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& BY MASS,

% BY VOLUME,
MOLARITY, & MOLALITY

Mrs. Wilhelmina I. Galiza


General Chemistry 2 Teacher
CONCENTRATION OF SOLUTIONS
• The concentration of a solution is a measure of the
amount of solute in a given amount of solvent of
solution.
• A solution concentration is a measure of the
quantity of solute that has been dissolved in a given
quantity of solvent or solution. One that contains a
relatively high volume of dissolved solute is a
concentrated solution. That that contains a
relatively minimal volume of dissolved solute is a
dilute solution.
WAYS OF EXPRESSING THE
CONCENTRATIONS OF SOLUTIONS
• Mass Percentage (w/w):
• When the concentration is expressed as the
percent of one component in the solution by
mass it is called mass percentage (w/w).
Suppose we have a solution containing
component A as the solute and B as the
solvent, then its mass percentage is
expressed as:

Example #1
Determine the volume/volume percent solution made by
combining 25 mL of ethanol with enough water to produce
200 mL of the solution.
• Solution
• Given parameters are
• Volume of solute is 25 mL
• Volume of the solution is 200 mL
• Substitute the values in the given formula,
• Volume percent = volume of solute /volume of solution x
100%
• = {25 mL / 200 mL }x 100%
• Volume percent = 12.5 %
• Example 2
• A solution is prepared by dissolving 90 mL of
hydrogen peroxide in enough water to make 3000 mL
of solution. Identify the concentration of the
hydrogen peroxide solution.
• Solution
• The given parameters are
• Volume of solute is 90 mL
• Volume of solution is 3000 mL
• Substitute the values in the given formula,
• Volume percent = volume of solute /volume of
solution x 100%
• = 90 mL/ 3000mL x 100%
• Volume percent = 3 %
Example #3
25 g of urea was dissolved
in 500g of water. Calculate
the percentage by mass of
urea in the solution.
• Molarity or molar
concentration is the number
of moles of solute per liter of
solution, which can be
calculated using the following
equation:
• A chemist has a jar
containing 388.2 g of
iron filings. How many
moles of
• iron does the jar
contain?
• 64.1 g of aluminum ans
• 850.5 g of zinc ans:
Importance of Calculating Molarity
• Molarity is very important in chemistry for
one big reason. It is the measurement of
concentration in any mixture. The molarity of
any solution is a way to know the specific
elements or compounds which are present in
any solution. To calculate molarity, you divide
the miles of a solute by the number of litters of
its solutions. With molarity calculation, you can
easily identify the exact amount of any element
or compound in a solution.
Sample Problems

#1. What is the molarity of a solution


that contains 4.53 moles of lithium
nitrate in 2.85 liters of solution?
Sample Problems

#1. What is the molarity of a solution


that contains 4.53 moles of lithium
nitrate in 2.85 liters of solution?

4.53 mol LiNO3 = 1.59 M LiN03
• 2.85 L soln

#2. Calculate the molarity if a flask
contains 1.54 moles potassium sulfate
in 125 ml of solution.

#2. Calculate the molarity if a flask
contains 1.54 moles potassium sulfate
in 125 ml of solution.

1.54 mol K2SO4 = 12.3 M K2SO4
• 0.125 L soln

• Molality is a measure of number of
moles of solute present in 1 kg of
solvent. A commonly used unit for
molality in chemistry is mol/kg. A
solution of concentration 1 mol/kg is
also sometimes denoted as 1 molal.
• 1. What is the molality of a
solution if 1.57 moles of
solute dissolved to make a
2.35 kilograms of solution?
2.) 45.7 g of magnesium
chloride (MgCl2) is dissolved
in 2.40 kg of water. What is
the molality (m) of the
solution?
• 15.8 g of KCl is dissolved in
225 mL of water. Calculate
the molarity.
5

• 15.8/74= .21mol/.225= .93M


Finished.

or .93mol/L
• 3.50 g of NaCl is dissolved
in 250.0 mL of water.
Calculate the
concentration.

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