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NCERT Based Questions (Chemistry)
NCERT Based Questions (Chemistry)
Chemistry
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Chemistry
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Chemistry
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Chemistry
Answers
1 D 2 A 3 A 4 A 5 B
6 A 7 B 8 D 9 A 10 B
11 A 12 C 13 B 14 D 15 B
16 B 17 A 18 A 19 C 20 C
21 D 22 C 23 B 24 A
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Chemistry
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Chemistry
6. The statement which is incorrect
(d) all
9. Anoxia is
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Chemistry
11. Which is correct for an ideal solution
(a) 0 (b) 0
(a) 0 (b) V 0
16. If V.P. of pure benzene is 0.85 bar. When a non- volatile solute of
mass 0.5gm added in 39gm of benzene then V.P. of solution is
found to be 0.845 bar. The molar mass of solute is
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Chemistry
18. The freezing point of 0.1 molal aquous solution would be (kF = 1.86
kg K mol-1)
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Chemistry
22. An unknown solute of mass 10gm dissolve in 180gm of H2O
showing R.L.V.P 0.005. The molar mass of solute is
(a) 200 (b) 199
25. Two elements of A & B form compound having formula AB2 and
AB4 when dissolve in 20gm of benzene, 1gm of AB2 lower the F.p
by 2.3K and 1gm of AB4 lowers by 1.3K (KF =5.1 K Kp mol-1) atomic
mass of A is
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Chemistry
27. Which is are example of osmosis
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Chemistry
32. a 5% (w/w) of can sugar solution has F.p depression 271K.
Calculate F.p. of 5% glucose solution if F.p of H2O is 273.15K.
33. 3.42% sucrose solution to is isotonic with urea solution. The mass
of urea required is
34. The graph which is correct for CHCl3 & Acetone solution
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Chemistry
Answer Key
1 a 2 b 3 b 4 b 5 a
6 b 7 d 8 b 9 a 10 d
11 d 12 c 13 a 14 d 15 a
16 b 17 d 18 b 19 a 20 b
21 b 22 b 23 b 24 a 25 a
26 a 27 c 28 c 29 b 30 b
31 b 32 a 33 b 34 b 35 b
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Chemistry
(a) r3 > r2 > r1 if [A] > 1 (b) r1 > r2 > r3 if [A] < 1
(a) E a Ea
1 2
(b) E a Ea
1 2
(c) E a Ea
1 2
(d) none
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Chemistry
5. if half life of a 1st order reaction is t/2 what is time period required
for completion upto 75% reaction
(d) None
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Chemistry
(d) all
13. For which part of completion of 1st of order of reaction is ten times
of half life Pd
14. A first order reaction has a rate constant 1.15 103 sec-1 if 5gm of
reactant reduced to 3gm. The time period required is
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Chemistry
t / 21 a1 t / 21 a2
n1 n
(a) (b)
(t / 2)2 a2 (t / 2)2 a1
t / 21 a2 t / 21 a1
n1 n
(c) (d)
(t / 2)2 a1 (t / 2)2 a2
A product
S.No [A] t/2
1 5M 10 minutes
2 10M 5 minutes
18. A first order reaction has a specific reaction rate 10-3 sec-1. How
much time it will take for 10gm of reactant to reduce to 2.5gm
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Chemistry
19. The half life Pd of a 1st order reaction is 60minutes the percentage
of reactant left after 240 minutes.
a
20. A product. The ratio of was found 1/8 after 60 minutes. The
ax
rate of reaction will be if [A] = 0.1M
(a) 3.46 10-4 mol litre-1 min-1 (b) 3.46 10-3 mol litre-1 min-1
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Chemistry
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Chemistry
(d) None
(c) The no. of collisions per sec per unit –volume is found to be
very low
Answer Key
1 a 2 d 3 d 4 a 5 a
6 d 7 d 8 a 9 b 10 a
11 c 12 d 13 c 14 c 15 a
16 c 17 b 18 a 19 c 20 b
21 b 22 b 23 a 24 b 25 b
26 d 27 d 28 b 29 c 30 c
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Chemistry
2. Isolated system is
(a) H 2 H1 H (b) T2 T1 T
(c) U 2 U1 U (d) P2 P1 P
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Chemistry
VF
(c) W = - 2.303 n RT. log (d) None of these
Vi
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Chemistry
(d) 2 H(g) H2
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Chemistry
17. If ∆H0f of CO(g) N2O(g) and N2O4(g)are 110, 393, 31 & 9.7 kJ mol-1.
The enthalpy of reaction is.
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Chemistry
(a) ∆G (b) ∆H
26. Bond dissociation energy for Cl2, I2 & ICl are 242.3, 151 and 211.3
kJ mol-1 respectively enthalpy of sublimations of I2 is 62.8
kJ/mol. The ∆Hf0 of ICl(g) is
(a) ∆H = ∆E (b) ∆H = T ∆S
(c) ∆H = O (d) ∆S = O
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Chemistry
28. For the reaction A(s) + 3B(g) 4C(g) + D(l) ∆ U and ∆G are related as
If ∆H0f of CO2(g) and C8H18(g) are 490, 240 and 160 kJ mol-1
respectively.
30. For the reaction of one mole of Zn dust with one mole H 2SO4 acid
in bomb calorimeter, ∆ µ and w comes pound to
Answer key
1 b 2 - 3 d 4 c 5 a
6 d 7 a 8 b 9 a 10 d
11 b 12 a 13 b 14 c 15 a
16 a 17 a 18 a 19 c 20 b
21 d 22 b 23 d 24 a 25 d
26 - 27 b 28 c 29 b 30 a
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Chemistry
Which is correct:-
(a) It occur at m. p.
(b) There is no exchange of heat to surrounding
(c) Masses of two phases remains constant
(d) All of these
2. The statement correct about Equilibrium
(a) It is applied for close system only
(b) both opposing processes occurs at different rates
(c) All measurable properties of system remains constant
(d) a and c are correct
3. Which QC >1 then
(a) Rate of Forward reaction is more than backward reaction
(b) Rate of Forward reaction is less than backward reaction
(c) Rate of Forward reaction and rate of backward reaction both
are equal
(d) It is independent of rate of reaction
4 If n 0 then
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Chemistry
7. The equilibrium in which pressure has no effect
(a) H 2 I 2
(g) (g)
2HI ( g ) (b) N2 3H 2
(g) (g)
2NH3( g )
Ksp
(c) s (d) none
2
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Chemistry
14. If Ksp of MX2 is 3.2 10-11 then solubility of ions is
[S ] [S ]
(c) pH = pka – log (d) pH = pka + log
[ A] [ B]
1
(c) K2 = 1/ 2
(d) K2 = K1
K1
(a) 9 (b) 8
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Chemistry
20. The relation which is correct
(a) Ka Kb = Kw (b) Ka / Kb = Kw
(c) Kb / Ka = Kw (d) Ka – Kb = Kw
(a) 90 :1 (b) 92 :1
(c) 94 :1 (d) 95 : 1
26. The species which acts as bronsted acid and base both .
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Chemistry
27. A sample of PCl5 was introduced into an evacuated vessel at 473 K.
When equilibrium was stabilised coucen of PCl5 was 0.05 m if Kc is
8.3 10-3 the con—of Cl2 & PCl3 at equilibrium is
Answer Key
1 d 2 d 3 b 4 a 5 a
6 c 7 a 8 a 9 d 10 c
11 c 12 b 13 b 14 a 15 c
16 b 17 c 18 a 19 b 20 a
21 a 22 d 23 b 24 b 25 c
26 d 27 a 28 a
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Chemistry
(a) +6 (b) +4
(c) +3 (d) +2
(a) +1 (b) +2
(c) -1 (d) -2
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Chemistry
(c) +1 (d) +2
11. For the redox reaction MnO4 C2O42 H Mn 2 CO2 H 2O the correct
coefficients of the reactants for the balanced equation are:
MnO4 C2O42 H
(a) 2 5 16
(b) 16 5 2
(c) 5 16 2
(d) 2 16 5
(a) +5 (b) +3
(c) -3 (d) +2
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Chemistry
(a) +7 (b) +6
(c) +3 (d) +2
(c) +4 (d) +6
(a) +7 (b) -1
(c) +5 (d) +1
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Chemistry
20. The standard oxidation potentials, E0, for the half reactions are as:
Zn Zn 2 2e , E 0 0.76volt
Fe Fe2 2e , E 0 0.41volt
21. Four colourless salt solutions are placed in separate test tubes
and a strip of copper is dipped in each. Which solution finally
turns blue?
(a) Al (b) Ni
(c) Pb (d) Cu
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Chemistry
x, y and z are
(a) 1, 3, 1 (b) 4, 1, 4
(c) 3, 2, 3 (d) 2, 1, 2
28. The oxidation numbers of sulphur in S8, S2F2, H2S respectively are:
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Chemistry
(a) +1 (b) +3
(c) +5 (d) +7
31. In alkaline medium, H2O2 reacts with Fe3+ and Mn2+ separately to
give:
(a) +4 (b) +5
(a) +3 (b) +5
(c) -3 (d) +2
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Chemistry
Answer key
1 a 2 d 3 a 4 b 5 a
6 c 7 d 8 c 9 a 10 c
11 a 12 a 13 b 14 b 15 a
16 b 17 a 18 c 19 a 20 a
21 b 22 b 23 a 24 d 25 d
26 a 27 a 28 a 29 c 3 b
31 c 32 c 33 b 34 d 35 b
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Chemistry
5. Cl (Z = 58) is a member of
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Chemistry
6. The element with highest ionization enthalpy is
7. The first ionization enthalpies of Na, Mg, Al and Si are in the order
of
(c) Sodium atom has 11 electrons and sodium ion has 10 electrons
(a) Fe (b) K
(c) Ba (d) N
11. Which of the following element has the maximum electron gain
enthalpy?
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Chemistry
12. Transition metals are characterised by the properties except
(a) Less than atomic radus (b) more than atomic radius
(a) F (b) Cl
(c) Br (d) I
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Chemistry
18. The outer most electronic configuration of the most electronegative
element is:
(a) ns2 np3 (b) ns2np4
(c)ns2 np5 (d) ns2np6
19. Which of the following has the lowest ionization enthalpy:
(a) Na (b) K
(c) Mg (d) Al
20. Which of the following is smallest cation
(a) Na+ (b) mg2+
(c) Ca2+ (d) Ae3+
21. Aluminium is diagonally relaled to
(a) Li (b)Si
c) Be (d) B
22. Which one is the correct order of the size of the iodine species:
(a) I > I+ >I- (b) I >I- >I+
(c) I+ > I- > I (d) I- > I > I+
23. Which of the following transition involves maximum energy?
(a) M (g) M(g) (b)M2+ (g) M3+(g)
(c) M+(g) M2+(g) (d) M(g) M+(g)
24. The process requiring the absorption of energy is :
(a) F F (b) Cl Cl
(c) O O2- (d) H H
25. Which of the following species has the highest electron gain
enthalpy
(a) F (b) O
(c) O (d) Na+
26. Element with atomic number 56 blongs to which block ?
(a) s – block (b) p – block
(c) d – block (d) f – block
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Chemistry
28. Chloride ion and potassium ion are isoelectronic. Then
(a) Their sizes are same
(b) Cl ion is relatively bigger than K+ion
(c) K+ion is relatively bigger
(d) Cannot predicted
29. Identify the least stable ion amongst the following
(a) Li (b) Be
(c) B (d) C
(a) Li < K < Na < Rb < Cs (b) Li < Na < K < Rb < Cs
(c) Cs < Rb < K < Na < Li (d) K < Li < Na < Rb < CS
(c) N3-, O2-, P2-, S2- (d) Li+, Na+ , Mg2+, Ca2+
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Chemistry
35. An element having electronic configuration [Ar] 3d2, 4s2 blongs to
(a) A (b) A2
(c) A5 (d) A7
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Chemistry
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Answer key
1 d 2 a 3 b 4 c 5 d
6 b 7 a 8 c 9 c 10 a
11 b 12 d 13 a 14 a 15 d
16 a 17 b 18 c 19 b 20 d
21 c 22 d 23 b 24 c 25 b
26 a 27 a 28 b 29 b 30 c
31 a 32 b 33 a 34 b 35 a
36 b 37 c 38 c 39 b 40 b
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Chemistry
(a) Low gonization potential of one atom and high electron affinity
of the other atom
(b) High electron affinity and high ionization onthalpy of both the
atoms
(c) Law electron affinity and law ionization potential of both the
atoms
(d) High ionization potential of one atom and low electron affinity
of the other atom
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Chemistry
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Chemistry
16. Among the following species, identify the is structural pairs NF3,
NO 3 ,BF3, H3O+, NH4+
(a) [NF3,NO 3 ] and [BF3,H3O+] (b) [NF3, NH+] and [NO 3 , BF3]
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Chemistry
21. The bond that exists between NH3 and BF3 is called
24. BeCl2 has zero dipole moment where as H2O has a dipole moment
because
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Chemistry
28. NH3 has much higher boiling point than PH3 because:-
(c) Ammonia contains ionic bond while PH3 contains covalent bond
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Chemistry
(a) O2 2 (b) B2
(c) N 2 (d)O2
34. Which of the following molecules /ions are all the bonds are equal.
36. The no and type of bond between two carbon atoms in calcium
carbide are.
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Chemistry
Answer key
1 c 2 a 3 b 4 a 5 c
6 b 7 a 8 b 9 d 10 a
11 c 12 b 13 d 14 d 15 b
16 c 17 d 18 a 19 d 20 a
21 c 22 a 23 c 24 b 25 c
26 c 27 a 28 d 29 a 30 d
31 a 32 d 33 a 34 a 35 b
36 b 37 d 38 a 39 b 40 c
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Chemistry
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Chemistry
5 The correct increasing order of basic character of following NH3,
PH3 AsH3 SbH3 BiH3
(a) NH3 < PH3 < AsH3 < SbH3 < BiH3
(d) NH3 has highest boiling point among the hydrides of nitrogen
family
8 Nitrogen in its oxides and oxo acids can show maximum oxidation
state up to
(a) + 3 (b) +4
(c) + 5 (d) +2
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Chemistry
9 Nitrogen form N2O3 and N2O5
(d) E2O3 of nitrogen and phosphorus are basic while all acidic
(a) N2O5 < P2O5 < As2 O5 < Sb2O5 < Bi2O5
(b) N2O5 > P2O5 > As2 O5 > Sb2O5 > Bi2O5
(c) P2O5 > As2 O5 > Sb2O5 > Bi2O5 > N2O5
(d) P2O5 > N2O5 > As2O5 > Sb2O5 > Bi2O5
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Chemistry
13 Regarding halides of nitrogen family, which of the following is
correct?
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Chemistry
17 Which of the following is true?
20 In iron and steel industry, the inert diluent used for reactive
chemical is
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Chemistry
22 Ammonia is manufactured by Haber’s process
23 In ammonia
(a) It has three bond pairs , one lone pair and tetrahedral zeometry
(c) It has three bond pairs, one lone pair and pyramidal zeometry
(d) It has two bond pairs two lone pairs and pyramidal zeometry
25 Ammonia is used
(c) as a refrigerant
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Chemistry
26 The O.S. of nitrogen in nitrous oxide (laughing gas)
(a) +1 (b) +2
(c) + 3 (d) + 5
28 NO2 dimerises
30 Hyponitrous acid is
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Chemistry
32 Laboratory grade nitric acid contains
(a) 68% of the HNO3 by mass (b) 98% of the HNO3 by mass
(c) Attacts most metals except noble metals such as gold and
platinum
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Chemistry
37 Which statement regarding white phosphorus is true
(b) It is poisonous
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Chemistry
Answer key
1 a 2 b 3 c 4 c 5 d
6 c 7 b 8 c 9 b 10 b
11 b 12 c 13 b 14 d 15 a
16 c 17 c 18 c 19 a 20 b
21 d 22 d 23 c 24 b 25 d
26 a 27 c 28 a 29 c 30 c
31 c 32 a 33 c 34 b 35 d
36 d 37 a 38 b 39 c 40 d
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Chemistry
(a) ( n – 1) d0 – 10 ns 0 – 2 (b) ( n – 1) d1 – 10 ns 0 – 2
(c) ( n – 1) d1 – 10 ns 2 (d) ( n – 1) d1 – 10 ns 1– 2
(a) Ti (b) Cu
(c) Cr (d) Sc
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Chemistry
(a) Cr3+ has d5 configuration (b) C3+ has half filled t 2g orbitals
(c) Cr2+ has ds configuration (d) Cr2+ has a half filled t2g orbitals
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Chemistry
(c) Cr2 O72 VO2 MnO4 (d) Cr2 O72 VO2 MnO4
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Chemistry
(c) Hyd H for Cu2+ (aq) is much more negative than that of Cu+
(aq)
(d) Hyd H for Cu+ (aq) is much more negative than that of Cu2+
(aq)
(c) Oxygen and fluorine have small size and high electronegativity
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Chemistry
23 +2 oxidation state becomes more and more stable in the first half
of the first row teansition elements
(a) +2 (b) +4
(c) +3 (d) +1
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Chemistry
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Chemistry
(d) Cu2+ ions are blue and Cr2O 72 ions are yellow
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Chemistry
(a) Fe (b) Sc
(c) Os (d) Co
(a) Pt (b) W
(c) Pd (d) Au
(a) Cs (b) Na
(c) Hg (d) Sn
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Chemistry
Answer key
1 c 2 d 3 4 d 5 d
6 a 7 c 8 9 b 10 b
11 d 12 b 13 d 14 b 15 a
16 b 17 b 18 19 20 c
21 c 22 b 23 c 24 b 25 c
26 c 27 c 28 a 29 30
31 b 32 b 33 d 34 b 35 b
36 c 37 38 b 39 b 40 c
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Chemistry
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Chemistry
6 Which of the following show optical Isomerism
10 [Ni(CO)4] is
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Chemistry
12 No of Unparied electrons in the square planar [Pt(CN)4]2- ion.
(c)5.2x10-14 (d)5.2x1014
(c) CN (d) O H
(a) +1 (b) +2
(c) +3 (d) +4
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Chemistry
18 Which of the following is correct statement?
21 How many ions are produced from the complex [CO (NH3)6]Cl2 in
solution
(a) 6 (b) 4
(c) 3 (d) 2
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Chemistry
24 In the formation of K4 [Fe(CN)6] the hybridization involved is
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Chemistry
31 In Fe(CO)5, The Fe – C bond possesses
(c) C l F OH H 2 O CN (d) F CN O H C l H 2O
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Chemistry
37 The crystal field stabilization energy (CFSE) is the highest for
(c) 4 (d) 6
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Chemistry
Answer key
1 d 2 c 3 4 b 5 b
6 a 7 b 8 c 9 b 10 a
11 b 12 a 13 b 14 c 15 c
16 b 17 a 18 b 19 c 20
21 c 22 b 23 c 24 b 25 b
26 d 27 c 28 d 29 a 30 b
31 d 32 a 33 d 34 a 35 c
36 c 37 c 38 a 39 b 40 b
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Chemistry
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Chemistry
10. Methylphenyl ether can be obtained by reacting
(a) Phenolate ions and methyl iodide
(b) Methoxide ions and bromobenzene
(c) Methanol and phenol
(d) Bromo benzene and methyl bromide
11. The strongest acid among the following aromatic compounds is
(a) ortho-nitrophenol (b) para-chlorophenol
(c) para-nitrophenol (d) meta-nitrophenol
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Chemistry
19. Azo-dyes are prepared from
(a) Aniline (b) Benzaldehye
(c) Benzoic acid (d) Phenol
20. Compound ‘A’ reacts with PCl5 to give ‘B’ which on treatment with
KCN followed by hydrolysis gave propanoic acid as the product. What
is ‘A’
(a) Ethane (b) Propane
(c) Ethyl chloride (d) Ethyl alcohol
21. The boiling point of glycerol is more than propanol because of
(a) Hydrogen bonding (b) Hybridisation
(c) Resonance (d) All the above
22. Which of the following is not true in case of reaction with heated
copper at 300 o C
(a) Phenol Benzyl alcohol (b) Primary alcohol Aldehyde
(c) Secondary alcohol Ketone (d) Tertiary alcohol Olefin
23. The boiling point of ethyl alcohol should be less than that of
(a) Propane (b) Formic acid
(c) Dimethyl ether (d) None of these
24. Among the following, the compound that undergoes nitration readily
is
(a) Benzoic acid (b) Toluene
(c) Phenol (d) Nitrobenzene
25. Phenol on distillation with zinc dust gives
(a) C6 H6 (b) C6 H12
(c) C6 H5 OC6 H5 (d) C6 H5 C6 H5
26. The compound which gives the most stable carbonium ion on
dehydration is
CH 3
|
(a) CH 3 CH
|
CH 2 OH (b) CH 3 C OH
|
CH 3 CH 3
CH 3
|
(c) CH3 CH2 CH2 CH2OH (d) CH 3 CH CH 2 CH 3
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Chemistry
28. The compound which will give negative iodoform test is
(a) CH3 CHO (b) CH3 CH2OH
(c) Isopropyl alcohol (d) Benzyl alcohol
29. Which of the following is most acidic
(a) Phenol (b) Benzyl alcohol
(c) m-chlorophenol (d) Cyclohexanol
30. In which of the following reaction, phenol or sodium phenoxide is
not formed
(a) C6 H5 N2Cl alco. KOH (b) C6 H5 OCl NaOH
(c) C6 H5 N2Cl aq. NaOH (d) H 2O
C6 H5 NNCl
33. Which of the following will not form a yellow precipitate on heating
with an alkaline solution of iodine
(a) CH3OH (b) CH3CH2OH
(c) CH3CH(OH)CH3 (d) CH3CH2CH(OH)CH3
35. Which of the following compound give yellow precipitate with I2 and
NaOH
(a) CH3OH (b) CH3CH2CH2OH
(c) C2 H5OC2 H5 (d) CH3CH2OH
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Chemistry
36. Which of the following react with benzoic acid to form ethyl
benzoate
(a) Ethyl alcohol (b) Cinnamic acid
(c) Sodium ethoxide (d) Ethyl chloride
39. On reaction with hot conc. H2 SO4 , which one of the following
compounds loses a molecule of water
(a) CH3COCH3 (b) CH3 COOH
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Chemistry
Answer Key
1 D 2 C 3 C 4 A 5 C
6 B 7 D 8 C 9 A 10 A
11 C 12 C 13 A 14 C 15 B
16 A 17 C 18 A 19 D 20 D
21 A 22 A 23 B 24 B 25 A
26 B 27 B 28 D 29 C 30 B
31 B 32 B 33 A 34 A 35 D
36 A 37 B 38 D 39 D 40 A
41 A 42 A
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Chemistry
4. Ketones (R C R1 )
||
where R R1 alkyl group. It can be obtained in one
O
step by
(a) Hydrolysis of esters
(b) Oxidation of primary alcohol
(c) Oxidation of secondary alcohol
(d) Reaction of acid halide with alcohols
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Chemistry
OH
(a) OH
CH –
CH
O COO O CH2OH
(b) +
H H
O COO O CH2OH
(c) +
H H
Cl Cl
(d) OH
OH
CH –
CH
C C
l l
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Chemistry
12. A and B in the following reactions are
B R OH
R C R HCN
A
C
|| KCN R CH 2 NH 2
O
CN OH
(a) A RR' C , B LiAlH4 (b) A RR' C , B NH3
OH COOH
CN
(c) A RR' C , B H 3 O (d) A RR' CH2CN, B NaOH
OH
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Chemistry
19. Aldol condensation of acetaldehyde involves the formation of which
of the following intermediate
(a) Acetate ion (b) A carbanion
(c) A carbonium ion (d) A free radical
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Chemistry
27. When CH3COCH3 reacts with Cl 2 and NaOH, which of the following is
formed
(a) CHCl3 (b) CCl4
(c) CCl2 H 2 (d) CH3Cl
28. Which gives difference between aldehyde and ketone
(a) Fehling's solution (b) Tollen's reagent
(c) Schiff's reagent (d) Benedict's solution
(e) All of these
29. An aldehyde on oxidation gives
(a) An alcohol (b) An acid
(c) A ketone (d) An ether
34. The aldehyde which react with NaOH to produce an alcohol and
sodium salt is
(a) HCHO (b) CH3 CHO
(c) CH3 CH2 CHO (d) CH3CH2CH2CHO
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Chemistry
35. Which of the following react with NaHSO3
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Chemistry
43. The general formula for monocarboxylic acids is
(a) CnHnCOOH (b) CnH2n1COOH
(c) CnH2n1COOH (d) CnH2nO2
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Chemistry
52. Acetic acid is manufactured by the fermentation of
(a) Ethanol (b) Methanol
(c) Ethanal (d) Methanal
(a) (CH3 )2 C(OH)CN, (CH3 )2 C(OH)COOH (b) (CH3 )2 C(OH)CN, (CH3 )2 C(OH)2
55. The acid formed when propyl magnesium bromide is treated with
carbon dioxide is
(a) C3H7COOH (b) C2H5COOH
(c) Both (a) and (b) (d) None of the above
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Chemistry
59. Acetic acid will be obtained on oxidation of
(a) Ethanol (b) Propanal
(c) Methanal (d) Glyoxal
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Chemistry
66. Which one of the following orders of acid strength is correct
(a) RCOOH HC CH HOH ROH (b) RCOOH ROH HOH HC CH
(c) RCOOH HOH ROH HC CH (d) RCOOH HOH HC CH ROH
69. Which one of the following orders is wrong with respect to the
property indicated
(a) Formic acid > acetic acid > propanoic acid (acid strength)
(b) Fluoroacetic acid > chloroacetic acid > bromoacetic acid (acid
strength)
(c) Benzoic acid > phenol > cyclohexanol (acid strength)
(d) Aniline > cyclohexylamine > benzamide (basic strength)
71. Which one of the following has the maximum acid strength
(a) o-nitrobenzoic acid (b) m-nitrobenzoic acid
(c) p-nitrobenzoic acid (d) p-nitrophenol
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Chemistry
74. Urea upon hydrolysis yields
(a) Acetamide (b) Carbonic acid
(c) Ammonium hydroxide (d) NO2
HCN HOH
75. CH 3 CHO A B. The product B is
(a) Malonic acid (b) Glycolic acid
(c) Lactic acid (d) Malic acid
(a) OH
|
(b) COOH
C COOH CH 2 C CH 3
|
CH 3 OH
OH CN
(c) (d) |
CH 2 C CH 3 C C H3
|
CN OH
H
|
77. C6 H5CHO HCN C6 H5 C CN
|
OH
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Chemistry
Answer Key
1 C 2 B 3 D 4 C 5 D
6 D 7 C 8 C 9 C 10 D
11 C 12 A 13 A 14 C 15 C
16 B 17 D 18 D 19 B 20 D
21 D 22 C 23 B 24 C 25 A
26 D 27 A 28 E 29 B 30 C
31 D 32 B 33 B 34 A 35 D
36 D 37 C 38 C 39 D 40 D
41 C 42 C 43 B,D 44 A 45 A
46 C 47 C 48 C 49 A 50 D
51 C 52 A 53 A 54 C 55 A
56 A 57 B 58 A 59 A 60 A
61 D 62 B 63 C 64 C 65 A
66 C 67 B 68 C 69 D 70 A
71 A 72 D 73 A 74 B 75 C
76 A 77 B 78 D 79 C
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Chemistry
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Chemistry
10 Reaction of ethyl chloride with sodium leads to
(a) Ethane (b) Propane
(c) n-butane (d) n-pentane
11 Phosgene is the common name for
(a) CO2 and PH3 (b) Phosphoryl chloride
(c) Carbonyl chloride (d) Carbon tetrachloride
12 Grignard reagent is prepared by the reaction between
(a) Zinc and alkyl halide
(b) Magnesium and alkyl halide
(c) Magnesium and alkane
(d) Magnesium and aromatic hydrocarbon
13 If we use pyrene (CCl4 ) in the Riemer-Tiemann reaction in place of
chloroform, the product formed is
(a) Salicylaldehyde (b) Phenolphthalein
(c) Salicylic acid (d) Cyclohexanol
14 Benzyl chloride when oxidised by pb(NO3 )2 gives
(a) Benzoic acid (b) Benzaldehyde
(c) Benzene (d) None
15 CCl4 cannot give precipitate with AgNO3 due to
(a) Formation of complex with AgNO3
(b) Evolution of Cl2 gas
(c) Chloride ion is not formed
(d) AgNO3 does not give silver ion
16 Ethyl bromide reacts with silver nitrite to form
(a) Nitroethane (b) Nitroethane and ethyl nitrite
(c) Ethyl nitrite (d) Ethane
17 Which of the following reactions leads to the formation of
chloritone
(a) CHCl3 CH3COCH3 (b) CCl4 Acetone
(c) CHCl3 KOH (d) CHCl3 HNO3
18 A CCl4 KOH Salicylic acid, ‘A’ in above reaction is
OH NO2
(a) (b)
CHO
(c) (d)
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Chemistry
OH
O C2 H 5
C2 H5 I Product
Anhydrous (C H OH )
2 5
19
In the above reaction product is
(a) C6 H5OC2 H5 (b) C2 H5OC2 H5
(c) C6 H5OC6 H5 d) C6 H5 I
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Chemistry
27 Toluene reacts with excess of Cl2 in presence of sunlight to give a
product which on hydrolysis followed by reaction with NaOH gives
COOH COONa
(a) (b)
COONa
(c) N (d) None of these
a
27 The reaction of an aeromatic halogen compound with an alkyl
halides in presence of sodium and ether is called
(a) Wurtz reaction (b) Sandmeyer’s reaction
(c) Wurtz-fittig reaction (d) Kolbe reaction
28 The reaction of an aeromatic halogen compound with an alkyl
halides in presence of sodium and ether is called
(a) Wurtz reaction (b) Sandmeyer’s reaction
(c) Wurtz-fittig reaction (d) Kolbe reaction
29 Chloropicrin is obtained by the reaction of
(a) Chlorine on picric acid
(b) Nitric acid on chloroform
(c) Steam on carbon tetrachloride
(d) Nitric acid on chlorobenzene
30 Reaction of alkyl halides with aromatic compounds in presence of
anhydrous AlCl3 is known as
(a) Friedal-Craft reaction (b) Hofmann degradation
(c) Kolbe’s synthesis (d) Beckmann rearrangement
31 Bottles containing C6 H5 I and C6 H5CH2I lost their original labels. They
were labelled A and B for testing. A and B were separately taken in
test tubes and boiled with NaOH solution. The end solution in each
tube was made acidic with dilute HNO3 and then some AgNO3 solution
was added. Substance B give a yellow precipitate. Which one of the
following statements is true for this experiment
(a) A was C6 H5 I
(b) A was C6 H5CH2I
(c) B was C6 H5 I
(d) Addition of HNO3 was unnecessary
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Chemistry
32 The major product formed in the following reaction is
CH 3
|
CH3 O
CH 3 C CH 2 Br
| CH3 OH
H
CH 3
|
(a) CH 3 C CH 2 OCH 3
|
(b) CH3 C H CH 2 CH3
|
H OCH3
CH 3 CH 3
| |
(c) CH 3 C CH 2 (d) CH 3 C CH 3
|
OCH 3
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Chemistry
40 Use of chlorofluoro carbons is not encouraged because
(a) They are harmful to the eyes of people that use it
(b) They damage the refrigerators and air conditioners
(c) They eat away the ozone in the atmosphere
(d) They destroy the oxygen layer
Answer Key
1 A 2 A 3 B 4 A 5 A
6 C 7 C 8 D 9 B 10 C
11 C 12 B 13 C 14 B 15 C
16 A 17 A 18 A 19 A 20 C
21 D 22 A 23 D 24 C 25 D
26 A 27 B 28 C 29 B 30 A
31 A 32 D 33 C 34 C 35 A
36 C 37 B 38 B 39 B 40 C
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Chemistry
5. When ethanol is mixed with ammonia and passed over alumina the
compound formed is
(a) C2H5 NH2 (b) C2H4
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Chemistry
8. Which of the following reactions will not give primary amine
(a) CH3CONH2
KOH .Br
2
(b) LiAlH
CH3CN 4
(c) CH3 NC
LiAlH
4
(d) LiAlH4
CH3CONH2
9. Na ROH
CH 3CONH2 Z H2O.
What is Z ?
(a) CH3CH2NH2 (b) CH3CH2 NC
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Chemistry
16. Reaction of primary amines with aldehyde yields
(a) Amides (b) Aldimines
(c) Nitriles (d) Nitro compounds
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Chemistry
23. In reaction
HCl
CH3CN 2H Boiling H 2O
X
Ether
Y; the term Y is
(a) Acetone (b) Ethylamine
(c) Acetaldehyde (d) Dimethylamine
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Chemistry
30. Aniline in a set of reactions yielded a product D.
NH2
NaNO2 CuCN H2 HNO2
A B
C D
HCl Ni
Z is identified as :
(a) C6 H5 NH CH3 (b) C6 H5 COOH
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Chemistry
Answer Key
1 A 2 C 3 D 4 C 5 A
6 C 7 D 8 C 9 A 10 D
11 A 12 A 13 B 14 D 15 C
16 B 17 C 18 C 19 A 20 C
21 B 22 B 23 D 24 C 25 A
26 A 27 A 28 B 29 A 30 A
31 D 32 A 33 A 34 B 35 A
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Chemistry
4. A carbohydrate consists of
(a) C and O (b) C, H and O
(c) C, H, N and O (d) C and H
7. Chemically 'digestion' is
(a) Hydrolysis (b) Change in bacteria
(c) Hydrogenation (d) Dehydrogenation
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Chemistry
11. Glucose is a
(a) Monosaccharide (b) Disaccharide
(c) Trisaccharide (d) Polysaccharide
12. When amylases catalyse the hydrolysis of starch, the final product
obtained is chiefly
(a) Cellobiose (b) Glucose
(c) Maltose (d) Sucrose
14. Raffinose is
(a) Trisaccharide (b) Monosaccharide
(c) Disaccharide (d) None of these
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Chemistry
15. Glycolysis is
(a) Conversion of glucose to haem
(b)Oxidation of glucose to glutamate
(c) Conversion of pyruvate to citrate
(d)Oxidation of glucose to pyruvate
16. The charring of sugar, when treated with conc. H2 SO4 , is due to
(a) Oxidation (b) Reduction
(c) Dehydration (d) Hydrolysis
19. Insulin is
(a) An amino acid (b) Protein
(c) A carbohydrate (d) A lipid
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Chemistry
23. The enzyme ptylin used for the digestion of food is present in
(a) Saliva (b) Blood
(c) Intestines (d) Adrenal glands
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Chemistry
31. Which of the following protein destroys the antigen when it enters in
body cell
(a) Antibodies (b) Insulin
(c) Chromoprotein (d) Phosphoprotein
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Chemistry
39. The energy change produced by the combustion of food is called the
'calorific value'. The highest calorific value is given by
(a) Proteins (b) Fats
(c)Carbohydrates (d) Vitamins
43. The segment of DNA which acts as the instructional manual for the
synthesis of the protein is
(a) Nucleoside (b) Nucleotide
(c) Ribose (d) Gene
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Chemistry
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Chemistry
Answer Key
1 D 2 B 3 C 4 B 5 C
6 C 7 A 8 A 9 B 10 C
11 A 12 C 13 C 14 A 15 d
16 c 17 A 18 A 19 B 20 A
21 C 22 A 23 A 24 A 25 B
26 A 27 A 28 B 29 C 30 B
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