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Assignment 07 ON CARBONYL COMPOUNDS
Assignment 07 ON CARBONYL COMPOUNDS
Assignment # 07
ORGANIC CHEMISTRY
(Topic: Carbonyl Compounds)
(for JEE-Mains & Advanced 2024)
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Q.1 Among the following acids :
Me
(A) HCOOH (B) PhCOOH (C) Me COOH (D)
COOH
COOH Me
(E) Et3C – COOH (f) (G) COOH
Me
Me
(H) PhCH2COOH
‘n1’ no. of acids are not capable to perform HVZ reaction with Br2/red P
Consider the following reaction sequence
Me
N
1 eq. semicarbazide
CH=O (P)
O
O
Cl
(a) O
O
O
O COOH
Cl
(b) O (c)
Cl
O
COOH + COOH
(d)
Cl Cl
page no # 1
Q.3 KCN
PhCH2Br H3 O
(A) (B)
(B) on reaction with Br2/red P gives :
H
O
CH2COOH
(c) (d) Br C
Br pH
HOOC OH
O O
O O O
O O O
(a) (b) (c) (d)
Et Me Et Et Me
Me Me Et
HOOC
COOH
Q.5 OH Product is :
HO
O O COOH
(a) O (b)
HOOC O
O
HOOC O
HOOC
(c) (d) O
O
+
Q.6 n—BuCOOMe MeONa Product is :
O
OMe
(a) (b) OMe
O O O
O
O O
OMe
(c) O Me (d)
O
O
page no # 2