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Fiitjee: All India Test Series
Fiitjee: All India Test Series
Section – A
1. B, C
Q t /RC 3Q/2 3Q/2 B R A
Sol. Q t
2
e C
Q t /RC –Q/2 +Q/2
lt e (from B to A)
2RC
2
Q / 2 Q2
Total heat dissipated =
2C 8C
2. A, D
2
Dx 9
Sol.
D x 1
Dx
3
Dx
D x 3D 3x
4x = 2D
D 120
x 60 cm
2 2
x = 60 cm
D2 x 2 (120 120) (60 60)
Now, f
4D 4 120
f = 22.5 cm
3. B, C
Sol. The two springs have different spring constants. Also energy remains conserved during the
motion as no friction is present.
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 2
4. B, D
Sol. From equation, PV = nRT 2 B P = KV
2
VC VS
V
5. A
Sol. Fcos mg
mv 2 F v
F sin
R
2
2 mv 2 mg
F mg
R
F 2 N.
6. B, D
Sol. Case I:
Since there is no relative motion,
F F F 8
a 1 f f F1 max Ff
5 3 3
Case II:
F F Ff 8
a f 2 F2 max Ff
5 3 5
F1max 5
Clearly, F1(max F2max and .
F2 max 3
7. D
v 332
Sol. 0.332m.
n 1000
8. C
Sol. The apparent frequency for reflecting surface as observer is
332 64
n 1000 1320 Hz
332 32
9. C
10. B
Sol. (for Q. 9 to 10):
The maximum acceleration with which the blocks can move together without slipping
mg 0.3 1 10 2
amax 0.5 m/s
3M 32
Fmax 2(M m)amax 6 0.5 3 N
The friction force between the front blocks,
FS = (M + 2m) amax = 4 0.5 = 2 N
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3 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
Section – B
11. 4
2
Sol. a + R = A cos t …(i)
f = ma …(ii)
1
fR = mR2 …(iii)
2 a
f + 2f = mA2 cos t
1
f mA2 cos t f
3
1 1
(max) mA2R 6 2 1 4 N-m
3 3
12. 20
2 m1F2 m2F1 2 2 27 4 9 2 90
Sol. max 150 6 0.20 m 20 cm
k m1 m2 150 24
13. 3
m 3r 3mv 2 F
Sol. F 2 =
2 8 16r
Section – C
14. 03.40
15. 04.74
Sol. (for Q. 14 to 15): y
Using conservation of momentum
P = P2 cos …(i) P1
P1 = P2 sin …(ii) P
Squaring and adding, we get x
P2 P12 P22
2mk + 2m1k1 = 2m2K2 P2
4k + k1 = 10k2
10k2 k1 = 4k
10k2 k1 = 44. …(iii)
Also, k1 + k2 = k |Q|
k1 + k2 = 11. 2.86
k1 + k2 = 8.14 …(iv)
Adding (iii) and (iv), we get
11k2 = 52.14
k2 = 4.74 MeV
k1 = 8.14 4.74
k1 = 3.40 MeV
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 4
16. 03.00
17. 01.00
Sol. (for Q. 16 to 17):
3a
4TaB 3TaA = 0 aB M=3
4
3a a
2TaB TaA TaP = 0 aP 2aB aA a
2 2
a
aP K=1
2
18. 180.00
19. 02.00
Sol. (for Q. 18 to 19):
At the instant shown both particles are at their mean positions and moving in opposite direction.
Phase difference = 180
As is same for both the particles
GM
the phase difference will be maintained throughout and they can never meet.
R3
vmax A For a particle undergoing S.H.M
v1 R 2
So,
v2 R / 2 1
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5 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
Chemistry PART – II
Section – A
20. B, C
Sol. The V.D. and molar mass of the emergent gas will always be greater than that of pure gas.
In case of CH3 OH molar mass 32 g mol1 and acetone (molar mass 58 g mol1 )
Molar mass of N2 being 28 g mol1
Molar mass of H2 O being 18 g mol1 .
Molar mass of D2 O being 20 g mol1 .
21. B
Sol. HO
HO
NaOH
O 2N N2
Fa int ly basic medium
O 2N N N
22. A, B, C
Sol. (A) Below critical micelle concentration soap behaves like normal electrolyte; no micillisation
of the anions.
(B) In water-in-oil emulsion, oil forms external (continuous) phase.
(C) SnO2 2NaOH Na2 SnO3 H2 O
(D) Cations will be effective in coagulation of negatively charged sol formed in option (C).
23. A, B, D
Sol. 1. S(entropy) is not the measure of available energy.
2. S between the two states is not path dependent whether reversible or irreversible
S S2 S1 .
3. Heat supplied into the isothermal reversible expansion of ideal gas is equal to work of
expansion of the gas.
4. G is equal to the available energy of the system to do useful work.
24. A, B, C, D
Sol. 1. Ethers have much lower boiling point than alcohol of similar molecular mass, alcohols
undergo molecular association through intermolecular hydrogen bonding.
2. Intramolecular hydrogen bonding makes ortho-isomer weaker acid than para-isomer.
3.
At lower temperature 20o C , the reaction between phenol and conc. H2 SO 4 is
kinetically controlled and product composition depends on relative rate of formation.
4. Owing to intramolecular H-bonding in ortho-nitrophenol, its boiling point is less than that
of p-nitrophenol (molecular association due to inter molecular H-bonding).
25. A, B, C
Sol. Brass – Cu + Zn
Bell metal – Cu + Sn
Nickeloy – Al + Cu + Ni
Magnalium – Al + Mg + Ni
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 6
26. D
27. B
Sol. (for Q. 26 and 27):
O
3
1 O
2 Zn H O
2
CHO
X
OH N2 H4 /
O
O O N N
,
CHO ,
CHO CHO
E
F G Z
Possible enolates Cyclic hydrazene
CHO
Aldol
E
Aldol
F
OH
O
Aldol
G
28. B
29. D
Sol. (for Q. 28 and 29):
Sulphur excess of HCl
ZnO X
ZnS P H2 S R ZnCl2 S
Philosopher 's wool White substance Foul smell gas Solution
SO2 Q Aq. NaOH
Zn OH2 T
white ppt.
Excess of NaOH
Na2 ZnO 2
Sol. 28. (A) ZnO – is an amphoteric oxide.
(B) ZnO is white powder which on heating turns yellow but again on cooling becomes white.
(C) Lithopone is mixture of ZnS BaSO4
(D) ZnO CoO CoZnO2 or CoO.ZnO
Rinmann's green
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7 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
Sol. 29. 3
AgNO
Ag2 S
Black
KMnO 4 Acidic
H2 S K 2 SO 4 MnSO 4 S H2 O
3 CH
2
COO Pb
PbS
Black
3 CH
2
COO Cd
CdS
Yellow
Section – B
30. 16
Sol. O O
3 3 5 0 0 5
N H4 N O2 O S S S S O have difference of oxidation states
O O greater than 2.
Total compounds 4 P
2
S
3 5
N H4 N O3 6
O S O
O
NH4 NO3 N2 O 2H2 O
5
2NaNO3
Na2 O N2 O2 No NO2 g evolved
2
5
2KNO3 K 2 O N2 O2
2
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 8
Section – C
33. 00.10
34. 04.00
Sol. (for Q. 33 and 34):
1 2
Partial pressure of X2 before reaction pX2 0.4 atm
23
23
Partial pressure of Y2 before reaction pY2 1.2 atm
23
0.6
Atm of X2 g and Y2 g each reacted 0.3 atm
2
pX2 at equilibrium 0.4 0.3 0.1 atm
pY2 at equilibrium 1.2 0.3 0.9 atm
2
2
pXY 0.6
Kp KC 4.0
pX2 pY2 0.1 0.9
35. 02.00
36. 11.00
Sol. (for Q. 35 and 36):
2.0 0.05 3.0 2 0.05
CN in the resulting solution
23
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9 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
0.4
0.08 M
5
K W H OH 2 10 7 2 107
4.0 10 14 M2
CN H2 O HCN OH K b 2 104
14
KW 4 10
K a of HCN 2 1010
Kb 2 104
KW 4 1014
‘X’ – Hydrolysis constant K H of CN 10
2.0 104
Ka 2 10
1
‘Y’ – pH =
2
pK W pK a log C
1
log 4 10 14 log 2 10 10 log 0.08
2
1 3
14 2log 2 10 log 2 log 2 102
2
1
24 3 log 2 2 3 log 2
2
= 11
37. 01.05
38. 03.43
(3.42 – 3.43)
Sol. (for Q. 37 and 38):
Let Po be initial partial pressure of NO.
2Po be initial partial pressure of NO2.
2NO2 N2 O 4 K P1 6.8 atm 1
2Po 3.4 P 1.7
NO NO 2 N2 O3
o o
P P 2P 3.4 P P
1.7
K P for 1st equilibrium 6.8 2
2P o
3.4 P
or, 2Po 3.4 P 0.5
or, 2Po P 3.9 …. (1)
Also, total pressure (at equilibrium) PNO2 PN2 O4 PNO PN2O3
5.05 0.5 1.7 Po P P
Po 2.85 atm
Now from Equation (1) 2Po P 3.9
2 2.85 P 3.9 P 1.8 atm
Equilibrium pressure of NO Po P 2.85 1.80 = 1.05 atm.
PN2O3 1.8
K P2 3.42 atm 1 .
PNO PNO2 1.05
0.5
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AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22 10
Section – A
39. A, D
Sol. a 666, a a 0
aB aC aD
40. A, B, C
2 2 2
Sol. C:x +y =b
S : x + y = a where a2 = 2b2
2 2 2
41. A, B, C, D
Sol. if k = 0 P = 0 and if k = r P = 2022!
42. A, C
4
Sol. Area of R = 6
2/3
2 2
Equation of R : x + 2y + (2 + )z – 30 – 15 = 0 where = –4
3 2
4 9
Equation of R: x + 2y – 2z + 30 = 0
43. A, C, D
Sol. ai represent vertices of a regular octagon so
8 8
ai a j 0 ; ai a j 4
i j j1 1 i j 8
8 8
ai a j 0 ;
i j j1
a a
1 i j 8
i j 4
2 1
44. A, C
Sol. P(t) is clearly continuous t but non-differentiable whenever the person turns
1 9 4
limP t 1
t 9 16 5
1
16
45. D
Sol. Make cases based on denominator
46. A
20
Sol. Probability is
255
47. B
Sol. a = 50, b = 25, c = 50
48. D
Sol. None of the functions are periodic as local extrema keeps on decreasing after every 4 seconds
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11 AITS-FT-X (Paper-2)-PCM(Sol.)-JEE(Advanced)/22
Section – B
49. 4
Sol. 2c sin(A – B) cos(A + B) = b sin B – a sin A
c[sin 2A – sin 2B] = b sin B – a sin A
2 c sin A cos A + a sin A = b sin B + 2c sin B cos B
1 1
c cos A a b c cosB
2 2 1 5 3
cosC 5 sinC
sinB sin A 2 2
50. 6
3 3 3
Sol. () = and + = + = 0, 1, –1
3
If = 0 ( + ) = + = = 0, 1 –1
2 2
Corresponding equation are x = 0 ; x x = 0
3
If = 1 ( + ) = 4( + ) + = 0, 2, –2
Corresponding equation are x2 2x + 1 = 0
3
If = –1 ( + ) + 2( + ) = 0 + = 0
Corresponding equation is x2 – 1 = 0
51. 8
2
x 2 y 2 4 4xy 2y 2 2xy 2 4y xy 2 2y 2 2y xy 2 xy 2 2y
Sol. = = 2 2 2 2
xy 2 2y y xy 2 y xy 2
Section – C
52. 01.57
/ 2
2ln sec y 1 1
/2
2lnsec y 1 2ln cosec y 1
Sol. Let ex – 1 = tan2 y I1 dy = dy
0
ln tan y 2 0 ln tan y
/2
1 2ln tan y
= dy
2 0 ln tan y 2
53. 00.00
Sol. Let x = 2 + y I2
2
ln 2 y
dy
2
ln 4 y 2 dy
2 4y 2
0 4y 2
Also, let x = 4 – t2 I2 2
2
ln 4 t 2
dt I 2
I2 = 0
0 4t 2 2
54. 01.41
kz2 1 k z 3
Sol. zi equals 1, -1, i ; a = min. of z1 = 2
k 1 k
55. 02.67
i 8
Sol. z b
3 3
56. 01.41
57. 03.16
Sol. (for Q. 56 to 57):
PA 5 ; PB 2 ; PC 10
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