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R Sum AtomedeBohr-en
R Sum AtomedeBohr-en
I- Model of Rutherford
This model is based on the existence of the nucleus in which the entire mass of the atom is
concentrated and around which electrons revolve.
Mechanical stability results from compensation of FEattraction forces by centrifugal forces Fc due to rotation of
electrons around the nucleus.
E P= - k e2/ r (2)
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c: speed of light: c3.108 m = . s-1; h: Planck constant: h = 6.626.10-34 J.s
ΔE = l Ef – Ei l = hν Ef: end state
Ei: initial state
Absorption: When an electron passes from a level n (orbit of radius rn) to a level n’ (n'>n) higher (orbit of radius
rn'), it absorbs radiation of frequency νn-n'.
Emission: When an electron goes from a level n’ to a level n (n’ > n), it emits radiation of frequency
νn’-n.
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−
c 1
υ= υ=
Each line is characterized by its frequency λ or number of λ waves that can be measured.
The only possible energy exchanges between the atom and the outside are given by the relationship:
2 4 2
2 π me k 1 1
ΔEn →n =En −En = 2
( 2− 2 )
2 1 2 1
h n1 n2 (9)
where n1 et n2are integers called quantum numbers.
When n = n2 >1, the atom is in an excited state and the electron occupies a n2 orbit.
This change of orbits induces emitted or absorbed lights characterized by
ΔE
υ=
frequencies ==> h
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1
υ=
Gold: λ = cT and T
c 1 υ
⇒ λ= υ= =
υ so λ c
(
υ= 2 π 2 me4 k 2
ch 3 )(
2 π 2 me 4 k 2 1 1
−
ni nf
2 2 ) (10)
( )
1 1
υ=R H −
ni n f
2 2
By posing RH (Rydberg Cte) = 109677 cm-1then (12)
This relationship makes it possible to calculate the different wavelengths corresponding to the
electronic transitions of hydrogen between two energy levels.
In general, there are several spectrum series depending on the state of the electron:
Each group of rays is called series and bears the name of the scientist who discovered it
There are several series of lines:
* Lyman Series: n1= 1 and n2 >1 (n2= 2,3…, ) located in the far ultraviolet
* Balmer Series: n1 = 2 and n2 >2 (n2 = 3,4…, ) located in the visible and ultraviolet
* Paschen Series: n1 = 3 and n2 >3 (n2 = 4,5…, ) located in the near infrared
* Brachett Series: n1 = 4 and n2 >4 (n2 = 5.6…, )
* Pfund Series: n1 = 5 and n2 >5 (n2 = 6.7…, )
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V- Application of the Bohr model to hydrogenoids
Definition of a hydrogenoid
A hydrogenoid is an atom that has lost all but one of its electrons; the charge of the nucleus is +Z.e
and that of the peripheral electron (-e). exemples :He+ ; Li++; Be+++……
The problem of an electron moving around a +Ze charge nucleus is similar to that of hydrogen.
The force of attraction in this case is: -Z K e2/r2 and the condition of stability of the orbit is:
mev2/r = Z K e2/r2
and the condition of orbit stability is: mev2/r =ZK e2/r
A reasoning similar to that followed for the hydrogen atom leads to a value of r such that:
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r n =n 2 x x 0 ,53 ( A ° )
r =n2h2/4 2K mee2Z ==> Z
E = -Z2(2 2Kee4)/n2h2 ==> En = Z2 En(hydrogène)
13 , 6 2
En =− Z
n2 (eV)
1 1 1
=R H xZ2 x ( 2 − '2 )
λ n n
VI- Application du modèle de Bohr aux atomes à plusieurs électrons :
Si l’électron responsable de l’émision du spectre optique de raies est séparé du noyau par des
électrons profonds, il existe un effet d’écran de la part de ces électrons vis-à-vis de l’électron
optique.
La force d’attraction du noyau sera affaiblie, on a: Zeff. = Z - Zeff. : Z effectif
k (Z-σ )e2
F e=
Hence: r2
0,53
r n =n 2
Hence: ( Z−σ ) (A°)
1
En = 2 (−13,6 )(Z−σ )2
n (eV)
−
1 1 1
υ = =R H ( Z- σ )2 ( 2 − '2 )
λ ni n f est la constante d’écran qui dépend de n.
Cette formule est analogue à la loi de moseley.
Conclusion
Il faut signaler l’importance de la théorie de Bohr assimilant un électron tournant autour du noyau
comme la lune autour de la terre : outre son succès remarquable dans l’interprétation du spectre de
l’atome d’hydrogène, elle a confirmé les idées révolutionnaires de Planck sur la quantification de
l’énergie.
Mais cette théorie simple s’est révélée une théorie approchée. On n’arrivait pas à expliquer l’effet
Zeeman par exemple (un atome a un spectre d’émission plus complexe dans un champ
magnétique).
La théorie de Bohr ne pouvait pas non plus expliquer les détails du spectre des atomes possédant
plusieurs électrons.
La théorie de Bohr laissa place vers 1924 à la théorie moderne de la structure atomique.