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Answer Test-1 ON CARBONYL COMPOUNDS.
Answer Test-1 ON CARBONYL COMPOUNDS.
ORGANIC CHEMISTRY
(Topic : Carbonyl Compounds)
(for JEE-Mains & Advanced 2023)
Time : 30 : 00 Min. Max. Marks : 60
* Each question + 4 (for correct answer) & - 1 (for wrong answer)
=============================================================================================================
01. The major product obtained in following reaction is
O
_
+
i)
OH ii) H
O
OH OH COOH
(a) (b)
COOH
O
*(c) OH (d)
COOH COOH
02. What is the major product obtained from the following reaction ?
CN
+
i)
H3O ii) heat
O
COOH COOH CH2 —OH
(a) (b) *(c) (d)
OH O O
O
03. An aldehyde (A) can perform Cannizzaro reaction. (A) on treatment with Brady’s re-
agent gives
Me
(c) Ph CH2 CH = N NH CO NH2 *(d)
CH = N NH—— NO2
NO2
page no # 5
O
05. Ph—MgBr (1mole) + (CH3)2 CH— C —Cl [X] Zn—Hg/
HCl
[Y]
_
06. O CHO OH
(A) , (A) is :
CHO CHO
_
O CH2 OH O COO
*(a) +
COO _ CH2 OH COO _ CH2 OH
_
O CH2 OH O COO
(b) +
COO _
CH OH CH2 OH
2 C OO _
O CHO O CHO
(c) (d)
COO _ CH2 OH O
O
O
*(a) (b)
COOH
OH OH
(c) (d)
OH
08. In the given transformation which of the following is the most appropriate reagent “
page no # 6
09. The intermediate formed in aldol reaction is :
(a) carbocation whose +ve charge is stabilised by resonance .
(b) carbocation whose +ve charge is not stabilised by resonance .
*(c) carbanion whose —ve charge is stabilised by resonance .
(d) carbanion whose —ve charge is not stabilised by resonance .
CH2 Cl
10. aq.
NaOH
Product is :
Br CHO
O O
OH OH
OH
Br
HO COONa
*(a) (b)
O O
CH=O
Cl Cl Cl
OH HO CHO
HO HO COONa
(c) + (d)
O O
CH=O CH=O
*(a) — (b)
O
N _
(c) (d) p—TsO
N
O
page no # 7
Me
HO N
12. C OH Conc.
H2SO4
Product is :
Me
O
*(a) NH——C——
O
(b) NH——C——
O
(c) C——NH——
O
(d) C——NH——
+
14. i)
Mg, ether ii) Methyl ethanote, then H3O
(excess)
HO
OH
OH
HO
CH3
page no # 8