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Enthuse Med Minor-03 21 May So
Enthuse Med Minor-03 21 May So
PHASE : 1 To
COURSE
TARGET : PRE-MEDICAL 2024
ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 3 1 1 3 3 2 2 3 3 4 2 2 2 1 1 3 4 3 4 1 4 1 4 4 1 1 2 3 2 1
Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 2 3 1 2 2 4 3 1 4 2 2 1 1 3 2 4 3 3 2 1 2 2 1 2 2 2 4 2 1 4
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. 3 3 2 4 4 1 2 3 4 3 4 4 4 1 3 3 1 2 4 3 2 4 2 2 3 3 4 2 4 2
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. 4 4 2 2 2 4 2 1 2 3 3 3 1 2 3 3 2 2 1 3 3 2 2 4 4 3 3 3 3 3
Q. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150
A. 4 2 4 4 2 4 1 3 4 3 1 2 3 3 2 3 1 4 1 2 1 4 3 2 4 2 1 3 2 4
Q. 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
A. 2 4 1 3 3 2 2 3 3 3 1 2 3 2 4 4 1 1 4 2 3 3 3 3 4 2 2 2 1 2
Q. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
A. 3 2 4 4 2 3 3 4 2 3 2 4 2 2 4 4 3 3 1 3
HINT – SHEET
2. Ans ( 1 )
F = G(3)(1) ( 11 + 14 + 16
1
+. . . . . . . . . . ∞) = 4G
3. Ans ( 1 )
GMr G4πR3 ρr 4π Gρ r
g= = =
R 3 3R 3 3
4. Ans ( 3 )
dp
F= = 8t − 2
dt
at t = 1 sec, F = 8 – 2 = 6 N
T1 cosθ1 = mg .......(i)
5. Ans ( 3 )
II = 1 × 10–3 × 0.25 = 25 × 10–5 NS T1 sinθ1 = mg .......(ii)
III = 1 × 2 × 10–3 × 0.3 = 3 × 10–4 NS by squaring and adding
2
T12 (sin2 θ1 + cos2 θ1 ) = 2(mg)2
IIII = 1 –3
× 1 × 10 × 1 = 5 × 10 NS –4
2 ∴ T1 = √2mg
1
IIv = × 1 × 10–3 × 1 = 5 × 10–4 NS
2
1015CMD303361230017 HS-1/6
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1015CMD303361230017 HS-3/6
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Rate of reaction =
−1 d[A] d[B] d[C] d[D]
=− = =
2 dt dt dt dt
Let rate of reaction = k[A]a[B]b
d[C]
Or, = k[A]a [B]b
dt
Using the data given 74. Ans ( 1 )
–3
1.2 × 10 = k[0.1]a[0.1]b ....(i) For zero order t1/2 ∝ [conc.]0
1.2 × 10–3 = k[0.1]a[0.2]b ....(ii) 75. Ans ( 3 )
2.4 × 10 –3
= k[0.2]a[0.1]b ....(iii) For nth order reaction r = K[A]n
r (Molar/s)
From equation (i) and (ii) K = n =
[A] (Molar)n
a b
1.2 × 10−3
=
k[0.1] [0.1]
⇒b=0 = (Molar)1 – n s–1
1.2 × 10−3 k[0.1]a [0.2]b 1−n
= ( mol ) s−1
From equation (i) and (iii) L
a b mol1 – n Ln – 1 s–1
1.2 × 10−3 k[0.1] [0.1]
= ⇒a=1
2.4 × 10−3 k[0.2]a [0.1]b 76. Ans ( 3 )
d[C] For an elementary reaction, order of reaction =
Thus, = k[A]1 [B]0
dt stoichiometric coefficient.
70. Ans ( 3 ) 78. Ans ( 2 )
Note : Correct the reactions given in question [A]0 – [A] = kt
as [A]0 − [A]
K=
X2 ⇌ X + X (fast) t
X + Y2 → XY + Y (slow) 79. Ans ( 4 )
2X¯ + Y2 → 2Y– + X2 → EYo 2|Y − > EXo 2|X −
Slow step is the rate determining step.
2Z¯ + X2 → 2X¯ + Z2 → EXo 2|X − > EZo2|Z −
Rate = k[X] [Y2] ...(i)
2W¯ + Y2 → no reaction ⇒ EWo 2|W − > EYo 2|Y −
[X]2
Equilibrium constant for fast step, K =
[X2 ] SECTION-B
[X] = √K[X ] 2 93. Ans ( 2 )
By substituting [X] in equation (i), we get K = A ⋅ e−Ea /RT
Rate = k√K[X2 ] [Y2 ] = k′ [X2 ]1/2 [Y2 ] Given K = A · e–1000
1 3 Ea
∴ Order of reaction = + 1 = = 1.5 = 1000
2 2 RT
71. Ans ( 4 ) 94. Ans ( 2 )
For zero order reaction C0 – Ct = Kt The value of rate constant of a pseudo first order
If Ct = 0.5 M ; t = 25 sec ; K = 2 × 10–2 then reaction depends on temperature as well as on
C0 = 1.0 M concentration of reactant present in excess, e.g.,
hydrolysis of ethyl acetate.
HS-4/6 1015CMD303361230017
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HS-6/6 1015CMD303361230017