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21-01-2024 - SR - Super60 - Elite, Target & LIIT-BTs - Jee-Main-GTM-15 - KEY & Sol'S
21-01-2024 - SR - Super60 - Elite, Target & LIIT-BTs - Jee-Main-GTM-15 - KEY & Sol'S
CHEMISTRY
31) 3 32) 3 33) 4 34) 2 35) 4
36) 2 37) 4 38) 1 39) 1 40) 1
41) 1 42) 1 43) 3 44) 4 45) 1
46) 4 47) 1 48) 1 49) 1 50) 1
51) 5 52) 4 53) 3 54) 3 55) 5
56) 6 57) 3 58) 4 59) 4 60) 1
MATHEMATICS
61) 2 62) 2 63) 2 64) 1 65) 1
66) 3 67) 2 68) 1 69) 2 70) 3
71) 3 72) 1 73) 4 74) 4 75) 1
76) 3 77) 1 78) 1 79) 3 80) 1
81) 1 82) 32 83) 2223 84) 0 85) 5
86) 1 87) 103 88) 3 89) 1 90) 8
SOLUTIONS
PHYSICS
1. Here we shall divide the arrangement into three parts as shown and then apply the
principle of superposition. E1 x along x axis
4 0 a
Similarly
E3 x (along x axis)
4 0 a
And E2 x 0 E2 y (along y axis)
2 0 a
So, EC E1 E2 E3 EC 0
C1 V2 5i 5
2. C1V1 C2V2
C2 V1 3i 3
C1 i 3
2
1
i C2
2V R
[Pressure]
Force
3. ML1T 2 .
Area
4. Efficiency of heat engine
T 1 T
1 s 1 s [ Ts sink temperature]
T 4 T
3
4Ts 3T or , Ts T ……… (i)
4
1 T 58
1 s ……… (ii)
2 T
From equation (i) & (ii)
3 58 1 1 58 3
T 232 Ts T 1740 C
4 T 2 4 T 4
5. F .d 12 2c 6 6 2c 12
c6
6. Their velocity of approach is
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 2
SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐15_KEY &SOL’S
Q1 Q2
R x P
1 T1 1 T2 n2 l1 T2
9. n1 , n2
2l1 m 2l2 m n1 l2 T1
Let l1 100l , l2 55l
T1 100T , T2 121T
n2 100l 121T 100 11
2 n2 2n1
n1 55l 100T 55 10
10. As charge on both particles is same, so electric force acting on them will be same. Since
the particles are allowed to move for the same time, their final momentum will be same.
Because change in momentum = impulse = force time, so
P2 1 KE1 m2
KE
gives KE 2 :1
2m m KE2 m1
11. Given Q1M H 2 2; M O2 32
RT
Speed of sound, v
M
1
v
M
vH 2 M O2 32
4 :1
vO2 M H2 2
Q Q2 CV 2CV 3V
12. VC 1
C1 C2 KC 2C K 2
13. Taking torque about the attachment point for W , we get
T1 0.4 L T2 0.3L 500 0.2 L 0
T 1000 N , where T1 T2 T
Fy 0 2T W 500 0
W 1500 N
14. When we are giving an angular acceleration to the rod, the bead is also having an
instantaneous a L . This will happen when a force is exerted on the bead by the rod.
N
A
N ma
15. l decreases as the block moves up. H will also decrease because when the coin is in the
water it will displace equal volume of water, whereas when it is on the block an equal
weight of water is displaced.
16. Let the distance from the mean position is X.
Given KE= PE
1
2
1
So, M 2 A2 x 2 M 2 x 2
2
A
A 2 x 2 x 2 A2 2 2 x
2
2
l l Id
17. Restoring torque 2 k
2 2 dt 2
kl 2
2
d 6k 1 6k
2 f
dt 2 Ml 2 M 2 2 m
12
18. We know that energy is released when heavy nuclei undergo fission or light nuclei
undergo fusion. Therefore statement (I) is correct. The second statement is false because
for heavy nuclei the binding energy per nucleon decreases with increasing Z and for light
nuclei, B. E/nucleon increases with increasing Z.
19. A. In instrinsic semiconductor, Fermi level is between the two bands.
B. In n type semiconductor, Fermi level is close to conduction band.
C. In p type semiconductor, fermi level is near to valence band.
D. In metal, Fermi level inside the conduction band.
20. For same value of current higher value of voltage is required for higher frequency. Hence
(a) is correct answer.
21. V A VB V0 VB V0 AA 1 2 1 4 2V .
2A
O
1A
2 B 4
22. Let tension in strings connecting A and B is T. From FBD of block A and pulley to
which it is attached, for vertical equilibrium, we get
mg
2T mg T ............... i
2
From FBD of B, for horizontal equilibrium, we get
3
T T cos mg
4
Substituting value of T from Eq. (i),
mg mg 3 1
We get cos mg cos 600
2 2 4 2
Just after F is withdrawn, the block will accelerate as shown. Let’s assume tension in
string connected to A be T.
From FBD of pulley connected to block A, T 2T ........... ii
1 1 1 1 1
Further, 1 req 1
req r1 r2 2 2
Now this resistance is in series with the third resistance so the equivalent emf of these
two is 6 3V 3V and the internal resistance will be 1 1 2 .
24. The magnetic force acting on the rod is given by
F I l B Il kˆ B ˆj BIl iˆ
a
I , N1 Mg And f1 N1 N N 2 Mg
3
Balancing the torque about point A,
Mg l cos 300 N 2 a sin 0
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SRI CHAITANYA IIT ACADEMY, INDIA 21‐01‐24_ Sr.Super60_Elite, Target & LIIT-BTs _Jee‐Main_GTM‐15_KEY &SOL’S
Mg
a
3
cos 300 Mg a sin 0
1 3 1
cos sin sin
3 2 2
On solving further, we get
1
cot 1 2 x 2 and y 3 x y 5
3
26. Final angular velocity
2 1800
i 2 f 60 rad / s
60
Initial angular velocity
2 600
f 20 rad / s
60
Using f i t 60 20 10
Angular acceleration, 4 rad / s 2
1
We have, 0t t 2
2
1
20 10 4 10 2 400 radian.
2
400
Number of rotations n 200
2 2
mdv ˆ
27. ˆ 2ˆ
F ti 3t j ti 3t 2 ˆj
dt
v t t
m 1 kg , dv tdtiˆ 3t 2dtjˆ
0 0 0
2 t3
t
v iˆ t 3 ˆj Power F .v 3t 5
2 2
8
At t 2, power 3 32 100
2
28. When n drops combined potential of bigger drop V 1 n 2/3V
2/3
V 1 33 .18 9 18 162V
29. The relation between Y , , is given by
Y 3K 1 2 Y 2 1
161D k 2 D
30. Fringe width,
d d
16 600
k 24
400
Hence the number of fringes observed in the same segment of the screen = 24
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CHEMISTRY
hc 6.626 1034 3 108
31. E hv E 4.97 1019 J
10
4000 10
4.97 1019 J
1 1 2
3.1 eV KE mv 2 9 1031 kg 6 105 ms 1
1.6 1019 J eV 1 2 2
1.62 1019 J 1J kg .m 2 s 2 1 eV
According to photoelectric effect,
K .E. hv hv0 hv0 hv K .E.
Work function W0 E K .E. 3.1 1 2.1eV
32. As difference in 3rd and 4th ionization energies is high, so atom contains 3 valence
electrons.
33.
V 40
34. w nRT ln 2 , W 2 8.314 103 300ln , w 11.488J
V1 4
35. NH 4OH HCl
NH 4Cl s H 2O H1 51.46 kJ / mol …… (i)
NaOH HCl NaCl s H 2O H 2 55.90 kJ / mol ……….. (ii)
On subtracting eq. (ii) from eq. (i)
NH 4OH NH 4 aq OH aq
Enthalpy of ionization 51.46 55.90 4.44 kJ / mol
36. At equilibrium, rate of forward reaction = Rate of backward reaction.
37. Temperature plays a significant role on pH measurements. As the temperature rises,
molecular vibrations increase which results in greater ability of water to ionize and form
more hydrogen ions. As a result, the pH will drop. So assertion is incorrect.
The dissociation of water molecules into ions is bond breaking and is therefore an
endothermic process. So reason is also incorrect.
38. C H N
9 1 3.5 108
Moles n 2
12 1 14 54
3 1
: 1:
4 4
3 : 4: 1
39. Conceptual
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No. of 3 – centre – 2 electron bonds 2 .
40. Conceptual
P0 P
41. Psolution Psolution X solvent X Solute
P0
1 2n 1 1
42. t1/2
n 1 k a n1
1000 1 1 1000
43. m 1000; m
M M xy
COOH
44.
O
45.
46. Ni atom under go sp3 hybridization in Ni CO 4
47. Molar conductivity increases with decrease in concentration for weak electrolyte
48. pseudo first order reaction example
49. Due to lanthanide contraction Zr and Hf have similar size
1
50. Rate of SN2
stearic crowding near to reaction centre
51. Tollen’s reagent test
52. keto acid undergo decarbaxylation
53. Carbyl amine reaction
54. Geometrical isomerism conditions
55. Obey huckle’s rule and conditions of aromaticity
56. 2MnO2 4 KOH O2 2 K 2 MnO4 2 H 2O
57. Conceptual
58.
O O
HO S O O S OH
O O
MATHEMATICS
x2
61. Let I dx
2
x sin x cos x
Multiplying and dividing it by x cos x , we get
I x sec x .
x cos x dx
x sin x cos x 2
I II
x cos x d x cos x
I x sec x. dx x sec x dx dx
2
2
x sin x cos x dx x sin x cos x
1 1
x sec x. x sec x.tan x sec x . dx
x sin x cos x x sin x cos x
x sec x
x sin x cos x dx
x sin x cos x cos2 x. x sin x cos x
x sec x
tan x c
x sin x cos x
2
62. Here, the curve is x 2 4 x 1 y, ie, x 2 y 5
y
y mx
x
A O B
3
x
2
y 1
64. Equation of common chord is 4kx k 0
2 2
Given equation is 4 x 5 y k 0
65. f x 2 x3 5 2 x3 5
Let 2x3 t g t t where t [2,16)
g is continuous at t 2 and discontinuous t t 3,4,.......,15 13 points.
1
66. Sum of probability = 1 K 1,
10
366
Mean 3.66
100
67.
a cos
a sin b sin
a
b
b cos
a
a sin
a cos
ab sin 2 cos 2 a 2 b2 sin cos
ab
a 2 b2
sin 2
2
A is maximum when sin 2 is maximum. Therefore,
Amax ab
a 2 b2 1
2
a b .
2 2
68.
69. x1x2 x3.........xn
xi2 400
x12 x22 ...... xn2 400
xi 40
x1 x2 x3 xn 40
A M of mth power m n power of A. M.
m
x1m x2m ...... xnm x1 x2 .... xn
n n
Put m 2
2
x12 x22 ...... xn2 x1 x2 ...... xn
n 2
2
400 40 400 1600
n n n n2
400 n 1600 n4
z i x iy i
70.
z 1 x iy 1
x x 1 y y 1 i y x 1
x 12 y 2
Put 0 x2 x y 2 y 0
2 2
1 1 1 1 1
x y C ,
2 2 2 2 2
1 5 1 4
z 3 3i PC 2 2
2 2 2 2
P 33
12
22
O
71. Let R be the given relation.
y y
tan C , tan B
ax ax
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y y
tan C B tan k a x a x tan k locus is x 2 y 2 2 xycotk a 2 0
y y
1
ax ax
x2 x1 y2 y1 z2 z1 i j k
79. S .d a1 b1 c1 a1 b1 c1
a2 b2 c2 a2 b2 c2
80. Given equation is px 2 qx r 0
Let, f x px 2 qx r
f 0 r 0
f 1 p q r 0
f 1 p q r 0
Hence, one root lies in 1,0 and the other in 0,1
1 and 0 1
81. 2xy x 2 y xy 2
2 xy x 2 y xy 2 0
xy 2 x y 0
x 0, y 0, x y 2 are the sides of triangle.
Triangle is right angled
Centroid x 0, y 0, x y 2
Hence, circum centre.
0
2 2 0 2
C 2 , 2 , 1,1
2 2
Orthocenter H , 0,0
5 4 31 31 2 2 2
2 2
5 0 4 0 3 3 2 1 1 2 2 2 1 1
3 3
C
D 5,0
0 1,2
4y x 7
A B 5,4
3, 4
82.
Centre O ab
OA OB
O 1, 2
C 5,0
AB 8
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BC 4 32
83. 3, 6, 9, 12,…….. up to 78
Last term 3 78 1 3 234
5,9,13,17,........up to 59
Last term 5 59 1 4 237
Common terms in series is 9, 21, 32, ……
If last term is 234 then 234 9 n 112
237 12n n 19 (as we consider integral value of n )
19
So, sum of common terms series 2 9 19 112 2223 .
2
22
84. Total no. of relations 2 16
Fav. Relation , x, x , y, y , x, x y, y , x, y , y, y , x, y , y, x
5
Three relations are reflexive as well as transitive probability
16
85. n B A
n A B 25 x
n B A 2 x
n A B 2x
n A n A B n A B
25 x 2 x 25 3x
n B n B A n A B
2 x 2n 4x n A 2n B
25 3x 2 4 x 5 x 25 x5
x 4 x6 x 2 x3
86. x ...... x ...
2 4 2 4
x x2
x 2
1 1 x
2 2
2x 2 x2
x x 1 0
2 x 2 x2
x 0,1 but 0 x 2
x 1
1 0 0 1 0 0 1 0 0
87. P 4 1 0 4 1
2
0 8 1 0
16 4 1 16 4 1 48 8 1
1 0 0 1 0 0 1 0 0
P3 8 1 0 4 1 0 12 1 0
48 8 1 16 4 1 96 12 1
1 0 0
n
P 4n 1 0
8 n 2 n 4n 1
1 0 0
50
P 200 1 0 P50 Q I
8 50 52 200 1
Equating we get q21 200
q31 400 51 q32 200
q31 q32 400 51 200
2 51 1 103
q21 200
88. Number of constants = 3
89. f x x 2 x 3 x ....... nx x 2 x 3 x ...... nx
x 2 x 3x ......... nx
1 1 1
Period of f x LCM 1, , ,........ 1
2 3 n
1 3
90. Let A
4 7
A A1 I A1A
1 5. x2 5 x 5 4
x 5 x 5 4
x2 5x 6 0
x 6, 1 ,