TEJAS

Practice Sheet JEE Chemistry

ATOMIC STRUCTURE

SINGLE CHOICE QUESTION 7. An excited state of H-atom emits a photon of

1. A 5g orbital has wavelength  and returns in the ground state, the
(A) Zero angular node and zero radial node principal quantum number of excited state is given
(B) Zero radial node and 2 angular nodes by:
(C) 4 radial nodes and 4 angular nodes R
(D) Zero radial node and 4 angular nodes (A) R(R −1) (B)
(R − 1)
2. An electron beam can undergo diffraction by (R − 1)
(C) √𝜆𝑅(𝜆𝑅 + 1) (D)
crystals. Through what potential should a beam of R
electrons be accelerated so that its wavelength
becomes equal to 1.54 Å? 8. The energy of I, II and III energy levels of a certain
(A) 54.3 volt (B) 63.3 volt
atom are E, 4E/3 and 2E respectively. A photon of
(C) 66.2 volt (D) None of these
wavelength  is emitted during a transition from III
3. Radiation corresponding to the transition n = 4 to to I. What will be the wavelength of emission for
n = 2 in hydrogen atoms falls on a certain metal transition II to I ?
(work function = 2.5 eV). The maximum kinetic (A) /2 (B) 
energy of the photo-electrons will be : (C) 2 (D) 3
(A) 0.55 eV
(B) 2.55 eV 9. Balmer gives an equation for wavelength of visible
(C) 4.45 eV
kn 2
(D) 0.05 eV
radiation of H-spectrum as  = n − 4 . The value
2

4. An electron in an atom jumps in such a way that its of k in terms of Rydberg's constant R, is -
x (A) R (B) 4R
kinetic energy changes from x to . The change
4 (C) R/4 (D) 4/R
in potential energy will be :
3 3 10. Which of the following has the maximum number
(A) + x (B) − x
2 8 of unpaired electrons?
3 3 (A) Cr (B) Ti
(C) + x (D) − x (C) V (D) Mn
4 4

5. The possible set of quantum no. for the unpaired 11. Wave function of an orbital is plotted against the
electron of chlorine is : distance from nucleus. The graphical
representation is of:
n  m
(A) 2 1 0
(B) 2 1 1
(C) 3 1 1
(D) 3 0 0

6. The angular velocity of an electron occupying the

second Bohr orbit of He+ ion is (in sec–):
(A) 2.067 × 1016 (A) 1s (B) 2s
(B) 3.067 × 1016 (C) 3s (D) 2p
(C) 1.067 × 1018
(D) 2.067 × 1017
12. A hydrogen atom has electron in the fourth energy
level. The number of different possible photons lie 20. Identify the correct statement(s) :
in which of following series – (A) Wavelength associated with a 1 kg ball
(A) 3 Lyman, 2 Balmer, 1 Paschen moving with the velocity 100 m/s can’t be
(B) 2 Lyman, 1 Balmer, 1 Paschen calculated.
(C) 2 Lyman, 1 Paschen, 1 Brackett
(B) Wave nature of the running train is difficult to
(D) 1 Lyman, 1 Balmer, 1 Paschen
observe because wavelength is extremely
13. A proton and an α-particle are accelerated through small.
the same potential difference. The ratio of their de- (C) Wavelength associated with the electron can
Broglie wavelength is h
be calculated using the formulae E =
(A) 2 
(B) 1: 2 (D) An electron with initial kinetic energy
(C) 2 2 :1 of 100eV is acceleration through a potential
(D) 2 difference of 50V. Now the de-Broglie
wavelength of electron becomes 1 Å.
14. The orbital represented by ψ4,2,0 is
(A) 4dz2 (B) 4px 21. For radial probability curves, which of the
(C) 4pZ (D) 4dxy following is/are correct?
(A) The number of maxima in 2s orbital are two
15. The ratio of angular momentum of an electron in (B) The number of spherical or radial nodes is
3rd orbit and angular momentum of 3d- orbital is equal to n –  – 1
3 (C) The number of angular nodes are ‘’
(A) 6 (B)
2
(D) 3dz2 has 3 angular nodes
2 1
(C) (D)
3 6
22. Which of the following sets of quantum number
is(are) incorrect:
INTEGER TYPE QUESTION
1
16. A transition for H-atom from II to I orbit has same (A) n = 5, l = 4, m = 0, s = +
wavelength as from nth to 2nd orbit for He+ ion.
2
1
What is the value of “n”? (B) n = 3, l = 3, m = +3, s = +
2
17. How many electrons in an atom can have n = 3, l = 1
(C) n = 6, l = 0, m = +1, s = –
2, m = +2? 2
(D) n = 4, l = 2, m = +2, s = 0
18. The radiations obtained from de-excitation of H-
atom from 2nd orbit to 1st orbit, striked on a metal
of work function 4.2 ev. The wavelength (in Å) of 23. The angular momentum of electron can have the
ejected electron having maximum kinetic energy value
is…….? h
(A) 2.5
MORE THAN ONE CORRECT QUESTIONS 2
19. Which is/are true statements? h
(B)
(A) Rest mass of an electron is 9.1 × 10–28 g 0.5
(B) The order of energies of orbitals in H-like h
(C)
species is 3s = 3p = 3d. 
(C) Wavelength of an electron accelerated h
(D) 0.5
through a potential difference of 1 volt is 
12.27 Å.
(D) e/m of an electron is 1.7 × 108 coulomb/g
MATRIX MATCH TYPE QUESTIONS 25. Match the List-I with List-II:
24. Match the List-I with List-II: List I List II
List I List II I. No. of orbitals in the nth P. 2(2l + 1)
I. 2s P. n = 4, l = 2, m = 0 shell
II. Max. no. of electrons in Q. n
II. 2px Q. n = 4, l = 2, m = –2 or +2
a subshell
III. 4dx2 −y2 R. n = 2, l = 1, m = 0 III. No. of subshells in nth R. 2l + 1
shell
IV. 4d z2 S. n = 2, l = 0, m = 0
IV. No. of orbitals in a S. n2
I II III IV subshell
(A) S R Q P I II III IV
(B) S R P Q (A) S R Q P
(C) R S Q P (B) R S P Q
(D) Q P S R (C) R S Q P
(D) S P Q R

ANSWER KEY

1. (D) 8. (D) 15. (B) 22. (B,C,D)

2. (B) 9. (D) 16. (4) 23. (B,C,D)
3. (D) 10. (A) 17. (2) 24. (A)
4. (A) 11. (C) 18. (5) 25. (D)
5. (C) 12. (A) 19. (A,B,C,D)
6. (A) 13. (C) 20. (B,D)
7. (B) 14. (A) 21. (A,B,C)

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