706 Aed 831676438
706 Aed 831676438
TIRUNELVELI
PG - COURSES – AFFILIATED COLLEGES
Course Structure for M.Sc. Chemistry
( Choice Based Credit System)
( with effect from the academic year 2016- 2017 onwards )
(44th SCAA meeting held on 30.05.2016)
Page 1 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr. No.13 / Core-7
Basic Principles– Base peak – molecular ion – nitrogen rule – metastable ions – isotopic
peak - daughter ions – Mc–Lafferty rearrangement – RDA – General rules for fragmentation
pattern – Fragmentation pattern of simple compounds of hydrocarbons, alcohols, amines,
aldehyde, ketone, ether, acids, phenols ,nitro compounds, alicyclic compounds .
Alternative electron impact ionization technique– CI, FAB, ESI – MS, MALDI –MS,
MALDI-TOF, ICP- MS.
One conjunction problem based on UV, IR, H1 NMR, 13C NMR and Mass
spectroscopic techniques is compulsory under section – c. Problems shall be based on the
reference books.
Page 2 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr. No.13 / Core-7
pericyclic reactions: Atomic and molecular orbital‟s -Woodward-Hoffmann rules, FMO method
and correlation diagram approaches:
Electrocyclic reaction: con and dis rotatory motions for 4n and 4n+2system (butadiene and
1,3,5-hexatrienes)- Stereochemical course of electro cyclic reaction in terms of conservation of
orbital symmetry.
Cyclo addition: suprafacial and antarafacial, [2+2] and [4+2] cyclo addition reactions (ethylene
and butadiene)
Sigmatropic rearrangements - [i, j] shift of C-H and C-C bonds (1,3) and (1,5) carbon
migration.
Pyranose and furanose forms of aldohexose and ketohexose-methods used for the
determination of ring size-A Detailed study on the structure of maltose, lactose and starch.
REFERENCES :
1. J.March, „ Advanced organic chemistry‟, Fourth Edition, John Wiley and Sons,
Newyork, 2006.
2. Depuy, E.C.H. and Chapman, O.S., “Molecular reactions and photochemistry” ,
Prentice Hall, New York, 1988.
3. I.L. Finar, „Organic Chemistry‟, volume 2, sixth Edition, Pearson Education
Inc., Singapore, 2006.
4. Raj K. Bansal, „Organic Reaction mechanisms”, Tata Mc Graw Hill, Third Editon,
2007.
5. Y.R. Sharma,‟Fundamentals of Organic spectroscopy‟.
6. S. Kalsi, „Spectroscopy of organic spectroscopy‟, second Edition , New Age International
publishers Limited, 1995 .
Page 3 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr. No.13 / Core-7
7.Jag Mohan, „Organic Analytical Chemistry Theory and Practice, „ Narosa Publishing
House, 2003.
8. W.Kemp, „Organic spectroscopy‟, Third Edition, Macmillan, 1994.
9. S.M. Silverstein, G.V.Bassler and T.C. Morril, „Spectrometric Identification of organic
compounds, sixth Edition, Wiley 2004.
10. D.H.Williams and Ian Fleming, „Spectroscopic methods in organic chemistry,‟fifth
Editon, Tata Mc Graw Hill, 1988.
11.F.W. Wherli and T. Wirthilin, „Interpretation of carbon – 13 spectra‟, Heyson and sons,
London.
12. V.R. Dani, „Organic spectroscopy‟, Tata Mc Graw Hill, 1995.
13 . J.R. Dyer, „Application of Absorption spectroscopy, prentice Hall, 1987.
14. Pavia, Lampmann, Kriz and Vyuyan, spectroscopy, cengage learning India Private Ltd.,
First Indian Reprint,2008.
15. D.H. William and R.D. Bower, „Mass spectrometry – principles and Applications,‟ I.
Howe, Mc Graw Hill.
16.R.M. Silverstein and F.X.Webster, „Spectrophotometric Identification of Organic
Compounds‟ John Wiley and Sons, Ine., Sixth Edition, 1997.
17.Singh, J., and Singh, J., “Photochemistry and Pericyclic reaction”, New Age
International, New Delhi, 2004.
18.H.O. House, „Modern synthetic Reaction,‟Second Edition , W.A. Benjamin, Inc.,
London, 1972
19.R.K. Mackie, M.M. Smith and R.A. Aitken,‟Guide Book to Organic Synthesis‟
Second Edition, Longman Seientific and Technical, Singapore, 1990.
20.Carrutherus , W., “ Some Modern Methods in Organic Syntheis”, Third edition,
Cambridge University Press, New York, 1997.
21.F.A. Carey and J.Sundberg,‟Advanced Organic chemistry „ part A and B, Plenum
Press, 2005.
22. Michael B. Smith, „Organic Synthesis,‟ Mc Graw Hill international Edition ,
1994.
23. P. Sykes, „A Guide book to mechanism in organic chemistry‟, Orient Longman,
1989.
24.Gurdeep R. Chatwal, „Reaction mechanism and Reagents in organic chemistry‟,
Himalaya publishing House, Bombay 1992.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr. No.13 / Core-7
25. R.T. Morrison and R.N. Boyd,‟Organic Chemistry‟ sixth Edition, Prentice Hall,
1994.
26. R.O.C .Norman, Principles of organic synthesis- Chapman and hall, London.
27. De Mayo, Molecular rearrangements
28. E.S. Gould, „Mechanism and structure in organic chemistry‟ Holt, Rinehart and
Winston Inc., 1959
29. F.A. Carey, Organic chemistry – Tata Mc Graw Hill, Delhi, 5th edition 2005.
30. Stryer, L., “Biochemistry”, Fifth edition, W.H.Freeman and company, San Francisco,
2002.
31. Jain, J.L., “Fundamentals of Biochemistry”,Fourth edition, S.Chand & Company
Limited, New Delhi.2007.
32. Bansal, K., “Heterocyclic Chemistry”, Fourth edition, New Age International, New
Delhi, 2005.
33. Organic chemistry by Clayden,Greeves, Warren & Wothers.
34. Pericyclic reactions by Ian Fleming.
35.Organic chemistry by John McMurry.
36. Organic chemistry by L.G. Wade. JR.
37. Named Organic reactions by Thomas laue & Andreas Plagens.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.14 / Core-8
Organometallic compounds as catalysts and the requirements - Oxidative addition and reductive
elimination- insertion and elimination reactions - nucleophilic and electrophilic attack of
coordinating ligands - addition to bimetallic species and cyclo metallation reactions.
Homogeneous catalysis –Wilkinson‟s catalyst and hydrogenation reactions, Tollman‟s catalytic
loop; hydroformylation (oxo) reaction, Wacker and Monsanto acetic acid processes. Cluster
compound, polymer-supported and phase-transfer catalysis. Heterogeneous catalysis – synthesis
gas and water gas shift reactions; Fischer Tropsch process and synthetic gasoline, Ziegler-Natta
polymerization and mechanism of stereo regular polymer synthesis. Cyclo oligomerisation of
acetylenes (Reppe‟s or Wilke‟s catalyst)-Olefin isomerisation using Ni catalyst – olefin Meta
thesis catalysed by Schröck type carbene.
NMR Spectroscopy: 31P, 19F and 15N - NMR - applications in structural problems based on
number of signals, multiplicity, anisotropy (like [H Ni(PPh3)4]+, CFCl3, SF4, TiF4,PF5, HPF2,
H2PF3, PF3(NH2)2, P4S3, mer - and fac – Rh (PPh3)3Cl3, P3N3(CH3)2Cl4,P4N4Cl6(NHC6H5)2,NF3,
NH3- fluxional molecules (including organometallic compounds) and study of fluxionality by
NMR technique - NMR of paramagnetic molecules - contact shifts. Evaluation of rate constants -
monitoring the course of reaction using NMR.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.14 / Core-8
EPR spectroscopy: Zero field splitting and Kramer‟s degeneracy - Application of EPR in the
study of transition metal complexes based on number of signals, multiplicity, anisotropy (like bis
(salicylaldimine)copper(II),[Cu(bpy)3]2+,[Cu(Phen)Cl2],[(NH3)5Co-O2-Co(NH3)5]5+,Co3(CO)9Rh,
[CoF6]4-, [CrF6]3-, VO(acac)2, Fe(CO)5+, Fe(CO)5-, [Fe(CN)5NO]2-,[Mn(dppe)2],[MnF6]4-).
Applications in predicting the covalent character of M-L bond and Jahn-Teller distortion in
Cu(II) complexes. EPR spectroscopy of metallo biomolecules: copper and iron proteins.
Theory and principles of thermo gravimetric analysis, differential thermal analysis and
differential scanning colorimetry – characteristic features of TGA and DTA curves-factors
affecting TGA and DTA curves- complementary nature of TGA and DTA – applications of
thermal methods in analytical chemistry - thermometric titrations - the study of minerals and
metal compounds. Principle and applications of colorimetry, spectrophotometry, nephelometry,
turbidimetry, fluorimetry, atomic absorption spectroscopy and atomic emission spectroscopy
based on plasma sources.
Frank Condon and thermally equilibrated excited (THEXI) states - properties of excited states of
metal complexes (life time, redox potential etc.) – charge transfer excitation – bimolecular
deactivation (quenching) and energy transfer – photochemical path ways : oxidation-reduction,
isomerisation and substitutional processes – photochemistry of Cr(III), Co(III) complexes –
Photochemical reactions of metal carbonyls. Photo physical and photochemical properties of
[Ru(bpy)3]2+and comparison with [Fe(bpy)3]2+– Applications of inorganic photochemistry:
photochemical conversion and storage of solar energy – inorganic photochemistry at semi-
conductor electrodes - Catalyzed photo reduction of CO2 and CO – TiO2as a green photo catalyst
in removing air and water pollutants.
REFERENCES:
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.14 / Core-8
Page 8 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.15 / Core - 9
UNIT-II: GROUP THEORY II Standard Reduction Formula. Symmetry selection rules for
infrared, Raman and electronic Spectra and Mutual exclusion principle. Determining Symmetries
of normal vibrational modes for non linear molecules H2O, NH3 and trans-N2F2. Projection
operators and construction of Symmetry Adopted Linear Combinations. Determination of Hybrid
orbitals in non-linear molecules (BF3, CH4, XeF4, BF3, PF5, and SF6). Electronic Spectra of
Ethylene and formaldehyde- Simplification of HMO calculations using group theory. Calculation
of delocalization energy for ethylene, cyclo propenyl, 1,3-butadiene, and benzene systems.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.15 / Core - 9
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no.15 / Core - 9
REFERENCES:
1. George Davidson,Introductory Group Theory For Chemists.
2. F. Albert Cotton, Chemical Applications of Group Theory,Third Edition, John Wiley &
Sons, Singapore, 2003.
3.V. Ramakrishnan and M. S. Gopinathan,Group Theory in Chemistry, Vishal
Publication,1986.
4. Robert L. Carter, Molecular Symmetry and Group Theory, John Wiley and Sons, Inc., New
York, 1998.
5. R.L. Flurry, Jr, Symmetry Groups – Prentice Hall, New Jersy 1980.
6. K. V. Raman,Group Theory and its applications to Chemistry.
7. K.Veera Reddy,Group Theory and Spectroscopy.
8. B.K. Battacharya,Group Theory and its Chemical applications
9. C McGraw Hill, New Delhi, 2000. N. Banwell and E. M. McCash, Fundamentals of
Molecular Spectroscopy, 4th ed., Tata
10. K. V. Raman, R. Gopalan and P. S. Raghavan, Molecular Spectroscopy, Thomson and
Vijay Nicole, Singapore, 2004.
11.P. Atkins and J. de Paula, Physical Chemistry, 7th ed., Oxford University Press, Oxford,
2002.
12. I N. Levine, Molecular Spectroscopy, John Wiley & Sons, New York, 1974.
13. A. Rahman, Nuclear Magnetic Resonance-Basic Principles, Springer-Verlag, New York,
1986.
14. D. L. Andrews, Lasers in Chemistry, 3rd ed., Springer-Verlag, London, 1997.
15. K. Nakamoto, Infrared and Raman Spectra of Inorganic and coordination Compounds, Part
B: 5th ed., John Wiley & Sons Inc., New York, 1997.
16. R. S. Drago, PhysicaI Methods in Chemistry; Saunders: Philadelphia, 1977.
17. J. A. Weil, J. R. Bolton and J. E. Wertz, Electron Paramagnetic Resonance; Wiley
Interscience: 1994
18.McGraw-Hill Publishing Company, New Delhi, 1988. D. H. Williams and I.Fleming,
Spectroscopic Methods in Organic Chemistry, 4th ed., Tata.
19.R. M. Silverstein and F. X. Webster, Spectroscopic Identification of Organic Compounds,.
6th ed., John Wiley & Sons, New York, 2003.
20.I. N. Levine, Molecular Spectroscopy, John Wiley & Sons, New York, 1974
21. G. Aruldhas, Molecular structure and spectroscopy
Page 11 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no. 16 / Core-10
Access points for searching CA indexes- Index guide, general subject, terms, chemical
substance names, molecular formulas, ring systems, author names, patent numbers.
Locating the reference: finding the abstract, finding the original document chemical abstract -
service source index.
Identification of research problem – assessing the status of the problem - guidance from
the supervisor – actual investigation and analysis of experimental results – conclusions.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no. 16 / Core-10
Sample preparation of UV, FT-IR, TEM, SEM, EDAX, AFM and XRD techniques -
Characterization of observed results – Data analysis - Report.
ASAP – Alerts, CA Alerts, scifinder, chemport, science direct, STN international, journal
home pages. Online browsing of research articles – online submission of research papers in
various Journals (ACS, RSC, Elsevier, Springer etc.) –Instructions to the authors – Impact
factors. Writing project proposal to funding agencies (UGC, DST etc.).
REFERENCES
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-III / Ppr.no. 16 / Core-10
Page 14 of 27
MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-IV / Ppr.no.17 / Core-11
Organic Chemistry – IV
Modern Reagents: Introductory treatment of the application of silicon (Tri alkyl silyl
halides, organo silanes), Boron (9 – BBN, borane, and alkyl borane), phosphorus
(phosphoranes), palladium (Still coupling, Suzuki Coupling, Heck and Negishi reactions)
samarium(SmI2),Ruthenium(RuO2,Ru-Binap Complex), Rhodium(Wilkinson‟s Catalyst), and
platinum (PtO2, Adam‟s Catalyst) reagents in organic synthesis.
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester-IV / Ppr.no.17 / Core-11
UNIT-V: STEROID
REFERENCES :
1.J.March, „Advanced organic chemistry‟, Fourth Edition, John Wiley and Sons, Newyork,
2006.
2. R.T. Morrison and R.N. Boyd,‟Organic Chemistry‟ sixth Edition, Prentice Hall, 1994
3. Michael B. Smith, „Organic Synthesis,‟ Mc Graw Hill international Edition , 1994
4. R.O.C. Norman, Principles of organic synthesis- Chapman and hall, London.
5. Carrutherus , W., “ Some Modern Methods in Organic Synthesis”, Third edition,
Cambridge University Press, New York, 1997.
6. P. Sykes, „A Guide book to mechanism in organic chemistry‟, Orient Longman,
1989.
7. J.M.Swan and D.St.C.Black, Organometallics in Organic synthesis
8. Gurdeep R. Chatwal, „Reaction mechanism and Reagents in organic chemistry‟,
Himalaya publishing House, Bombay 1992
9. E.L. Eliel, stereochemistry of carbon compounds – Mc Craw Hill, 1999
10. Gurdeep R. Chatwal, „Reaction mechanism and Reagents in organic chemistry‟,
Himalaya publishing House, Bombay 1992.
11.R.C.Mehrota and A.Singh, Organometallic chemistry-a unified approach-Wiley
Eastern
12.F.A. Carey and R.A Sundberg, „Advanced Organic Chemistry‟ (part A and B)
plenum publishers, 2000.
13.B.M.Trost & I Fleming. Comprehensive Organic Synthesis. Vols 1-9, Pergamon
(1991).
14. I.L. Finar, Organic Chemistry , Vol. II. ELBS
15. L.Fieser and Mary Fieser, Steroids-Reinhold
16.A.L. Lehninger, D.L.Nelson and M.M.Cox-Principles of Biochemistry-Worth
Publisher Inc. USA,1993.
17. F.A Carey,‟Organic Chemistry, Tata Mc Graw Hill, fifth reprint, 2005.
18. A.Burger, Medicinal chemistry-Acdemic press.
19.R.E. Ireland,Organic Synthesis-Prentice Hall of India (P)Ltd.
20.S.Warren,A Programmed Synthon approach-John Wiley & Sons.
21.R.K.Mackie & D.M.Smith, Guide book t organic syntheisi-ELBS.
22.Progress in chemistry of Natural products, Vol.19,1961, JCSC Lon., 869, 1952
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.17 / Core-11
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.18 / Core-12
Inorganic Chemistry- IV
Mossbauer spectroscopy: Principle – isomer shift (IS) – splitting of resonance lines: quadrupole
splitting and magnetic hyperfine splitting. Applications: MB spectra of iron compounds/
complexes – structural elucidation, π- bonding effect, HS and LS determination, spin state
crossover determination, cis–trans determination – nature of the complexes - mixed valence
complexes. Tin compounds: MB spectra of Sn(II) and Sn(IV) compounds, oxidation states of Sn
in its different compounds. MB spectra of iodine and 129Xe containing compounds.
Photo electron spectroscopy :Theory – types of PES –origin of fine structures – shapes of
vibrational fine structures – adiabatic and vertical transitions – PE spectra of homo (like N2, O2)
and hetero nuclear diatomic molecules (like CO) - polyatomic molecules like H2O, CO2,
CH4,NH3.Evaluation of vibrational constants – Koopman‟s theorem - application and limitation
of the theorem. XPS (ESCA): structure of N3-ion, CCl3CH3, N(1s) spectrum of
[Co(en)2(NO)2]NO3,C(1s) spectrum of C2H5COOCF3.Shake-up and shake-off processes –
Structural and bonding information in metal carbonyls – Auger (OhJay) electron spectroscopy.
Non-metals and metals in biological systems, essential and trace elements; classification of
metallo-biomolecules, coordination environment and entatic state. Metallo porphyrins–
chlorophyll and photo synthesis; cytochromes, hemoglobin, myoglobin and dioxygen binding,
vitamin B12 and co-enzyme - in vivo and in vitro nitrogen fixation. Iron storage and transport:
ferritin, transferrins and siderophores - iron proteins: hemerythrin, cytochrome P450 enzyme,
ferredoxin and rubredoxin.
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.18 / Core-12
Copper proteins and Enzymes: plastocyanin, azurin, hemocyanin and ascorbic oxidase - different
types of Cu present in proteins and enzymes. Zinc enzymes: carboxypeptidase A, carbonic
anhydrase and superoxide dismutase. Inhibition and poisoning of enzymes illustrated by xanthine
oxidase and aldehyde oxidase. Toxicity of metals and the role of metallothionins - excess and
deficient levels of Cu and Fe and the consequent diseases - chelate therapy – metal complexes as
drugs, anticancer and antiarthritic agents. Metal complexes as probes of nucleic acids.
UNIT – V: CHEMISTRY OF INORGANIC MATERIALS
REFERENCES:
1. R.S. Drago, Physical Methods in Inorganic Chemistry, Chapman and Hall Ltd., London,
1965.
2. R.S. Drago, Physical Methods in Chemistry, Saunders Golden Sunburst series.
3. E.A.V. Ebsworth, D.W.H. Rankin and S.Cradock, Structural Methods in Inorganic
Chemistry, ELBS, 1988.
4. B.P.Straughan and S.Walker, Spectroscopy Volume 3, John Wiley and Sons Inc.,
Newyork, 1976.
5. G.H.Jeffery, J. Bassett, J. Mendham and R.C. Denney,Vogel‟s Textbook of Quantitative
Chemical Analysis, Revised 5th edition, ELBS, 1989.
6. James E.Huheey, Ellen A.Keiter and Richard L.Keiter, Inorganic Chemistry, Priciples of
Structure and Reactivity, 4th Edition, Harper Collins College Publishers, 1993.
7. F.Albert Cotton, Geoffrey Wilkinson, Carlos A.marilo and Manfred Bochman, Advanced
Inorganic Chemistry, Wiley Interscience Publication,6th Edition, 1999.
8. K.F.Purcell and J.C.Kotz, Advanced Inorganic Chemistry, Saunders Golden Publishers.
9. D.E.Fenton, Bio-coordination Chemistry, Oxford Science Publications, 1995.
10. I.Bertini, H.B.Gray, S.J.Lippard and J.S.Valantine, Bioinorganic Chemistry, Viva Books
Pvt. Ltd., 1998.
11. Mark.T.Weller, Inorganic Materials Chemistry, Oxford Chemistry Press, Oxford Science
Publications, Reprint 1996.
12. Inorganic chemistry by Catherine E. Housecroft.
13. Inorganic chemistry by Miessler.
14. NMR, NQR, EPR & MOSSBAUER spectroscopy in inorganic chemistry by R.V.Parish.
15. Biological inorganic chemistry: An introduction by Robert R.Chrichton.
16. Bioinorganic chemistry: A short course by Rosette M. Roat – Malone.
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.19 / Core-13
Physical Chemistry- IV
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.19 / Core-13
REFERENCES
1. Chemical Kinetics and Dynamics; Jeffrey I Steinfeld, Joseph S. Francisco and William L.
Hase. Prentice Hall, 2nd edition, 1998.
2. Laidler, K. J.; “Chemical Kinetics", 3rd Edition 1997 , Benjamin-Cummings. Indian
reprint - Pearson 2009.
3. R.G.Frost and Pearson, Kinetics And Mechanism, Wiley, New York,1961.
4. W.J.Moore and R.G.Pearson, Kinetics And Mechanism,1981.
5. C.Capellos and B.J.J.Bielski,Kinetics Systems,Wisely Inter Science,New York, 1972.
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester-IV / Ppr.no.19 / Core-13
6. Ambur and G.G.Hammes, Chemical Kinetics, Principles And Selected Topics, Mcgraw
Hill, New York, 1968.
7. G.M.Harris, Chemical Kinetics, D.C.Heat And Co.,1966.
8. G. L. Agarawal, Basic Chemical Kinetics, Tata McGraw Hill, 1990.
9. G. D. Billing & K. V. Mikkelson, Molecular Dynamics and Chemical Kinetics, John
Wiley, 1996.
10. G. D. Billing & K. V. Mikkelson, Molecular Dynamics and Chemical Kinetics, John
Wiley, 1996.
11. A.W. Adamson, A.P. Gast, Physical chemistry of surfaces, Wiley, 1997.
12. H.-J. Butt, K. Graf, M. Kappl, Physics and Chemistry of Interfaces, Wiley-VCH, 2006.
13. D.K. Chakrabarty and B. Viswanathan, Heterogeneous Catalysis, New Age, 2008.
14. H. Kuhn, H.-D. Forsterling, D.H. Waldeck, Principles of Physical Chemistry, Wiley, 2009.
15. G.A. Somorjai, Y. Li , Introduction to Surface Chemistry and Catalysis (2n ed.), 2010.
16. J.J Bikertman, Surface Chemistry: Theory and Applications, Academic Press, New York
(1972).
A. List of Estimations
1. Ethyl methyl ketone
2. Glucose-Lane Eynon and method
3. Glucose-Bertrand‟s method
4. Saponification value of oil
5. Iodine value of oil
6. Determination of Percentage purity in an unsaturated acid.
7. Purity of Glucose
B. List of Two stage preparations
1. Benzaldehyde Benzoic acid m-nitro benzoic acid
2. Acetanilide p-acetanilide p-Bromoaniline
3. Methyl benzoate m-nitro methyl benzoate m-nitro benzoic acid
4. Acetanilide p-nitro acetanilide p - nitroaniline
5. Benzophenone Benzo phenone oxime Benzanilide
6. Benzophenone Benzpinacol Benzpinacolone
7. Phthalic acid Phthalic anhydride Phthalimide
8. Thiourea s-benzyl isothiuronium chloride s- Benzyl-isothiuronium
benzoate
9. Aniline Tri bromoaniline Sym-Tribromobenzene
Students are expected to submit at the time of practical examination at least eight
recrystallised samples of the final products, for evaluation by the examiners.
(I)Chromatographic techniques
1. TLC of Nitroaniline
2. TLC of Analgesic Drug
3. Column Chromatography-Separation of leaf pigments
4. Paper Chromatography-Analysis of Inks and Dyes
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester III & IV / Ppr. No.20 /
Practical-IV
(II)Spectral analysis:
5. Interpretation of H1 NMR spectra of pure ethyl alcohol and aqueous ethyl alcohol.
6. DEPT spectra of isopentyl acetate.
7. Mass spectrum of Anisole, Phenol and Crotonaldehyde
N.B: 1.Section -C is course work only.
2. It is for the purpose of internal assessment only.
REFERENCES
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester III & IV / Ppr.no.21 /
Practical-V
I . Quantitative estimation of a mixture containing two metal ions (Volumetric and Gravimetric
Estimations ).
Note: For examination , a mixture may be given from which one cation is to be estimated
volumetrically and the other gravimetrically .
Note : Characterisation of any two metal complex prepared during the practicals by UV or IR
spectral techniques (course work only )
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MSU / 2016-17 / PG-Colleges / M.Sc.(Chemistry) / Semester III & IV / Ppr.no.22 /
Practical- VI
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MSU / 2016-17 / PG-Colleges / M.Sc. (Chemistry) / Semester IV / Ppr.no.23 / Project
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