

a. always water.
b. always a liquid.
c. the substance being dissolved.
d. the substance present in the greatest amount.

9. In which of the following pairs of properties are both members of the pair

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colligative properties?
a. density, boiling point
b. vapor pressure, osmotic pressure
c. solubility, freezing point
d. none of the above

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10. The molar mass of a nonvolatile solute is 58.0. Calculate the boiling point of a
solution containing 24.0g of the solute dissolved in 600g water. The barometric

a. 100.079 ºC
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pressure is such that pure water boils at 99.725ºC.
c. 99.090 ºC
b. 101.080 ºC d. 110.010 ºC

b. What’s In
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Activity 3: “Fix Me”
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Directions: Arrange the jumbled letter in each sentence to understand more

about freezing point depression and boiling point elevation.

On the cooling of most dilute solutions, the solvent begins to (1.) yrlstceazli
____________ before the solute crystallizes. The (2.) attrpeemrue ____________ at
which the solvent crystals first begin to appear in the freezing point of that solution.
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The freezing point solution is always (3.) lerow ________ than the freezing point of
the (4.) urep lvesont _____ _______. In (5.) utedil __________ solutions, the
freezing point lowering is (6.) ctlydrei ___________ proportional to the number of
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moles solute (number of molecules) present. The change in freezing pointis determine
by (7.) actingsubtr ________________ the true freezing point of the solution from the
freezing point of the pure solvent.

Compared to the (8.) lingboi ____________ point of the pure solvent, dilute
solutions containing that solvent boil at a (9.) ghhier ___________ temperature. In
dilute solutions, the (10). evatielon _________ of the boiling point is directly
proportional to the number of moles of solute (or molecules).

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

c. What is It
Activity 4: What can you suggest?

1. The molal freezing point of water is 1.86ºC/m (1.86K/m), which can be

expressed as 1.86ºC ● kg H2O/mol solute (1.86K ● kg H2O/mol solute) after
some algebraic rearrangement. This means that a solution of 1 mol cane sugar
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(342g, over lb) dissolved in 1kg of water should freeze at -1.86ºC.

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4

Describe the freezing point drop suggestes in number 1.

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________________________________________________________________
________________________________________________________________

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________________________________________________________________
________________________________________________________________
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2. The molal boiling point constant of water is 0.512ºC/m. If 1 mol cane sugar
(342g/mol) is dissolved in 1kg water, the solution will boil at 100.512ºC,
assuming standard pressure. By this relationship, a half of a mole of sugar
(171g) would boil at 100.256 C/m and 2 mol sugar (684g) should boil at
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101.024ºC/m. However, these are not necessarily solutions that can be mixed;
684g of sugar is nearly a pound and a half of sugar, which you are supposed to
dissolved in a liter of water!
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From the given situation above, why is it important to understand the constants
relating to water?
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________________________________________________________________
________________________________________________________________
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________________________________________________________________
________________________________________________________________
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Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

D.3 ENGAGEMENT
a. What is more?

1. A solution containing 4.50 g of a non electrolyte (i=1) dissolved in 125 g of water

freezes at -0.372ºC. Calculate the molar mass of the solute.
Step 1: First compute the molality of the freezing point equation.

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Step 2. Then, from the definition of molality, compute the number of moles
solute, n(solute), in the sample.

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Step 3. Solve for the molar mass.
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2. A solution was produced by dissolving 3.75 g of a nonvolatile solute in 95g of

acetone. The boiling point of pure acetone was observed to be 55.95 ºC, while the boiling
point of the solution was 56.50ºC. If the boiling point for acetone is 1.71ºC/m, what is the
approximate molar mass of solute?
Step 1: First compute the molality of the boiling point equation.
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Step 2. Then, from the definition of molality, compute the number of moles
solute, n(solute), in the sample.

Step 3. Solve for the molar mass.

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

b. What I can Do?

Directions. Solve the problem.

1. Salt is often used to melt ice and snow on roads in the winter and the
temperature right now is -4.500ºC. How much NaCl (complete dissociation) would be
necessary to melt 1000kg of ice by bringing down the freezing temperature to -
4.500ºC?

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D.4 ASSIMILATION

a. What I have Learned?

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Activity 6: “For Real”
Directions: From the given problem, answer the following questions.
1. An organic compound is known to be nonvolatile and non electrolyte. A 0.35-
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g sample is dissolved in water and diluted to 150mL. The osmotic pressure is measured as
0.04 atm at 25ºC. The approxuimate mass number for this compound is 1400g/mol.
From the data provided in this problem and knowing that the density of the solution is 1.00g/mL

a. Calculate the freezing point of the solutions

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b. Determine if the freezing point change would be a good way to determine the
molecular mass of the compound

c. Would the boiling point change be a better determining factor than the freezing point
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change?
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b. Assessment / What I can show

Activity 7: “My Final Test!”
Directions: Read each question and choose the correct answer. Write your
answer on a separate sheet of paper.
1. In which of the following pairs of properties are both members of the pair colligative
properties?
a. density, boiling point
b. vapor pressure, osmotic pressure
c. solubility, freezing point
d. none of the above

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

2. The molar mass of a nonvolatile solute is 58.0. Calculate the boiling point of a solution
containing 24.0g of the solute dissolved in 600g water. The barometric pressure is such that
pure water boils at 99.725ºC.
a. 100.079 ºC c. 99.090 ºC
b. 101.080 ºC d. 110.010 ºC

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3. The vapor pressure of a solution containing a nonvolatile solute is directly proportional to
the
a. molality of the solvent. c. molarity of the solvent.
b. osmotic pressure of the solute. d. mole fraction of solvent.

4. In which of the following pairs of properties are both members of the pair colligative

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properties?
a. density, boiling point
b. vapor pressure, osmotic pressure
c. solubility, freezing point
d. none of the above
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5.What is the freezing point of 10% (by weight) solution of CH3OH water?
a. -4.5ºC c. -6.5ºC
b. -5.5ºC d. 7.5ºC
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6. Which of the following is NOT a colligative property?
a) freezing point depression c. osmotic pressure
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b) boiling point elevation d) solubility

7. Pressure cooker reduces cooking time for food because

a. heat is more evenly distributed in the cooking space
b. boiling point of water involved in cooking is increased
c. the higher pressure inside the cooker crushes the food material
d. cooking involves chemical changes helped by a rise in temperature
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8. A solution jof gold(III)nitrate is to be used in electroplating; it has been produced by

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dissolving 12.75g Au(NO3)3 in 500mL H2O (density 1.000). What are the expected freezing
point and boiling point?
a. FP = -0.549ºC and BP = 100.14ºC c.FP=-0.495ºCandBP = 100.14ºC
b. FP = -0.495ºC and BP = 100.14ºC d.FP=-0.495ºCandBP = 111.14ºC

9. A solution containing 6.35 g of nonelectrolyte dissolved in 500g of water freezes at -0.465ºC.

Determine the molar mass of solute.
a. 50.8 g/mol c. 70.8 g/mol
b. 60.8 g/mol d. 80.8 g/mol

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045

 Republic of the Philippines
Department of Education
REGION IV-A CALABARZON
SCHOOLS DIVISION OF BATANGAS

10. The freezing point of pure camphor is 178.4ºC and its molal freezing point constant is
40.0ºC/m. Find the freezing point of a solution containing 1.50 g of a compound that has the
molar mass 125 g/mol dissolved in 35.0 g of camphor.
a. 10.7ºC c. 12.7ºC
b. 11.7ºC d. 13.7ºC

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D. Rubrics
Short Answer

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E. Reflection
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Learners will write on their notebooks or journals their insights about the lesson.
I understand that_____________________.
I realized that _______________________.

F. References
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a. Book
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Shaum’s Outline of College of Chemistry

Address: Provincial Sports Complex, Bolbok, 4200 Batangas City

(043)722-1840 / 722-1796 / 722-1437 / 722-2675 / 722-1662
[email protected]
www.depedbatangas.org

CRN 44 100 18 93 0045