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Atomic Structure
Atomic Structure
1. Which of the following fact was proposed by Thomson in his atomic model?
(A) Concept of valence electron
(B) Loss or gain of electrons by atoms
(C) Movement of electrons along definite paths
(D) Concentration of positive charge at the centre of the atom
6. The electron configuration of an ion(X3+) is 2, 8, 1. How many electrons are present in the
valence shell of ‘X’?
(A) 1 (B) 2
(C) 4 (D) 6
7. Which of the following was discovered by the experiment in which alpha particles were
bombarded to a thin gold foil?
(A) Neutron (B) Electron
(C) Nucleus (D) Proton
8. Which of the following electron transition in hydrogen atom is accompanied with emission of
a radiation with the largest frequency?
(A) K L (B) L K
(C) M N (D) N M
10. The electron, identified by quantum number n and I (i) n = 4, I = 1 (ii) n = 4, I = 0 (iii) n = 3,
I = 2 (iv) n = 3, I = 1 can be placed in order of increasing energy from the lowest to highest
as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii).
11. If the nitrogen atom had electronic configuration 1s7, it would have energy lower than that of
the normal ground state configuration 1s22s22p3, because the electrons would be closer to
the nucleus. Yet 1s7 is not observed because it violated.
(A) Heisenberg uncertainty principal (B) Hund’s rule
(C) Pauli’s exclusion principle (D) Bohr postulates of stationary orbits.
15. Which of the following represents the incorrect set of the four quantum number of
4f-electrons?
1
(A) 4, 3, 2, + (B) 4, 2, 1, 0
2
1 1
(C) 4, 3, -2, (D) 4, 3, 1, -
2 2
16. The radial distribution curve of the orbital with double dumbbell shape in the 4th principle
shell consists of ‘n’ nodes, n is
(A) 2 (B) 0
(C) 1 (D) 3
18. The first emission line in the atomic spectrum of hydrogen in the Balmer Series appears at
9RH 7RH
(A) cm1 (B) cm1
400 144
3RH 5RH
(C) cm1 (D) cm1
4 36
19. When the frequency of light incident on a metallic plate is doubled, the KE of the emitted
photoelectron will be;
(A) Doubled ‘
(B) Halved
(C) Increased but more than doubled of the previous KE
(D) Remains unchanged
20. A bulb takes 10 seconds to dissociate all molecules in 104 moles of chlorine. Bond energy
of ClCl bond is 3.2 x 1017 Joule/molecule. Power of bulb is:
(A) 19.27 watt (B) 15.27 watt
(C) 192.7 watt (D) 152.7 watt
22. Time period of an e moving in 2nd Bohr orbit is x then time period of the e moving in 5th orbit
of same atom is
2 4
(A) x (B) x
5 25
125 8
(C) x (D) x
8 125
23. Frequency of an electron revolving in 3rd orbit of Hydrogen atom is f, then frequency of
electron revolving in 3rd orbit of Li2+ ion is
(A) 3 f (B) 9 f
(C) f/3 (D) f/9
24. Velocity of electron moving in 2nd orbit of hydrogen atom is , then velocity of electron
moving in 3rd orbit of He+ is
(A) (9/4) (B) (1/2)
(C) (9/8) (D) (4/3)
27. Energy of 5th orbit of a hydrogen like species is E, then the ionization energy will be
(A) E (B) E/2
(C) 25 E (D) 2.5 E
28. Energy needed to ionize Li2+ ion, which has its electron in 4th orbit is
(A) 13.6 eV (B) 122.4 eV
(C) 7.65 eV (D) 30.6 eV
29. Ratio of wavelengths of 1st to 3rd spectral line in Be3+ ion corresponding to Paschen series
is
20 3
(A) (B)
3 20
260 12
(C) (D)
180 7
31. The minimum energy required to escape out an e- from its ground state is called as
(A) Ionization potential (B) Separation energy
(C) Excitation energy (D) Kinetic energy
33. The radius ratio of two Bohr’s orbit of He+ is 9 : 25. Then what would be their nomenclature?
(A) K, L (B) M, N
(C) M, O (D) P, L
35. What is the separation energy of electron in Li2+ when it is escape out from fourth shell?
(A) 3.4 eV (B) 7.65 eV
(C) -13.6 eV (D) 0.85 eV
36. A 100W bulb emits a monochromatic light of wavelength 400 nm. Calculate the no. of
photons emitted/sec by the bulb.
(A) 2 x 1020 photon/sec (B) 6.62 x 1034 photon/sec
23
(C) 6.023 x 10 photon/sec (D) 4 x 104 photon/sec
38. What is ratio of time period of revolution of e- in 2nd and 3rd bohr orbit of Be+3 atom.
T 8 T 27
(A) 1 (B) 1
T2 27 T2 4
T 4 T 2
(C) 1 (D) 1
T2 9 T2 3
39. What is the ratio of velocity(V1/V2) of electron in 2nd orbit of Li+2(V1) and 3rd orbit of Be+3(V2)?
V 9 V 729
(A) 1 (B) 1
V2 8 V2 512
V 18 V 81
(C) 1 (D) 1
V2 90 V2 64
45. If the nitrogen atom has electronic configuration 1s7, it would have lower energy than that of
the normal ground state configuration 1s2 2s2 2p3 because the electrons would be closer to
the nucleus, yet 1s7 is not observed because it violates
(A) Heisenberg’s uncertainty principle (B) Hund’s rule
(C) Pauli’s exclusion principle (D) Bohr’s postulate of stationary orbits
47. The number of electrons in an atom with atomic number 105 having (n + l) = 8 are:
(A) 30 (B) 17
(C) 15 (D) unpredictable
A
1 2
(A) 3 = 1 + 2 (B) 3
1 2
(C) 1 + 2 + 3 = 0 (D) 23 12 22
50. An ion Mna+ has the magnetic moment equal to 4.9 BM. The value of a is:
(A) 3 (B) 4
(C) 2 (D) 5
51. The ratio of (E2 – E1) to (E4 – E3) for H-atom is approximately:
(A) 10.2 (B) 15.4
(C) 5.6 (D) 12.4
52. Which of the following gas should be used in the discharge tube experiment so that the
e
anode ray will have the largest value of ratio?
m
(A) Oxygen (B) Hydrogen
(C) Nitrogen (D) Neon
54. The third energy shell(M) of an atom contains six electrons. How many electrons are present
in its dinegative ion?
(A) 8 (B) 16
(C) 18 (D) 10
nh
55. The angular momentum of an electron in an atom is given by the formula , where ‘n’ is
2
the number of orbit along which the electron revolves. What is the angular momentum of the
valence electron of potassium?
h 3h
(A) (B)
2
2h h
(C) (D)
2
56. Which of the following atom with the given electron configuration can form positive ion with
supply of the lowest amount of energy?
(A) 2, 8, 5 (B) 2, 8, 1
(C) 2, 8, 6 (D) 2, 8, 2
57. The energy difference between which of the following orbit is maximum?
(A) K and L (B) L and M
(C) M and N (D) All have same energy difference
58. The dinegative ion of an atom contains 18 electrons. How many electrons are present in the
valence shell of the atom?
(A) 2 (B) 4 (C) 6 (D) 8
59. Which of the following atom attains the electronic configuration of an inert gas by losing two
electrons?
(A) Na (B) Ca
(C) Si (D) P