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SAFETY DATA SHEET

SFE-450 PART A

Section 1. Product and Company Identification

Product Name: SFE-450 Part A


Supplier: CSNRI | 621 Lockhaven Drive. Houston, TX 77073 | +1 281.590.8491
Emergency Phone Number: 800.424.9300 (CHEMTREC)
+1 703.741.5970 (Outside the US)
Product Description: Epoxy resin
Product Use: Intended to repair pipes

Section 2. Hazards Identification

Classification of the substance or mixture


Acute toxicity / oral – Category 4
Acute toxicity / dermal – Category 4
Skin Sensitization – Category 1
Germ cell mutagenicity – Category 2
STOT-RE – Category 2
Aquatic hazard (Chronic) – Category 2

Hazard Pictograms:

Signal word: Warning


Hazard statements:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs (gastrointestinal)
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P273 Avoid release to the environment.
P301 + P312 IF SWALLOWED: Call a Poison Center / doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Other Hazards: None known.

Section 3. Composition/Information on Ingredients

Mixture:

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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SAFETY DATA SHEET

SFE-450 PART A

Chemical Name CAS No. % by Weight


Oxiranemethanamine, N,N'-(methylenedi-4,1-
28768-32-3 30 - 60
phenylene)bis[N-(oxiranylmethyl)-
Oxiranemethanamine, N-(4-(oxiranylmethoxy)phenyl)-N-
5026-74-4 30 - 60
(oxiranylmethyl)-

Section 4. First Aid Measures

First Aid Measures for Accidental:


Inhalation: Remove source of exposure or move to fresh air.
Skin contact: Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. If
skin irritation or a rash occurs, get medical advice/attention.
Eye contact: Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding
the eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion: Do not induce vomiting; immediately call for medical help.
First-aid comments: Some of the first-aid procedures recommended here require advanced first-aid training.
Most important symptoms and effects, both acute and delayed: None known

Section 5. Fire-fighting Measures

Suitable extinguishing media: CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use firefighting measures that suit the environment.
Unsuitable extinguishing media: None known.
Special protective equipment and precautions for fire-fighters: Fire-fighters should wear appropriate
protective equipment and self-contained breathing apparatus (SCBA). A full body encapsulating chemical
protective suit with positive pressure SCBA may be necessary.
Specific hazards arising from the chemical: Heating increases the release of toxic vapor.

Section 6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures


Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use
the Personal protective equipment recommended in Section 8 of this safety data sheet.
Environmental precautions: If the spill is inside a building, prevent product from entering drains, ventilation
systems and confined areas.
Methods and materials for containment and cleaning up: Contain and soak up spill with absorbent that does
not react with spilled product. Dike spilled product to prevent runoff.
Other information: Report spills to local health, safety and environmental authorities, as required.

Section 7. Handling and Storage

Precautions for safe handling: Only use where there is adequate ventilation. Wear personal protective
equipment to avoid direct contact with this chemical. Keep containers tightly closed when not in use or empty.
Conditions for safe storage: Store in an area that is: well-ventilated. Empty containers may contain hazardous
residue. Store separately. Keep closed. Follow all precautions given on this safety data sheet.

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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SAFETY DATA SHEET

SFE-450 PART A

Section 8. Exposure Controls/Personal Protection

Exposure Limits: No exposure limit noted for the ingredients.


Appropriate Engineering Controls: Use a local exhaust ventilation and enclosure, if necessary, to control
amount in the air.
Personal Protective Equipment:
Respiratory protection: Wear a NIOSH approved air-purifying respirator with an organic vapor cartridge if using
in an unventilated area.
Eye protection: Wear chemical safety goggles.
Skin protection: Wear chemical protective clothing e.g. gloves, aprons, boots.

Section 9. Physical and Chemical Properties

Physical Appearance: Clear light-yellow liquid


Odor: Faint
pH: Neutral
Flash Point: ~ 228 ºC (442 ºF) Method: Closed cup
Melting Point Range: No data available
Boiling point: No data available
Evaporation rate (ether=1): No data available
Flammability (solid, gas): No data available
Specific Gravity: No data available
Viscosity: No data available
Water Solubility: Practically insoluble in water
Solubility in other solvents: No data available
Vapor Pressure: No data available
Vapor density (Air=1) No data available
Relative Density: ~ 1.2
Partition coefficient (n-octanol/water): No data available
Auto-ignition Temperature: No data available
Decomposition Temperature: No data available
Explosive Properties: No information available
Oxidizing Properties: No information available
VOC Content (%): No information available
Flammability Limits in Air: No data available

Section 10. Stability and Reactivity

Reactivity: Not reactive under normal conditions of use.


Chemical stability: Normally stable.
Possibility of hazardous reactions: Reacts with acids, alkalis and oxidizing agents; reacts with amines.
Conditions to avoid: Prolonged exposure to high temperatures. Temperatures above 60.0 ºC (140.0 ºF)
Incompatible materials: Polymerizes on contact with: amines (e.g. triethylamine), strong acids (e.g.
hydrochloric acid), strong bases (e.g.sodium hydroxide), strong oxidizing agents (e.g. perchloric acid). Not
corrosive to metals.
Hazardous decomposition products: Carbon monoxide and carbon dioxide.

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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SAFETY DATA SHEET

SFE-450 PART A

Section 11. Toxicological Information

Likely Routes of Exposure: Skin absorption; eye contact.


Acute Toxicity:
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Oxiranemethanamine, N,N'-(methylenedi-4, 1- - > 10000 mg/kg (rat) -
phenylene)bis [N-(oxiranylmethyl)-
Oxiranemethanamine,N-(4-(oxiranylmethoxy) - ~ 1037 mg/kg (rat) > 4000 mg/kg (rat)
phenyl)-N-(oxiranylmethyl)-

Skin corrosion/irritation: Human experience and animal tests show mild irritation.
Serious eye damage/irritation: There is limited evidence of mild irritation.
STOT (Specific Target Organ Toxicity) - single exposure:
Inhalation: Reactive airways dysfunction syndrome (RADS).
Skin absorption: Symptoms may include redness, rash, swelling and itching.
Ingestion: Irritation of the mouth, throat and stomach.
Aspiration hazard: Symptoms may include coughing, choking, shortness of breath, difficult or rapid breathing,
and wheezing.
STOT (Specific Target Organ Toxicity) – repeated exposure
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Respiratory and/or skin sensitization: Respiratory sensitizer. Skin sensitizer. In sensitized people, exposure
to a very small amount of product can cause symptoms including wheezing, difficult breathing, sneezing and
runny or blocked nose. Can cause death. Symptoms can develop immediately following exposure or hours later.
Repeated exposure will make the reaction worse.
Carcinogenicity: Not known to cause cancer.
Reproductive Toxicity:
Development of offspring: Not known to harm the unborn child.
Sexual Function and fertility: Not known to cause effects on sexual function or fertility.
Effects on or via lactation: Not known to cause effects on or via lactation.
Germ cell mutagenicity: Causes mutagenicity in in vitro tests.
Interactive effects: No information was located.

Section 12. Ecological Information

Ecotoxicity Effects: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Not readily biodegradable. This product shows a low bioaccumulation potential.

Acute aquatic toxicity:


Chemical Name LC50 Fish ErC50 Algae
Oxiranemethanamine, N,N'-(methylenedi-4,1- ~ 7 mg/L (96-hour) -
phenylene)bis[N-(oxiranylmethyl)-
Oxiranemethanamine, N-(4-(oxiranylmethoxy) ~ 4.2 mg/L (96-hour) ~ 13 mg/L (72-hour)
phenyl)-N-(oxiranylmethyl)

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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SAFETY DATA SHEET

SFE-450 PART A

Chronic aquatic toxicity:


Chemical Name NOEC Fish EC50 Fish NOEC Crustacea EC50 Crustacea
Oxiranemethanamine, - - ~ .42 mg/L (21-day) -
N-(4-(oxiranylmethoxy)
phenyl)-N-(oxiranylmethyl)

Persistence and degradability: No ingredient of this product or its degradation products is known to be highly
persistent.
Mobility in soil: No information was located.
Other adverse effects: There is no information available.

Section 13. Disposal Considerations

Waste treatment methods: Bury in a licensed landfill or burn in an approved incinerator according to federal,
provincial/state, and local regulations.
Uncleaned packaging: Empty containers should be taken to an approved waste handling site for recycling or
disposal. Dispose of in accordance to all local, state, national and/or international legislation/regulations.

Section 14. Transport Information

Canadian TDG
Proper Shipping Name: Not Regulated

U.S. DOT
Proper Shipping Name: Not Regulated

IMO (Marine)
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s.( Oxiranemethanamine, N,N'-
(methylenedi-4,1-phenylene)bis[N-(oxiranylmethyl))
UN-Number: UN3082
Hazard Class: 9
Packing Group: III

IATA (Air)
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s.( Oxiranemethanamine, N,N'-
(methylenedi-4,1-phenylene)bis[N-(oxiranylmethyl))
UN-Number: UN3082
Hazard Class: 9
Packing Group: III

Environmental hazards: Marine Pollutant


Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable

Section 15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture:

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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SAFETY DATA SHEET

SFE-450 PART A

Canada
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All ingredients are listed on the
DSL or are not required to be listed.

USA
Toxic Substances Control Act (TSCA) Section 8(b): All ingredients are listed on the TSCA Inventory.

Section 16. Other Information

NFPA hazard ratings:


Health hazard: 2 Flammability: 1 Instability: 0

Key Legend Information:


N/A – Not Applicable
ND – Not Determined
OSHA – Occupational Safety and Health Administration
NIOSH – National Institute for Occupational Safety and Health

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies.
Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic
properties of combustion or decomposition products that are known to be generated in significant quantities.

The information contained herein is based on the data available to us and is believed to be accurate. The data is offered in good
faith as typical values and not as product specification. The information in this data sheet was compiled from information
supplied by the vendors of the components of this compound. CSNRI makes no warranty either expressed or implied regarding
the accuracy of these data or the results to be obtained from the use thereof. The recommended industrial hygiene and safe
handling procedures are believed to be genuinely applicable. However, each user should review these recommendations in the
specific context of the intended use and determine whether they are appropriate. CSNRI assumes no responsibility for injury
from the use of the product described herein. The information is intended only to assist in the safe handling of this material.
CSNRI DISCLAIMS ALL EXPRESS AND IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE, OR FREEDOM FROM PATENT INFRINGEMENT. CSNRI WILL NOT BE LIABLE FOR ANY
SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.

Date of issue: 08/08/2011 Revision date: 08/31/2021 Supersedes: 12/17//2019 Version: 4.0

CSNRI 621 Lockhaven Drive, Houston, Texas 77073 Phone +1 281.590.8491 cs-nri.com
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