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Cho 203 Cre - Ii 2023
Cho 203 Cre - Ii 2023
B.Tech./DD IV Semester
CHO: 203 Chemical Reaction Engineering-II
Time: 2 Hours Max. Marks: 30
QAa) Name the suitable catalyst for the following industrial processes: (4x2-8)
0eam reforming of methape Ammonia synthesis
WoHydrogenation of vegetable oifs vyAutomobile exhaust control,
(byGiyethe various expression for rate of a chemical reaction? How they are related to each
other?
(9Whát is the mechanism of solid catalyzed reaction?
(d) State the assumptions of Langmuir Model?
Q2 h¡t are the different steps involved in catalyst preparation? What is the precipitation
mèhodof preparation of catalyst? (4)
Q3 The adsorption of CO on activated carbon was followed experimentally at 0 °C. At given
proZSures, the following quantities of adsorbed gases were measured (corrected to standard
pressure of l bar)
(5x2=10)
Q.1 What are the different regimes of fluidization technique?
,(bYWhat is /he significance of Hatta number fluid-fluid reactions?
gas-liquid non-catalytic reaction.
Nc)8ketch the concentration profile for an instantaneous the particles do not change their size on
(d)oiyé twoexamples of fluid-solid reaction in which
Raction. Does at) ever equal to zero for the
(eDraw the sketch of catalyst activity as a function of time.
arst order decay law?
(.cm' cat).
(radius= 2 cm) catalyst pellet is 10 mol/0.lcms
Q2(a) The observed rate using a cylinderrate constant. The effective diffusivity is and
Calculate the value of first order reaction pellet is 2 x 10 molcm'. (5)
concentration of reactant at the exterior surface of
following
experimental mixed flow reactor. From the
baseous A reacts (A-’R) in an equation to represent the reaction. (5)
onversion data at various conditions, find a rate
2 1.2 CAO = 10 molm'
vo (m'hr) 3
W =4gm
0.2 0.3 0.5
XA
and S),
(B). A and B react to form products (Rorder.
(A) flows over a spherical solid particle
QB Fluid reactionis elementary (A+B >R+S) and of first
S
where R is a fluid and S is a solid. The physical
also called ash, which is porous and leaves behind an unreacted core of B. The
is particle size and physical structure remain the
properties of8are similar to B, and the overall
with time is
of change of size of the unreacted core
same.
(a Discuss and determine how the rate (5)
obtained if it is controlled by diffusion through S.
three cases using the given
(b/Determine the rate-controlling mechanisms for the following (5)
conversion data (by chemical analysis):
dp, mm XB 1. sec
Case 1 1 0.75
0.3
Case 2 240
1.5 360
Case 3
0.875
1
Q.4 Atrickle bed reactor packed with alunmin-uDDorled palladium catalyst is used to ox11
Se aqeous propanol to propanoic acid using nure oxygen at 12 atm and 25 °C. The reaction
procceds as follows:
(b) Find the fraction of propanol oxidized to propanoic acid under the following
conditions: (6)
Q.s{a)7L model is used for what kind of reactor? State the assumptions of this model. Discuss
the model in detail. (5)
(bWhat is Catalyst deactivation? Discuss about different types of catalyst deactivation and their
mechanism. Suggest some protective or recovery measures to get rid of these problems. (5)
Quiz 1
(Even Semester: 2022-2023)
CHO: 203 Chemical Reaction Engineering-II
Time: 45 min Max. Marks: 10
Q.1(ayGive four reasons why heterogeneous catalysts are preferred in industrial processes. (4)
Q2For acylindrical pore of length Lwith reactant A'diffusing into the pore and reacting on the
surface, derive an equation of Thiele modulus for zero örder reaction. (6)
(ven Sebeater:2022-2023)
Time: 45 min ClO: 203 Chemieal Reaction Cngineering-I|Max. Marks: 10
Q1(a) ow do you classity the kinetic regimes in non-cntalytie g1v-liquid rentions? packed
(b) Gaseous Aabsorbs and rencts with Bin reaction in: a
liquid according to lollowing
bed: