A Great Disorder National Myth and The Battle For America Richard Slotkin Full Chapter
A Great Disorder National Myth and The Battle For America Richard Slotkin Full Chapter
Richard Slotkin
Introduction
PART I Myths of the White Republic
1 The Myth of the Frontier
2 The Myth of the Founding
PART III The Nation Transformed: From the Civil War to the Good
War
6 Industrialization, Vigilantism, and the Imperial Frontier
7 The Great Exception: The New Deal and National Myth
8 The Myth of the Good War: Platoon Movies and the Reconception
of American Nationality
PART IV American Apotheosis: From Kennedy’s New Frontier to
Reagan’s Morning in America
9 The New Frontier: Savage War and Social Justice
10 Cultural Revolution: The Sixties, the Movement, and the Great
Society
11 Back in the Saddle: Reagan, Neoliberalism, and the War against
the Sixties
12 Rising Tide: Climate Change and the Fossil Fuel Frontier
13 Cowboys and Aliens: The Global War on Terror
“Lewisite”
The one arsenical which created the most discussion during the
War, and about which many wild stories were circulated, was
“Lewisite,” or as the press called it, “Methyl.” Its discovery and
perfection illustrate the possibilities of research as applied to
Chemical Warfare, and points to the need of a permanent
organization to carry on such work when the pressure of the situation
does not demand such immediate results.
The reaction of ethylene and sulfur chloride, which led to the
preparation of mustard gas, naturally led the organic chemists to
investigate the reaction of this gas and other unsaturated
hydrocarbons, such as acetylene, upon other inorganic chlorides,
such as arsenic, antimony and tin. There was little absorption of the
gas, either at atmospheric or higher pressures, and upon distilling
the reaction product, most of the gas was evolved, showing that no
chemical reaction had taken place. However, when a catalyser, in
the form of aluminium chloride, was added, Capt. Lewis found that
there was a vigorous reaction and that a highly vesicant product was
formed. The possibilities of this compound were immediately
recognized and the greatest secrecy was maintained regarding all
the details of preparation and of the properties of this new product.
At the close of the War, this was considered one of the most valuable
of Chemical Warfare secrets, and therefore publication of the
reactions involved were withheld. Unfortunately or otherwise, the
British later decided to release the material for publication, and
details may be found in an article by Green and Price in the Journal
of the Chemical Society for April, 1921. It must be emphasized that
the credit for this work belongs, not to these authors, but to Capt. W.
Lee Lewis and the men who worked with him at the Catholic
University branch of the American University Division (the Research
Division of the C. W. S.).
On a laboratory scale, acetylene is bubbled through a mixture of
440 grams of anhydrous arsenic trichloride and 300 grams of
anhydrous aluminium chloride. Absorption is rapid and much heat is
developed. After six hours, about 100 grams of acetylene is
absorbed. The reaction product was dark colored and viscid, and
had developed a very powerful odor, suggestive of pelargoniums.
Attempts to distill this product always led to violent explosions. (It
may be stated here that Lewis was able to perfect a method of
distillation and separation of the products formed, so that pure
materials could be obtained, with little or no danger of explosion.)
The English chemists therefore decomposed the product with ice-
cold hydrochloric acid solution of constant boiling point (this
suggestion was the result of work done by Lewis). The resulting oil
was then distilled in a current of vapor obtained from constant boiling
hydrochloric acid and finally fractionated into three parts.
The first product obtained consist in the addition of one acetylene
to the arsenic trichloride molecule, and, chemically, is
chlorovinyldichloroarsine, CHCl: CH·AsCl₂, a colorless or
faintly yellow liquid, boiling at 93° at a pressure of 26 mm. A small
quantity, even in very dilute solution, applied to the skin causes
painful blistering, its virulence in this respect approaching that of
mustard gas. It is more valuable than mustard gas, however, in that it
is absorbed through the skin, and as stated on page 23, three drops,
placed on the abdomen of a rat, will cause death in from one to three
hours. It is also a very powerful respiratory irritant, the mucous
membrane of the nose being attacked and violent sneezing induced.
More prolonged exposure leads to severe pain in the throat and
chest.
The second fraction (β, β′-dichlorodivinylchloroarsine) is a
product resulting from the addition of two acetylene molecules to one
arsenic trichloride, and boils at 130° to 133° at 26 mm. It is much
less powerful as a vesicant than chlorovinyldichloroarsine, but its
irritant properties on the respiratory system are much more intense.
English Masks
The Black Veiling Respirator. The first form of the English mask
is known as the Black Veiling respirator and consisted of cotton
waste enclosed in a length of black veiling. The waste was soaked in
a solution of:
Sodium thiosulphate 10 lbs.
Washing soda 2.5 lbs.
Glycerine 2 lbs.
Water 2 gals.
The glycerine was put in to keep the respirator moist, thus
obviating the need for dipping before use.
The respirator was adjusted over the mouth and nose, the cotton
waste being molded to the shape of the face and the upper edge of
the veiling pulled up so as to protect the eyes. These respirators
were used in the attacks of May 10th and 12th, 1915 and were
reasonably efficient against the low concentration of chlorine then
used; they were difficult to fit exactly to the face, which resulted in
leakage. The cotton waste often became lumpy and had to be
shredded out or discarded.
The Hypo Helmet. The next development of the British
protection was the so-called Hypo helmet. This is said to have
resulted from the suggestion of a Canadian sergeant that he had
seen a German pulling a bag over his head during a gas attack. It
consisted of a flannel bag soaked in the same solution as was used
for the veiling respirator and was fitted with a pane of mica as a
window. The helmet was tucked down inside the jacket which was
then buttoned up tightly around the neck. As may be seen from
Figure 43, this would not prove very satisfactory with the American
type of uniform.
This helmet had many advantages over the veiling respirator but
the window often became cracked or broken from the rough
treatment in the trenches. Later the mica was replaced by celluloid
and still later by glass eyepieces set in metal rings. These were very
effective against chlorine in the field.
The P and PH Helmets. During the summer of 1915 it became
evident that phosgene-chlorine mixtures would be used in gas
attacks and it was therefore necessary to provide protection against
this. The hypo helmet, which offered no protection against
phosgene, was soaked in an alkaline solution of sodium phenolate
(carbolic acid) containing glycerine, and with this new form of
impregnation was called the P helmet. It protected against 300 parts
of phosgene in a million of air. Since this solution attacks flannel, two
layers of flannelette were used. The helmet was further improved by
the addition of an expiratory valve, partly to prevent the man from
breathing any of his own breath over again and partly to prevent the
deterioration of the alkali of the mask by the carbon dioxide of the
expired air.
The protection was later further increased by the addition of
hexamethylenetetramine, and this mask is known as the PH helmet.
This increased the protection to 1,000 p.p.m.
The early types of helmet offered no protection against
lachrymators. For this purpose goggles were used, the later types of
which had glass eyepieces and were fitted around the eyes by
means of rubber sponge. While intended for use only after a
lachrymatory bombardment, the troops frequently used them during
and after an ordinary gas attack when the mask should have been
worn. Consequently they were withdrawn.
The PH helmet was unsatisfactory because of the following
reasons:
French Masks
M-2 Mask. The early protection of the French Army was obtained
from a mask of the type M-2 (Fig. 46).
This mask consists of a number of layers of muslin impregnated
with various absorbent chemicals. A typical mask was made up of 20
layers of cheesecloth impregnated with Greasene and 20 layers
impregnated with Complexene. These solutions were made up as
follows:
Complexene: 39.0 lbs. Hexamethylenetetramine
37.5 lbs. Glycerine
Nickel sulfate (NiSO₄·7
27.5 lbs.
H₂O)
Sodium carbonate
11.8 lbs.
(Na₂CO₃)
Water
Greasene: 107.0 Castor oil
lbs.
81.0 lbs. Alcohol (95%)
10.7 lbs. Glycerine (90%)
Sodium hydroxide
3.1 lbs.
(NaOH)
This mask fits the face tightly and as a consequence the inhaled
air can be obtained only by drawing it through the pores of the
impregnated fabric. There is no outlet valve. The exhaled air makes
its escape through the fabric. The eyepieces are made of a special
non-dimming celluloid. The mask is protected from rain by a flap of
weather proof fabric, which also protects the absorbent chemicals
from deterioration.
At the beginning of the war the United States experimented
considerably with the French mask. Several modifications of the
impregnating solutions were suggested, as well as methods of
application. One of these was to separate the components of the
complexene solution and impregnate two separate layers of cloth;
this would make a three-layer mask. In view of the phosgene which
was in use at that time, the following arrangement was suggested:
20 layers of hexamethylenetetramine,
10 layers of nickel sulfate-sodium carbonate,
10 layers of greasene.