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  • Subject: Chemistry DATE: 19-03-2024: Stereoisomerism

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    1) The document discusses different types of stereoisomerism including optical isomerism, geometrical isomerism, and chiral centers. 2) It provides examples of compounds that can exhibit optical isomerism, geometrical isomerism, or both. It also gives examples of compounds with multiple stereoisomers. 3) Key concepts covered include the definition of stereoisomers, determining the number of isomers possible based on molecular structure, and identifying optically active versus inactive molecules.

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    1) The document discusses different types of stereoisomerism including optical isomerism, geometrical isomerism, and chiral centers. 2) It provides examples of compounds that can exhibit optical isomerism, geometrical isomerism, or both. It also gives examples of compounds with multiple stereoisomers. 3) Key concepts covered include the definition of stereoisomers, determining the number of isomers possible based on molecular structure, and identifying optically active versus inactive molecules.

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    7 views3 pages

    Subject: Chemistry DATE: 19-03-2024: Stereoisomerism

    Uploaded by

    10 Million Subscribers
    1) The document discusses different types of stereoisomerism including optical isomerism, geometrical isomerism, and chiral centers. 2) It provides examples of compounds that can exhibit optical isomerism, geometrical isomerism, or both. It also gives examples of compounds with multiple stereoisomers. 3) Key concepts covered include the definition of stereoisomers, determining the number of isomers possible based on molecular structure, and identifying optically active versus inactive molecules.

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    of 3

    STEREOISOMERISM

    SUBJECT: CHEMISTRY DATE: 19-03-2024

    1. The value of equilibrium constant (K) for the following equilibria

    H
    H3C e a
    C
    H CH 3
    H3C e H H
    CH 3 a
    CH3 H 3C C CH 3
    C C
    H 3C H3C H C CH 3
    CH3 3

    Chair Twist boat

    (A) K = 1 (B) K > 1 (C) K < 1 (D) Cannot related


    2. Compound which can show both optical & geometrical isomerism:

    H H
    (A) N–D (B) N–Me
    Me D

    Me

    Me
    (C) H 2 C  N – CH – CH  NH (D)
    |
    D Me
    3. Select the correct statement for following compound:

    O O

    (A) It can show G.I. & O.I. (B) It has 5 optically inactive stereoisomers.
    (C) It has 2 enantiomeric compound (D) It has 2 diastereomers.
    Narayana Jaipur HO: B-28, Gopalpura Bypass Road, 10-B Scheme, Near Ridhi Sidhi Circle, Jaipur, Rajasthan 302018
    (1)
    4. Identify optically active molecules

    Br Cl

    NH
    (A) (B) NH

    Cl Br
    Cl
    Cl
    (C) (D)
    Cl
    Br

    5. Match the List.


    List-I List-II

    H
    (P) H C (1) It can show geometrical isomerism
    Cl

    H H
    (Q) C (2) Optically active compound
    Cl Cl

    O O
    (R) (3) Presence of odd number of chiral carbon atom
    N N
    H H

    Br
    Br H
    (S) C=C–C–C=C (4) Resolvable compound
    H Br
    H H H
    (A) P  1, 2;Q  2, 4;R  1, 2, 4;S  1, 2,3,4
    (B) P  1, 2,3,4;Q  2, 4;R  1, 2, 4;S  1, 2,3,4
    (C) P  1,3, 4;Q  2, 4; R  1, 2, 4;S  1,2,3
    (D) P  3, 4;Q  3, 4;R  1,2,3;S  1, 2,3,4

    Narayana Jaipur HO: B-28, Gopalpura Bypass Road, 10-B Scheme, Near Ridhi Sidhi Circle, Jaipur, Rajasthan 302018
    (2)
    6. How many steroisomers are possible for the following compound ?
    CH3
    Cl Br
    Cl Br
    H3C CH3
    Br Cl
    Cl Br
    CH3
    7. How many acyclic isomers of C5H10 are possible which are incapable of showing Optical Isomerism ?

    8. (a) How many geometrical isomers are possible for the following structure ?

    H
    (b) How many plane of symmetry are present in prismane (C6H6) ?

    (c) How many chiral centres are present in the following compound ?

    S Ph
    O
    Br
    (d) Minimum carbon atoms required for an alkane to show optical isomerism.
    Write answer of part (a), (b), (c) & (d) in the same order and present the four number as answer.
    For example: All these answer are 9 then the reported answer is 9999.

    Narayana Jaipur HO: B-28, Gopalpura Bypass Road, 10-B Scheme, Near Ridhi Sidhi Circle, Jaipur, Rajasthan 302018
    (3)

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