Professional Documents
Culture Documents
Material Safety Data Sheet: 1. Chemical Product and Company Identification
Material Safety Data Sheet: 1. Chemical Product and Company Identification
2. Hazards identification
Precaution:
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P284 - Wear respiratory protection.
Treatment:
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 - IF ON SKIN: Wash with plenty of water/….
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P308+P311 - IF exposed or concerned: Call a POISON CENTER/doctor/….
P310 - Immediately call a POISON CENTER/doctor/….
P314 - Get medical advice/attention if you feel unwell.
P321 - Take … treatment.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor/….
P362+P364 - Take off contaminated clothing and wash it before reuse.
P363 - Wash contaminated clothing before reuse.
Storage:
P405 - Store locked up.
Disposal:
P501 - Dispose of contents/container according to waste related regulations.
2.3. Hazards - Other hazards which do not result in classification - Hazard Risk
Not applicable
3. Composition/information on ingredients
Product form : Mixture
Titanium Dioxide C.I. 77891 / C.I. Pigment White 6 / CAS-No.: 13463-67-7 1–3
Titanium oxide (TiO2) / CI 77891 / KECI-No.: KE-33900
Titanium(IV) oxide / C.I. Pigment
White 7 / Pigment White 6 / Titanium
dioxide nanoparticles / TITANIUM
DIOXIDE / Titanium oxide / Titanium
dioxide(2)
4. First-aid measures
5. Fire-fighting measures
K-9018B3R
No data available
(12001-26-2)
Korea - Occupational Exposure Limits
(471-34-1)
Korea - Occupational Exposure Limits
OES TWA [1] 10 mg/m³ (containing no asbestos and <1% crystalline silica-inhalable dust)
CaF2 (7789-75-5)
China - Occupational Exposure Limits
(1344-09-8)
No data available
OES TWA [1] 10 mg/m³ (containing no asbestos and <1% crystalline silica-inhalable dust)
Iron (7439-89-6)
Korea - Occupational Exposure Limits
NAB (OEL TWA) 10 mg/m³ (not containing Asbestos and the crystal content is <1%)
OES TWA [1] 10 mg/m³ (containing no asbestos and <1% crystalline silica-inhalable dust)
Nickel (7440-02-0)
Korea - Occupational Exposure Limits
Nickel (7440-02-0)
China - Occupational Exposure Limits
BEI 5 μg/l Parameter: Nickel - Medium: urine - Sampling time: post-shift at end of workweek
(background)
IDLH 10 mg/m³
Chromium (7440-47-3)
Korea - Occupational Exposure Limits
Chromium (7440-47-3)
OEL PC-TWA (Highly Toxic Goods) 0.15 mg/m³
BEI 0.7 μg/l Parameter: Total chromium - Medium: urine - Sampling time: end of shift at end of
workweek (population based)
Molybdenum (7439-98-7)
Korea - Occupational Exposure Limits
Molybdenum (7439-98-7)
USA - IDLH - Occupational Exposure Limits
Respiratory protection:
Eye protection:
Safety glasses
Hand protection:
Protective gloves
(12001-26-2)
LD50 oral rat > 5000 mg/kg (Rat, Literature study, Oral)
(471-34-1)
LD50 oral rat > 2000 mg/kg bodyweight Animal: rat, Animal sex: female, Guideline: OECD Guideline
420 (Acute Oral Toxicity - Fixed Dose Method), Guideline: EU Method B.1 bis (Acute Oral
Toxicity - Fixed Dose Procedure)
LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity), Guideline: EU Method B.3 (Acute Toxicity (Dermal))
LC50 Inhalation - Rat > 3 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity),
Guideline: EU Method B.2 (Acute Toxicity (Inhalation)), Guideline: EPA OPPTS 870.1300
(Acute inhalation toxicity)
CaF2 (7789-75-5)
LD50 oral rat 4250 mg/kg
LC50 Inhalation - Rat > 5.07 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)
(1344-09-8)
LD50 oral rat 3400 mg/kg Source: SIDS
LD50 dermal rat > 5000 mg/kg bodyweight Animal: rat, Guideline: EPA OPPTS 870.1200 (Acute Dermal
Toxicity)
LC50 Inhalation - Rat > 2.06 mg/l air Animal: rat, Guideline: EPA OPPTS 870.1300 (Acute inhalation toxicity)
LC50 Inhalation - Rat > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
Iron (7439-89-6)
LD50 oral rat 98600 mg/kg bodyweight Animal: rat, Animal sex: male, Guideline: OECD Guideline 401
(Acute Oral Toxicity)
LC50 Inhalation - Rat > 250 mg/m³ air (6 h, Rat, Male, Experimental value, Inhalation (dust))
Nickel (7440-02-0)
LD50 oral rat > 9000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral
Toxicity)
Chromium (7440-47-3)
LD50 oral rat > 5000 mg/kg bodyweight (Equivalent or similar to OECD 420, Rat, Male / female, Read-
across, Oral, 14 day(s))
LC50 Inhalation - Rat > 5.41 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)
Molybdenum (7439-98-7)
LD50 oral rat > 2000 mg/kg Source: ECHA
LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Skin corrosion/irritation:
Causes severe skin burns.
Respiratory sensitization:
May cause allergic reactions, asthma or shortness of breath and etc if inhaled.
Skin sensitization:
May cause an allergic skin reaction.
Carcinogenicity:
Not classified
Titanium Dioxide (13463-67-7)
IARC group 2B - Possibly carcinogenic to humans
Nickel (7440-02-0)
IARC group 2B - Possibly carcinogenic to humans
Chromium (7440-47-3)
IARC group 3 - Not classifiable
Mutagenicity:
Not classified
Reproductive toxicity:
Not classified
STOT-single exposure:
May cause damage to organs.
STOT-repeated exposure:
May cause damage to organs through prolonged or repeated exposure.
(471-34-1)
NOAEL (oral, rat, 90 days) 1000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 422 (Combined
Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening
Test)
NOAEC (inhalation, rat, dust/mist/fume, 90 days) ≥ 0.212 mg/l air Animal: rat, Guideline: OECD Guideline 413 (Subchronic Inhalation
Toxicity: 90-Day Study)
Nickel (7440-02-0)
LOAEC (inhalation, rat,dust/mist/fume, 90 days) 0.004 mg/l air Animal: rat, Guideline: OECD Guideline 412 (Subacute Inhalation Toxicity:
28-Day Study)
Chromium (7440-47-3)
LOAEC (inhalation, rat,dust/mist/fume, 90 days) ≥ 0.0044 mg/l air Animal: rat, Guideline: OECD Guideline 413 (Subchronic Inhalation
Toxicity: 90-Day Study)
Molybdenum (7439-98-7)
NOAEC (inhalation, rat, dust/mist/fume, 90 days) > 0.1 mg/l air Animal: rat, Guideline: OECD Guideline 413 (Subchronic Inhalation Toxicity:
90-Day Study)
STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard:
Not classified
(471-34-1)
Viscosity, kinematic (calculated value) (40 °C) Not applicable (solid)
CaF2 (7789-75-5)
Density 3.18 g/cm³ Type: 'density'
(1344-09-8)
Density 1350 – 1380 kg/m³
Iron (7439-89-6)
Density 7.87 g/cm³ Type: 'density' Temp.: 20 °C
Nickel (7440-02-0)
Viscosity, kinematic (calculated value) (40 °C) Not applicable (solid)
Chromium (7440-47-3)
Density 7.19 g/cm³ (at 20 °C)
Molybdenum (7439-98-7)
Density 10.2 g/cm³ (at 20 °C)
12.1. Ecotoxicity
Ecology - general : Before neutralisation, the product may represent a danger to aquatic organisms.
(471-34-1)
LC50 - Fish [1] > 56000 mg/l Source: ECOTOX
EC50 - Crustacea [1] > 100 % (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, Locomotor effect)
EC50 96h - Algae [1] 22000 mg/l Source: Ecological Structure Activity Relationships
EC50 72h - Algae [1] > 14 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
ErC50 algae > 100 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, Nominal concentration)
CaF2 (7789-75-5)
LC50 - Fish [1] 51 mg/l Test organisms (species): other:summary of finidngs in various species
LC50 - Fish [2] 165 mg/l Test organisms (species): other:summary of finidngs in various species
EC50 - Crustacea [1] 97 – 270 mg/l (48 h, Daphnia magna, Static system, Fresh water, Literature, Fluorine ion)
EC50 96h - Algae [1] 7444.076 mg/l Source: Ecological Structure Activity Relationships
EC50 72h - Algae [1] > 100 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names:
Raphidocelis subcapitata, Selenastrum capricornutum)
NOEC (chronic) 14.1 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
NOEC chronic fish 4 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri)
Duration: '21 d'
(1344-09-8)
LC50 - Fish [1] 1108 mg/l Test organisms (species): Danio rerio (previous name: Brachydanio rerio)
LC50 - Fish [2] 3185 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static])
EC50 - Crustacea [1] 1700 mg/l Test organisms (species): Daphnia magna
EC50 72h - Algae [1] 207 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
EC50 72h - Algae [2] > 345.4 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)
EC50 - Crustacea [1] 19.3 mg/l Test organisms (species): Daphnia magna
EC50 - Crustacea [2] 27.8 mg/l Test organisms (species): Daphnia magna
EC50 - Other aquatic organisms [1] > 100 mg/l Test organisms (species):
EC50 72h - Algae [1] > 100 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names:
Raphidocelis subcapitata, Selenastrum capricornutum)
ErC50 algae 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
NOEC (chronic) ≥ 2.92 mg/l Test organisms (species): Daphnia magna Duration: '21 d'
Iron (7439-89-6)
LC50 - Fish [1] 8.65 mg/l Source: ECHA
EC50 - Crustacea [1] > 100 mg/l Test organisms (species): Daphnia magna
EC50 - Crustacea [2] > 10000 mg/l Test organisms (species): Daphnia magna
EC50 72h - Algae [1] 250 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names:
Raphidocelis subcapitata, Selenastrum capricornutum)
ErC50 algae 250 mg/l (Equivalent or similar to OECD 201, 72 h, Pseudokirchneriella subcapitata, Static
system, Fresh water, Weight of evidence)
Nickel (7440-02-0)
LC50 - Fish [1] > 100 mg/l (Exposure time: 96 h - Species: Brachydanio rerio)
LC50 - Fish [2] 1.3 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [semi-static])
EC50 - Crustacea [1] > 100 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 - Crustacea [2] 1 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
EC50 96h - Algae [1] 0.174 – 0.311 mg/l (Species: Pseudokirchneriella subcapitata [static])
BCF - Other aquatic organisms [1] 8 – 45 (≤ 4 week(s), Cambarus sp., Flow-through system, Fresh water, Experimental
value, Fresh weight)
Chromium (7440-47-3)
LC50 - Fish [1] 13.9 – 210 mg/l Source: GESTIS
Molybdenum (7439-98-7)
LC50 - Fish [1] 609.1 mg/l Source: EHCA
Partition coefficient n-octanol/water (Log Pow) 0.23 Source: SRC Access on Jan 2006
(12001-26-2)
Persistence and degradability Biodegradability: not applicable.
(471-34-1)
Persistence and degradability Biodegradability in soil: not applicable.
Biodegradability: not applicable.
CaF2 (7789-75-5)
Persistence and degradability Biodegradability: not applicable.
(1344-09-8)
Persistence and degradability Biodegradability: not applicable.
Iron (7439-89-6)
Persistence and degradability Biodegradability in soil: not applicable.
Biodegradability: not applicable.
Nickel (7440-02-0)
Persistence and degradability Biodegradability in soil: not applicable.
Biodegradability: not applicable.
Chromium (7440-47-3)
Persistence and degradability Biodegradability: not applicable.
Molybdenum (7439-98-7)
Persistence and degradability Biodegradability: not applicable.
(12001-26-2)
Bioaccumulative potential No bioaccumulation data available.
(471-34-1)
BCF - Fish [1] (no bioaccumulation)
CaF2 (7789-75-5)
Bioaccumulative potential No bioaccumulation data available.
(1344-09-8)
BCF - Fish [1] (no bioaccumulation expected)
Iron (7439-89-6)
Bioaccumulative potential No bioaccumulation data available.
Nickel (7440-02-0)
BCF - Other aquatic organisms [1] 8 – 45 (≤ 4 week(s), Cambarus sp., Flow-through system, Fresh water, Experimental
value, Fresh weight)
Chromium (7440-47-3)
BCF - Fish [1] 0.0048 (Pisces, Literature study, Dry weight)
Molybdenum (7439-98-7)
BCF - Fish [1] 260 – 500 (Tilapia rendalli)
Partition coefficient n-octanol/water (Log Pow) 0.23 Source: SRC Access on Jan 2006
(12001-26-2)
Ecology - soil No (test)data on mobility of the substance available.
(471-34-1)
Mobility in soil 4.971 Source: Quantitative Structure Activity Relation
CaF2 (7789-75-5)
Ecology - soil No (test)data on mobility of the substance available.
(1344-09-8)
Ecology - soil No (test)data on mobility of the component(s) available.
Iron (7439-89-6)
Surface tension Not applicable (solid)
Nickel (7440-02-0)
Surface tension Not applicable (solid)
Nickel (7440-02-0)
Ecology - soil No (test)data on mobility of the substance available.
Chromium (7440-47-3)
Surface tension No data available (test not performed)
Molybdenum (7439-98-7)
Partition coefficient n-octanol/water (Log Pow) 0.23 Source: SRC Access on Jan 2006
14.1. UN number
Not applicable Not applicable Not applicable Not applicable
International
EU Regulatory Information
EU Candidate list (SVHC) Contains no substance on the REACH candidate list
EU authorization list (REACH Annex XIV) Contains no REACH Annex XIV substances
EU restriction list (REACH Annex XVII) Not applicable
US Regulatory Information
CERCLA Section 103 (40CFR302.4) Contains listed substances
EPCRA Section 302 (40CFR355.30) Not applicable
EPCRA Section 304 (40CFR355.40) Not applicable
EPCRA Section 313 (40CFR372.65) Contains listed substances
International agreements
No data available
16.1. Data sources: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006,Classification according to Classification,
Labelling and Packaging of Substances and Mixtures (SEA) Regulation published in the
Official Journal numbered 28848 on December 11, 2013,ECHA (European Chemicals
Agency),Supplier's safety documents,No data available,This MSDS is prepared based on
Article 41 of the Occupational Safety and Health Act and Notice No.2016-19 of the Ministry
of Employment and Labor (based on the availability of material safety and health data),
taking into account the status of regulations related to Korea,This MSDS is prepared based
on KOSHA, NITE, ESIS, NLM, SIDS, IPCS, NCIS, etc,This safety data sheet was compiled
with data and information from the following sources : RTECS, ECOSAR, HSDB, SIDS
SIAP, ChemWATCH, CESAR, Chemical DB.
16.2. Issue date: 11/3/2020
16.3. Revision number and date: 1.0, 27/12/2021
16.4. Other information: No data available
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.