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IIT-JEE/NEET

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CHEMISTRY Redox reactions DPP-1

1. In which of the following reaction H2O2 acts as a reducing agent?


(1) H2O2 + 2H+ + 2e– → 2H2O
(2) H2O2 -2e– → O2+2H+
(3) H2O2 + 2e– → 2OH–
(4) H2O2 + 2OH– -2e– → O2 + 2H2O
(a) (1), (3) (c) (1), (2)
(b) (2), (4) (d) (3), (4)

2. Which of the following reactions is an example of a redox reaction?


(1) XeF4 + O2F2 → XeF6 + O2 (3) XeF6 + H2O → XeOF4 + 2HF
(2) XeF2 + PF5 → [XeF]+ PF6– (4) XeF6 + 2H2O → XeO2F2 + 4HF

3. Which of the following is a redox reaction?


(1) NaCl + KNO3 → NaNO3 + KCl (3) Mg(OH)2 + 2NH4C1 → MgCl2 + 2NH4OH
(2) CaC2O4 + 2HCl → CaCl2 + H2C2O2, (4) Zn + 2AgCN → 2Ag + Zn (CN)2

4. What is the change in oxidation number of carbons in the following reaction?


CH4(g) + 4Cl2 (g) ⟶ CCl4(l) + 4HCl(g) (NEET 2020)
1) 0 to –4 (2) +4 to +4 (3) 0 to +4 (4) –4 to +4

5. The correct order of N-compounds in its decreasing order of oxidation states is (NEET 2018)
(a) HNO3, NO, N2, NH4Cl (b) HNO3, NO, NH4Cl, N2
(c) HNO3, NH4Cl, NO, N2 (d) NH4CI, N2, NO, HNO3

6. Hot concentrated Sulphuric acid is a moderately strong oxidizing agent. Which of the following
reactions does not show oxidizing behavior? (NEET 2016)
(a) Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O (b) S + 2H2SO4 → SO2 + 2H2O
(c) C + 2H2SO4 → CO2 + 2SO2 + 2H2O (d) CaF2 + 2H2SO4 → CaSO4 + 2HF

7. (I) H2O2 + O3 → H2O + 2O2


(II) H2O2 + Ag2O → 2Ag + H2O + O2
Role of hydrogen peroxide in the above reactions is respectively

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(a) oxidizing in (l) and reducing in (II) (b) reducing in (l) and oxidizing in (II)
(c) reducing in (I) and (II) (d) oxidizing in (I) and (II)

8. In acidic medium, H2O2 changes Cr2O72- to CrO5. Oxidation state of Cr in CrO5 is (AIPMT
2014)
(a) +5 (b) +3 (c) +6 (d) -10

9.A mixture of potassium chlorate, oxalic acid and Sulphuric acid is heated. During the reaction
which element undergoes maximum change in the oxidation number? (AIPMT 2012)
(a) S (b) H (c) Cl (d) C

10. The oxidation state of phosphorus in hypo phosphoric acid is +---------- (JEE 2023)

11.The difference in oxidation state of chromium in chromate and dichromate salts is………. (JEE
2022).

12. Which of the given reactions is not an example of disproportionation reaction? (JEE 2022)
(A) 2H2O2 → 2H2O + O2 (B) 2NO2 + H2O → HNO3 + HNO2
(C) MnO4– + 4H+ + 3e– → MnO2 + 2H2O (D) 3MnO42– + 4H+ → 2MnO4– + MnO2 + 2H2O

13. Which one of the following is an example of disproportionation reaction? (JEE 2022)

14. The oxidation states of 'P' in H4P2O7, H4P2O5 and H4P2O6, respectively, are: (JEE 2021)
(1) 7, 5 and 6 (2) 5, 4 and 3 (3) 5, 3 and 4 (4) 6, 4 and 5

15. Identify the process in which change in the oxidation state is five(JEE 2021)
(i) Cr2O2-7 → 2Cr3+ (ii) MnO4- → Mn2+ (iii) CrO42- → Cr3+ (iv) C2O42-→ 2CO

16. The oxidation states of nitrogen in NO, NO2, N2O and N2O3 are in the order of:
-
1) NO2 < NO < N2O3 < N2O (2) N2O < NO < N2O3 < NO2
(3) NO2 < N2O3 < NO < N2O (4) N2O < N2O3 < NO

17. The compound that cannot act both as oxidizing and reducing agent is: (JEE 2020)
(1) H2O2 (2) H2SO3 (3) HNO2 (4) H3PO4

18. An example of a disproportionation reaction is: (JEE 2019)

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(A) 2KMnO4→K2MnO4 + MnO2 + O2
(B) 2MnO−4 +10I−+16H+ → 2Mn2+ +5I2 + 8H2O
(C) 2CuBr→CuBr2+Cu
(D) 2NaBr+Cl2→2NaCl+ Br2

ANSWERS

1.(B) 2. (A) 3. (D) 4.(D) 5.(A) 6.(D) 7.(C )8.(C) 9.(C) 10.(4) 11.(0) 12.(C) 13.(A) 14.(C )15(.B) 16.(B) 17.(A) 18. (C)

Our Centres:
Rourkela | Koelnagar | Basanti | Rajgangpur | Dalmiya Vidya Mandir |
Jharsuguda | Sarbahal | Vedanta | Bhushan | School Integrated Programs | DAV Bandhabahal | DAV Brajrajnagar
| DAV Basundhara | DAV Tensa | DAV Kalinga | DAV Dera |
Classroom Helpline No.: 8093626300, 9853705762, 8210001633

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