EC safety data sheet

Trade name: MAPP

Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name

MAPP
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Fuel gas
Uses advised against
No data available.

1.3 Details of the supplier of the safety data sheet

Address
ROTHENBERGER Werkzeuge GmbH
Industriestraße 7
65779 Kelkheim
Telephone no. +49 (0) 61 95 / 800 - 1
Fax no. +49 (0) 6195 / 800 - 3500
e-mail [email protected]
Advice on Safety Data Sheet
[email protected]

1.4 Emergency telephone number

For medical advice (in German and English):
+49 (0)551 192 40 (Giftinformationszentrum Nord)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 (CLP)
Flam. Gas 1; H220
Press. Gas compr.; H280
Classification information
This product is assessed and classified using the methods and criteria below referred to in Article 9 of Regulation (EC)
n° 1272/2008:
Physical hazards: determined through assessment data based on the methods or standards referred to in part 2 of
Annex I to CLP
Health hazards and environmental hazards: determined through toxicological and ecotoxicological assessment data
based on the methods or standards referred to in Part 3, 4 and 5 of Annex I to CLP.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Hazard pictograms

GHS02
Signal word
Danger
Hazard statement(s)
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
Precautionary statement(s)
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

Page 1 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

P103 Read label before use.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/container to a facility in accordance with
local/regional/national/international regulations.

2.3 Other hazards

During and after use possible formation of combustible mixture with solvents. Contact with the liquid can cause cold
burns or frostbite.
PBT assessment
The components of this product are not considered to be a PBT.
vPvB assessment
The components of this product are not considered to be a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not applicable. The product is not a substance.

3.2 Mixtures
Hazardous ingredients
No Substance name Additional information
CAS / EC / Index / Classification (EC) 1272/2008 (CLP) Concentration %
REACH no
1 propene pls. refer to footnote (1)
115-07-1 Flam. Gas 1; H220 < 100.00 Vol%
204-062-1 Press. Gas compr.; H280
601-011-00-9
-
Full Text for all H-phrases and EUH-phrases: pls. see section 16
(1) Aberrant from/in addition to the classification set out in Annex VI, this substance is classified according to European
Regulation (EC) No 1272/2008 (CLP), Article 4 (3), paragraph 2.

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
Remove affected person from danger area, lay him down. If the patient is likely to become unconscious, place and
transport in stable sideways position. In case of persisting adverse effects, consult a physician.
After inhalation
Ensure supply of fresh air. In case of persisting adverse effects consult a physician.
After skin contact
In case of frostbite, rinse with plenty of water. Do not remove clothing. In case of contact with skin wash off
immediately with copious amounts of water. Consult a doctor if skin irritation persists.
After eye contact
Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the
unaffected eye (at least 10 to 15 minutes). Get immediate ophthalmic treatment.
After ingestion
Get medical attention if pain still persists. Do not induce vomiting. Never give anything by mouth to an unconscious
person.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms
Frostbite; Dazyness; Shortness of breath; Unconsciousness

4.3 Indication of any immediate medical attention and special treatment needed
No data available.

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EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Extinguishing powder; Carbon dioxide; Foam
Unsuitable extinguishing media
Water

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon monoxide and carbon dioxide; May explode if exposed to
heat. Liquefied gas: Spilled liquid can cause cold burns. This gas is heavier than air and may accumulate in low areas.
Vapours are heavier than air and may spread along floors.

5.3 Advice for firefighters

Use self-contained breathing apparatus. Wear protective clothing. Cool closed containers exposed to fire with water.
Pressure increase, bursting and explosion hazard during heating.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Risk of explosion. Ensure adequate ventilation. Keep away
sources of ignition. Evacuate all unprotected personnel from the danger zone. Use personal protective clothing. Do not
inhale vapours.
For emergency responders
Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

6.3 Methods and material for containment and cleaning up

Ensure adequate ventilation. Allow to vaporise. When picked up, treat material as prescribed under heading "Disposal
considerations".

6.4 Reference to other sections

Information regarding safe handling, see chapter 7. Information regarding personal protective measures, see chapter
8. Information regarding waste disposal, see chapter 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
Product inherent handling risks must be minimised taking the appropriate measures for protection and preventive
actions. The working process should be designed to rule out the release of hazardous substances or skin contact as
far it is possible by the state of the art. Provide good room ventilation even at ground level (vapours are heavier than
air). Open and handle container with care. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50 °C. Do not pierce or burn, even after use. Handle with care - avoid bumps, friction and
impact.
General protective and hygiene measures
Wash hands before breaks and after work. Do not inhale gases. Do not eat, drink or smoke during work time. Keep
away from food, drink and animal feeding stuffs. Avoid contact with eyes and skin.
Advice on protection against fire and explosion
Vapours can form an explosive mixture with air. Isolate from sources of heat, sparks and open flame. Take
precautionary measures against electrostatic loading (earthing necessary during loading operations). Use explosion-
proof equipment/fittings and non-sparking tools. Electrical equipment should be protected to the appropriate standard.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions
Keep container tightly closed in a cool, well-ventilated place, open and handle carefully. Protect from heat and direct
sunlight.

Page 3 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

Requirements for storage rooms and vessels

Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers
of same material as the original one.
Incompatible products
Substances to be avoided, pls. See chapter 10.

7.3 Specific end use(s)

No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No parameters available for monitoring.

8.2 Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, local exhaust at the work station if necessary.
Personal protective equipment
Respiratory protection
In case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace
threshold values are not specified. If workplace exposure limits are exceeded, a respiration protection approved for this
particular job must be worn.
Eye / face protection
Tightly fitting safety glasses (EN 166).
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of
skin contact with the product. Before use, the protective gloves should be tested in any case for its specific work-
station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the
manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves.
Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid
permanent use of protective gloves.
Other
Chemical-resistant work clothes. Fire-resistant antistatic protective clothing. Protective shoes.
Environmental exposure controls
No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Form/Colour
Compressed gas
380
colourless
10

Odour
20
odourless
Odour threshold
No data available
pH value
No data available
Boiling point / boiling range
Value -48 °C
Source supplier -48

Melting point / melting range

Value -185 °C
Source supplier -185

Decomposition point / decomposition range

Page 4 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

No data available
Flash point
Value -108 °C
Source supplier -108

Auto-ignition temperature
Value 497 °C
Source supplier 497

Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
Value 2 % vol
Source
2
supplier 40

Upper flammability or explosive limits

Value 11 % vol
Source
11
supplier 40

Vapour pressure
Value 900 kPa
Reference temperature 15 °C
Source supplier 900

Vapour density
Value 1.5
Reference temperature 0 °C
Source supplier
Comments Air = 1 1.5

Evaporation rate
No data available
Relative density
Value 0.6
Source supplier 0.6

Density
No data available
Solubility in water
Source supplier
Comments essentially insoluble
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
log Pow 1.77
Reference temperature 20 °C
Source ECHA 1.77

Viscosity
No data available

9.2 Other information

Other information
No data available.

Page 5 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available.

10.2 Chemical stability

Stable under recommended storage and handling conditions (See section 7).

10.3 Possibility of hazardous reactions

Risk of formation of explosive gas mixtures in air.

10.4 Conditions to avoid

Heat, naked flames and other ignition sources.

10.5 Incompatible materials

Oxidizing agents

10.6 Hazardous decomposition products

No data available.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute oral toxicity
No data available
Acute dermal toxicity
No data available
Acute inhalational toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met. Lk.3661

Reproduction toxicity
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met. Lk.3661

Carcinogenicity
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
Source ECHA
Evaluation/classification
Lk.3661
Based on available data, the classification criteria are not met.
STOT - single exposure
No data available
STOT - repeated exposure
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1

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EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met. Lk.3661

Aspiration hazard
No data available

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
LC50 51.7 mg/l
Duration of exposure 96 h
Species fish
Method QSAR
Source
Lk.9016
ECHA
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
EC50 28.2 mg/l
Duration of exposure 48 h
Species Daphnia
Method QSAR
Source
Lk.9025
ECHA
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
EC50 12.1 mg/l
Duration of exposure 96 h
Species Algae
Method QSAR
Source
Lk.9025
ECHA
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No data available

12.2 Persistence and degradability

Biodegradability
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
Type Anaerobic biodegradability (ThOD)
Value 50 %
Duration 2.36 day(s)
Method QSAR
Source ECHA
Lk.7002472

Abiotic Degration
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
Type Photolysis
Half-life 14.6 h
Source ECHA
Lk.3710

Page 7 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

12.3 Bioaccumulative potential

Partition coefficient: n-octanol/water
No Substance name CAS no. EC no.
1 propene 115-07-1 204-062-1
log Pow 1.77
Reference temperature 20 °C
Source ECHA 1.77

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment
PBT assessment The components of this product are not considered to be a PBT.
Lk.2045
vPvB assessment
Lk.2046
The components of this product are not considered to be a vPvB.

12.6 Other adverse effects

No data available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
dispose of in accordance with local regulation.
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement
with the regional waste disposal company.
Packaging
Compressed gas packaging under pressure. Do not open by force. Do not heat above 50°C. Dispose of compressed
gas packagings only if completely discharged. Do not burn empty compressed gas packagings. Do not pierce, cut or
weld uncleaned containers.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN
Class 2
Classification code 2F
Hazard identification no. 23
UN number UN1077
Proper shipping name PROPYLENE
Tunnel restriction code B/D
Label 2.1

14.2 Transport IMDG

Class 2.1
UN number UN1077
Proper shipping name PROPYLENE
EmS F-D, S-U
Label 2.1

14.3 Transport ICAO-TI / IATA

Class 2.1
UN number UN1077
Proper shipping name Propylene
Label 2.1

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

No data available.

Page 8 of 9
EC safety data sheet
Trade name: MAPP
Product no.: 035521-A 035521-B 035521-C 35698 035698-A 035698-B
Current version : 1.1.0, issued: 05.08.2019 Replaced version: 1.0.0, issued: 30.07.2019 Region: GB

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not relevant

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC)
1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain
substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject
to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON
THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
The product is considered being subject to REACH regulation (EC) 1907/2006 annexe No 40
XVII.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances
This product is subject to Part I of Annex I, risk category: P2
Other regulations
Adhere to the national sanitary and occupational safety regulations when using this product.

15.2 Chemical safety assessment

A chemical safety assessment has not been carried out for this mixture.

SECTION 16: Other information

Further information
Alterations/supplements:
Alterations to the previous edition are marked in the left-hand margin.
Sources of key data used to compile the data sheet:
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
National Threshold Limit Values of the corresponding countries as amended in each case.
EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EU
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding
chapter.
Department issuing safety data sheet
UMCO GmbH - D-21107 Hamburg, Georg-Wilhelm-Strasse 187, Tel.: +49(40)555 546 300, Fax: +49(40)555 546 357,
e-mail: [email protected]
This information is based on our present knowledge and experience.
The safety data sheet describes products with a view to safety requirements.
It does not however, constitute a guarantee for any specific product properties and shall not establish a legally valid
contractual relationship.

Document protected by copyright. Alterations or reproductions require the express written permission of UMCO GmbH.
.
Prod-ID 753555

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