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CHEMISTRY-11-03 - (12th & 13) (POI) Paper-1
CHEMISTRY-11-03 - (12th & 13) (POI) Paper-1
PART-A
Q.34 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The pka
of –COOH group in methionine is 2.8 and pkb of basic group is 4.8. Pick out only incorrect statement
among the following. [Use log 2 = 0.3]
(A) pH of original amino acid solution was ~ 2.05
(B) pH of solution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH of solution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
Q.35 Which of the following compound(s) will give blue colour when it is converted into Lassaigne's extract
and FeSO4 is added followed by FeCl3.
(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV
Q.37 The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min –1) for the rate of
disappearance of N2O5 is
2.303 2.303 100 2.303 90 100
(A*) (B) log (C) log (D)
500 500 90 500 100 10 500
Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?
Product is:
Q.43 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
Q.45 Which of the following will racemize in presence of acid or base impurities in aqueous medium.
CH 3 H
| |
(A) Me C C Ph (B) Me C CH 2 C CH 3
|| | || |
O Cl O D
H
|
(C) (D*) Ph C C CH 2 CH 3
|| |
O CH 3
Q.46 (X) + K2CO3 + Air Heat (Y)
(Y) + Cl2 (Z) Pink
Which of the following is correct?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y = colourless KBiO2, Z = KBiO3
(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I
Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question you are required to choose any one of the following responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertion is true but the reason is false.
(D) If assertion is false but the reason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason : – H of carbonyl compounds are active (acidic). [Ans. D]
Q.51 PhCHO & HCHO will behave differently with which of the following reagents
(A) Tollen's Reagent (B*) Fehling Solution (C)Schiff's reagent (D) NaBH4
(A*) chain isomers (B) positional isomers (C) conformers (D) enantiomers
Q.54 FeSO4 is a very good absorber for NO, the new compound formed by this process is found to contain
number of unpaired electrons
(A) 4 (B) 5 (C*) 3 (D) 6
Q.57 Which of the following heptanols are chiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A) All are chiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol
Q.58 What products are formed during, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) I only (B) I & II only (C) I & III only (D*) I, II & III
NaNO
2 P
HCl
(A*) (B)
(C) (D)
Q.60 The product Octalone is obtained by Michael addition followed by aldol condensation of reactants R
and S in presence of a base. S gives positive iodoform test.
B ,
R + S
Octalone
R and S are respectively:
(C*) + CH 2 CH C CH 3 (D) + CH 3 CH 2 C CH 3
|| ||
O O
Q.62 Which of the following metals are obtained by auto reduction method:
Pb, Mn, Cu, Cr, Fe, Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu
O
||
(I) (II) OHC C C CH 2 C CHO
|| ||
O O
O
||
(III) CHO (IV) OHC C C CH 2 CH O
| ||
CHO O
(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV
CH ONa
Q.64 In the reaction; 3 ; the product is
CH 3OH
HBr
Q.66 CH2=CH–CH2–CH2–CCH ( Product is
1eq )
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C) CH 2 CH CH 2 CH 2 C CH 2 (D*) CH 3 CH CH 2 CH 2 C CH
| |
Br Br
P A P ER - 1
PART-A
Q.34 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The pka
of –COOH group in methionine is 2.8 and pkb of basic group is 4.8. Pick out only incorrect statement
among the following. [Use log 2 = 0.3]
(A) pH of original amino acid solution was ~ 2.05
(B) pH of solution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH of solution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
Q.35 Which of the following compound(s) will give blue colour when it is converted into Lassaigne's extract
and FeSO4 is added followed by FeCl3.
(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV
Q.37 The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min –1) for the rate of
disappearance of N2O5 is
2.303 2.303 100 2.303 90 100
(A*) (B) log (C) log (D)
500 500 90 500 100 10 500
Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?
Product is:
Q.43 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
Q.45 Which of the following will racemize in presence of acid or base impurities in aqueous medium.
CH 3 H
| |
(A) Me C C Ph (B) Me C CH 2 C CH 3
|| | || |
O Cl O D
H
|
(C) (D*) Ph C C CH 2 CH 3
|| |
O CH 3
Q.46 (X ) + K 2CO3 + Air Heat
(Y)
(Y) + Cl2 (Z) Pink
Which of the following is correct?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y = colourless KBiO2, Z = KBiO3
(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I
Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question you are required to choose any one of the following responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertion is true but the reason is false.
(D) If assertion is false but the reason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason : – H of carbonyl compounds are active (acidic). [Ans. D]
Q.51 PhCHO & HCHO will behave differently with which of the following reagents
(A) Tollen's Reagent (B*) Fehling Solution (C)Schiff's reagent (D) NaBH4
(A*) chain isomers (B) positional isomers (C) conformers (D) enantiomers
Q.54 FeSO4 is a very good absorber for NO, the new compound formed by this process is found to contain
number of unpaired electrons
(A) 4 (B) 5 (C*) 3 (D) 6
Q.57 Which of the following heptanols are chiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A) All are chiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol
Q.58 What products are formed during, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) I only (B) I & II only (C) I & III only (D*) I, II & III
NaNO
2 P
HCl
(A*) (B)
(C) (D)
Q.60 The product Octalone is obtained by Michael addition followed by aldol condensation of reactants R
and S in presence of a base. S gives positive iodoform test.
B ,
R + S
Octalone
R and S are respectively:
(C*) + CH 2 CH C CH 3 (D) + CH 3 CH 2 C CH 3
|| ||
O O
Q.62 Which of the following metals are obtained by auto reduction method:
Pb, Mn, Cu, Cr, Fe, Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu
O
||
(I) (II) OHC C C CH 2 C CHO
|| ||
O O
O
||
(III) CHO (IV) OHC C C CH 2 CH O
| ||
CHO O
(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV
CH ONa
Q.64 In the reaction; 3 ; the product is
CH 3OH
HBr
Q.66 CH2=CH–CH2–CH2–CCH ( Product is
1eq )
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C) CH 2 CH CH 2 CH 2 C CH 2 (D*) CH 3 CH CH 2 CH 2 C CH
| |
Br Br