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Atomic Structure Sheet
Atomic Structure Sheet
(c) 2 × 10–7 m–1 (d) 4 × 104 cm–1 (a) de Broglie (b) Einstein
17. Rank the following types of radiations from the highest
(c) Planck (d) Bohr
energy to the lowest.
ultraviolet/visible/X-ray/microwave/infrared 25. Which is not characteristics of Planck’s quantum theory
(a) X-ray, ultraviolet, microwave, infrared, visible of radiation ?
(b) ultraviolet, X-ray, visible, infrared, microwave (a) Radiation is associated with energy.
(c) infrared, microwave, ultraviolet, visible, X-ray
(b) Energy is not absorbed or emitted in whole number or
(d) X-ray, ultraviolet, visible, infrared, microwave
multiples of quantum.
18. The frequency of a green light is 6 × 1014 Hz. Its wavelength
is : (c) The magnitude of energy associated with a quantum
(a) 500 nm (b) 5 nm is proportional to the frequency.
(c) 50,000 nm (d) None of these (d) Radiation energy is neither emitted nor absorbed
Planck’s Quantum Theory continuously but in small packets called quanta.
19. Which wave property is directly proportional to energy of
26. Which of the following is not a characteristic of Planck’s
electromagnetic radiation :
quantum theory of radiation ?
(a) velocity (b) frequency
(c) wave number (d) all of these (a) Energy is not absorbed or emitted in whole number
multiples of quantum.
20. The number of photons of light of Q = 2.5 × 106 m–1
necessary to provide 1 J of energy are (b) Radiation is associated with energy.
(a) 2 × 1018 (b) 2 × 1017 (c) Radiation is associated with energy emitted or
(c) 2 × 1020 (d) 2 × 1019 absorbed continuously but in the form of small packets
called quanta.
21. The number of photons emitted in 10 hours by a 60 W
sodium lamp (O of photon = 6000 Å) (d) The magnitude of energy associated with quantum is
proportional to frequency.
(a) 6.50 × 1024 (b) 6.40 × 1023
(c) both wave-like and particle-like behaviour of light 38. The ionization energy of H atom is 13.6 eV. The ionization
energy of Li2+ ion will be
(d) neither wave-like nor particle-like behaviour of light
(a) 54.4 eV (b) 40.8 eV
32. Ultraviolet light of 6.2 eV falls on aluminium surface (work
function = 4.2 eV). The kinetic energy (in joule) of the (c) 27.2 eV (d) 122.4 eV
fastest electron emitted is approximately : 39. The ratio of the difference in energy between the first and
–21 –19 the second Bohr orbit to that between second and third
(a) 3 × 10 (b) 3 × 10
Bohr orbit is
(c) 3 × 10–17 (d) 3 × 10–15
1 1
33. The threshold wavelength for photoelectric effect on (a) (b)
2 3
sodium is 5000 Å. Its work function is :
(a) 4 × 10–19 J (b) 1J 27 4
(c) (d)
5 9
(c) 2 × 10–19J (d) 3 × 10–10 J
40. Energy of electron of hydrogen atom in second Bohr 48. The Bohr orbit radius for the hydrogen atom (n = 1) is
orbit is approximately 0.530 Å. The radius for the first excited state
(a) –5.44 × 10–19 J (b) –5.44 × 10–19 kJ (n = 2) orbit is
(a) 0.13 Å (b) 1.06 Å
(c) –5.44 × 10–19 cal (d) –5.44 × 10–19 eV
(c) 4.77 Å (d) 2.12 Å
41. The energy of second Bohr orbit in the hydrogen atom is
–3.4 eV. The energy of fourth orbit of He+ ion would be 49. According to Bohr model, angular momentum of an electron
in the 3rd orbit is :
(a) –3.4 eV (b) –0.85 eV
(c) –13.64 eV (d) +3.4 eV 3h 1.5h
(a) (b)
S S
42. The energy of an electron in the first Bohr orbit of H atom
is –13.6 eV. The possible energy value(s) of the excited 3S 9h
(c) (d)
state(s) for electrons in Bohr orbits to hydrogen is (are) h S
(a) –3.4 eV (b) –4.2 eV 50. Electronic energy is a negative energy because
(c) –6.8 eV (d) +6.8 eV (a) Electron carries negative charge.
43. The ionization energy of hydrogen atom is 13.6 eV. The (b) Energy is zero near the nucleus and decreases as the
energy required to excite the electron in a hydrogen atom distance from the nucleus increases.
from the ground state to the first excited state is
(c) Energy is zero at an infinite distance from the nucleus
(a) 1.69 × 10 –18
J (b) 1.69 × 10 –23
J and decreases as the electron comes closer to the
nucleus.
(c) 1.69 × 1023 J (d) 1.69 × 1025 J
(d) There are interelectronic repulsions.
44. In a Bohr’s model of atom when an electron jumps from
51. Ratio of frequency of revolution of electron in the second
n = 1 to n = 3, how much energy will be emitted or absorbed
excited state of He+ and second state of hydrogen is
(1erg = 10+ J)
47. The radius of first Bohr’s orbit for hydrogen is 0.53 Å. (c) 15 (d) 4
The radius of third Bohr’s orbit would be 54. What transition in He+ ion shall have the same wave number
(a) 0.79 Å (b) 1.59 Å as the first line in Balmar series of H atom ?
(c) 3.18 Å (d) 4.77 Å (a) 7 o 5 (b) 5 o 3
(c) 6 o 4 (d) 4 o 2
55. An electron jumps from 6th energy level to 3rd energy de-Broglie Concept
level in H-atom, how many lines belong to visible region ?
64. The de–Broglie wavelength associated with a material
(a) 1 (b) 2 particle is
(c) 3 (d) Zero (a) Directly proportional to its energy
56. The wavenumber for the shortest wavelength transition (b) Directly proportional to momentum
in the Balmer series of atomic hydrogen is (c) Inversely proportional to its energy
(d) Inversely proportional to momentum
(a) 27420 cm–1 (b) 28420 cm–1
65. The de Broglie wavelength of a tennis ball of mass 66 g
(c) 29420 cm–1 (d) 12186 cm–1 moving with the velocity of 10 metres per second is
57. The difference in wavelength of second and third lines of approximately
Balmer series in the atomic spectrum is (a) 10–35 metres (b) 10–33 metres
(a) 131 Å (b) 524 Å
(c) 10–31 metres (d) 10–36 metres
(c) 324 Å (d) 262 Å
66. The wavelength of a cricket ball weighing 100 g and
58. The third line in Balmer series corresponds to an electronic
travelling with a velocity of 50 m/s is
transition between which Bohr’s orbits in hydrogen atom
(a) 5 o 3 (b) 5 o 2 (a) 1.3 × 10–28 m (b) 1.3 × 10–37 m
(a) 15200 cm–1 (b) 60800 cm–1 70. If uncertainty in the position of an electron is zero, the
uncertainty in its momentum would be
(c) 76000 cm–1 (d) 136800 cm–1
63. A certain transition in H spectrum from an excited state to h
(a) zero (b) t
the ground state in one or more steps gives rise to a total of 4S
10 lines. How many of these belong to the UV spectrum ?
h
(a) 3 (b) 4 (c) (d) infinite
4S
(c) 6 (d) 5
71. For an electron, if the uncertainty in velocity is 'v, the Quantum Numbers
uncertainty in its position ('x) is given by : 77. For each value of A, the number fo ms values are
(a) 2A (b) nA
h S
(a) Sm'Q (b) (c) 2A + 1 (d) n – A
2 hm'Q
78. A subshell with n = 6, A = 2 can accommodate a maximum
h 2Sm of
(c) (d)
4Sm'Q h'Q
(a) 10 electrons (b) 12 electrons
72. A ball of mass 200g is moving with a velocity of 10m sec–1. (c) 36 electrons (d) 72 electrons
If the error in measurement of velocity is 0.1%, the 79. Which of the following sets of quantum number is correct
uncertainty in its position is :
for an electron in 4f orbital ?
(a) 3.3 × 10–31 m (b) 3.3 × 10–27 m
(a) n = 3, A = 2, m = –2, s = +1/2
–25 –32
(c) 5.3 × 10 m (d) 2.64 × 10 m (b) n = 4, A = 4, m = –4, s = –1/2
73. The Heisenbergs Uncertainty Principle states that ........... . (c) n = 4, A = 3, m = +1, s = +1/2
(a) no two electrons in the same atom can have the same (d) n = 4, A = 3, m = +4, s = +1/2
set of four quantum numbers
80. For a d-electron, the orbital angular momentum is
(b) two atoms of the same element must have the same
number of protons (a) 6 h / 2S (b) 2 h / 2S
(c) it is impossible to determine accurately both the
(c) h/2S (d) zero
position and momentum of an electron simultaneously
81. The correct designation of an electron with n = 4, l = 3,
(d) electrons of atoms in their ground states enter
m = 2, and s = 1/2 is :
energetically equivalent sets of orbitals singly before
they pair up in any orbital of the set (a) 3d (b) 4f
74. If the uncertainty in the position of an electron is zero, the (c) 5p (d) 6s
uncertainty in its momentum be 82. A 3d-electron having s = +1/2 can have a magnetic quantum
no :
h
(a) Zero (b) (a) +2 (b) +3
2S
(c) –3 (d) +4
h
(c) (d) Infinity Electronic Configuration
4S
83. The electrons identified by n and l
75. If uncertainty in the measurement of position and
momentum of an electron are equal then uncertainly in the (i) n = 4, l = 1 (ii) n = 4, l = 0
measurement of its velocity is approximately : (iii) n = 3, l = 2 (iv) n = 3, l = 1
(a) 8 × 1012 m s–1 (b) 6 × 1012 m s–1 can be placed in order of increasing energy, from lowest to
highest
(c) 4 × 1012 m s–1 (d) 2 × 1012 m s–1
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii)
Quantum Mechanical Model of an Atom
(c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii)
76. In the Schrodinger’s wave equation \ represents
84. According to (n + l) rule after completing ‘np’ level the
(a) Orbit (b) Wave function electron enters to :
(c) Wave (d) Radial probability (a) (n – 1) d (b) (n + 1) s
(c) nd (d) (n + 1) p
85. The correct ground state electronic configuration of (Atomic number : Cr = 24, Fe = 26, Co = 27 and Ni = 28)
chromium atom (Z = 24) is The correct sequence of increasing number of unpaired
(a) [Ar] 3d 4s 5 1
(b) [Ar] 3d 4s 4 2 electrons in these ions is
(a) 1, 2, 3, 4 (b) 4, 2, 3, 1
(c) [Ar] 3d6 4s0 (d) [Ar] 4s1 4p5
(c) 1, 3, 2, 4 (d) 3, 4, 2, 1
86. In manganese atom, Mn (Z = 25), the total number of
orbitals populated by one or more electrons (in ground 93. The quantum numbers for the outermost electron of an
state) is element are given below
(a) 15 (b) 14 1
n 2, A 0, m 0, ms
(c) 12 (d) 10 2
87. The correct set of quantum numbers for the unpaired The atom is
electron of chlorine atom is (a) hydrogen (b) lithium
n A m (c) beryllium (d) boron
(a) 2 1 0 94. For which one of the following sets of four quantum
(b) 2 1 1 numbers an electron will have the highest energy
(c) 3 1 1 n A m s
88. The maximum number of 4d-electrons having spin quantum (b) 4 1 0 –1/2
(c) 4 2 –1 1/2
1
number s are (d) 5 0 0 –1/2
2
95. Which electronic configuration does not follow the Pauli’s
(a) 10 (b) 7
exclusion principle ?
(c) 1 (d) 5
(a) 1s2, 2s2 2p4 (b) 1s2, 2s2 2p4, 3s2
89. Which of the following has maximum number of unpaired
electrons ? (c) 1s2, 2p4 (d) 1s2, 2s2 2p6, 3s3
91. Presence of three unpaired electrons in phosphorus atom 2p1y 2p1z and not 1s 2 ,2s 2 2p x2 2p1y 2p 0z . It was proposed by :
can be explained by
(a) Aufbau principle
(a) Pauli’s rule
(b) Pauli’s exclusion principle
(b) Uncertainty principle
(c) Hund’s rule
(c) Aufbau’s rule
(d) Uncertainty principle
(d) Hund’s rule
98. Which of the following has maximum number of unpaired
92. Consider the following ions
electron (atomic number of Fe 26)
1. Ni2+ 2. Co2+ (a) Fe (b) Fe (II)
2+ 3+
3. Cr 4. Fe (c) Fe (III) (d) Fe (IV)
99. A compound of vanadium has magnetic moment of 1.73 104. Which d-orbital does not have four lobes ?
B.M. The electronic configuration of the vanadium ion in
(a) d x2 y2 (b) d xy
the compound is
(c) [Ar] 4s23d0 (d) [Ar] 4s03d3 105. 3py orbital has .......... nodal plane
100. The total spin and magnetic moment for the atom with (a) XY (b) YZ
atomic number 7 are
(c) ZX (d) Any
(a) r 3, 3 BM (b) r 1, 8 BM 106. The number of angular nodes in a 3s atomic orbital is
(a) 0 (b) 1
3
(c) r , 15 BM (d) 0, 8 BM (c) 2 (d) 3
2
107. The number of radial nodes in a 3s atomic orbital is
Nodes
(a) 0 (b) 1
101. How many spherical nodes are present in 4s orbital in a
hydrogen atom ? (c) 2 (d) 3
1. (c) 2. (b) 3. (a) 4. (b) 5. (d) 6. (a) 7. (b) 8. (a) 9. (a) 10. (c)
11. (a) 12. (b) 13. (c) 14. (a) 15. (d) 16. (d) 17. (d) 18. (a) 19. (d) 20. (a)
21. (a) 22. (a) 23. (a) 24. (c) 25. (b) 26. (a) 27. (d) 28. (a) 29. (c) 30. (c)
31. (a) 32. (b) 33. (a) 34. (a) 35. (d) 36. (c) 37. (c) 38. (d) 39. (c) 40. (a)
41. (a) 42. (a) 43. (a) 44. (b) 45. (b) 46. (d) 47. (d) 48. (d) 49. (b) 50. (c)
51. (a) 52. (c) 53. (b) 54. (c) 55. (d) 56. (a) 57. (b) 58. (b) 59. (a) 60. (d)
61. (b) 62. (d) 63. (b) 64. (d) 65. (b) 66. (c) 67. (c) 68. (c) 69. (b) 70. (d)
71. (c) 72. (d) 73. (c) 74. (d) 75. (a) 76. (b) 77. (c) 78. (a) 79. (c) 80. (a)
81. (b) 82. (a) 83. (a) 84. (b) 85. (a) 86. (a) 87. (c) 88. (d) 89. (d) 90. (b)
91. (d) 92. (a) 93. (b) 94. (c) 95. (d) 96. (d) 97. (c) 98. (c) 99. (a) 100. (c)
101. (c) 102. (c) 103. (d) 104. (c) 105. (c) 106. (a) 107. (c) 108. (d)