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Quantitative and Qualitative
Quantitative and Qualitative
1 During the fusion of organic compound with sodium metal, nitrogen present in the organic compound
is converted into 27-03-2021
(1) (2) (3) (4)
Key:3
Hint:
2 Which of the following compounds will give blood red colour while doing the Lassaigne’stest ?
1) 2) 3) 4)
Key:3
Hint:
Sol:
Contains both N and S
Key:3
Hint:
4 Lassaigne extract is acidified with acetic acid and lead acetate is added to it. Formation of black
precipitate shows the presence of :
1) C (carbon) 2) N (nitrogen) 3) S (sulphur) 4) I (iodine)
Key: 3
Hint:
(NCERT-12.9)
5 An organic compound is heated with Na2O2 . Now fused mixture is boiled with conc. HNO3 and
ammonium molybdate. On cooling we get yellow colour or ppt. It indicates the presence of :
1) N (nitrogen) 2) S (sulphur) 3) P (phosphorus) 4) I (iodine)
Key: 3
Hint: ‘P’ compound
(NCERT-12.9)
(Yellow ppt)
6
71. Which of the following compound(s) will not give test of nitrogen in the Lassaigne’s method?
(01.02.2021)
H 2 N NH 2 H 2 N CH 2 NH 2 CH 3 NH 2
1) 2) 3) 4)
Key: 1
Hint: does not contain carbon to produce NaCN. (NCERT-12.9)
7 On complete combustion 0.246 g of an organic compound gave 0.198 g of CO2 and 0.1014 g of
H 2O . Determine the percentage composition of C and H in the compound.
1) 29.15 C, 5.48 H 2) 21.95 C, 4.58 H 3) 51.29 C, 8.54 H 4) 21.95 C, 4.85 H
Key: 2
Hint:
(NCERT-12.10)
8 In Carius method, 0.15 g of an organic compound gave 0.12 g of AgBr (molar mass = 188g). The
percentage of Br is :
1) 3.44% 2) 34.04% 3) 44.03% 4)40.34%
Key: 2
Hint:
(NCERT-12.10)
9 Which of the following compounds will give blood red colour while doing the Lassaigne’stest ?
1) 2) 3) 4)
Key:3
Hint:
Sol:
Contains both N and S
Page 2 of 15
10 Which statement is false?
(1) Kjeldahl method is used forestimation of nitrogen
(2) Carius tube is used for estimation of sulphur
(3) Carius tube is used for estimation of Nitrogen
(4) Carbon is estimated using Liebig’s method
Key:3
Hint:
Key:1
Hint:
Sol: Two solids having different solubilities in a given solvent can be separated by using
crystallization.
Page 3 of 15
15 Chloroform and aniline can be purified by
(1) Sublimation (2) Crystallization (3) Distillation (4)
Chromatographic
Key:3
Hint:
Sol: Two liquids having difference in boiling point can be separated by distillation.
Key:1
Hint:
Sol: When a substance has different solubilities in different solvents, it can be separated
by differential extraction.
Key:4
Hint:
Sol: Sodium metal is used in Lassaigne test because it is a very reactive metal which reacts
with many elements to form ionic compound which are water soluble.
18 Which of the following compound will give blood red colour while doing the Lassaigne’s
test for Nitrogen and Sulphur?
1) 2) 3) 4)
Key:2
Page 4 of 15
Hint:
Sol: Formation of blood red colour in Lassaigne test is due to formation of Fe(SCN)3which
indicates thepresence of both N and S.
Key:3
Hint:
Sol: Violet red color in Lassaigne's test of sulphar is due to the formation of
sodiamthionitroprusside
20 In Duma’s method for determining the nitrogen content of an organic compound, the
nitrogen content is determined in the form of
(1) Gaseous NH3 (2) NaCN (3) Gaseous N2 (4)
(NH4)2SO4
Key:3
Hint:
Sol: In Duma's method nitrogen is set free as nitrogen gas; compound having nitrogen +
CuO N2. The volume of N2 is measured and from that percentage of N is
estimated.
Key:2
Hint:
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Sol: % of H
= 10%
Key:3
Hint:
Sol: Aqueous solution of NaHCO3 can be used to separate benzoic acid from its mixture
with camphor. Benzoic acid form water soluble sodium salt
Key:4
Hint:
Page 6 of 15
Key:3
Hint:
Sol: A liquid, which decomposes at its normal boiling point can be purified by vacuum
distillation. As its boiling point will be reduced
Key:2
Hint:
Sol: Lassaigne’s test is given by those nitrogenous compounds in which carbon is also
present along with nitrogen.
In NH2. NH2. HCl, carbon is absent, so it does not given Lassaigne’s test.
26 In Lassaigne’s test, a blue colour is obtained if the organic compound contains nitrogen. The
blue colour is due to
1) K4[Fe(CN)6] 2) Fe4 [Fe(CN)6]3 3) Na3[Fe(CN)6] 4)
Cu2[Fe(CN)6]
Key:2
Hint:
Sol: In the Lassaigne’s test, a blue colour is obtained if the organic compound contains
nitrogen. The blue colour is due to ferri-ferro cyanide 𝑖. 𝑒., Fe4[Fe(CN)6]3.
27 During the fusion of an organic compound with sodium metal, nitrogen of the compound is
converted into
1) NaNO2 2) NaNH2 3) NaCN 4) NaNC
Key:3
Page 7 of 15
Hint:
Sol: When organic compound is fused with sodium metal, nitrogen of the compound is
converted into sodium cyanide as Na + C + N → NaCN
Key:2
Hint:
Key:4
Hint:
Key:2
Hint:
Page 8 of 15
Sol: Nitrogen in the organic compound is converted to N2 gas in Dumas method
Key:2
Hint:
32 0.765g of an acid gives 0.535g of CO2 and 0.138 g of H2O. Then, the ratio of the percentage of
carbon and hydrogen is
1) 19:2 2) 18:11 3) 20:17 4) 1:7
Key:1
Hint:
Sol:
Key:2
Hint:
Page 9 of 15
Sol:
34 Anthracene is purified by
1) Filtration 2) Distillation 3) Crystallization 4)
Sublimation
Key:4
Hint:
35
84. Na2S + Na2[Fe(CN)5NO] → Purple colour. It is due to
1) Na4[Fe(CN)3NOS] 2) Na3[Fe(CN)5NOS]
3) Na4[Fe(CN)5NO] 4) Na4[Fe(CN)5NOS]
Key:4
Hint:
Page 10 of 15
Key:2
Hint:
37
In Kjeldahl’s method of estimation of nitrogen, CuSO4 acts as
1) Oxidising agent 2) Reducing agent 3) Catalytic agent 4) Hydrolysis
agent
Key:3
Hint:
Sol: Kejldahl’s method is used for the estimation of nitrogen. The organic compound is
heated with conc. H2SO4 in presence of K2SO4 (used to elevate boiling point of H2SO4)
and CuSO4 (used as catalyst) to convert all the nitrogen into (𝑁𝐻4)2𝑆𝑂4.
38 In paper chromatography
1) The moving phaseis liquid and stationary phase is a solid
2)The movingphase is a solid and stationary phase is a liquid
3)Both the phases are liquids
4)Both the phases are solids
Key:3
Hint:
Sol: Water trapped in the filter paper is the stationary phase and the solvent is the mobile
phase
Key:3
Hint:
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Weight of 𝑁𝐻3=0.5 ×17mg=8.5mg
40 In Kjeldahl’s method, ammonia from 5g of food neutralizes 30 𝑐𝑚3 of 0.1 N acid. The
percentage of nitrogen in the food is
1) 0.84 2) 8.4 3) 16.8 4) 1.68
Key:1
Hint:
An organic compound on heating with CuO produces CO2 but no water. The organic
41 compound may be
1) Carbon tetrachloride 2) Chloroform
3) Methane 4) Ethyl iodide
Key:1
Hint:
Sol: Since, the compound on heating with CuO produced𝐶𝑂2, it contains carbon. Again, it
does not produce water, hence it does not contain hydrogen. So, the organic
compound is carbontetrachloride (𝐶𝐶𝑙4).
43
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Ans-4
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