Conforms to HazCom 2012/United States

SAFETY DATA SHEET

141 BioTreat™ Premium Diesel

Section 1. Identification
GHS product identifier : 141 BioTreat™ Premium Diesel
Other means of : Not available.
identification
Product type : Liquid.
Identified uses
Fuel additive for diesel and biodiesel fuels.

Supplier's details : Schaeffer Mfg. Company

102 Barton Street
Saint Louis, Missouri 63104
Tel: 314-865-4100
Fax: 314-865-4107
Toll Free: 1-800-325-9962
E-Mail: [email protected]
Web: http://www.schaefferoil.com

Emergency telephone : +1 314 865-4105 (24-hour response number)

number (with hours of
operation)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
CARCINOGENICITY - Category 2
ASPIRATION HAZARD - Category 1
AQUATIC HAZARD (ACUTE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 2
GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : Flammable liquid and vapor.
Harmful if swallowed or in contact with skin.
Causes serious eye damage.
Causes skin irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
Toxic to aquatic life with long lasting effects.

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Section 2. Hazards identification
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Wear protective clothing. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.
Use only non-sparking tools. Take precautionary measures against static discharge.
Keep container tightly closed. Avoid release to the environment. Do not eat, drink or
smoke when using this product. Wash hands thoroughly after handling.
Response : Collect spillage. IF exposed or concerned: Get medical attention. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Call a
POISON CENTER or physician if you feel unwell. Take off contaminated clothing. If
skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Ingredient name % CAS number
Light aromatic petroleum naphtha 30 - 60 64742-95-6
2-Ethylhexyl nitrate 10 - 30 27247-96-7
Solvent naphtha (petroleum), heavy aromatic 10 - 30 64742-94-5
1,2,4-Trimethylbenzene 10 - 30 95-63-6
2-Butoxyethanol 5 - 10 111-76-2
2,4-Di-tert-butylphenol 1-5 96-76-4
2,6-Di-tert-butylphenol 1-5 128-39-2
2-tert-Butylphenol 1-5 88-18-6
Naphthalene 1-5 91-20-3

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns
must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain

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Section 4. First aid measures
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty
of soap and water. Wash contaminated clothing thoroughly with water before removing
it, or wear gloves. Continue to rinse for at least 20 minutes. Chemical burns must be
treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory
system. Exposure to decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
Skin contact : Harmful in contact with skin. Causes skin irritation.
Ingestion : Harmful if swallowed. May be fatal if swallowed and enters airways. May cause burns
to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No known significant effects or critical hazards.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

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Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing : Use dry chemical, CO2, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet or water-based fire extinguishers.
media

Specific hazards arising : Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. This material is toxic to aquatic life with long lasting
effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Move containers from fire area if this can be done without risk. Use water spray to keep
for fire-fighters fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

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Section 7. Handling and storage
Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. See also Section 8 for additional information on hygiene
measures. Remove contaminated clothing and protective equipment before entering
eating areas.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

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Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Light aromatic petroleum naphtha NIOSH REL (United States, 1/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
Manufacturer (United States).
TWA: 40 ppm 8 hours.
1,2,4-Trimethylbenzene ACGIH TLV (United States, 6/2013).
TWA: 123 mg/m³ 8 hours.
TWA: 25 ppm 8 hours.
NIOSH REL (United States, 4/2013).
TWA: 125 mg/m³ 10 hours.
TWA: 25 ppm 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 25 ppm 8 hours.
TWA: 125 mg/m³ 8 hours.
2-Butoxyethanol ACGIH TLV (United States, 6/2013).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 4/2013). Absorbed through skin.
TWA: 24 mg/m³ 10 hours.
TWA: 5 ppm 10 hours.
OSHA PEL (United States, 2/2013). Absorbed through skin.
TWA: 240 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
Naphthalene ACGIH TLV (United States, 6/2013). Absorbed through skin.
STEL: 79 mg/m³ 15 minutes.
STEL: 15 ppm 15 minutes.
TWA: 52 mg/m³ 8 hours.
TWA: 10 ppm 8 hours.
NIOSH REL (United States, 4/2013).
STEL: 75 mg/m³ 15 minutes.
STEL: 15 ppm 15 minutes.
TWA: 50 mg/m³ 10 hours.
TWA: 10 ppm 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 50 mg/m³ 8 hours.
TWA: 10 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

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Section 8. Exposure controls/personal protection
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Dark.
Odor : Aromatic. [Slight]
Odor threshold : Not available.
pH : Not applicable.
Melting point/ Dropping : Not available.
Point
Boiling point : >148.88°C (>300°F)
Flash point : Closed cup: 55°C (131°F) [Pensky-Martens.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : <0.013 kPa (<0.1 mm Hg) [room temperature]
Vapor density : Not available.
Relative density : 0.922
Solubility : Dispersible.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.

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Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, reducing
materials, acids and alkalis.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Light aromatic petroleum naphtha LD50 Oral Rat 8400 mg/kg -
2-Ethylhexyl nitrate LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >10000 mg/kg -
1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³ 4 hours
LD50 Oral Rat 5 g/kg -
2-Butoxyethanol LC50 Inhalation Vapor Rat 450 ppm 4 hours
LD50 Dermal Rabbit 220 mg/kg -
LD50 Oral Rat 250 mg/kg -
2,4-Di-tert-butylphenol LD50 Dermal Rabbit 2200 mg/kg -
LD50 Oral Rat 1.5 g/kg -
2,6-Di-tert-butylphenol LD50 Dermal Rabbit >10 g/kg -
LD50 Oral Rat 1320 mg/kg -
2-tert-Butylphenol LC50 Inhalation Dusts and mists Rat 1070 mg/m³ 4 hours
LD50 Dermal Rabbit 7450 mg/kg -
LD50 Dermal Rat 705 mg/kg -
LD50 Oral Rat 440 mg/kg -
Naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Light aromatic petroleum naphtha Eyes - Mild irritant Rabbit - 24 hours 100 µL -
Solvent naphtha (petroleum), heavy Skin - Mild irritant Rabbit - 24 hours 500 µL -
aromatic
2-Butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 mg -
Eyes - Severe irritant Rabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
2,4-Di-tert-butylphenol Skin - Moderate irritant Rabbit - 0.5 Grams -
2,6-Di-tert-butylphenol Skin - Moderate irritant Rat - 0.5 Mililiters -
2-tert-Butylphenol Eyes - Severe irritant Rabbit - 4 hours 100 -
microliters
Skin - Severe irritant Rabbit - 4 hours 500 -
microliters
Naphthalene Skin - Mild irritant Rabbit - 495 mg -
Skin - Severe irritant Rabbit - 24 hours 0.05 mL -

Sensitization
There is no data available.
Carcinogenicity
There is no data available.
Classification
Product/ingredient name OSHA IARC NTP
2-Butoxyethanol - 3 -
Naphthalene - 2B Reasonably anticipated to be a human carcinogen.

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Section 11. Toxicological information
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
1,2,4-Trimethylbenzene Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
There is no data available.
Aspiration hazard
Name Result
Light aromatic petroleum naphtha ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), heavy aromatic ASPIRATION HAZARD - Category 1

Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory
system. Exposure to decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
Skin contact : Harmful in contact with skin. Causes skin irritation.
Ingestion : Harmful if swallowed. May be fatal if swallowed and enters airways. May cause burns
to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No known significant effects or critical hazards.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : No known significant effects or critical hazards.
effects
Potential delayed effects : No known significant effects or critical hazards.
Long term exposure
Potential immediate : No known significant effects or critical hazards.
effects
Potential delayed effects : No known significant effects or critical hazards.
Potential chronic health effects
General : No known significant effects or critical hazards.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
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Section 11. Toxicological information
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 1088.9 mg/kg
Dermal 1486.5 mg/kg
Inhalation (vapors) 28.84 mg/L
Inhalation (dusts and mists) 53.5 mg/L

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
1,2,4-Trimethylbenzene Acute LC50 4910 µg/l Marine water Crustaceans - Elasmopus pectenicrus - 48 hours
Adult
Acute LC50 22.4 mg/L Fresh water Fish - Tilapia zillii 96 hours
2-Butoxyethanol Acute EC50 >1000 mg/L Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1000 mg/L Marine water Crustaceans - Chaetogammarus marinus - 48 hours
Young
Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours
Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours
Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - Larvae 96 hours
Chronic NOEC 0.67 ppm Fresh water Fish - Oncorhynchus kisutch 40 days

Persistence and degradability

There is no data available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
2-Ethylhexyl nitrate 5.24 - high
Solvent naphtha (petroleum), heavy 2.8 to 6.5 99 to 5780 high
aromatic
1,2,4-Trimethylbenzene 3.63 243 low
2-Butoxyethanol 0.81 - low
2,4-Di-tert-butylphenol 4.8 251.19 low
2,6-Di-tert-butylphenol 4.5 - high
2-tert-Butylphenol 3.31 78 low
Naphthalene 3.4 36.5 to 168 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe
way. Care should be taken when handling empty containers that have not been cleaned
or rinsed out. Empty containers or liners may retain some product residues. Vapor
from product residues may create a highly flammable or explosive atmosphere inside
the container. Do not cut, weld or grind used containers. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

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Section 13. Disposal considerations

United States - RCRA Toxic hazardous waste "U" List

Ingredient CAS # Status Reference
number
Naphthalene 91-20-3 Listed U165

14. Transport information

Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification UN1993 FLAMMABLE LIQUIDS, N. 3 III This product may be re-
O.S. (Light aromatic classified as "Combustible
petroleum naphtha, 1,2, Liquid," unless transported
4-Trimethylbenzene). by vessel or aircraft. Non-
Marine pollutant bulk packages (less than or
(2-Ethylhexyl nitrate, 2,4-Di- equal to 119 gal) of
tert-butylphenol) RQ combustible liquids, that are
(Naphthalene, Xylene) marine pollutants, are not
regulated as hazardous
materials in package sizes
less than the product
reportable quantity, unless
transported by vessel.

The marine pollutant mark

is not required when
transported on inland
waterways in sizes of ≤5 L
or ≤5 kg or by road, rail, or
inland air in non-bulk sizes.

Reportable quantity
At all time please check for
possible RQ (Reportable
Quantities)

IMDG Class UN1993 FLAMMABLE LIQUIDS, N. 3 III The marine pollutant mark
O.S. (Light aromatic is not required when
petroleum naphtha, 1,2, transported in sizes of ≤5 L
4-Trimethylbenzene). or ≤5 kg.
Marine pollutant
(2-Ethylhexyl nitrate, 1,2,
4-Trimethylbenzene)

IATA-DGR Class UN1993 FLAMMABLE LIQUIDS, N. 3 III The environmentally

O.S. (Light aromatic hazardous substance mark
petroleum naphtha, 1,2, may appear if required by
4-Trimethylbenzene) other transportation
regulations.

PG* : Packing group AERG : 128

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL
73/78 and the IBC Code

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Section 15. Regulatory information
U.S. Federal regulations : TSCA 8(a) PAIR: Naphthalene; 2-tert-Butylphenol
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 307: Naphthalene
Clean Water Act (CWA) 311: Xylene; Naphthalene

Clean Air Act Section 112 : Listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
2-Ethylhexyl nitrate 10 - 30 Yes. No. No. Yes. No.
1,2,4-Trimethylbenzene 10 - 30 Yes. No. No. Yes. No.
2-Butoxyethanol 5 - 10 No. No. No. Yes. No.
2,4-Di-tert-butylphenol 1-5 No. No. No. Yes. No.
2,6-Di-tert-butylphenol 1-5 No. No. No. Yes. No.
2-tert-Butylphenol 1-5 No. No. No. Yes. No.
Naphthalene 1-5 Yes. No. No. Yes. Yes.

SARA 313
Product name CAS number %
1,2,4-Trimethylbenzene 95-63-6 10 - 30
Form R - Reporting 2-Butoxyethanol 111-76-2 5 - 10
requirements Naphthalene 91-20-3 1-5
1,2,4-Trimethylbenzene 95-63-6 10 - 30
Supplier notification 2-Butoxyethanol 111-76-2 5 - 10
Naphthalene 91-20-3 1-5

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

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 141 BioTreat™ Premium Diesel
Section 15. Regulatory information
State regulations
Massachusetts : The following components are listed: 1,2,4-Trimethylbenzene; Naphthalene;
2-Butoxyethanol
New York : The following components are listed: Cumene; Naphthalene
New Jersey : The following components are listed: 1,2,4-Trimethylbenzene; Cumene; Naphthalene;
2-Butoxyethanol
Pennsylvania : The following components are listed: 1,2,4-Trimethylbenzene; Cumene; Naphthalene;
2-Butoxyethanol
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
Naphthalene Yes. No. Yes. No.
Cumene Yes. No. No. No.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 2 * Flammability : 2 Physical hazards : 0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards
or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings
are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).
HMIS® materials may be purchased exclusively from J. J. Keller.

The customer is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

Health : 2 Flammability : 2 Instability : 0
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National
Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection
Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only
by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of
chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are
classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

US Tariff Heading Number : 3811.90.0000

Schedule B Code : 3811.90.0000

History
Date of issue mm/dd/yyyy : 05/15/2014
Version : 1
Revised Section(s) : Not applicable.
Prepared by : KMK Regulatory Services Inc.
Although the information and recommendations set forth herein (hereafter referred to as information) are presented in good faith and believed to be
accurate and factual as of the date hereof, Schaeffer Mfg. Company makes no representation as to the completeness or accuracy thereof. Information is
supplied upon the condition that the person receiving the same will make their own determination as to its safety and suitability for their purposes prior to
use. In no event will Schaeffer Mfg. Company be responsible for damages of any natures whatsoever resulting from the use or reliance upon information.
No representation or warranty, either expressed or implied, of merchantability or fitness for a particular purpose is made with respect to
information of the product to which the information refers. Compliance with all applicable federal, state, and local regulations remains the
responsibility of the user.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)

www.kmkregservices.com www.askdrluc.com www.ghssmart.com

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