Test Organic Chemistry (25!11!2023)

25112023 Test Ranker Batch
ORGANIC CHEMISTRY
(for JEE-Mains & Advanced 2025)
Time : 2 : 30 Hr. Max. Marks :416
* Each question + 4 (for correct answer) & - 1 (for wrong answer)
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01. Benzene on reaction with allyl chloride in presence of anhyd. AlCl3 gives (A), which
on ozonolysis gives (B) and (C). The DBE of (B) is ‘n1’ and that of (C) is ‘n2’ {n1> n2}.
(A) on reduction with H2–Ni gives (D).
Which of the following is correct :
CH2
(a) (A) is Ph–C and n1 + n2 is 6.
CH3
(b) (A) is PhCH2CH=CH2 and n1 & n2 both are odd numbers.
(c) Position iosmer of (A) is PhCH=CHCH3 and n1 – n2 is equal to DBE of (D).
(d) Both (b) and (c).
02. PhCH2COOH on heating with sodalime gives (A) and PhCH2CH2COOH on heating with
sodalime gives (B)
Which of the following is correct.
(a) (A) on reaction with Br2/Fe gives PhCH2Br
(b) (B) on reaction with Br2/hv gives PhCH2CH2Br
(c) (A) on reaction with Conc. HNO3/Conc. H2SO4 gives product at faster rate as
compared to that of (B) in the same reaction.
(d) (A) on reaction with hot alkaline KMnO4 gives different product than the product
obtained on reaction of (B) with hot alkaline KMnO4.
03. on reaction with Br2 /hv mainly gives :
Br Br
Br
(a) (b) (c) (d)
Br
COOH
NaOH/CaO Conc. HNO 3

04. (A) (B)
Heat Conc. H2SO 4
CH2COOH
(B) Br2 / Fe (C) ; The structure of (C) is :
Me NO2
Br Br NO 2
(a) (b) NO 2 (c) Br (d)

NO2 Me Me CH2 Br
Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
Contact Number : 9889655556 page no # 1
NHCOCH3 NO2
Conc. HNO 3
05. (A) ; Br2 / Fe (B)
Conc. H2SO 4
Which of the following is Incorrect :

(a) The formation of (A) takes place at faster rate than that of (B).
(b) The sum of number of nitrogen atoms in one molecule of each of (A) and (B) is 3.
(c) (A) is p-nitroacetanilide and (B) is mixture of o, p-bromonitrobenzene.
(d) In the formation of (A) the attacking reagent is NO2 and in the formation of (B)
the attacking reagent is Br .
06. Which of the following can show geometrical isomerism :
CH3 CH3 CH3 CH3
(a) (b) (c) (d) C2H5
CH3 CH3 CH3
07. o/p ratio is highest for nitration of which of the following compound ?
(a) Ethyl benzene (b) Toluene
(c) Isopropyl benzene (d) Tertiarybutyl benzene
08. p-Nitrotoluene on further nitration gives :
CH3 CH3 CH2OH
CH2OH
NO 2
NO2 NO2
(a) (b) (c) (d)
NO 2
NO 2 NO 2 NO 2 O2N
09. Which order is correct for the decreasing reactivity to ring monobromination of the
following compounds:
(I) C6H5CH3 (II) C6H5COOH (III) C6H6 (IV) C6H5NO 2
(a) I > II > III > IV (b) I > III > II > IV (c) II > III > IV > I (d) III > I > II > IV
10. In a reaction of C6H5Y, the major product (>60%) is m-isomer, so the group Y is :
(a) –COOH (b) –Cl (c) –OH (d) –NH2
11. If meta-nitroaniline is chlorinated, the major product is :
NH2
NH 2 NH2 NH2
Cl Cl
(a) (b) (c) (d)
NO 2
NO 2 Cl NO 2 NO 2
Cl
12. If p-methoxy toluene is nitrated, the major product is :
CH3 CH3 CH2NO 2

NO 2
(a) (b) (c) (d) None
NO 2
OCH3 OCH3 OCH3
13. If the mixture of the following four aromatic compounds on oxidation by strong
oxidising agent gives :
CH3 C2H 5 CH2OH CHO
, , and
(a) Mixture of C6H5CH2OH + C6H5COOH (b) Mixture of C6H5CHO + C6H5COOH

(c) Only C6H5COOH (d) None of the these
14. Decide the correct order of reactivity of following compounds towards halogena-
tion with (Cl2 + AlCl3).
COOPh CH3 Et
(IV)
(I) (II) (III)
(a) I > II > III > IV (b) II > III > IV > I
(c) III > II > IV > I (d) II > III > I > IV
15. Benzene on treatment with neopentyl chloride in presence of AlCl3 gives :
(a) neopentyl benzene (b) t—pentyl benzene
(c) sec—pentyl benzene (d) isopentyl benzene
16. PhCOOH 
NaOH (CaO)/heat Br2 /Fe
  Mg/ ether
   (A)
(A) 
Methyl alcohol
 Product is :
(a) Toluene (b) Phenol (c) anisole (d) benzene
COOPh
17. In the attack of NO2+ results in the formation of :
COOPh OCOPh COOPh OCOPh

(a) (b) (c) (d)
NO2 NO2
NO2 NO2
18. Major product obtained in given reation is :
+ (2 mole) 
H2 SO4

(a) (b) (c) (d)
O
(B)
C
19. (A) N The bromination takes place at :
(D)
CH2
(C)
(a) A (b) B (c) C (d) D

OH
20. on reaction with Br2— H2O gives :

——OH
SO3 H COOH
(a) CxHyO2Br6 (b) C13HxO4Br4 (c) C12HxO2Br5 (d) CxH7O2Bry

21. The no. of sp2 carbons in salol are ‘x’ and the no. of sp3 carbons in phenolphthalein
are y . x + y is :
(a) 12 (b) 14 (c) 13 (d) 15
22. The no. of bonds having bond order 1 in the intermediate obtained during the reaction
of benzene with isobutyl chloride in presence of AlCl3 are equal to :
(a) 18 (b) 21 (c) 19 (d) 20
NO2
23. ———C———O——OH (A) + (B)

Conc.
 H2SO4

Me Me
(A) gives H2 gas on reaction with Na and (B) on Clemmensen reduction gives (C). (A)
on reaction with Br2/ H2O gives CxHyOBrz. (C) is :
+ _
NH3 Cl NO2
(a) and x + y + z = 18 (b) and x + y + z = 15
NH2 NH——
(c) and x +y + z = 18 (d) and x + y + z = 15
Me
Ph
O—OH
24. O—OH Conc.

 H2SO4
 Product is :
NO2 Me
(a) PhOH + p–cresol (b) PhOH + p–nitrophenol
(c) MeOH + p–cresol (d) MeOH + p–nitrophenol
+
25. HO CN i)
K2S2O8/ KOH ii) H3O
 Product is :
HO
HO
(a) HO COOH (b) HO CH2 NH2
HO HO
HO
OH
OH OH
(c) HO COOH (d) HO
OH HO
OH
O
OH
26. HNO
2 Product is :
NO2
OH OH OH OH
O2 N NO2 NO
ON NO
(a) (b) (c) (d)
NO2 NO2 NO2 O=N NO2
27. Among the following compounds how many produce violet colour with neutral FeCl3
OH
(A) Phenol, (B) Aspirin, (C) oil of wintergreen (D) Salol , (E)
O——H-----O
(F) Me——C C——OEt , Pinacol :

CH
(a) 4 (b) 3 (c) 5 (d) 2
28. Benzaldehyde undergoes Perkin reaction with a reagent (A) in presence of (B) to give
compound (C). (A), (B), (C) are :
Ph
C = C——COOH
(a) (Ph CH2 CH2 CH2 CO)2 O , Ph CH2 CH2 CH2 COOK , CH2 CH3
O O Me
CH=CH— —COOH
(b)Me– – C –O– C – –Me , ,
COONa
O OK
(c) . ,
Me Me Me
O COONa
(d) , , .
29. The intermediate (I) in Etard oxidation of toluene contains ‘x’ no. of ‘O’ atoms. In the
preparation of DDT chlorobenzene is treated with a reagent (R) in presence of conc.
H2SO4. The no. of ‘Cl ‘ atoms in (R) are :
(a) x — 1 (b) x (c) x + 1 (d) x2
F Br
_
30. Br on reaction with MeO K+ gives :
NO2
H
F
OMe OMe
H
(a) (b)
MeO
Br
NO2
NO2
F H OMe H
MeO
(c) Br (d) Br
NO2 NO2
NO2
31. i)  
Zn—HCl ii) NaOH iii) NaNO2/ HCl; cold —naphthol
 (A)
NO2
+ _ _
i)
Sn/ HCl ii) NaNO2/ H2SO4 iii) steam
 PhN2 Cl / OH
  (B)
NO2
i)
Br2 / Fe ii) TiCl3 / HCl iii) Ac2O
 Br
2/ CH3COOH
 (C)
(A) , (B) , (C) are :
OH Br
N=N— NHAc
N=N
OH
(a) , ,
Br
N=N N=N—— NHAc

OH
(b) , , Br
OH Br
OH Br Br
OH
N=N NHAc
(c) , ,
N2 Ph
(d) None is correct .

NO2 NO2
32. (NH
  (A) Ac
4)2 S
 2O
 (B) ; (B) Conc.  (C)
HNO3/ Conc. H2SO4

(C) is :
NHAc NHAc NO2 NHAc NHAc NO2
NO2 NHAc
(a) (b) (c) (d)

O2 N
NO2 NO2 NO2 NO2
33. Most stable carbonium ion :


F
  F
F F F F
(a)  F (d)
F (b) (c)
F F F F
F F F
34. n-hexane can be prepared by hydrogenation of ‘X’ number of isomeric alkynes of
formula CyH2y – 2 of which (A) is the terminal alkyne.
Na ,  alkyl bromide
(A)   , NaBr + (C)
(B)
(B) on Wurtz coupling reaction gives (D). (C) and (D) are :
(a) n–BuCC–CH2CH2CH=CH2 , CH2 = CH(CH2)4 CH = CH2 , x + y is equal to DBE of
biphenyl methane.
(b) n–PrCH2CC–CH2CH2CH2CH=CH2 , CH2 = CH(CH2)6 CH = CH2 , x + y is equal to
DBE of Anthracene.
(c) CH3CH2CH2CH2–C C–CH2CH2CH=CHCH3 , CH3CH=CHCH2(CH2)4CH2CH=CHCH3
, x + y is equal to DBE of C30H42NClBr2O5 .
(d) CH3CH2(CH2)2CC–CH2CH2CH2CH2CH=CH2 , CH2 = CH(CH2)8CH=CH2 , x + y is
equal to DBE of C40H60N2Cl4Br2O8 .
35. The attacking reagents in the reactions
R1 : CH3 CH2 CH = CH2 + BrCl 
R2 : CH3 CH2 CH = CH2 + HCl , peroxide  are :
+
(a) Br , H +
(b) Br , Cl
+
(c) Br , H+ (d) Br , Cl
36. During mutarotation of -D-glucose in aqueous solution angle of optical rotation
(a) Remains constant value of + 111° (b) Remains constant value of + 19.2°
(c) Changes from an angle of +112° to a constant value of +52.5°
(d) Changes from an angle of +19.2° to a constant value of +52.5°
37. Which of the following is correct about cellulose?
(a) It is an important food material
(b) It has only -glycosidic linkage between two D-glucose unit
(c) It has only -glycosidic linkage between two D-glucose unit
(d) It is sweet in taste
38. Which of the following is an essential amino acid?
(a) Asparagine (b) Glutamine (c) Histidine (d) Alanine
39. Peptides are composed of amino acids joined by amide bonds. which of the follow-
ing statements is not correct ?
(a) Amide group are more resistant to hydrolysis than one similar ester groups
(b) p- resonance stabilizes the amide bond
(c) Stable conformations of peptides are restricted to those having planar amide
groups
(d) Amide groups do not participate in hydrogen bonding interaction
40. Complementary bases present in DNA are :
(a) Uracil & Adenine : Cytosine & Guanine
(b) Thymine & Adenine : Guanine & Cytosine
(c) Adenine & Thymine : Guanine & Uracil
(d) Adenine & Guanine : Thymine & Cytosine
41. Which of the following statements would correctly describe the isoelectric point of
cysteic acid an oxidation product of cysteine ?
(a) Lower than that of aspartic acid (b) About the same as that of aspartic acid
(c) About the same as that of Cysteine (d) Higher than that of lysine
42. Dinucleotide is obtained by joining two nucleotides together by phosphodiester link-
age. Between which carbon atoms of pentose sugar of nucleotides are these link-
ages presents.
(a) 5' and 3' (b) 1' and 5' (c) 5' and 5' (d) 3' and 3'
43. Which of following are essential amino acids–
(1) Aspartic acid (2) Leucine (3) Valine (4) Glycine (5) Alanine
(a) 1, 2 & 3 (b) 1, 2, 4 & 5 (c) 2 & 3 (d) 1, 3, 4 & 5
44. A single stand of DNA can act as a template on which a molecule of RNA is synthe-
sized in a specific manner. This process is known as :
(a) Replication (b) Transcription (c) Translation (d) Denaturation
45. Column-I (Reaction of Glucose) Column-II (Product)
HI , 
(a) Glucose  (p) Osazone

Br2 water
(b) Glucose  (q) n-Hexane

Nitric Acid
(c) Glucose  (r) Gluconic acid

3Ph–NH–NH 2
(d) Glucose (s) Saccharic acid
H
(a) a – q, b – s, c – p, d - r (b) a – q, b – p, c – r, d - s
(c) a – q, b – s, c – r, d - p (d) a – q, b – r, c – s, d - p
46. Column-I (Carbohydrates) Column-II (Monosaccharide unit)
(a) Maltose (p) -D-Glucose
(b) Lactose (q) Two -D-Glucose
(c) Cellulose (r) -D-Galactose & -D-Glucose
(d) Sucrose (s) -D-Glucose & - D-Fructose
(a) a – q, b – s, c – r, d - p (b) a – q, b – r, c – p, d - s
(c) a – r, b – s, c – p, d - q (d) a – r, b – p, c – q, d - s
47. Which of the following statements are correct?
( i) Lact ose is a -galactoside.
(ii) The -carbon of all 20D-amino acids of proteins except cysteine has R-configu-
ration.
(iii) In Killiani –Fischer synthesis,arabinose gives equimolar mixture of glucose
and mannose .
(iv) On oxidation with nitric acid, arabinose gives an opticallly active dicarboxylic
acid .
(a) Only (ii) and (iii) (b) Only (i) ,(iii) and (iv)
(c) Only (i) ,(ii) and (iv) (d) Only (i) and (iii)
48. Both cysteine and methionine are chiral L-amino acids that incorporate a single
sulfur. The C-2 configuration is S in methionine, but R in cysteine. Why ?
(a) biosynthesis of cysteine proceeds by inversion at C-2.
(b) the sulfur in cysteine prevents zwitterion formation.
(c) the sulfur atom in methionine is remote from C-2 and does not influence the
sequence rule.
(d) the sulfur atom in cysteine is remote from C-2 and does not influence the se-
quence rule.
49. A hexapeptide has the composition Ala,Gly,Phe,Val3. Both the N-terminal and C-
terminal units are Val. Cleavage of the hexapeptide by chymotrypsin gives two dif-
ferent tripeptides, both having Val as the Nterminal group. Among the products of
random hydrolysis is a Ala-Val dipeptide fragment. What is the primary structure of
the hexapeptide ?
(a) Val-Gly-Phe-Val-Ala-Val (b) Val-Ala-Phe-Val-Gly-Val
(c) Val-Gly-Ala-Val-Phe-Val (d) Val-Phe-Val-Ala-Gly-Val
50. The structure of the product that results when piperidine reacts with pentanal fol-
lowed by catalytic reduction with H2 is :
(a) N (b) N
(c) N=C (d)

N
51. Ninhydrin reagent reacts with -amino acids to give a purple colour.
In the the reaction of ninhydrin with phenylalanine, which of the following is re-
sponsible for this colour ?
O---H-O O
C6H5
(I)
N (II)
C=O
O O O--HO
OH--O
C6H 5 CHO C6H5
(III) (IV) N
C6H5 H
O
(a) I (b) II (c) III (d) IV
Comprehension : (Q. No 52 to 59)
There are two vessels V1 & V2. In V1 vessel two different alkyl chlorides (A) and (B) are
present in presence of ether. In vessel V2 two different alkyl chlorides (C) and (D) are
present in presence of ether. The difference in molecular weights of (A) & (B) is d1 and
difference in molecular weights of (C) & (D) is d2. The value of d1 is greater than d2. Na
is introduced in both the vessels. Wurtz coupling reaction occurs resulting in formation
of alkanes (E), (F), (G) in vessel V1 and (E), (H), (I) in vessel V2. (E) can be prepared by
Sabatier—Senderens hydrogenation of an alkene (J) .
(J) HBr/
 peroxide
 (K) Na
/ ether
 n—decane.
Answer the following questions :
52. (F) is : (a) Propane (b) n–butane (c) n–pentane (d) n–octane
53. (G) is : (a) ethane (b) n–butane (c) n–hexane (d) n–pentane
54. The value of d1 is :
(a) 14 (b) 28 (c) 42 (d) 56
55. The value of d2 is :
(a) 14 (b) 28 (c) 42 (d) 56
56. (H) and (I) are :
(a) ethane, n-butane (b) ethane, n-hexane
(c) n-butane, n-octane (d) n-hexane, n-butane
57. (J) on treatment with Cl2/CCl4 gives :
(a) CH3CH2CHClCHClCH3 (b) CH3CHClCH2CH2CH2Cl
(c) CH3CH2CH2CHClCH2Cl (d) CH3CH2CHClCH = CH2
58. (F) can be prepared by Wurtz coupling reaction of an alkyl bromide (L). (L) on treat-
ment with alc. KOH gives
(a) 2–butene (b) 1–butene (c) 1–hexene (d) propene
59. The no. of isomeric alkenes whose hydrogenation result in the formation of (E) are :
(a) 1 (b) 3 (c) 4 (d) 2
Comprehension fir Q. no. 60 to 62
Mild oxidizing agents, e.g. bromine water, Tollen’s regent, Fehling’s solution etc., oxi-
dize aldoses into aldonic acids. Both glucose and fructose can be oxidized by Tollen’s
reagent and Fehling’s solution despite the presence of a keto group in fructose. Strong
oxidizing agents like conc. HNO3 oxidizes glucose to a dibasic acide (saccharic acid).
Fructose under similar condidtions is also oxidized. Both glucose and fructose can be
reduced by red P/HI, LiAlH4 , Clemmensen and Wolff-Kishner reduction.
60. Which of the following cannot be oxidized by bromine water?
(a) D-arabinose (b) D-glyceraldehyde (c) L-glucose (d) L-fructose.
61. One mole of each of glucose and fructose require x and y moles of periodic acid re-
x
spectively, for oxidation. Hence .
y
1 2 5 9
(a) (b) (c) (d)
1 1 4 4
62. When one mole of D-arabinose is oxidized by periodic acid, the product (s) formed is
(are) :
(a) 5 moles of HCOOH (b) 4 moles of HCOOH and one mole of HCHO
(c) 3 moles of HCOOH and 2 moles of HCHO (d) 5 moles of HCHO
Multiple Choice Type #
CH2
01. (R) on reaction with HBr/peroxide gives a product (P). Which of the
D
following is/are correct ?
(a) (R) but not (P) show geometrical isomerism.
(b) (P) but not (R) show geometrical isomerism.
.
(c) (P) is primary alkyl halide. (d) The attacking reagent is Br
CH3 CH2
02. (R) on reaction with excess HBr/peroxide gives (P).
Which of the following is/are correct ?

(a) (P) contains primary and secondary alkyl bromides.
(b) (P) shows Geometrical isomerism.
(c) The sum of DBE of (R) and (P) is 26. (d) (R) shows Geometrical isomerism.
03. 1-methyl cyclohexene on reaction with Cl2/hv does not give :
Me Cl
CH2Cl Me
Me
(a) (b) Cl (c) (d)
Cl Cl
04. 3-methyl cyclohexene on reaction with Cl2/hv gives :
Me Me Cl Me CH2Cl
Cl
(a) (b) (c) (d)
Cl
05. Which of following compound will show geometrical isomerism ?
(a) (b) (c) (d)

O O
06. Which of the following compounds can show geometrical isomerism ?

Br CH3 CH3
H3 C CH3
Br CH3
(a) (b) (c) (d)
Cl
H3 C CH3 H3 C CH3
Cl
07. Which of the following will show geometrical isomerism.
Me Me
(a) (b) (c) Cl (d)
Me
08. Geometrical isomer is shown by :
(a) (b)
(c) (d)
09. Which of the following compounds will show geometrical isomerism:

(a) Chlorocylopropane (b) 1, 1, 2 –Trichlorocyclopropane
(c) Hexachlorocyclopropane (d) 1,2-Dichlorocyclopropane
10. Geometrical isomerism is possible in :
CH3
(a) (b) (c) (d)
CH3
Br2 / hv alc. KOH

11. (A) (B), Formula of (A) is CxHyBr .
Heat
Which of the following is/are correct.
(a) DBE of (B) is equal to the number of geometrical isomers of
MeCH=CH–CH2–CH=CH–CH2–CH=CH–Me
(b) (B) on ozonolysis gives a product whose DBE is equal to the number of geometri-
cal isomers of MeCH=CH–CH2–CH=CH–CH2–CH=CHEt.
(c) (A) can show geometrical isomerism but (B) can not show geometrical isomer-
ism.
(d) (B) on reduction with D2 (1 mol)/Ni gives a product which can not show geo-
metrical isomerism.
12. Electrophilic attack of NO2 at meta position is observed in :

CCl3 NO2 NMe 3 O
(a) (b) (c) (d)
13. Benzoic acid may be prepared by the oxidation of :

CH2CH3 CH2OH COCH3 OH
CH2CH3 CH3
(a) (b) (c) (d)
14. Which of the following statements is/are not true?

(a) All ortho-para directing groups activates the ring towards electrophilic substi-
tution.
(b) Halobenzene is ortho para directing but deactivating in nature
(c) All meta-directing groups have -bond on the atom directly attached to the ring
(d) All meta directing groups are deactivating.
15. Geometrical isomerism is shown by :
H Cl CH2 CHCl
(a) H (b) (c) (d)
Br H Cl H Cl
16. In which of the following order of stability of alkene is correct :
(a) < < (b) > >
(c) > >
(d) < <
17. When D-Glucose reacts with three moles of phenylhydrazine it forms glucosazone.
Which of the following carbohydrates will give same osazone as that of D-Glucose?
(a) (b) (c) (d)
18. Which of the following compounds contain amide linkage?

(a) Nylon - 6 (b) Acetamide (c) Proteins (d) Cellulose
19. W h at w ou ld be t h e cor r ect st r u ct u r e of -D-Glucose?
(a) (b)
(c) (d)
20. Which of the following upon hydrolysis form only glucose?

(a) Lactose (b) Cellobiose (c) Maltose (d) Sucrose
21. Glucose can be detected by
(a) Molisch’s test (b) Fehling’s test (c) Tollen’s test (d) Benedict’s test
22. Glucose and Mannose are
(a) Enantiomers (b) Epimers (c) Anomers (d) Diastereomers
23. Which of the following sugars will form osazone ?
(a) (b)
(c) (d)
24. For "invert sugar", the correct statement(s) is/are (Given : Specific rotations of
(+)-sucrose, (+)-maltose, L-(–)-glucose and L-(+)-fructose in aqueous solution are
+66°, +140°, –52° and +92°, respectively)
(a) "Invert sugar" is prepared by acid catalyzed hydrolysis of maltose
(b) "Invert sugar" is an equimolar mixture of D-(+)-glucose and D-(–)-fructose
(c) Specific rotation of "invert sugar" is –20°
(d) On reaction with Br2 water, "invert sugar" forms saccharic acid as one of the
products
25. The Fischer presentation of D-glucose is given below.
(D-glucose)
The correct structure(s) of -L-glucopyranose is (are) :
(a) (b) (c) (d)
26. The correct statements about the following molecule is/are :
(a) It is a reducing sugar. (b) It is a furanose.

(c) It is an acetal. (d) It can show mutarotation
27. Which is/are correct statement?
(a) Starch is a polymer of -glucose (b) Amylose is a component of cellulose
(c) Proteins are composed of L- amino acids
(d) In cyclic structure of pyranose, there are five carbons and one oxygen atom
28. Which of the following is/are correct about isoelectric point of amino acid?
(a) At this point amino acid is present in the form of zwitter ion
(b) At this point amino acid is electrically neutral
(c) If pH > isoelectric point amino acid will move toward anode
(d) If pH > isoelectric point amino acid will move towards cathode
29. In the double helix structure of DNA, the base pairs are :
(a) Part of the backbone structure (b) Inside the helix
(c) Outside the helix (d) Bonded with covalent bond
30. Which statement is/are correct in following :
(a) Sucrose is dextrorotatory
(b) After hydrolysis of sucrose, dextrorotatory glucose and laevorotatory fructose
will obtained.
(c) Laevorotation of fructose is more than dextrorotation of glucose.
(d) Cane sugar gives nonequimolar mixture of D- (+)-glucose and D- (–)-fructose.
Integer Type #
OMe
6 7
5
01. (R) on reaction with phthalic anhydride in presence of anhyd.
4 1
3 8 2
AlCl3 gives a product (P). The number of functional groups (don’t consider benzene
as functional group) in (P) are ‘n1’ . The electrophilic attack takes place at position
‘n2’ of the reactant (R). The DBE of (P) is ‘n3’.
3
Calculate the value of  in .

i 1
i
02. The number of geometrical isomers of

CH2=CH–CH–CH2–CH=CH–CH2–CH=CH–CH3
CH=CH2
Me Me
are ‘n1’ and the number of geometrical isomers of are ‘n2’ .
Et Et
Calculate the value of (n1 + n2) ?
03. The number of geometrical isomeric pairs obtained on photomonochlorination of
methyl cyclohexane are n1 and the number of structural isomers obtained on
photomonochlorination of neohexane are n2. Calculate the value of |2n1 – 3n2|
04. 3,3-dimethyl cyclohexene on reaction with Cl2/hv gives a mixture of two isomeric
products (A) and (B).
Photomono
(A) H2 – Ni (P) ‘n1’ no. of isomeric dichlorides.
Chlorination
Photomono
(B) H2 – Ni (Q) ‘n2’ no. of isomeric dichlorides.
Chlorination
(Consider only structural isomers) (n1 > n2)
alc. KOH
(P) (R) {contains ‘n3’ no. of H – C hyperconjugated bonds }
Heat
alc. KOH
(Q) (S) {contains ‘n4’ no. of H – C hyperconjugated bonds }
Heat
4
Claculate the value of  in ?

i1
i
05. How many geometrical isomer are possible for the given compound ?
06. The double bond equivalent of Buckminster fullerene is 'n1' and the no. of cyclic
structures of C5H10 are 'n2'. Calculate the value of (n1 + n2).
07. How many geometrical isomers are possible for the following structure.
H
08. Consider the following compounds :
SO3 H SO2 R C Cl3 COOR +
NH3 OCOR NHCOR
(i) (ii) (iii) (iv) (v) (vi) (vii)
In How many compounds the electrophilic attack takes place at m—position ?Ans:5
09. Consider the following statements :
(P) —NH2 is more activating than —NHCOCH3
(Q) —OH is more activating than —NH2
(R) —CCl3 is activating while —Cl is deactivating
(S) —Cl is activating but —CCl3 is deactivating
How many are correct ?
10. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75),
alanine and phenylalanine. Glycine contributes 47.0% to the total weight of the hy-
drolysed products. The number of glycine units present in the decapeptide is ?
11. Calculate the sum of nitrogen atoms in one molecule each of Guanidine , Arginine,
Guanine, Cytosine, Cysteine, Methyl orange.
12. Among the following compounds
(i) Adenine (ii) -D-Ribose (iii) Mesitylene (iv) Barbituric acid
(v) Ascorbic acid (vi) Carpolactum
How many are heterocyclic .

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03. on reaction with Br2 /hv mainly gives :

NaOH/CaO Conc. HNO 3

(a) (b) NO 2 (c) Br (d)

Which of the following is Incorrect :

CH3 CH3 CH2NO 2

CH3 C2H 5 CH2OH CHO

(a) Mixture of C6H5CH2OH + C6H5COOH (b) Mixture of C6H5CHO + C6H5COOH

COOPh OCOPh COOPh OCOPh

18. Major product obtained in given reation is :

(a) (b) (c) (d)

(a) A (b) B (c) C (d) D

20. on reaction with Br2— H2O gives :

(a) CxHyO2Br6 (b) C13HxO4Br4 (c) C12HxO2Br5 (d) CxH7O2Bry

23. ———C———O——OH (A) + (B)

(a) and x + y + z = 18 (b) and x + y + z = 15

(c) and x +y + z = 18 (d) and x + y + z = 15

24. O—OH Conc.

(a) HO COOH (b) HO CH2 NH2

(c) HO COOH (d) HO

(a) (b) (c) (d)

NO2 NO2 NO2 O=N NO2

(F) Me——C C——OEt , Pinacol :

(A) , (B) , (C) are :

N=N N=N—— NHAc

(d) None is correct .

(a) (b) (c) (d)

33. Most stable carbonium ion :

(c) N=C (d)

Which of the following is/are correct ?

(a) (b) (c) (d)

06. Which of the following compounds can show geometrical isomerism ?

09. Which of the following compounds will show geometrical isomerism:

Br2 / hv alc. KOH

(a) (b) (c) (d)

13. Benzoic acid may be prepared by the oxidation of :

14. Which of the following statements is/are not true?

(a) < < (b) > >

(c) > >

(d) < <

(a) (b) (c) (d)

18. Which of the following compounds contain amide linkage?

20. Which of the following upon hydrolysis form only glucose?

The correct structure(s) of -L-glucopyranose is (are) :

(a) (b) (c) (d)

26. The correct statements about the following molecule is/are :

(a) It is a reducing sugar. (b) It is a furanose.

Calculate the value of  in .

02. The number of geometrical isomers of

Claculate the value of  in ?

(i) (ii) (iii) (iv) (v) (vi) (vii)

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