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Class Test Aldol and Cannizaro
Class Test Aldol and Cannizaro
CHO
‘Y’ is
– +
COO Na Ph COONa
(A) (B)
Ph
Ph CO2H
(C) Ph (D)
CO2H
H O
O H
(A) (B)
O H
O H
(C) (D)
+ NaOH
O O
O
(A) (B) (C) (D)
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5. Choose the major product of the following reaction.
O
Br2
?
H
O
O O O
Br
O O
O O
O
O O O
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CH3
KOH
10. Identify compound HO–CH2–C–CH2–OH + HCOO–
HCHO,
(A)
CH2–OH
O O
Ph O O
(A) Ph (B) (C) (D) Ph
O Ph Ph
+ H2C=O OH
O O O O
OH
(A) (B) (C) (D) OH
OH
LDA I
THF
O O OH
1. O3 OH
2. Me2S heat ?
O O O O
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15. What compound results from the aldol cyclization of
O O
CH3CCH2CH2CHCH2CCH3 ?
CH3
CH3 CH3
CH3 CH3 C=O C=O
O O CH3 CH3 CH3
CH3
CH3
CH3
I II III IV
O H
16. The aldol cyclization of CH 3CCH 2CH 2CH 2C=O produces which of these ?
O H O H CH3
C–CH3 CH3 C=O C=O O O O
I II III IV V
O O
– +
OH H3O ,heat H2,Ni
(CH3)3CCH + CH3CH2CH (A) (B) (C)
OH O
(A) (CH3)3CCH2CH2CH2OH (B) (CH3)3CCHCH2CH2CH
(C) (CH3)3CCH2CHCH2OH (D) (CH3)3CCH=CCH2OH
CH3 CH3
18. Which reactants would you use to synthesize this compound by an aldol condensation ?
O
C6H5CH=CHCC6H5
O O O O
(A) C6H5CH and C6H5CH2CH (B) C6H5CH2CH and C6H5CCH3
O O O
(C) C6H 5CH=CHCH and C6H 5OH (D) C6H 5CCH 3 and C6H 5CH
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19. Which of these is not among the reaction products when a crossed aldol addition occurs between ethanal
and butanal ?
OH H OH H OH H
OH H
(D) CH 3CH 2CH 2CHCH2C=O
O O
–
C6H5CH + CH3CH OH
heat
O O O
(A) C6H5CH2CCH3 (B) C6H5CCH2CH
OH OH O
(C) C6H5CHCH2CH2 (D) C6H5CH=CHCH
21. Which is the only one of these compounds which cannot self-condense in the presence of dilute aqueous
alkali ?
(A) Phenylethanal (B) 2-Methylpropanal
(C) 3-Methylpentanal (D) 2,2-Dimethylpropanal
22. Aldehyde V was treated with base to give the product shown.
H O
V OH
–H2O
Which of the following aldehydes is compound V ?
H H O
O
(A) (B) (C)
H O
H O H
(D) (E)
O
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CH3
O3 KOH
23. (A) (B)
Zn
O
CH = O
(A) Final product B is CH3 (B) Final product B is
O
(C) Final product B is (D) A B is intermolecular aldol.
O
O OH O O
(A) (B) OH (C) (D) HO
OH
are
O O
18 || 18 ||
HO NaO HO NaO
(A) and (B) and
O O
|| 18 ||
18
NaO NaO HO
(C) and HO (D) and
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Conc. KOH H O
27. (X) (Y)
O
Compound (X) is obtained by which of the following reaction
O
CH2 – OH C – O – Et
(A) 2 moles of PCC (B) 2 moles of DIBAL-H
in CH2Cl2 C – CH3
CH2 – OH
O
O
C – Cl
(C) 2H2 (D) CH3MgBr
Pd – BaSO4
CH2 – C – Cl
CHCl3 + KOH
(X) 50% KOH (Y)
is/are
OH OH OH OH
OH COOK
(A) (B) &
OH OH OH O
COOK C COOK
(C) OH (D)
&
OH
29. (x)
dil . NaOH (x) is
C – CH3
O
O O O
(A) O (B)
O O
(C) (D)
O O
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: OH ..
30. In Cannizzaro reaction given below , 2 Ph CHO Ph CH2OH + Ph CO 2 the slowest step is :
33. A mixture of benzaldehyde and formaldehyde on heating with conc. NaOH solution gives :
(A) benzyl alcohol and sodium formate (B) sodium benzoate and methyl alcohol
(C) sodium benzoate and sodium formate (D) benzyl alcohol and methyl alcohol
34. The number of aldol reaction (s) that occurs in the given transformation is :
OH OH
conc.NaOH
CH3CHO + 4HCHO
HO
OH
35.
(
i ) NaOH ( excess )100C
(ii ) H / H 2O
(A) (B)
(C) (D)
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OMe conc. KOH
36.
H O
Find out the product ‘p’ of the following reaction
(A) (B)
OMe OMe OMe OMe
CO2K OH CO2K CO2K
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