Telegram - @bohring - Bot: Online Test Series Contact Programme

(Academic Session: 2022 - 2023)
ONLINE TEST SERIES CONTACT PROGRAMME
JEE (MAIN + ADVANCE)
MAJOR TEST
DATE : 06-05-2023
(PAPER : 2)
PATTERN : ADVANCED COURSE : LEADER
READ THE INSTRUCTIONS CAREFULLY

Important Instructions:
1. This paper contains a total number of 54 questions.
2. The Questions appearing in the paper are based on Physics, Chemistry and Mathematics.
4. Duration of the test is 3 hours.
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Online Test Series/Leader Course/06-05-2023/Paper-2
PART-1 : PHYSICS
SECTION–I : (Maximum Marks : 12)
• This section contains 04 questions.
• Each question has FOUR options. ONLY ONE of these four options is correct.
• For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If only correct answer is given.
Zero Marks : 0 If no answer is given.
Negative Marks : –1 For incorrect answer
1. A solid cylinder of mass m and radius R is placed on layer of liquid of viscosity η. The height
of liquid is h (h << R). Now the cylinder is rotated about its vertical axis with constant
angular velocity ω. Then :-
(A) External power required to rotate the cylinder with constant angular velocity ω is
zero.
πω 2 R 4η
(B) External power required to rotate the cylinder with constant angular velocity ω is
h
(C) External power required to rotate the cylinder with constant angular velocity ω is
πω 2 R 4η
.
2h
(D) External torque required to rotate the cylinder with constant angular velocity ω is
πω R 4η
.
h
2. Three co-harrent sources kept along the same line produce intensity I0 each at point P on
this line. When S1 and S2 are switched on simultaneously, intensity at point P is 2I0. When
S2 & S3 are switched on simultaneously, intensity at point P is 2I0. Then :-
(A) When S1 and S3 are switched on simultaneously, intensity at P can be 2I0.
(B) When S1 and S3 are switched on simultaneously, intensity at P can be 9I0.
(C) When all three sources are switched on simultaneously, intensity at P can be I0.
(D) When all three sources are switched on simultaneously, intensity at P can be 3I0.
 Digital www.allendigital.in [1]
Target : JEE (Main + Advanced) 2023/06-05-2023/Paper-2
3. The pitch of a screw gauge is 1 mm and its circular scale is divided into 100 divisions. When
nothing is placed between its studs, the zero of the circular scale lies 6 divisions below the
reference line. When a wire is placed between its studs, the main scale reading is 2 mm and
56th division of circular scale coincides with the reference line of the main scale. The length
of wire is 8.68 cm. Find the curved surface area (in cm2) of the wire in true significant
figures.
(A) 6.82
(B) 6.28
(C) 8.26
(D) 8.82
4. In the circuit as shown in the adjoining figure the switch S1 is closed at t = 0. After steady
state is reached, the switch S2 is also closed for a long time. Then the total heat dissipated
in the circuit after the switch 'S2' is closed will be :
(A) 100 μJ
(B) 50 μJ
(C) 150 μJ
(D) 20 μJ
SECTION–II : (Maximum Marks : 24)

• This section contains SIX questions.
• Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these
four option(s) is (are) correct option(s).
• For each question, choose the correct option(s) to answer the question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 For incorrect answer
[2]
Telegram - @bohring_bot www.allendigital.in  Digital
5. A spherical ball of radius R is uniformly charged. The surrounding space of ball is charged
α
with volume charge density , where α is a constant and r is the distance from the centre
r
of the ball. The value of charge q on ball for which the strength of electric field outside the
ball is independent of r. (The relative permittivites of the ball and the surrounding space
are assumed to be equal to unity)
(A) Charge on ball is q = παR2

(B) Charge on ball is q = 2παR2
2α
(C) Electric field out-side the ball is E =
ε0
α
(D) Electric field out-side the ball is E =
2ε 0
6. A uniform disc of mass m and radius R lies on a board of mass M(M > m), which lies on a
frictionless inclined plane of inclination θ, as shown. String and pulley are ideal. Assume
that disc rolls without slipping on the board and assume that two string segments are
parallel to the plane. Which of the following is/are correct?
( M − m) g sin θ
(A) Acceleration of board is
M + 2m
( M − m) g sin θ
(B) Acceleration of board is
M + 3m
2( M − m) g sin θ
(C) Angular acceleration of disc is
( M + 3m ) R
(D) Angular acceleration of disc is
7. Two particles A and B start to move from origin along +ve x-axis. In the time interval t = 0
to t = 2 sec. the velocity -time graph of both particles is shown in below figures.
(A) Separation between A and B is maximum at t = 1 sec.

(B) Separation between A and B is maximum at t = 1.5 sec.
(C) Maximum Separation between A and B is 2m
(D) Maximum Separation between A and B is 2.5m
8. The figure shows the variation of current i of a discharging capacitor connected in series
with resistance 10Ω.
(A) The initial potential difference across the capacitor is 100 volt.
1
(B) The capacitance of the capacitor is F.
10n 2
500
(C) The total heat produced in the circuit will be Joules.
n 2
1
(D) The thermal power in the resistor will decrease with a time constant second.
3n 2
 x 
9. A potentiometer wire of resistance per unit length=r r0 1 +  (where x is distance from
 4 
left end of the potentiometer wire) is connected to four ideal batteries as shown in the
figure. Resistance of connecting wires is negligible. A cell of e.m.f. 1 volt is balanced against
potential drop on potentiometer wire, then null point can be obtained :
[4]
(A) Between point A and B.

(B) At point B.
(C) Between point D and E.
(D) At point C
10. A conducting rod of mass 'm' and length 'ℓ' is placed on a pair of smooth horizontal conducting
parallel rails connected at one end by an inductor of inductance L and by a capacitor of
capacitance 'C' at the other end as shown in the figure. A uniform vertical magnetic field 'B'
exists in the region perpendicular to the plane of rails. The conductor starts from rest at t = 0
from the left end of the rails due to constant external horizontal force F = 2mg applied to it. Then
choose the correct option(s). (Take CB2ℓ2 = m)
8mgL
(A) The maximum horizontal displacement of the rod is
B 22
4mgL
(B) The maximum horizontal displacement of the rod is
B 22
B
(C) The angular frequency of the oscillations of the rod is
mL
B
(D) The angular frequency of the oscillations of the rod is
2mL
SECTION–III : (Maximum Marks : 24)

‚ This section contains EIGHT questions.
‚ The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
‚ Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only correct answer is given.
Zero Marks : 0 In all other cases
Negative Marks : –1 In all other cases
1
11. A small particle of mass m moves in such a way that the potential energy U = mb 2 r 2 ,
2
where b is a constant and r is the distance of the particle from the origin (Nucleus). Assume
Bohr model of quantization of angular momentum and circular orbits is applicable. If the
radius of nth allowed orbit is proportional to n4/k, then value of K is:-
12. A light string attached to a bead passing over a smooth fixed pulley at a distance of d = 15
m from the vertical rod as shown in the figure. At the other end of the string a block of mass
1 kg is attached, lying over a smooth fixed inclined plane of inclination angle 37°. Mass of
the bead is 1 kg and friction between bead and vertical rod is zero. The bead is held in level
with the pulley and released. If the speed of the bead when the string between bead and
α ×1000
pulley makes an angle 53° with the horizontal is m/s, find value of α.
41
[take g = 10 m/s2]
13. In a region of free space, a uniform magnetic field of induction B varies with time t as shown
in the graph. At the instant t = 0, a particle of charge q and mass 2 kg enters the region with
velocity 4m/s perpendicular to the direction of the magnetic field, neglect the influence of
the induced electric field and explore motion of the particle for what minimum value of
charge q (in C), will the particle follow a closed path ?
14. Three small balls A, B and C of masses m, 2m and 2m respectively are placed on a
smooth horizontal surface. Balls A and B as well as B and C are connected by light
inextensible strings each of equal length ℓ. The string connecting balls A and B is taut. The
 3
initial distance between the balls B and C is and BC is perpendicular to AB. The ball
2
‘C’ is given a horizontal velocity v0 = 23 m/s parallel to AB as shown in the figure. Find the
initial velocity of ball A (in m/s) just after string BC becomes taut.
[6]
15. A satellite is projected into space from a point ‘P’ at a distance ‘r0’ from the centre of the
GM
earth with an initial velocity v0 = at an angle α = 37° with the horizontal at point 'P'
r0
as shown in the figure. It is found that the satellite is propelled into an elliptical orbit. If the
eccentricity of the elliptical orbit is e, then value of 5e is :-
16. Two wires of same length ℓ = 1 m and same cross-sectional area A = 10 mm2 are welded
together and their ends are rigidly clamped between two walls as shown in the
figure. Given :
α1 = 2 × 10–5 C–1, Y1 = 1 × 1010 N/m2, μ1 = 0.4 kg/m
α2 = 1 × 10–5 C–1, Y2 = 2 × 1010 N/m2, μ2 = 0.1 kg/m
The tension in the wires is produced by reducing the temperature of system by 20°C. If
the first overtone frequency of transverse vibration of the system with joint 'O' as a node
is 5n Hz, then find the value of n.
17. A metallic surface is illuminated alternatively with electromagnetic radiations of

wavelengths 4500 Å and 6000 Å. It is observed that the maximum speeds of the
photoelectrons emitted under these illuminations are in the ratio 2 :1. Find the work
function (in eV in nearest integer) of the metal. (Take hC = 1242 eV-nm)
18. A uniform stick with mass m and length 6 meter lies on a frictionless horizontal surface (so
you can ignore gravity in this problem). Stick is pivoted at a point a distance x from its
center. A spring (at its relaxed length) with spring constant k is attached to the far end of
the stick, perpendicular to the stick, as shown in figure. If the stick is given a tiny kick, what
value of x (in meter) yields the largest frequency of small oscillations?
[8]
www.allendigital.in  Digital
PART-2 : CHEMISTRY
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
1. Which of the following is correct order of solubility of given salts in aqueous solution ?
(A) LiClO4 < NaClO4 < KClO4 < RbClO4
(B) CaCO3 < NaHCO3 < KHCO3 < RbHCO3
(C) LiF > NaF > KF > RbF > CsF
(D) AgF < AgCl < AgBr < AgI
2. For an electrolytic cell undergoing following balanced reaction :

NO3− + 3H3O+ + Hg 22+ → 2Hg 2+ + HNO2 + 4H2O
Under standard state conditions Ecell = 0.02V . If an average current of 10 amp. passes
0
through the cell, how long will it take to produce 0.3mole of HNO2 by this reaction?
2.303RT
[Given NO3− + 3H3O+ + 2e− →= =
HNO2 + 4H2O, E0 0.94V and 0.06 ]
F
(A) 1.6 hours (B) 16 hours
(C) 3.2 hours (D) 32 hours
3.
2+ +
H3C – C ≡ C – OCH3 
Hg /H /H O
→ P, P is :
2
(A) (B)
(C) (D)
4. Monomer units of Biodegradable polymer PHBV are :
(A)
(B)
(C)
(D)
• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is
(are) correctanswer(s).
• For each question, choose the option(s) corresponding to (all ) the correct answer(s)
• Answer to each question will be evaluated according to the following marking scheme:
Partial Marks : +3 If all the four options are correct but ONLY three options are
chosen.
chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is
chosen and it is a correct option.
Negative Marks : –2 In all other cases.
5. Which of the following statement(s) is are correct ?

(A) 2ClO2 + 8H+ + 10I– → 5I2 + 2Cl– + 4H2O
(B) ClO2 is diamagnetic in nature
(C) ClO2 in alkaline solution undergoes disproportionation
(D) Chlorine dioxide (ClO2) is powerful oxidising agent but bleaching action is lower than
Cl2
6. Which of the following are correct statements(s) :

(A) CoCl3.3NH3 shows facial and meridional isomerism.
(B) [Co(gly)3] shows geometrical isomerism as well as optical isomerism.
(C) K4[FeII(CN)5(O2)] is paramagnetic.
(D) [Co(EDTA)]– shows optical isomerism.
7. Which of the following statement(s) is/are False ?

(A) If heat of vaporization of water at 100°C is 40.6 KJ/mol, then when 9gm of water
vapours are condensed to liquid at 100°C & 1 atm, then ΔSsystem = 54.42 J/K
(B) When (ΔGsystem)P,T < 0 ; the reaction must be exothermic.
(C) dG = Vdp – SdT is applicable for closed system in which both PV and non-PV work
occurs
(D) If (ΔGsystem)P,T < 0, then process can be work producing
[ 10 ]
8. To an aqueous solution containing a mixture of 0.05M NaCl and 0.05M NaI when AgNO3 is
slowly added to such a solution, then correct option(s) is/are :
(K sp AgCl= 10−10 ,K sp AgI= 4 × 10−16 )
(A) Concentration of Ag+ required to precipitate Cl⊝ is 2 × 10–9M
(B) Concentration of Ag+ required to precipitate I⊝ is 8 × 10–15M
(C) AgCl and AgI will precipitate out of the solution together
(D) First AgI will precipitate
9. Which oxidasing agent can not be used to convert Propanal to Propanoic acid :
(A) (B) HNO3
(C) SeO2 (D) CrO3 /
10. Which reagent can be used to form 2-Chloropropane from Propan-2-ol
(A) NaCl (B) (i) , (ii) NaCl
(C) NH4Cl (D) PCl3

• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
• For each question, enter the correct integer value of the answer in the place designated to
enter the answer.
• For each question, marks will be awarded in one of the following categories
Full Marks : +3 If only the correct answer is given.
(x + y)
11. Consider Al2(OH)6 compound and calculate the value of .
z
Where X = Total number of (2C – 2e–) bond
Y = Total number of (3C – 2e–) bond
Z = Total number of (3C – 4e–) bond
12. How many of following elements produces NO2 gas on reaction with concentrated HNO3?
Zn, Fe, Pb, Cu, Ag, Au, Pt, Sn
 Digital www.allendigital.in [ 11 ]
13. Find the number of impurities which deposited as anode mud in electrorefining of
copper.
Sb, Se, Te, Ag, Pt, Al
14. An electron in a He+ ion is in a state with directional dependence and has a total of one
5RC
node. A photon of frequency causes this election to jump into a higher state which
9
can have total five possible orientations in space. Find magnitude of the change in (n + ℓ)
values corresponding to two states ?
(R = Rydbergs constant, C = speed of light)
15. 1g of a monobasic acid dissolved in 200g of water lowers its freezing point by 0.186°C. On
the other hand when 1g of same acid is dissolved in 200ml of water, this solution
requires 125ml of 0.1N NaOH for complete neutralization. If degree of ionisation of this
acid in water is 'α' find value of '10α' ?
[Given : For water Kf = 1.86 K-Kg mol–1]
−dp
16. For the reaction : 2NO(g) + H2 (g) → N2O(g) + H2O(g), the value of was found to be
dt
1.5PaS–1 for a pressure of 372 Pa for NO and 0.25 PaS–1 for a pressure of 152 Pa for NO,
the pressure of H2 being constant. If pressure of NO was kept constant, the value of
−dp
was found 1.60 PaS–1 for a pressure of 289 Pa for H2 and 0.79PaS–1 for a pressure of
dt
144 Pa for H2. If order of reaction with respect to NO and H2 are a and b, respectively,
then find nearest integer value of (a + b) ?
17. Consider following reactions & write number of reaction which are given with correct
major product
I. II.
III. IV.
V.
VI.
[ 12 ]
18. Consider following compounds & write no. of compounds which can show faster SN1 reaction
than .
, , , ,
, , ,
PART-3 : MATHEMATICS
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
1. The value of is :
(E) 2
(F) 1
(G) 0
(H) None
2. A Point S moves in space so that the points A, B, C taken on X, Y, Z axes respectively are
such that SA, SB, SC are mutually perpendicular and volume of tetrahedron OABC is 6,
where O is origin then locus of S is :
(x )
3
(E) 2
+ y2 + z2 6 xyz
=
(x )
3
(F) 2
+ y2 + z2 168 xyz
=
(x )
3
(G) 2
+ y2 + z2 288 xyz
=
(H) ( x2 + y 2 + z 2 ) =
3
48 xyz
3. The coefficient of x45 in is :
(E) –8
(F) –6
(G) 6
(H) 2
[ 14 ]
4. Let α, β, γ be non-zero real roots of the equation x3 + αx2 + βx + γ = 0 then
(E) There are three such triplets (α, β, γ)
(F) There are two such triplets (α, β, γ)
(G) There are eight such triplets (α, β, γ)
(H) There are four such triplets (α, β, γ)

• This section contains SIX (06) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is
(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all ) the correct answer(s)
• Answer to each question will be evaluated according to the following marking
scheme:
Partial Marks : +3 If all the four options are correct but ONLY three options are
chosen.
chosen and both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is
chosen and it is a correct option.
Negative Marks : –2 In all other cases.
f 2( x )
5. Consider the function g( x=
) + 5x5 − 5 where f(x) is continuous and differentiable
2
function. It is given that g(x) is monotonically increasing function and f(0) = 6 then
(E) g(3) > 13
1
(F) g   > 11
2
(G) f (1) > 26
2
(H) f 2 (–1) < 46
6. If and α ∈ R+ then α is equal to :
(E) characteristic value of log1039

 sin(4sin x ) 
(F) lim  
x →0
 x 
(G) number of non-differentiable points of
f(x) = x2 − 3 x + 2
(H) Re ( 23 − 10 2 i ) (where i= −1 )
I /2 I
sin( nx )
7. ∫
If α n = cos n x cos nx dx and βn =
0
∫
0
sin x
dx then for the sequence {αn} and {βn} : {Where
I = Kπ, K ∈ N}
(E) α1 , α2 ..., αn are in GP
(F) β1 , β2 ..., βn are in GP
2000
(G) If I = π then ∑ β=
i =1
i 1000π
π
(H) If I = π then α100 =100
2
8. Let f : R → R is given by
then which of the following option is/are correct?

(E) f has a point of local maximum and a point of local minimum in (–∞ ,0)
(F) f is an onto function
(G) f is an increasing on (–∞ ,0)
(H) f ' is not differentiable at x = 1
 −1 0 0 
9.  −1 0 −1 which of the following is/are true.
For the matrix A =
 
 0 −1 0 
 1 0 0
(E) A
=  K 1 0 , K ∈ N
2K
 
 K 0 1
 −1 0 0
(F) A 2 K −1  0 −1 , K ∈ N
 K
=−
 − K − 1 −1 0 
 1 0 0
(G) A 100
= 50 1 0
25 0 1
 −1 0 0 
 −50 0 −1
(H) A = 99
 
 −49 −1 0 
[ 16 ]
10. Pushpa is standing at (1,2) (height of pushpa is negligible). Another person Konda reddy is
moving on a circular path (x – 6)2 + (y – 8)2 = 4. Pushpa wants to kill the Konda reddy by
firing the bullet than which of the following is/are correct : (Assuming path of bullet is
straight line).(Possibility of killing is inversely proportional to distance between pushpa &
Konda)
 15 + 228 
(E) The minimum angle pushpa can fire with +ve x-axis is tan −1   .
 21
 
 30 + 228 
(F) The maximum angle pushpa can fire with +ve x-axis is tan −1   .
 21
 
(G) The minimum distance between pushpa and Konda is ( )
61 − 2 .
 10 12 
(H) The least possibility to kill the Konda is when he is at the point  +6 , + 8 .
 61 61 

• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
• For each question, enter the correct integer value of the answer in the place designated
to enter the answer.
• For each question, marks will be awarded in one of the following categories
Full Marks : +3 If only the correct answer is given.
( )
t − 1 dt
= 8tan −1 ( g(t)) + C and g(1) =
11. If ∫ 2 then the value of
( ) ( )
t + t 5/4 + t 3/4 t 1/4 t 1/2 + 1
2g2(16) is :
(where C is integration constant)
12. A continuous function y = f(x) is defined in a closed interval [–7, 6]. If A(–7,–4),
B(–2, 6), C(0, 0), D(1, 6), E(2, –3), F(3, 6), G(5,–6) and H(6, 0) are consecutive points on the
graph of f(x) and if these points are joined as line segments AB, BC, CD, DE, EF, FG, GH, then
graph of f(x) is formed and if number of real solutions of f(f(x)) = 6 is λ then λ – 10 is equal
to :
x 19
Let g1 , g2 , g3 : (0, ∞) → R be defined by g1 (x) =∫ Π ( t − i ) dt , x > 0 and
i
13.
i =1
0
g 2(x) = 98(x − 1)50 − 100(x − 1)49 + 2450, x > 0

and g3(x) =
(x − 1)2020 (x − 2)2021 (x − 3)2022 , x > 0
Let αi and βi respectively denote the number of points of local minima and the number of
points of local maxima of the function gi , i = 1, 2, 3 in (0, ∞) and if the value of
n
=
α1β1 + α2β2+ α3β3 is λ then λ – 20 equal to ( where Π a i a1a2a3 ......a n ,n ∈ N )
i =1
14. The area bounded by the curve f(x) = x + sinx and its inverse between the ordinates x = 0
to x = 3π is 3K, K ∈ N then K is
15. X wants to put 6 different rings in 3 specified fingers. The number of different ways he can
put such that no finger remains empty and no finger can have more than 3 rings is 6! × λ.
Then the value of λ is : (λ ∈ N)
16. If y = g(x) is the solution of the differential equation x(y3 –x)dy = y (x + y3)dx and
1
g −1 ( −4)
g(1) = ( −2)3 then is equal to : (where g–1 denotes the inverse of g(x))
16
17. The number of solution(s) of the equation tan −1 2 x= 16x 4 − 8x 2 + 1 , is(are)
18. Let f(x) be an invertible function and f(f–1(x)) = f–1 (f(x)) = x for f(x) = x3 – 2x–3 + 10 (x > 0),
d −1
then the value of 9 (f (x)) at x = 9 is :
dx
[ 18 ]
PART-1 : PHYSICS
ANSWER KEY
Que. 1 2 3 4
Section-I
Ans. C C A B
Que. 5 6 7 8 9 10
Section-II
Ans. BD BC BD ABC AD BD
Que. 11 12 13 14 15 16 17 18
Section-III
Ans. 8 7 4 2 3 4 2 1
SOLUTIONS
1. Ans. (C)
R
 rω − 0 
=∫ dτ ∫η ( 2π rdr ) 
0
h 
× r
R
2πηω 3
h ∫0
= r dr
2πηω  R 4  πηω R 4
= =
h  4  2h
πηω 2 R 4
Power = τω =
2h
2. Ans. (C)
I = I 0 + I 0 + 2 I 0 I 0 cos θ
cosθ = 0
π
θ =
2
3. Ans. (A)
The pitch of screw gauge, P = 1mm
P 1
least count, L.C.
= = = 0.01mm
N 100
Diameter of the wire,
d = 2mm + 56 × L.C. – 6 × L.C
d = 2.50 mm = 0.250 cm
ℓ = 8.68 cm
Curved surface area of the wire,
S = πdℓ
22
= × 0.250 × 8.68 =6.82cm 2
7
4. Ans. (B)
ΔQ1 = 120 – 100 = 20 mC

ΔQ2 = – 90 – (–100) = 10 mC
Now, ΔWb = ΔU + ΔH
20 × 10–6 × 100 + 10 × 10–6 × 50 – 30 × 10–6 × 80 =
1 1 1
× 6 × 10−6 × 400 + × 3 × 10−6 × 900 − × 2 × 10−6 × 2500 + ∆H
2 2 2
⇒ 100 × 10–6 = 50 × 10–6 + ΔH
⇒ ΔH = 50 × 10–6 = 50 μJ
5. Ans. (B, D)
α
∫ dq = ∫ r 4π r dr
2
r
 r2 
q = 4πα  
 2 R
= 2πα [r 2 − R 2 ]
[ 20 ]
k (Q + q )
=E
r2
k (Q + 2πα (r 2 − R 2 ))
E=
r2
kQ 2πα kR 2
E = 2 + 2πα k −
r r2
For E to be independent of r.
kQ 2πα kR 2
=
r2 r2
Q = 2παR2
1 α
For this E = 2πα k = 2πα × =
4πε 0 2ε 0
6. Ans. (B, C)
Mgsinθ – T1 – f = Ma....(i)
T1 – mgsinθ – f = ma....(ii)
mR
fR = α
2
mR  2a 
f =  
2  R
f = ma (iii)
(i) + (ii) ⇒ Mgsinθ – mgsinθ – 2f = (M + m)a
(M – m) gsinθ = (M + m) a + 2ma
a = (M – m) gsinθ/(M + 3m)
7. Ans. (B, D)
For max separation velocity of both should be same and that is at t = 1 sec. and t = 1.5 sec.
Separation at t = 1 sec. is 2m and that at t = 1.5 sec. is 2.5m
8. Ans. (A, B, C)
V0 = I0R = 10 × 10 = 100
I = I 0 e−t / RC
t 1
=C =
 I  10n 2
R n  0 
 I 
1 1 
 (100 )
2
heat produced = 
2  10n2 
500
= joules
n 2
9. Ans. (A, D)
There will be null point

(1) between A and B.
(2) At C.
10. Ans. (B, D)
e = Bvℓ
q = Cε = CBvℓ
dq dv
i1
= = CB
dt dt
Ldi2
= Bv
dt
 B 
∫ di2 =  L  ∫ vdt
i2 x
B
∫ di2 =
0
L ∫0
dx
[ 22 ]
 B 
i2 =  x  ........(ii )
 L 
dv
m = F − Bi
dt
mdv
F B(i1 + i2 )
=−
dt
mdv
=F − Bi1 − Bi2
dt
dv  dv   B 
m = 2mg − B  CB  − B   x
dt  dt   L 
d 2 x B 2 2  2mgL 
(m + CB 2  2 ) 2 =  x − 2 2 
dt L  B 
d 2x B 2 2  2mgL 
 x − 2 2  ∴ CB  = m 
2 2
2
−
=
dt 2mL  B 
∴ angular frequency of SHM executed by the rod is
B
ω =
2mL
The amplitude of SHM executed by the rod is
2mgL
A=
B 22
The maximum horizontal displacement of the rod
4mgL
Xmax = 2A =
B 22
11. Ans. (8)

dU 1
F=
− − 2mb2r =
= −mb2r
dr 2
12. Ans. (7)
10 × 3 1 1
–10 × + 10 × 20 = 1V12 + ×1× V22
5 2 2
V12 + V22
140 =
2
4
V1 × =V2
5
16 2
= V12 +
280 V1
25
280 × 25
V1 =
41
7000
V1 =
41
13. Ans. (4)

2π m
T=
qB
T = π sec
14. Ans. (2)
Using conservation of momentum of system.

 3v0 v 
2mv0 = 3mv2 + 2m  + 
 4 2
3v0
2v0 = 3v2 + v +
2
v
3v2 + v =0 ......(i )
2
 3v0 v 3 
2mv1 2m 
= − 
 4 2 
3v0 3v
=v1 −
4 2
3v0 3v
3=
v1 − ......(ii )
4 2
Also, v1cos30° + v2cos60° = v
[ 24 ]
3v1 v2
+ = v
2 2
3v=
1 2v − v2 ........(iii )
From equation (ii) and (iii)
3v0 3v
2v − v2 = −
4 2
3v0
7v − 2v2 =.........(iv)
2
23v2 = 2v0
2v0 2 × 23
v1
= = = 2m / s
23 23
15. Ans. (3)
Total mechanical energy

−GMm 1 2
=ε + mv0
r0 2
GMm 1 2 GMm GMm

=
− + mv0 =
− +
r0 2 r0 2r0
GMm
ε
= −
2r0
−GMm GMm
= −
2a 2r0
∴ Length of semi-major axis, a = r0
Hence point 'P' must be an extreme
Point of the minor axis of the elliptical orbit
∵ a sin α = ae
e = sin α = sin 37° = 0.6
Hence the eccentricity of the elliptical orbit
e = 0.60
16. Ans. (4)
The tension produced in each wire,
=F
(=
α1 + α 2 ) ∆θ 3 ×10−5 × 20 ×10−5
= 40 N
1 1 1.5 ×10−10
 + 
A  Y1 Y2 
n1 F n2 F
Now, =
2 µ1 2 µ2
n1 µ1 0.4
⇒ = =2
n2 µ2 0.1
In first overtone, n1 = 4, n2 = 2
Hence the first overtone frequency of the transverse vibration of the system,
n1 F
f =
2 µ1
4 40 4
f = = ×10 =20 Hz
2 ×1 0.4 2
17. Ans. (2)

E1 = k1 + ϕ ...(i)
E2 = k2 + ϕ ...(ii)
k1
Also, = 4 ⇒ k1 = 4k2 ...(iii)
k2
From (i) and (ii)
E1 k1 + φ
=
E2 k2 + φ
λ2 4k2 + φ
=
λ1 k2 + φ
6000 4k2 + φ
=
4500 k2 + φ
4 4k 2 + φ
=
3 k2 + φ
[ 26 ]
⇒ 4k2 + 4ϕ = 12k2 + 3ϕ
⇒ ϕ = 8k2 ...(iv)
hC
⇒ 9k 2
=
λ2
1242
⇒ 9k 2
=
600
⇒ 2.07 = 9k2
⇒ k2 = 0.23 eV
∴ ϕ = 8k2 = 8 × 0.23 = 1.84 eV
18. Ans. (1)

L  L 
τr =− k  + x θ ×  + x 

2  2 
2
 mL2  L 
 + mx 2  α = − k  + x  θ
 12  2 
2
L 
k  + x
2
α = −  2  θ
( )
mL 2
+ mx
12
2
L 
k  + x
2
ω2 =  2 
mL
+ mx 2
12
d (ω 2 )
=0
dx
2
 mL2  L  L 
 + mx 2  2k  + x  − k  + x  ( 2mx )
⇒  12  2  2  =0
2
 mL2

 + mx 2 
 12 
2
 mL2  L  L 
 + mx 2  2k  + x = k  + x  ( 2mx )
 12   2   2 
mL2
+ 2mx 2 =mLx + 2mx 2
6
L
x=
6
PART-2 : CHEMISTRY
ANSWER KEY
Que. 1 2 3 4
Section-I
Ans. B A B D
Que. 5 6 7 8 9 10
Section-II
Ans. AC ABCD ABC ABD ACD BD
Que. 11 12 13 14 15 16 17 18
Section-III
Ans. 5 6 5 2 6 3 3 7
SOLUTIONS
SECTION–I
1. Ans. (B)
CaCO3 < NaHCO3 < KHCO3 < RbHCO3
2. Ans. (A)
Total charge 0.6 F = 0.6 × 96500 C

Q = It = 10 × t = 0.6 × 96500
0.6 × 96500
=t = sec. 1.6hour
10
3. Ans. (B)
Kucherov reaction
4. Ans. (D)
Theoretical
SECTION–II
5. Ans. (A,C)
ClO2 is powerful oxidising agent also strong Chlorinating agent. It's bleaching power is
almost 30 times stronger than Cl2
→ In alkaline medium it undergoes disproportionation.
→ 2ClO2 + 2NaOH → NaClO + NaClO3 + H2O
6. Ans. (A,B,C,D)
(A) Ma3b3 type compounds shows facial and meridional isomerism.
(C) It is paramagnetic due to O2−1 ligand.
(D) EDTA4– containing complexes are optically active.
[ 28 ]
7. Ans. (A,B,C)
−40.6 × 1000
∆Ssystem = =
− 54.42J / K
2 × 373
8. Ans. (A,B,D)
10−10
Conc. of Ag+ required to ppt AgCl= = 2 × 10−9
0.05
4 × 10−16
Conc. of Ag+ required to ppt AgI= = 8 × 10−15
0.05
AgI give ppt first
9. Ans. (A,C,D)
Theoretical
10. Ans. (B,D)

Theoretical
SECTION–III
11. Ans. (5)
X = Total number of (2C – 2e–) bond = 10

Y = Total number of (3C – 2e–) bond = 0
Z = Total number of (3C – 4e–) bond = 2
12. Ans. (6)

Zn, Fe, Pb, Cu, Ag, Sn produces NO2 gas on reaction with
13. Ans. (5)

Refer notes.
14. Ans. (2)

e– Jumps from 2p(since n – 1 = 1 and it is not s–Orbital )
to 3d(since it is associated with five possible orientations in space )
and 5RC RC(2)2  12 − 12 
=
9 2 n 
So change in (n + ℓ) = 5 – 3 = 2
15. Ans. (6)
1 125
= × 0.1 ⇒ Macid= 80g / mol
Macid 1000
 1 
 
0.186= (1 + α )× 1.86 ×  80  α = 0.6
 0.2 
 
16. Ans. (3)

R = K(NO)a (H2 )b
a b
1.5  372   P 
=
0.25  152   P 
a=2
a b
1.6  P   289 
=
0.79  P   144 
b=1
(a + b) = 3
17. Ans. (3)

Theoretical
18. Ans. (7)

Theoretical
[ 30 ]
PART-3 : MATHEMATICS
ANSWER KEY
Que. 1 2 3 4
Section-I
Ans. C C D B
Que. 5 6 7 8 9 10
Section-II
Ans. A,B,C,D A,B A,C B,C,D A,D B,C,D
Que. 11 12 13 14 15 16 17 18
Section-III
Ans. 5 7 9 4 7 2 4 1
SOLUTIONS
1. Ans. (C)
Coefficient of x2r in (1+x+x2)n
= Coefficient of x2r in (1+x(1+x))n
n
 1 3
2
= Coefficient of x in   x +  + 
2r
 2  4 

Coefficient of x2r in (1+x(1+x))n
r n r+i
= ∑ i+r
i =0 n − r − i 2i r − i
n
 1 3
2
Coefficient of x 2r
in   x +  + 
 2  4 

2. Ans. (C)
SA⊥SB
SB⊥SC
SC⊥SA
SA·SB = 0 ⇒ α2 + β2 + γ2 = aα + bβ
SB·SC = 0 ⇒ α2 + β2 + γ2 = bβ + cγ
SC·SA = 0 ⇒ α2 + β2 + γ2 = cγ + aα
α2 + β2 + γ 2
So = aα = bβ = cγ
2
1   
Volume
= =[a b c ] 6
6
⇒ abc = 36
(α )
3
2
+ β2 + γ 2
= 36
8αβγ
3. Ans. (D)
(x – 1) (x2 – 2)..........(x10 – 10)
heighest power of x is 55 so we have to reduce 10 power's
= –10 + (9 + 16 + 21 + 24) – (14 + 18 + 20 + 30) + (24) = 2
4. Ans. (B)
α + β + γ = –α ⇒ 2α + β + γ = 0
αβ + βγ + γα = β ⇒ (α + β) γ – 1 = β
αβγ = – γ
⇒ αβ = – 1
(α + β) (–2α – β) – 1 = β
⇒ –2α2 – αβ – 2βα – β2 – 1 = β
⇒ –2α2 – β2 + 2 = β
1 −1
⇒ − 2α2 − +2=
α 2
α
⇒ 2α4 – 2α2 – α + 1 = 0
two real values of α such that exactly two solution
[ 32 ]
5. Ans. (A,B,C,D)
Sol. g' (x) = f(x) f'(x) + 25x4 > 0
⇒ f(x) f'(x) > –25x4
1 1
∫
⇒ f ( x ) f ′( x )dx > ∫ −25x dx
4
0 0
1 1
 f 2( x )   −25x5 
⇒  > 
 2 0  5 0
f 2(1) f 2(0)
⇒ − > − 5
2 2
f 2(1)
⇒ > 13 ⇒ f 2(1) > 26
2
0 0
∫ f ( x ) f ′( x )dx > ∫ (−25x )dx

4
−1 −1
f 2(0) f 2( −1)
⇒ − > − (5( −1))
2 2
⇒ f2 (–1) < 46
1
g(3) > g (0); g   > g(0)
2
1
g(3) > 13; g   > 13
2
6. Ans. (A,B)
 n  r 1/3 
n 1/3
∑
   
lim  r =1  n  
n
n →∞ n7/3 1
n2 ∑
r =1 r
2
 α + n 
 
1
∫x 3 dx
1/3
= 1= 0 4
1 − 1 1
+
0
(α + x )2 ∫
dx α + 1 α
3
⇒
4
( α ( α + 1) ) =15
⇒ α ( α + 1) =20
α = 4, –5
7. Ans. (A,C)
I /2
∫ cos
n −1
=α n −1 x cos( n − 1)x dx
0
I /2
∫ cos
n −1
=α n −1 (cos nx·cos x + sin nx·sin x ) dx
0
αn–1 = αn + αn ⇒ αn–1 = 2αn

0, if n ∈ even
βn =
 I , if n ∈ odd
8. Ans. (B,C,D)
f(x) is continuous at all x ∈ R
 3( x + 1)2 + 1 , x<0

 2x − 1 , 0< x <1
f ′( x ) = 
 x−4 , 1< x <3
 n ( x − 2 ) , x >3

9. Ans. (A,D)
 −1 0 0 
 −1 0 −1
A =
1
 
 0 −1 0 
1 0 0
A = 1 1 0
2
1 0 1
[ 34 ]
 −1 0 0 
 −2 0 −1
A =
3
 
 −1 −1 0 
1 0 0
A = 2 1 0
4
2 0 1
 −1 0 0 
 −3 0 −1
A =
5
 
 −2 −1 0 
10. Ans. (B,C,D)

eqn of PA & PB
5M − 6
2 = M(x − 1) ⇒ = 2
1 + M2
= (5M – 6)2 = 4 ( 1 + M2)
= 25 M2 – 60M + 36 = 4 + 4M2
= 21 M2 – 60M + 32 = 0
60 ± 912 30 ± 228
=M =
42 21
least possibility to kill is when Konda is at D
61x + 2 61y + 4
=6 =8
2 + 61 2 + 61
10 + 6 61 12 + 8 61
x= y=
61 61
11. Ans. (5)
(t 1/2
)
− 1 dt
∫ 1
( )
t 1 + t 1/4 + t −1/4 t 1/4 t 1/4 +
t 1/4
1 1 1 
t 1/4 + 1/4
=v 2 ⇒  t −3/4 − t −5/4  dt =2v dv
t 4 4 
1  t 1/2 − 1 
⇒  5/4  dt = 2v dv
4 t 
8vdv
= ∫ (v
=
+ 1)v
2
8tan −1 (v) + c
 1 
= 8tan −1  t 1/4 + 1/4  + c
 t
 
 1
2g 2(16) = 2 2 +  = 5
 2
12. Ans. (7)

f (f(x)) = 6 ⇒ f(x) = –2, 1 or 3
f(x) = –2 has 5 solutions.
f(x) = 1 has 6 solutions.
13. Ans. (9)

19
′1 ( x ) ∏( x − i)
i
g=
i =1
g′1(x) = (x – 1)1 (x – 2)2 (x – 3)3 ... (x – 19)19
α1 = { 19, 15, 11, 7, 3} = 5

β1 = {17, 13, 9, 5, 1} = 5
g′2(x) = 98 × 50(x – 1)49 – 100 × 49(x – 1)48
= 4900 (x – 1)48 (x –1 –1)
= 4900 (x – 1)48 (x – 2)
α2 = 1
β2 = 0
g3(x) = (x – 1)2020(x – 2)2021 (x – 3)2022
[ 36 ]
 2020 2021 2022 
′3 ( x ) g3 ( x ) 
g= + + 
 x −1 x −2 x −3 
g3 ( x )
= [2020(x – 2) (x – 3 ) + 2021 (x – 1) (x – 3) + 2022(x – 1) (x – 2)]
( x − 1)( x − 2)( x − 3)
= (x – 1)2019 × (x – 2)2020 × (x – 3 )2021 × [6063x2 – 24250x + 22227]
α3 = 2
β3 = 2
∴ λ – 20
= 25 + 0 + 4 – 20 = 9
14. Ans. (4)

f(x) is symmetric about y = x
3π
Required area = 2 ∫ f(x) − x dx
0
π π
2 × 3∫ ( f(x) − x ) dx =
= 2 × 3∫ sin xdx =
12
0 0
15. Ans. (7)

6!
123 × 3! × 2! × 3! = 6! × 6
1!2!3!
6! 2!2!2!
222 × × 3! = 6!
2!2!2! 3!
______________________________________
Sum = 6! × (6 + 1) = 6! × 7
∴λ=7
16. Ans. (2)

x(y3–x)dy = y (x+y3)dx
xy3dy – x2dy = xydx + y4dx
y3 (xdy – ydx) = x2dy + xy dx
y
⇒ y 3x2d   =
xd(xy)
x
d(xy) y y
⇒∫ ∫
= d
2 2
xy x  x 
⇒ y3 = –2x
17. Ans. (4)
tan −1=
2x (2x)2 − 1
18. Ans. (1)

let f–1(x) = g(x)
f(g(x)) = x
⇒ f ' (g(x)) . g' (x) = 1
1
g′(3) =
′
f (g(3))
f'(x) = 3x2 + 6x–4
−2
t+ + 10 = 9 ⇒ t 2 + t − 2 = 0
t
⇒ t = 1 ⇒ x3 = 1
x=1
[ 38 ]

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(Academic Session: 2022 - 2023)

ONLINE TEST SERIES CONTACT PROGRAMME

JEE (MAIN + ADVANCE)

PATTERN : ADVANCED COURSE : LEADER

READ THE INSTRUCTIONS CAREFULLY

Your Hard Work Leads to Strong Foundation

SECTION–II : (Maximum Marks : 24)

(A) Charge on ball is q = παR2

parallel to the plane. Which of the following is/are correct?

(D) Angular acceleration of disc is

(A) Separation between A and B is maximum at t = 1 sec.

(A) Between point A and B.

SECTION–III : (Maximum Marks : 24)

17. A metallic surface is illuminated alternatively with electromagnetic radiations of

2. For an electrolytic cell undergoing following balanced reaction :

4. Monomer units of Biodegradable polymer PHBV are :

5. Which of the following statement(s) is are correct ?

6. Which of the following are correct statements(s) :

7. Which of the following statement(s) is/are False ?

(A) (B) HNO3

(C) SeO2 (D) CrO3 /

10. Which reagent can be used to form 2-Chloropropane from Propan-2-ol

(A) NaCl (B) (i) , (ii) NaCl

(C) NH4Cl (D) PCl3

SECTION–III : (Maximum Marks : 24)

3. The coefficient of x45 in is :

SECTION–II : (Maximum Marks : 24)

(H) f 2 (–1) < 46

6. If and α ∈ R+ then α is equal to :

(E) characteristic value of log1039

then which of the following option is/are correct?

SECTION–III : (Maximum Marks : 24)

g 2(x) = 98(x − 1)50 − 100(x − 1)49 + 2450, x > 0

17. The number of solution(s) of the equation tan −1 2 x= 16x 4 − 8x 2 + 1 , is(are)

ΔQ1 = 120 – 100 = 20 mC

There will be null point

10. Ans. (B, D)

11. Ans. (8)

12. Ans. (7)

13. Ans. (4)

14. Ans. (2)

Using conservation of momentum of system.

15. Ans. (3)

Total mechanical energy

The tension produced in each wire,

17. Ans. (2)

18. Ans. (1)

Total charge 0.6 F = 0.6 × 96500 C

10. Ans. (B,D)

X = Total number of (2C – 2e–) bond = 10

12. Ans. (6)

13. Ans. (5)

14. Ans. (2)

16. Ans. (3)

17. Ans. (3)

18. Ans. (7)

= –10 + (9 + 16 + 21 + 24) – (14 + 18 + 20 + 30) + (24) = 2

∫ f ( x ) f ′( x )dx > ∫ (−25x )dx

αn–1 = αn + αn ⇒ αn–1 = 2αn

10. Ans. (B,C,D)

12. Ans. (7)

13. Ans. (9)