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  • SKN 233

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    Jiwan Raj
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    The document appears to be an examination paper for an inorganic chemistry course. It contains 5 questions, with each question having multiple parts. The questions cover various topics in inorganic chemistry including: 1) Transition metal complexes and their electronic transitions. 2) Coordination compounds and their structures/properties. 3) Organometallic compounds and catalysis. 4) Biological roles of metals and inorganic compounds. 5) Acid-base theories and silicate compounds.

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    SKN-233

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    The document appears to be an examination paper for an inorganic chemistry course. It contains 5 questions, with each question having multiple parts. The questions cover various topics in inorganic chemistry including: 1) Transition metal complexes and their electronic transitions. 2) Coordination compounds and their structures/properties. 3) Organometallic compounds and catalysis. 4) Biological roles of metals and inorganic compounds. 5) Acid-base theories and silicate compounds.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    8 views7 pages

    SKN 233

    Uploaded by

    Jiwan Raj
    The document appears to be an examination paper for an inorganic chemistry course. It contains 5 questions, with each question having multiple parts. The questions cover various topics in inorganic chemistry including: 1) Transition metal complexes and their electronic transitions. 2) Coordination compounds and their structures/properties. 3) Organometallic compounds and catalysis. 4) Biological roles of metals and inorganic compounds. 5) Acid-base theories and silicate compounds.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 7

    Printed Pages : 8

    SKN-233
    B.Sc. (Part-III) (Supplementary)
    Examination, 2022
    (New Course)
    CHEMISTRY
    (Inorganic Chemistry)
    [Paper : First ]
    Time Allowed : Three Hours
    Maximum Marks : 33
    Minimum Passing Marks : 11

    Note : Attempt all five questions. One question from each


    unit is compulsory. Marks are indicated against
    questions.

    lHkh ik¡p iz'uksa ds mÙkj nhft,A izR;sd bdkbZ ls ,d iz'u


    djuk vfuok;Z gSA vad lHkh iz'uksa ds le{k vafdr gSaA
    Unit-I / bdkbZ&I

    SKN-233/100 [P.T.O.]
    - ( 1 )
    1. (a) Which shows maximum trans effect ? [1]

    vf/kdre VªkUl izHkko n'kkZrk gS %


    – –
    (i) CN (ii) Cl
    –
    (iii) OH (iv) H2O

    (b) Explain the mechanism of nucleophilic


    substitution reaction of square planar complex.
    [3]

    oxZ leryh; ladqy esa ukfHkdLusgh izfrLFkkiu dh


    fØ;kfof/k dks le>kb,A
    (c) Write limitations of valence bond theory. [3]

    la;kstdrk cka/k fl)kar dh lhek,¡ fyf[k,A


    OR/vFkok

    (a) Explain Jahn-Teller distortion with example.


    [3]

    tku Vsyj foÑfr dks mnkgj.k lfgr le>kb,A


    (b) What do you understand by thermodynamic
    stability of complex? How do the nature of
    ligands affect the stability of complex? Explain.
    [4]

    SKN-233/100
    - ( 2 )
    ladqyksa ds Å"ekxfrdh LFkkf;Ro ls vki D;k le>rs gSa\
    fyxk.Mks dh izÑfr fdl izdkj ladqyksa ds LFkkf;Ro dks
    izHkkfor djrh gS\ le>kb,A
    Unit-II / bdkbZ&II

    2. (a) Describe different types of electronic


    transition in transition metal complex. [4]

    laØe.k /kkrq ladqyksa esa bysDVªkfud laØe.k ds izdkjksa dk


    o.kZu dhft,A
    (b) Explain the electronic spectra of [Ti(H2O)6]3+
    complex ion. [3]

    [Ti(H2O)6]3+ ladqy vk;u ds bysDVªkfud o.kZØe dh


    O;k[;k dhft,A
    OR/vFkok

    (a) Draw and explain orgel energy level diagram


    for d1 and d2 state. [3]

    d1 ,oa d2 voLFkkvksa ds fy, vkxsZy ÅtkZ Lrj vkjs[k


    cukdj le>kb,A
    (b) Write notes on : [4]

    fuEu ij fVIif.k;k¡ fyf[k, %

    SKN-233/100 [P.T.O.]
    - ( 3 )
    (i) Magnetic susceptibility

    pqEcdh; lqxzkfgrk
    (ii) L-S coupling

    L-S ;qXeu
    Unit-III / bdkbZ&III

    3. (a) Write the formula of Zeise’s salt. [1]

    ftls yo.k dk lw= fyf[k,A


    (b) Describe the methods of preparation of mono-
    nuclear metal carbonyl. [3]

    ,dukfHkdh; /kkrq dkcksZfuy cukus dh fof/k;ksa dk o.kZu


    dhft,A
    (c) Explain the mechanism of polymerization of
    ethene using Ziegler-Natta catalyst. [3]

    ftXyj&ukVk mRizsjd ds }kjk ,Fkhu ds cgqyhdj.k dh


    fØ;kfof/k le>kb,A
    OR/vFkok

    (a) Wilkinson’s catalyst is : [1]

    fofYdUlu mRizsjd gS %

    SKN-233/100
    - ( 4 )
    (i) Fe(CO)5

    (ii) K[PtCl3C2H4]

    (iii) K4[Fe(CN)6]

    (iv) [Rh(Cl) (PPh3)3]

    (b) What is hapticity? Explain the concept of


    hapticity with examples. [3]

    gSfIVdrk ls D;k le>rs gSa\ gSfIVdrk dh vo/kkj.kk dks


    mnkgj.k lfgr le>kb,A
    (c) Explain the structure of Fe(CO)5 (Iron Penta
    Carbonyl) on the basis of valence bond theory.
    [3]

    la;kstdrk cka/k fl)kar ds vk/kkj ij Fe(CO)5 ¼vk;ju


    isUVk dkcksZfuy½ dh lajpuk le>kb,A
    Unit-IV / bdkbZ&IV

    4. (a) Explain non-symbiotic biological nitrogen


    fixation. [4]

    vlgthoh tSoh; ukbVªkts u fLFkjhdj.k dks le>kb,A


    (b) Write a note on the toxicity of mercury. [2]

    edZjh fo"kkDrrk ij fVIi.kh fyf[k,A


    SKN-233/100 [P.T.O.]
    - ( 5 )
    OR/vFkok

    (a) Explain the structure and function of


    haemoglobin. [4]

    gheksXyksfcu dh lajpuk ,oa dk;Z le>kb,A


    (b) Describe the biological role of calcium ion.
    [2]

    dSfYl;e vk;u ds tSfod Hkwfedk dh foospuk dhft,A


    Unit-V / bdkbZ&V

    5. (a) Explain the uses of hard and soft acid-base


    theory. [3]

    dBksj rFkk e`nq vEy&{kkj fl)kar dh mi;ksfxrk dk


    o.kZu dhft,A
    (b) Write short notes on : [3]

    laf{kIr fVIif.k;k¡ fyf[k, %


    (i) Silicone oil

    flyhdkWu rsy
    (ii) Silicone rubber

    flfydkWu jcj

    SKN-233/100
    - ( 6 )
    OR/vFkok

    (a) What is phosphazene? Explain its structure.


    [2]

    QkLQsftu D;k gS\ bldh lajpuk dks le>kb,A


    (b) Explain the symbiosis concept and its uses.
    [2]

    lg&vfLrRo ladYiuk vkSj mi;ksfxrk dk o.kZu dhft,A


    (c) Explain the structure of cyclic silicates with
    example. [2]

    pØh; flfydsV dh lajpuk mnkgj.k lfgr le>kb,A


    -----×-----

    SKN-233/100
    - ( 7 )

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