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Oc PT 2 - Student Copy - (Eng)
Oc PT 2 - Student Copy - (Eng)
ALL BATCH
ORGANIC CHEMISTRY TIME : 45 MIN
SECTION–I : (Maximum Marks : 80)
This section contains TWENTY questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
(Binphenyl)
(A) (B) – : +
(C) + :– (D)
(A) Cl (B) Cl Cl
Cl
OH
Cl
(C) H2C=C=C (D)
Br OH
3. Compound which shows highest rate of electrophilic substitution :
CH3
H3C CH3
CH 3 CH3 CH3 C
O NO2 CH3
I II III IV
(A) IV > I > II > III (B) IV > II > I > III (C) II > IV > I > III (D) III > II > I > IV
O
H3CO
'n' RMgX
6. O
Cl
O
Value of 'n' is -
(A) 3 (B) 4 (C) 5 (D) 6
Mg 1. CO2
7. Br A + B
THF 1. H
LiAlH4
C
Correct statement about C.
(A) It gives turbidity in 5 min with lucas reagent (B) It is Ph—CHO
(C) It is Ph—CH2—OH (D) It gives racimisation with PCl3
(1) NaOH
8. Succinic acid (2) Electrolysis ?
The major organic product formed in above reaction is :
11. In which of the following reaction, one of the product obtained will give isocynide test ?
O
O
Br2 NH2 LAH
(A) CH3–C–NH2 ¾¾¾
KOH
® (B) ¾¾¾®
O
– + (i) CH - Br
N K ¾¾¾¾¾ ®
3
(C) (ii) H O+ (D) All of these
3
O
12. Which of the following is not correct ?
– –
(A) I > Br (Leaving group ability)
–
(B) HCºC– > OH (Nucleophilic strength)
(C) CH2 = CH2 > HC º CH (Electrophilic addition)
O Me O
(i) Mg
C Me— C— C—Me
(B) H C (ii) H2O
3 CH3 +
(iii) H / Me
R
(i)LiAlH 4
(C) R C Cl ¾¾¾¾
(ii)H 2O
® R C OH
O R
–
(D) Me3C–Cl + CH3O ¾® Me3C–OCH3
15. Major product of reaction is :
OH
(1) NaOH
+ CHCl3
(2) H +
OH OH OH OH
OHC CHO CHO
(A) (B) (C) (D)
CHO
CHO
1-Bromo-3-propylbenzene
O O
Br2 Cl Zn(Hg) Cl Br2 Zn(Hg)
(A) (B)
FeBr3 AlCl3 HCl AlCl3 FeBr3 HCl
O
Br2 Br2 Cl
Cl Zn(Hg)
(C) (D) FeBr3 AlCl 3
AlCl3 HCl FeBr3
18. Give the final major product from the following reaction sequence :
O
Ethylene glycol Collin's EtMgBr H+
OH + reagent H2O
H
HO O O O
O HO
19. Identify major product for the following reaction :
Cl
Cl
NaOMe / MeOH
O2N NO2
OMe Cl Cl OMe
MeO MeO MeO Cl
(A) (B) (C) (D)
O2N NO2 O2N NH2 O2N NO2 O2 N NO2
20. Among the following compounds, which will react with acetone to give a product containing
C=N – NH–
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
1. Number of moles of CO2 released when following molecule oxidised by O3/H2O followed by heating
OH O
(1) Cu, 300ºC (2) KMnO4 /HÅ (3) PCC /CH2Cl2 (4) K2Cr2O7 /HÅ
COOH
5. Total number 1,2-shift taking place during rearrangment of the given compound.