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    This document is an examination for Organic Chemistry I consisting of two sections - Section A and Section B. Section A contains 3 long answer questions worth 10 marks each, requiring students to answer any 2 questions. Section B contains 6 short answer questions worth 5 marks each, requiring students to answer any 4 questions. The document provides an overview of the exam structure, outlines the types of questions in each section, and lists the specific questions being asked about various organic chemistry topics such as hybridization, carbines, reaction mechanisms, isomerism, and more.

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    BSCCH-102

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    This document is an examination for Organic Chemistry I consisting of two sections - Section A and Section B. Section A contains 3 long answer questions worth 10 marks each, requiring students to answer any 2 questions. Section B contains 6 short answer questions worth 5 marks each, requiring students to answer any 4 questions. The document provides an overview of the exam structure, outlines the types of questions in each section, and lists the specific questions being asked about various organic chemistry topics such as hybridization, carbines, reaction mechanisms, isomerism, and more.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    69 views8 pages

    BSCCH 102

    Uploaded by

    pp1560078
    This document is an examination for Organic Chemistry I consisting of two sections - Section A and Section B. Section A contains 3 long answer questions worth 10 marks each, requiring students to answer any 2 questions. Section B contains 6 short answer questions worth 5 marks each, requiring students to answer any 4 questions. The document provides an overview of the exam structure, outlines the types of questions in each section, and lists the specific questions being asked about various organic chemistry topics such as hybridization, carbines, reaction mechanisms, isomerism, and more.

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    © All Rights Reserved
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    of 8

    Total Printed Page: 8 Roll No…………

    BSCCH-102/CH-02
    Organic Chemistry–I
    dkcZfud jlk;u
    Bachelor of Science (Bsc-12/16/17)
    First Year, Examination-2019

    Time: 3 Hours Max. Marks: 40


    …………………………………………………………………
    Note:- This paper is of Forty (40) marks divided into
    two (02) Section A and B. Attempt the
    question contained in these sections according
    to the detailed instructions given therein.

    uksV%& ;g iz'u&i= pkyhl ¼40½ vadksa dk gS tks nks ¼02½


    [k.Mksa ^d* rFkk ^[k* esa foHkkftr gSA izR;sd [k.M esa
    fn, x, foLr`r funsZ”kkssa ds vuqlkj bu iz”uksa dks gy
    djuk gSA
    Section-A ¼[k.M&d½
    (Long Answer Type Question) ¼nh?kZ mÙkjh; iz'u½
    Note:- Section - A contains Three (03) long answer-
    type questions of Ten (10) marks each.
    Learners are required to answer any Two
    (02) questions only. (2×10=20)

    S-91/BSCCH-102/CH-02 1 P.T.O.
    uksV%& [k.M ^d* esa rhu ¼03½ nh?kZ mÙkjh; iz'u fn;s x;s
    gSaA izR;sd iz'u ds fy, nl ¼10½ vad fu/kkZfjr gSaA
    f'k{kkfFkZ;ksa dks buesa ls dsoy nks ¼02½ iz'uksa ds mÙkj
    nsus gSaA

    1. (a) Explain the term hybridization. How many


    types of hybridization is found in the carbon
    compound? Explain.

    ladj.k ls vki D;k le>rs gS\ dkcZu ds ;kSfxdksa esa


    fdrus izdkj dk ladj.k gksrk gS\ le>kb,A
    (b) What are Carbines? What do you
    understand by singlet and triplet Carbone?

    dkchZu D;k gS\ flXysV o fVªiysV dkchZu ls vki


    D;k le>rs gS\ foLrkj ls le>kb,
    2. Discuss with examples any four of the
    following.

    (a) Saytzeff rule

    (b) Mechanism of electrophilic substitution


    reaction with special reference to nitration
    of benzene.

    S-91/BSCCH-102/CH-02 2 P.T.O.
    (c) Regio selective reaction

    (d) Anti markovnikov addition reaction.

    (e) Benzyne substitution.

    fuEufyf[kr esa ls fdUgha pkj dk mnkgj.k lfgr


    o.kZu dhft, %
    (a) lsVtsQ fu;e
    (b) bysDVªku Lusgh foLFkkiu vfHkfØ;k dh
    fØ;kfof/k fof”k’V :i ls csUthu ds
    ukbVªhdj.k ds ifjis{; esa
    (c) fjft;ks lysfDVo vfHkfØ;k;sa
    (d) ,UVh ekbØksfudkQ ;ksxkRed vfHkfØ;k
    (e) cSUtkbu izfrLFkkiu
    3. (a) What are aryl halide? Give three methods
    of preparation of aryl halides.

    ,fjy gSykbM D;k gS\ ,fjy gSykbM cukus dh rhu


    fof/k;k¡ nhft,A
    (b) What is optical isomerism? What are the
    main characteristics of optically active
    compounds? Explain with suitable example.

    S-91/BSCCH-102/CH-02 3 P.T.O.
    izdkf”kd leko;rk D;k gksrh gS\ fdlh ;kSfxd }kjk
    izdkf”kd leko;ork iznf”kZr djus ds fy, D;k&D;k
    xq.k gksus pkfg,\ mnkgj.k nsdj le>kb,A

    Section-B ¼[k.M&[k½
    (Short Answer Type Question) ¼y?kq mÙkjh; iz'u½
    Note:- Section-B contains six (06) short answer type
    questions of five (05) marks each. Learners
    are required to answer any four (04)
    questions only. (5×4=20)

    uksV%& [k.M ^[k* esa N% ¼06½ y?kq mÙkjh; iz'u fn;s x;s gSaA
    izR;sd iz'u ds fy, ik¡p ¼05½ vad fu/kkZfjr gSaA
    f'k{kkfFkZ;ksa dks buesa ls dsoy pkj ¼04½ iz'uksa ds mÙkj
    nsus gSaA
    1. How will you convert acetylene into the
    following compounds (Any five)

    (i) I – Butyne

    (ii) Neopreme

    (iii) Vinyl acetone

    S-91/BSCCH-102/CH-02 4 P.T.O.
    (iv) Cyclo Octatetraene

    (v) Cuprous methyl acetilyde

    (vi) Acrylic acid.

    ,flfVyhu dks vki fuEu ;kSfxdksa esa dSls ifjofrZr


    djsaxs ¼dksbZ ik¡p½
    (i) I – C;wVkbu

    (ii) uhvks izhu


    (iii) fouk;y ,flVksu
    (iv) lkbDyks vkDVkVsVªsbu
    (v) D;wizl feFkkby ,flVkbykbM
    (vi) ,Økbfyd ,flM
    2. How resonance reduces the basicity and
    increase the acidity of the molecule. Explain
    with suitable example.

    fdl izdkj vuquk; csfldrk dks ?kVkrh gS o


    vEyh;rk dks c<+krh gSA leqfpr mnkgj.k nsdj
    le>kb,A

    S-91/BSCCH-102/CH-02 5 P.T.O.
    3. Explain the mechanism of any two of the
    following :
    (i) Elimination reaction
    (ii) Addition reaction to C = C
    (iii) 1, 4, addition in 1, 3, Butadiene
    fuEu ls fdUgh nks ij fØ;kvksa dh fØ;k fof/k dk
    o.kZu dhft,A
    (i) foyksiu fØ;k,sa
    (ii) C = C ij ;ksx fØ;k
    (iii) O;wVk 1] 3] MkbbZu ij 1] 4 ;ksx fØ;k
    4. Write short notes on any two of the following :
    (i) Enantiomer and diastoreomer
    (ii) DL and RS nomenclature
    (iii) Boat and chair conformation
    cyclohexane
    fuEu esa ls fdUgha nks ij laf{kIr fVIi.kh fyf[k,A
    (i) foEo izfr foEo leko;h o MkbLVksfj;ksej
    (ii) ukedj.k dh DL o RS i)fr

    (iii) lkbDyks gSDlsu dh uko o dqlhZ la:i.k

    S-91/BSCCH-102/CH-02 6 P.T.O.
    5. Explain why (any two) :

    (i) Cyclopentadienyl anion is aromatic


    while Cyclo octatetraene is not
    aromatic

    (ii) Phenol is more reactive then


    nitrobenzene for electrophilic aromatic
    substitution reaction.

    (iii) Chlorine is of ortho/para directing but


    still deactivating in nature.

    O;k[;k dhft, D;ksa ¼dksbZ nks½


    (i) lkbDyks isUVk Mkbuk;y ,uk;u ,jkseSfVd gS
    tcfd lkbDyks vkDVk VsVªkbu ,jkseSfVd ugha
    gSA
    (ii) fQuky ukbVªkscSUthu ls byksDVªksfQfyd
    ,jkseSfVd izfrLFkkiu fØ;kvksa esa vf/kd
    lfØ; gSA
    (iii) ;|fi Dyksjhu dk vkFkkZs ,oa iSjk nSf”kd
    izHkko gS fQj Hkh csUthu pØ dh fØ;k”khyrk
    dks ?kVk nsrk gSA

    S-91/BSCCH-102/CH-02 7 P.T.O.
    6. What is the Walden inversion? Explain giving
    mechanism of reaction.

    okYMu buotZu D;k gS\ vfHkfØ;k dh fØ;k fof/k


    le>kb,A

    ******

    S-91/BSCCH-102/CH-02 8 P.T.O.

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