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Cat 8
Cat 8
A) B) +
C) D)
N CH2 N +
O H H O CH2
2. The shape of XeO 2F2 molecule is
A) trigonalbipyramidal B) square planar
C) tetrahedral D) see- saw
3. Assuming that Hund’s rule is violated, the bond order and magnetic nature of the diatomic
molecule B2 is
A) 1 and diamagnetic B) 0 and diamagnetic
C) 1 and paramagnetic D) 0 and paramagnetic
4. The Henry’s law constant for the solubility of N2 gas in water at 298 K is 1.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water at 298 K
and 5 atm pressure is
A) 4.0 × 10-4 B) 4.0 × 10-5 C) 5.0 × 10-4 D) 4.0 × 10-6
2 2
5. 2.5 mL of M weak monoacidic base (Kb = 1×10-12 at 250C) is titrated with M HCl in water at
5 15
250C. The concentration of H+ at equivalence point is (Kw = 1×10-14 at 250C)
A) 3.7×10-13 M B) 3.2×10-7M C) 3.2×10-2M D) 2.7×10-2M
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
6. In which compound(s) have their SP 2 carbon atoms and theindicated SP3 carbon atoms(pointed by
arrows) are in the same plane?
CH3
CH3 CH3 CH3
H3C
A) B) C) D)
Cl H
A) PF2Cl3 C) C C C D)
B) Cl
H
8. The correct statement(s) concerning the structures E, F and G is (are)
H3C O H3C OH H3C CH3
A) E,F and G are resonance structures B) E,F and E,G are tautomers
C) F and G are geometrical isomers D) F and G are diastereomers
9. Which compound(s) gives effervesces with 10% aq. NaHCO3 solution?
OH
OH
OH COOH O 2N NO 2
A) B) C) D)
NO 2
10. With respect to graphite and diamond, which of the statement(s) given below is (are) correct ?
A) Graphite is harder than diamond.
B) Graphite has higher electrical conductivity than diamond.
C) Graphite has higher thermal conductivity than diamond.
D) Graphite has higher C-C bond order than diamond.
11. Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical concentrations are
provided. The pair(s) of solutions which form a buffer upon mixing is (are)
A) HNO3 and CH3COOH B) KOH and CH3COONa
C) HNO3 and CH3COONa D) CH3COOH and CH3COONa
12. Among the following, the state function(s) is (are)
A) Internal energy B) Irreversible expansion work
C) Reversible expansion work D) Molar enthalpy
13 . The compound(s) formed upon combustion of lithium metal in excess air is (are)
A) Li2O2 B) Li2O C) Li3N D) LiO2
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
18. The concentration of R in the reaction R P was measured as a function of time and the following
data is obtained:
[R] (molar)
1.0 0.75 0.40 0.10
6 BD 7 AB 8 BCD 9 CD 10 BD
11 CD 12 AD 13 ABC 14 3 15 4
16 5 17 5 18 0